CN105860738B - A kind of self-luminous road sign gage mark coating and its application - Google Patents
A kind of self-luminous road sign gage mark coating and its application Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D157/00—Coating compositions based on unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D157/02—Copolymers of mineral oil hydrocarbons
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/22—Luminous paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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Abstract
The invention provides a kind of self-luminous road sign gage mark coating, the component of the self-luminous road sign gage mark coating includes in parts by weight：0 30 parts of road mark paint I, 55 96 parts of road mark paints II, and 4 15 parts of self-luminous microballons, wherein, the component of the self-luminous microballon includes in parts by weight：70 95 parts of microballon matrix, 5 30 parts of self-luminescent material, the self-luminescent material are aluminate long afterglow materials.Self-luminous microballon provided by the invention, because self-luminescent material and microballon matrix are integrally formed, there is the advantages of wearability and good weatherability, and luminescent material is scattered in microballon Medium Culture, microballon matrix has good mobility, is easy to construct in various types of identifier marking surfaces.
Description
Technical field
The invention belongs to traffic engineering traffic paint preparing technical field, more particularly to a kind of self-luminous road sign gage mark coating
And its application.
Background technology
In recent years, self-luminous road sign gage mark coating is promoted in fields such as traffic sign, urban beautification, commodity
And application, but existing self-luminous road sign gage mark coating commonly exist pliability and it is wear-resisting, weatherability is poor the shortcomings that, especially
It is the traffic sign for being sprayed at plank or road surface as night traffic warning function, such as discloses one kind in Chinese patent literature
Green environment-friendlymultifunctional multifunctional energy-night-storagenano-grade nano-grade luminescent paint (CN102898880A).Because luminescent material is exposed to sunlight for a long time
Or under the conditions of sleet, luminescent properties are easily lost, and the film on surface is easy to ftracture and come off.It is spontaneous in order to solve
This shortcoming of light road sign gage mark coating, the necessary Self-illumination road for developing pliability, wearability and good weatherability
Road sign will gage mark coating product.
The content of the invention
A kind of therefore, deficiency of the present invention regarding to the issue above, there is provided self-luminous function admirable self-luminous road sign mark
Line coating, containing low cost, it is easy to industrialized production, with the good self-luminous microballon of excellent pliability, wearability and weather resisteant.
Self-luminous road sign gage mark coating provided by the invention, its component include 0-30 part roadmarkings in parts by weight
Coating I, 55-96 part road mark paint II, and 4-15 part self-luminous microballons, wherein, the component of the self-luminous microballon is pressed
Parts by weight include：Microballon matrix 58-135 parts, self-luminescent material 5-30 parts；
The self-luminescent material is aluminate long afterglow materials, and the aluminate long afterglow materials are selected from SrAl2O4:Eu,Dy
And Sr4Al14O25:One kind in Eu, Dy.
Preferably, the road mark paint I includes 5-30 part self-luminescent materials in parts by weight, 15-40 part resins I,
15-18 parts quartz sand, 25-50 parts Paris white, 2-6 parts titanium dioxide, 1-2 parts EVA hot-melt adhesive, 15-18 part glass microballoons；
The one kind of the resin I in C 5 petroleum resin, C 9 petroleum resin, epoxy resin or acrylic resin.
Preferably, the microballon matrix is high molecular polymer, the self-luminous microballon include following parts by weight into
Point：High molecular polymer 70-95 parts, self-luminescent material 5-30 parts, wherein, the high molecular polymer be polyethylene, polypropylene,
Polystyrene, polymethacrylates, the one or more of thermoelastic.
It is highly preferred that the preparation method of the self-luminous microballon be by the high molecular polymer and self-luminescent material press than
Example is well mixed, is then extruded through double screw extruder, pelletizing obtains.
Preferably, the microballon matrix is by 20-50 parts titanium dioxide, 8-40 parts zirconium dioxide and 30-45 part silica
Composition.
It is highly preferred that the self-luminous microballon includes the composition of following parts by weight：30 parts of titanium dioxide, 25-30 parts two
Zirconium oxide, 30-33 parts silica and 5-12 part self-luminescent materials.
It is highly preferred that the preparation method of the self-luminous microballon is：By titanium dioxide, zirconium dioxide, silica and from
Luminescent material after broken, screening, metering, mixes in proportion to form compound, mixed material heating is melted respectively,
To continue to stir in fusion process, sieving, that is, obtain the self-luminous microballon.
