CN105862478A - Resist printing process of cellulosic fiber knitted fabric - Google Patents
Resist printing process of cellulosic fiber knitted fabric Download PDFInfo
- Publication number
- CN105862478A CN105862478A CN201610258121.5A CN201610258121A CN105862478A CN 105862478 A CN105862478 A CN 105862478A CN 201610258121 A CN201610258121 A CN 201610258121A CN 105862478 A CN105862478 A CN 105862478A
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- agent
- fiber knitted
- resist
- cellulose fiber
- printing technique
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/12—Reserving parts of the material before dyeing or printing ; Locally decreasing dye affinity by chemical means
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/008—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated using reactive dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/82—Textiles which contain different kinds of fibres
- D06P3/8204—Textiles which contain different kinds of fibres fibres of different chemical nature
- D06P3/8219—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and amide groups
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Abstract
The invention discloses a resist printing process of a cellulosic fiber knitted fabric. The resist printing process of the cellulosic fiber knitted fabric comprises the steps of firstly performing printing by using resist slurry on the cellulosic fiber knitted fabric, performing drying and then performing dyeing by using active dyestuff. The resist slurry is prepared by using the following components in percent by weight: 10 to 30 percent of self-made resist agent, 4.2 to 5.6 percent of thickener, 1 to 3 percent of penetrating agent, 0.1 to 1 percent of defoaming agent and balance of water. The self-made resist agent is prepared by using the following components in percent by weight: 10 to 20 percent of discharging agent, 20 to 40 percent of fluoride-free waterproof agent, 10 to 20 percent of binder and 20 to 60 percent of water. As compared with conventional active dyestuff resist agents such as rongalite and stannous chloride, the self-made resist agent disclosed by the invention can obtain an excellent anti-whitening effect, and the front and back surfaces of the cellulosic fiber knitted fabric have colors.
Description
Technical field
The invention belongs to technical field of textile printing, be specifically related to a kind of cellulose fiber knitted thing resisting printing technique.
Background technology
Resisting printing is to carry out stamp textile dyeing (or not yet colour developing or dyeing after not yet fixation) is front, containing stoping the resist agent contaminating (or colour developing, fixation) on ground colour dyestuff in printing paste, after stamp, then in staining machine, carry out dye (or colour developing, fixation).Because having resist agent at stamp and ground colour dyestuff can not go up dye (or colour developing, fixation), thus still keep at stamp pure white in vain, here it is anti-white resisting printing (being called for short anti-white).If meanwhile, printing paste adds the another kind of dyestuff that can not be destroyed by resist agent, post-treated stained with fiber, then the available pattern not covered dye by ground colour, here it is colored resist printing (being called for short color to prevent).Resisting printing technique can be used for cellulose fibre, silk fiber and synthetic fabrics, and the resisting printing with cellulose base fiber fabric is the most commonly used.
Conventional reactive dye resist agent uses the reducing substances such as rongalite, stannous chloride mostly, make reactive dye when running into these reducing substanceses owing to chromophoric group is destroyed not color development, thus reaches the purpose of resist printing.But when exhaust dyeing, owing to dyeing time is long, reactive dye contaminate on the flower pattern part being printed on above-mentioned resist agent is the easiest, and simply the degree of depth is shallower, does not reaches preferable resist printing effect.
It addition, the cellulose fibre resisting printing of routine is substantially employing circle/PLATE SCREAM PRINTING mode, due to the restriction that mesh is thick and starching amount is big, the fineness of circle/PLATE SCREAM PRINTING mode flower pattern is extremely difficult to.
Summary of the invention
It is an object of the invention to solve the problems referred to above, it is provided that a kind of cellulose fiber knitted thing resisting printing technique.
The technical scheme realizing the object of the invention is: a kind of cellulose fiber knitted thing resisting printing technique, is included on cellulose fiber knitted thing and first uses reactive dyeing again after resist printing serosity stamp and drying.
In order to obtain the anti-white effect of excellence, above-mentioned resist printing serosity is made up of the component of following weight percentage ratio: self-control resist agent 10%~30%, thickener 4.2%~5.6%, penetrating agent 1%~3%, defoamer 0.1%~1%, remaining is water.
Above-mentioned self-control resist agent is made up of the component of following weight percentage ratio: discharging agent 10%~20%, without fluoro water proofing agent 20%~40%, binding agent 10%~20% and water 20%~60%.
Above-mentioned discharging agent is sulfenic acids derivant.
Above-mentioned is Phobol RSH without fluoro water proofing agent.
Above-mentioned binding agent is Polyethylene Glycol, sodium polyacrylate, xanthan gum etc..
Above-mentioned thickener is guar gum or modified guar gum, and described modified guar gum is hydroxypropylguar.
Above-mentioned penetrating agent is the conventional anion-permeable membrane agent of printing and dyeing, such as dodecyl sodium sulfate, dodecylbenzene sodium sulfonate, fast penetrant T, alkali-resistant penetrant OEP-70, alkali-resistant penetrant AEP etc..