Preferably, the road mark paint II is hot-melt traffic coatings, and the component of the road mark paint II is pressed
Parts by weight include：The 15-40 parts of resin II, quartz sand 15-18 parts, Paris white 25-50 parts, titanium dioxide 2-6 parts, EVA hot melts
Glue 1-2 parts, glass microballoon 15-18 parts；
The one kind of the resin II in C 5 petroleum resin, C 9 petroleum resin, epoxy resin or acrylic resin.
Preferably, the road mark paint II includes component A and B component, and the mass ratio of component A and B component is 1-2：
2-1,
The component A includes the composition of following parts by weight：Resin III 30-45 parts, dispersant 0.2-0.6 parts, pigment 15-
35 parts, filler 10-35 parts, ultra-violet absorber 1-3 parts, toughener 1-2.5 parts；
The B component includes the composition of following parts by weight：The 30-45 parts of resin IV, dispersant 0.3-0.5 parts, pigment 25-
45 parts, filler 10-15 parts, ultra-violet absorber 1-3 parts, toughener 1-2.5 parts, curing agent 0.5-5 parts；
The resin III is alkyl acrylate；The resin IV is alkyl methacrylate；The curing agent was
Aoxidize dibenzoyl；The dispersant is unsaturated carboxylic acid polymer；The pigment is rutile titanium white powder, zinc oxide, zinc barium
In vain, at least one of chrome yellow, titan yellow；The filler is at least one of calcium carbonate, barium sulfate, talcum powder, Cab-O-sil；Institute
It is dioctyl phthalate or dibutyl phthalate to state toughener；The ultra-violet absorber is that benzotriazole is purple
Ultraviolet absorbers.
Self-luminous road sign gage mark coating provided by the invention is widely used, and is mainly used in roadmarking, in tunnel
The making of any mark in wall, Bridge guardrail, anti-collision wall, traffic sign label.
The present invention also provides the construction method of the self-luminous road sign gage mark coating, specifically comprises the following steps：
Determine that mark makes region first, then spraying the road mark paint II it is determined that identifying and making region, and
The uniform spreading of self-luminous microballon is applied on the road mark paint II, also can further spraying one layer of roadmarking again
Expect I.
When specifically used, also self-luminous microballon directly can be added into use in bi-component road mark paint.
The chromaticity coordinate of self-luminous road sign gage mark coating, its yellow and white self-luminous road sign gage mark coating exists
Table 1 below is surrounded polygon interior.
Each angle point chromaticity coordinate of the self-luminescent material of table 1
Self-luminous microballon provided by the invention, because self-luminescent material and microballon matrix are integrally formed, have wearability and
The advantages of good weatherability, and self-luminescent material is scattered in microballon, and microballon has good mobility, is easy to construct in various
The highway sign and marking coating surface of type.The self-luminous microballon is applied in highway sign and marking coating, efficiently solved
Traditional road identifier marking, the shortcomings of cost height, wearability, weatherability are poor, and luminescent material is difficult to be well mixed with coating, prepare
Simple with construction technology, cost of material is low, is easy to industrial scale production.
Embodiment
In order that those skilled in the art more fully understand that technical scheme can be practiced, with reference to specific
The invention will be further described for embodiment, but illustrated embodiment is not as a limitation of the invention.
Each composition Jun Ke cities used below to for preparing self-luminous microballon and self-luminous road sign gage mark coating
Field is commercially available.
Embodiment 1
A kind of marking lines self-luminous microballon, by being by quality parts ratio：30 parts of titanium dioxide, 30 parts of zirconium dioxides, 30
Part silica and 10 parts of self-luminescent materials are made.
Self-luminescent material therein using rare earth aluminate long-afterglow material, also referred to as overlength afterglow luminescent powder, its
Irradiated 10 minutes or so under the light sources such as natural light, daylight, light, night or dark place are sustainable luminous more than 12 hours, tool
Body, the self-luminescent material is SrAl2O4:Eu, Dy, spontaneous luminous intensity is high, its luminous angle point chromaticity coordinate for (0.420,
0.540)。
Specific preparation method is as follows：By titanium dioxide, zirconium dioxide, silica and self-luminescent material respectively by broken
After broken, screening, metering, mix in proportion to form compound, compound heats fusing in melting furnaces, will in fusion process
Lasting stirring, ensures that self-luminescent material is dispersed in glass metal, crosses the shaping of 60 mesh number vibratory sieves, that is, obtains of the present invention
Self-luminous microballon.