Above-mentioned defoamer is non-silicon defoaming agent, such as non-silicon defoaming agent H-2300 or non-silicon defoaming agent H-2900.
In order to obtain preferable flower pattern fineness, above-mentioned stamp uses intaglio printing mode.
Above-mentioned reactive dye are can anti-reactive dye.
Above-mentioned cellulose fibre is the conventional cellulose fiber such as cotton fiber, artificial cotton fiber, flaxen fiber.
The good effect that the present invention has: (1) present invention uses sulfenic acids derivant and makes resist agent without fluoro water proofing agent, this resist agent is obtained in that the anti-white effect of excellence compared to the reactive dye resist agent of the routine such as rongalite, stannous chloride, and the positive and negative of cellulose fiber knitted thing all has color.(2) present invention uses the mode of intaglio printing to carry out stamp, can be accurately controlled starching amount such that it is able to obtain the preferable flower pattern of fineness, especially for hachure flower pattern.
Accompanying drawing explanation
Fig. 1 is cotton/spandex (95/5) twill after embodiment 1 resisting printing.
Fig. 2 is cotton/spandex (95/5) twill after embodiment 2 resisting printing.
Detailed description of the invention
(embodiment 1)
The present embodiment is the resisting printing technique of cotton/spandex (95/5) twill, specific as follows:
1. 15g sulfenic acids derivant, 30g are configured to resist agent without fluoro water proofing agent Phobol RSH, 15g polyethylene glycol binder and 40g water.
Take the above-mentioned homemade resist agent of 20g and be configured to resist printing serosity with 5g hydroxypropylguar thickener, 2g anion-permeable membrane agent dodecylbenzene sodium sulfonate, 0.5g non-silicon defoaming agent H-2300 and 72.5g water.
2. use the mode of intaglio printing to be printed on cotton/spandex (95/5) twill by step resist printing serosity 1., and dry.It is carved with Scotland lattice flower pattern on the intaglio plate used.
3. cotton/spandex (95/5) twill after step 2. stamp can be dyeed by anti-reactive dye according to reactive dye conventional dyeing process, employing black in overflow cylinder, after dyeing terminates, the finished product carrying out routine arranges, finally giving colour combination and knit the stamp finished product of effect black white background Scotland lattice flower pattern, result is shown in Fig. 1.
(embodiment 2)
The present embodiment is substantially the same manner as Example 1, and difference is:
Being carved with cowboy's flower pattern on the step 2. middle intaglio plate used, step is 3. middle uses indigo to dye by anti-reactive dye, finally gives the stamp finished product of imitative cowboy's effect flower pattern, and result is shown in Fig. 2.
Claims (10)
1. a cellulose fiber knitted thing resisting printing technique, is included on cellulose fiber knitted thing and first uses reactive dyeing again after resist printing serosity stamp and drying;It is characterized in that:
Described resist printing serosity is made up of the component of following weight percentage ratio: self-control resist agent 10%~30%, thickener 4.2%~5.6%, penetrating agent 1%~3%, defoamer 0.1%~1%, remaining is water;
Described self-control resist agent is made up of the component of following weight percentage ratio: discharging agent 10%~20%, without fluoro water proofing agent 20%~40%, binding agent 10%~20% and water 20%~60%.
Cellulose fiber knitted thing resisting printing technique the most according to claim 1, it is characterised in that: described discharging agent is sulfenic acids derivant.
Cellulose fiber knitted thing resisting printing technique the most according to claim 1, it is characterised in that: described is Phobol RSH without fluoro water proofing agent.
Cellulose fiber knitted thing resisting printing technique the most according to claim 1, it is characterised in that: described binding agent is Polyethylene Glycol, sodium polyacrylate or xanthan gum.
Cellulose fiber knitted thing resisting printing technique the most according to claim 1, it is characterised in that: described thickener is modified guar gum.
Cellulose fiber knitted thing resisting printing technique the most according to claim 1, it is characterised in that: described penetrating agent is anion-permeable membrane agent.
Cellulose fiber knitted thing resisting printing technique the most according to claim 1, it is characterised in that: described defoamer is non-silicon defoaming agent.
Cellulose fiber knitted thing resisting printing technique the most according to claim 1, it is characterised in that: described reactive dye are can anti-reactive dye.
Cellulose fiber knitted thing resisting printing technique the most according to claim 1, it is characterised in that: described cellulose fibre is cotton fiber, artificial cotton fiber or flaxen fiber.