Embodiment 2
A kind of marking lines self-luminous microballon, by being by quality parts ratio：30 parts of titanium dioxide, 25 parts of zirconium dioxides, 33
Part silica and 12 parts of self-luminescent materials are made.The self-luminescent material is SrAl2O4:Eu, Dy, its luminous angle point chromaticity coordinate
For (0.400,0.530).
Specific preparation method is as follows：By titanium dioxide, zirconium dioxide, silica and self-luminescent material respectively by broken
After broken, screening, metering, mix in proportion to form compound, compound heats fusing in melting furnaces, will in fusion process
Lasting stirring, ensures that self-luminescent material is dispersed in glass metal, crosses the shaping of 80 mesh number vibratory sieves, that is, obtains of the present invention
Self-luminous microballon.
Embodiment 3
A kind of marking lines self-luminous microballon, by being by quality parts ratio：20 parts of titanium dioxide, 8 parts of zirconium dioxides, 30 parts
Silica and 5 parts of self-luminescent materials are made.The self-luminescent material is SrAl2O4:Eu, Dy, its luminous angle point chromaticity coordinate are
(0.450,0.490), specific solution is the same as embodiment 1.
Embodiment 4
A kind of marking lines self-luminous microballon, by being by quality parts ratio：50 parts of titanium dioxide, 40 parts of zirconium dioxides, 45
Part silica and 30 parts of self-luminescent materials are made.The self-luminescent material is SrAl2O4:Eu, Dy, its luminous angle point chromaticity coordinate
For (0.275,0.300), specific preparation method is the same as embodiment 2.
Embodiment 5
A kind of marking lines self-luminous microballon, by being by quality parts ratio：95 parts of polymethacrylates and 5 parts of self-luminous
Material is made.The self-luminescent material is Sr4Al14O25:Eu, Dy, its luminous angle point chromaticity coordinate is (0.265,0.290), specifically
Preparation method is：Polymethacrylates and self-luminescent material are mixed in proportion, then extruded through double screw extruder,
Pelletizing (pelletizing size and millet are suitable, or smaller) obtains.
Embodiment 6
A kind of marking lines self-luminous microballon, by being by quality parts ratio：70 parts of polyethylene and 30 parts of self-luminescent material systems
Into.The self-luminescent material is that rare earth self-luminescent material is SrAl2O4:Eu, Dy, its luminous angle point chromaticity coordinate for (0.390,
0.545), specific preparation method is：Polyethylene and self-luminescent material are mixed in proportion, then squeezed through double screw extruder
Go out, pelletizing obtains.
Self-luminous road sign gage mark coating provided by the invention, the component of the self-luminous road sign gage mark coating is by weight
Amount number includes：0-30 part road mark paint I, 55-96 parts road mark paint II, and 4-15 part embodiments 1-6 are provided
Self-luminous microballon.
Use, i.e., first sprayed in region to be identified for the product that above-mentioned road mark paint II can be existing purchase
One layer of existing road mark paint II is applied, then self-luminous microballon is spread on to the surface of road mark paint II.Can also be direct
Sprayed after self-luminous microballon and road mark paint II are well mixed.
Bilayer can be used if necessary, i.e., on the basis of above-mentioned construction completion, then spray one layer of road mark paint I, have
Body, road mark paint I can be mixed by existing road mark paint and self-luminescent material.
Road mark paint I and road mark paint II provided by the invention component can also be used, it is specific such as embodiment
Shown in 7-9.
Embodiment 7
A kind of self-luminous road sign gage mark coating, its component include in parts by weight：II 90 parts of road mark paint and
10 parts of self-luminous microballon, wherein, the self-luminous microballon is obtained by embodiment 1.
Specifically, the component of the road mark paint II includes II 17 parts of resin, 16 parts of quartz sand, carbonic acid in parts by weight
38 parts of calcium powder, 15 parts of glass microballoon, 2.5 parts of titanium dioxide, 1.5 parts of EVA hot-melt adhesive；The resin II is commercially available C5 classes roadmarking
Coating is resin dedicated (C 5 petroleum resin).
During Specific construction, line of being constructed first on roadmarking, then above-mentioned each raw material is put into mixer, through adding
After hot scorification, continue to be uniformly mixed, carry out spraying and prepare the pavement strip with self-luminosity energy.Or self-luminous will be removed
Other components outside microballon are uniformly mixed, and are sprayed, then by the uniform spreading of self-luminous microballon in the roadmarking
It is also possible on coating.
The pavement strip is high in the spontaneous luminous intensity of faint yellow, flat appearance.
Embodiment 8
A kind of self-luminous road sign gage mark coating, its component include in parts by weight：20 parts of road mark paint I, 90
Part road mark paint II and 10 parts of self-luminous microballons, wherein, the self-luminous microballon is obtained by embodiment 2.
Wherein, the road mark paint I includes 20 parts of self-luminescent materials, 30 parts of acrylic resins, 15 in parts by weight
Part quartz sand, 25 parts of Paris whites, 4 parts of titanium dioxides, 1EVA PURs, 15 parts of glass microballoons.
The road mark paint II is two-component (A+B), specifically,
Component A includes the composition of following parts by weight：45 parts of resin III, 0.6 part of dispersant, 35 parts of pigment, 35 parts of filler,
3 parts of ultra-violet absorber, 2.5 parts of toughener；
B component includes the composition of following parts by weight：IV 45 parts of resin, 0.5 part of dispersant, 45 parts of pigment, 15 parts of filler,
3 parts of ultra-violet absorber, 2.5 parts of toughener, 5 parts of curing agent；
The mass ratio of above-mentioned component A and B component is 1：1.
Specifically, being selected for the specific material of component A and B component, resin III is alkyl acrylate；Resin IV is first
Base alkyl acrylate；Curing agent is dibenzoyl peroxide；Dispersant is unsaturated carboxylic acid polymer；Pigment is rutile titanium
White powder；Filler is calcium carbonate；Toughener is dioctyl phthalate；Ultra-violet absorber is benzotriazole ultraviolet radiation absorption
Agent.
During Specific constructions, the other compositions of curing agent and B component are mixed, are sufficiently stirred, then component A and B component with
Weight ratio is 1:1 proportioning mixing is sprayed at road surface, then self-luminous microballon is spread on to the surface of road mark paint；And will tree
In the component input mixer of fat I, after heated scorification, continue to be uniformly mixed, be sprayed on the road sprinkled with self-luminous microballon
The surface of face graticule.
Pavement strip prepared by dual-component coating is very thin, and intensity is good, is particularly suitable for cold district such as China's northeast ground
The pavement strip in area makes.
Embodiment 9
A kind of self-luminous road sign gage mark coating, its component include in parts by weight：II 85 parts of road mark paint and
10 parts of self-luminous microballon, wherein, the self-luminous microballon is obtained by embodiment 5.
Wherein, component A includes the composition of following parts by weight：30 parts of resin III, 0.2 part of dispersant, 15 parts of pigment, filler
10 parts, 1 part of ultra-violet absorber, 1 part of toughener；
B component includes the composition of following parts by weight：IV 30 parts of resin, 0.3 part of dispersant, 25 parts of pigment, 10 parts of filler,
1 part of ultra-violet absorber, 1 part of toughener, 0.5 part of curing agent；
The mass ratio of above-mentioned component A and B component is 1：2.
Specifically, being selected for the specific material of component A and B component, resin III is alkyl acrylate；Resin IV is first
Base alkyl acrylate；Curing agent is dibenzoyl peroxide；Dispersant is unsaturated carboxylic acid polymer；Pigment is zinc oxide；
Filler is barium sulfate；Toughener is dibutyl phthalate；Ultra-violet absorber is Benzotriazole Ultraviolet Stabilizer.
During Specific construction, self-luminous microballon, component A are well mixed with B component and are sprayed at road surface.Also can first exist
One layer of existing traffic paint of road surface spray coating, then self-luminous microballon, component A are well mixed with B component and are sprayed at road surface.
Embodiment described above is only the preferred embodiment to absolutely prove the present invention and being lifted, and its protection domain is unlimited
In this.The equivalent substitute or conversion that those skilled in the art are made on the basis of the present invention, the protection in the present invention
Within the scope of, protection scope of the present invention is defined by claims.