10. according to the cellulose fiber knitted thing resisting printing technique one of claim 1 to 9 Suo Shu, it is characterised in that: described stamp uses intaglio printing mode.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610258121.5A CN105862478B (en) | 2016-04-22 | 2016-04-22 | Cellulose fiber knitted object resisting printing technique |
PCT/CN2016/106387 WO2017181667A1 (en) | 2016-04-22 | 2016-11-18 | Resist printing technique for cellulosic knitted good |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN201610258121.5A CN105862478B (en) | 2016-04-22 | 2016-04-22 | Cellulose fiber knitted object resisting printing technique |
Publications (2)
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CN105862478A true CN105862478A (en) | 2016-08-17 |
CN105862478B CN105862478B (en) | 2018-10-26 |
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CN201610258121.5A Active CN105862478B (en) | 2016-04-22 | 2016-04-22 | Cellulose fiber knitted object resisting printing technique |
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WO (1) | WO2017181667A1 (en) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106283739A (en) * | 2016-08-29 | 2017-01-04 | 盛虹集团有限公司 | Poly terephthalic acid 1,3 propylene glycol ester fabric free steam cleaning printing technique thickener |
WO2017181667A1 (en) * | 2016-04-22 | 2017-10-26 | 黄庄芳容 | Resist printing technique for cellulosic knitted good |
CN108385417A (en) * | 2018-02-26 | 2018-08-10 | 杭州小橙工业设计有限公司 | A kind of resist printing preparation process thereof implementation system |
CN109440496A (en) * | 2018-10-31 | 2019-03-08 | 山东华晨彩装科技有限公司 | A kind of white resist printing method for active emerald green orchid 21 |
CN109629262A (en) * | 2018-12-07 | 2019-04-16 | 广州市佐力新材料科技有限公司 | It is a kind of directly to paste dye cream and preparation method thereof |
CN110678601A (en) * | 2017-05-24 | 2020-01-10 | 仓敷纺绩株式会社 | Fiber assembly containing cellulose water-proof fiber, method for producing same, and fiber product |
CN111793993A (en) * | 2020-07-07 | 2020-10-20 | 山东黄河三角洲纺织科技研究院有限公司 | Anti-printing process of viscose/lyocell/cotton blended fabric |
CN113550047A (en) * | 2021-08-18 | 2021-10-26 | 浙江美欣达纺织印染科技有限公司 | Indigo-imitated jean fabric and production method thereof |
CN115807348A (en) * | 2022-12-08 | 2023-03-17 | 太仓宝霓实业有限公司 | Active digital printing sizing agent composition for knitted fabric and preparation method thereof |
CN115807348B (en) * | 2022-12-08 | 2024-07-02 | 太仓宝霓实业有限公司 | Reactive digital printing paste composition for knitted fabric and preparation method thereof |
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CN104562747A (en) * | 2013-10-15 | 2015-04-29 | 青岛三秀新科技复合面料有限公司 | Activated dye resist printing technology for cotton fabric |
CN103541219A (en) * | 2013-10-28 | 2014-01-29 | 湖州金塔地纺织厂 | Waterproof processing method for fabric |
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Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2017181667A1 (en) * | 2016-04-22 | 2017-10-26 | 黄庄芳容 | Resist printing technique for cellulosic knitted good |
CN106283739A (en) * | 2016-08-29 | 2017-01-04 | 盛虹集团有限公司 | Poly terephthalic acid 1,3 propylene glycol ester fabric free steam cleaning printing technique thickener |
CN110678601A (en) * | 2017-05-24 | 2020-01-10 | 仓敷纺绩株式会社 | Fiber assembly containing cellulose water-proof fiber, method for producing same, and fiber product |
CN108385417A (en) * | 2018-02-26 | 2018-08-10 | 杭州小橙工业设计有限公司 | A kind of resist printing preparation process thereof implementation system |
CN109440496A (en) * | 2018-10-31 | 2019-03-08 | 山东华晨彩装科技有限公司 | A kind of white resist printing method for active emerald green orchid 21 |
CN109440496B (en) * | 2018-10-31 | 2021-03-30 | 山东华晨彩装科技有限公司 | White printing prevention method for active turquoise blue 21 |
CN109629262A (en) * | 2018-12-07 | 2019-04-16 | 广州市佐力新材料科技有限公司 | It is a kind of directly to paste dye cream and preparation method thereof |
CN111793993A (en) * | 2020-07-07 | 2020-10-20 | 山东黄河三角洲纺织科技研究院有限公司 | Anti-printing process of viscose/lyocell/cotton blended fabric |
CN113550047A (en) * | 2021-08-18 | 2021-10-26 | 浙江美欣达纺织印染科技有限公司 | Indigo-imitated jean fabric and production method thereof |
CN115807348A (en) * | 2022-12-08 | 2023-03-17 | 太仓宝霓实业有限公司 | Active digital printing sizing agent composition for knitted fabric and preparation method thereof |
CN115807348B (en) * | 2022-12-08 | 2024-07-02 | 太仓宝霓实业有限公司 | Reactive digital printing paste composition for knitted fabric and preparation method thereof |
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Publication number | Publication date |
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CN105862478B (en) | 2018-10-26 |
WO2017181667A1 (en) | 2017-10-26 |
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