Claims (3)
- A kind of 1. self-luminous road sign gage mark coating, it is characterised in that the component of the self-luminous road sign gage mark coating Include in parts by weight：20 parts of road mark paint I, 90 parts of road mark paints II, and 10 parts of self-luminous microballons, wherein,The self-luminous microballon is made up of 30 parts of titanium dioxide, 25 parts of zirconium dioxides, 33 parts of silica and 12 parts of spontaneous finishes Material is made；The self-luminescent material is aluminate long afterglow materials, and the aluminate long afterglow materials are SrAl2O4:Eu,Dy；The road mark paint I includes 20 parts of self-luminescent materials in parts by weight, 30 parts of acrylic resins, 15 parts of quartz sands, 25 parts of Paris whites, 4 parts of titanium dioxides, 1 part of EVA hot-melt adhesive, 15 parts of glass microballoons；The road mark paint II includes component A and B component, and the mass ratio of component A and B component is 1：1；The component A bag Include the composition of following parts by weight：45 parts of resin III, 0.6 part of dispersant, 35 parts of pigment, 35 parts of filler, ultra-violet absorber 3 Part, 2.5 parts of toughener；The B component includes the composition of following parts by weight：IV 45 parts of resin, 0.5 part of dispersant, pigment 45 Part, 15 parts of filler, 3 parts of ultra-violet absorber, 2.5 parts of toughener, 5 parts of curing agent；The resin III is alkyl acrylate；Institute It is alkyl methacrylate to state resin IV；The curing agent is dibenzoyl peroxide；The dispersant is unsaturated carboxylic acid Polymer；The pigment is rutile titanium white powder；The filler is calcium carbonate；The toughener is dioctyl phthalate； The ultra-violet absorber is Benzotriazole Ultraviolet Stabilizer；Its construction method comprises the following steps：Determination identifies making region first, is then identifying the making region spraying road mark paint II, and by described in certainly The luminous uniform spreading of microballon is on the road mark paint II, then sprays one layer of road mark paint I.
- 2. self-luminous road sign gage mark coating according to claim 1, it is characterised in that the system of the self-luminous microballon Preparation Method is：By titanium dioxide, zirconium dioxide, silica and self-luminescent material respectively by crushing, sieve, after metering, press Ratio is well mixed to form compound, and mixed material heating is melted, and to continue to stir in fusion process, sieving, that is, obtain institute State self-luminous microballon.
- 3. self-luminous road sign gage mark coating according to claim 1, it is characterised in that the self-luminous road sign Gage mark coating is applied to mark any in roadmarking, tunnel inner wall, Bridge guardrail, anti-collision wall, traffic sign label Make.
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| CN107254222A (en) * | 2017-06-09 | 2017-10-17 | 北京路安交通科技发展有限公司 | A kind of traffic paint and its production technology |
| CN107337904A (en) * | 2017-08-02 | 2017-11-10 | 上海浦兴路桥建设工程有限公司 | A kind of self-luminous ground surface material and compound method |
| CN107573777B (en) * | 2017-09-12 | 2018-10-23 | 天途路业集团有限公司 | A kind of hot melt type gage mark coating and preparation method thereof |
| CN108546506A (en) * | 2018-05-10 | 2018-09-18 | 重庆新康意安得达尔新材料有限公司 | A kind of anti-dazzle optical coating and preparation method thereof |
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| CN1220169C (en) * | 2001-08-04 | 2005-09-21 | 大连路明发光科技股份有限公司 | Luminous-reflecting mark band and its making method |
| CN101372598B (en) * | 2007-08-20 | 2012-01-11 | 北京路桥瑞通养护中心 | Energy-storing self-luminescent road marking coating |
| CN102775872A (en) * | 2012-08-27 | 2012-11-14 | 山西省交通科学研究院 | Self-cleaning bi-component road marking coating and preparation method thereof |
| US9222230B2 (en) * | 2012-09-14 | 2015-12-29 | Potters Industries, Llc | Porous silicon oxide drying agents for waterborne latex paint compositions |
| CN104479437B (en) * | 2015-01-06 | 2017-01-25 | 东华大学 | Preparation method for super-hydrophobic self-luminous coating |
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