CN1220169C - Luminous-reflecting mark band and its making method - Google Patents
Luminous-reflecting mark band and its making method Download PDFInfo
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- CN1220169C CN1220169C CN 01125038 CN01125038A CN1220169C CN 1220169 C CN1220169 C CN 1220169C CN 01125038 CN01125038 CN 01125038 CN 01125038 A CN01125038 A CN 01125038A CN 1220169 C CN1220169 C CN 1220169C
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Abstract
The present invention relates to a luminous and reflecting sign band for road lineation. The luminous and reflecting sign band is prepared by a method that a film or a sheet is prepared by rubber and plastics or a mixture of rubber and plastics; luminous particles are prepared from a luminous material and resin; glass microspheres are used as reflecting particles; the luminous particles and the reflecting particles are bonded on one surface of the film or the sheet, and glue is applied to the other surface of the film or the sheet for attaching a release paper. The luminous and reflecting sign band has the characteristics of favorable reflection effect, high luminance, long afterglow time (as long as 12 hours), good weatherability, good abrasion resistance, good rebound resilience, good oil resistance, good chemical resistance, no cracking, skid prevention, fog prevention, long service life (more than five years) and convenient use. The construction can be completed in 15 minutes, and traffic can not be influenced.
Description
The present invention relates to colored belt and manufacture method that a kind of lines on road surface is used.
Lines on road surface all adopts cold lacquer or hot melt lacquer and adhesive type colored belt all over the world at present.These products rely on resin that high-abrasive material, pigment, reflective glass beads etc. are mixed into one and are coated with on the ground.Because the resin exposing surface, therefore easily being stained with pollutant causes the graticule blackening, and especially some porcelain earth cities and road are just outmoded eclipsed less than one or two months with the said goods line.And in the 2 years at most serviceable life of the said goods, four months at least, its reason was that the bonding agent that these products use solidifies too fast, the amount of going deep into the adhesive surface micropore is few, stretching resistance is also weak thereupon, adds floor-dust, earth, greasy dirt and handles unonly, makes bonding insecure.Soak through rainwater, graticule easily comes off.And all acomia light action in the said goods.
The described luminous reflecting marking band of CN1237752A, its aspect is the layer that " silver bowl " effect is arranged with spraying with self luminous glue with 20～40 order glass microballoons, its lower floor.Can expect that this one deck luminescent layer that present luminescent material is made is across one deck glass microballoon, its extinction and luminous ability are very limited, so in this patent application document, its illumination effect do not carried in a word.The described reflecting and luminous material of CN1254738A is very simply glass microballoon to be mixed use with luminescent material, and owing to interfering with each other of these two kinds of materials, its effect also is unsafty.
The present invention is by the light accumulation type embedded photoluminescent material (to call luminescent material in the following text) that adopts novel different kinds of ions to activate, and reaches all good purpose of reflective luminescent properties by being processed into incandescnet particle.
The present invention is achieved in that
One side spraying one deck adhesive layer of base material, spreading incandescnet particle and light-reflecting particles on adhesive layer; At base material another side coating one deck adhesive layer, compound off-style paper layer on adhesive layer.
The implementation step of luminous-reflecting mark band manufacture method is followed successively by:
1, the production of base material:
Base material can be film, the sheet that rubber, plastics or its potpourri are made, and thickness is 1.0～5.0mm, and with following rubber, plastic hybrid, thickness is that the base material of 1.5～2.5mm is advisable, and its composition (w%) is:
Rubber 5～50
Plastics 5～50
Filler 10～80
Pigment 5～30
Auxiliary agent 0～60
Described rubber is: the one or more combination in cis-butadiene cement, butadiene-styrene rubber, natural gum, polyurethane adhesive, ACM, nitrile rubber, EP rubbers, the chlorinated rubber;
Described plastics are: the one or more combination in tygon, polypropylene, Polyvinylchloride, ABS, nylon, polyester, polycarbonate, polyacrylate, the haloflex;
Described filler is: the one or more combination in lime carbonate, talcum powder, lithopone, wollastonite in powder, calcium sulphate, barium sulphate, the beaded glass;
Described auxiliary agent is: one or more in white carbon, antioxidant H, antioxidant DSTP, benzophenone, triazines, metallic soap class, silane coupling agent, titanate coupling agent, aluminate coupling agent, oleamide, erucyl amide, Tissuemat E, antioxidant T215, antioxidant 1010, dioctyl phthalate, dibutyl phthalate, epoxidised soybean oil, the decanedioic acid two (2-Octyl Nitrite);
The base material manufacture craft:
Rubber, plastics, filler, pigment, auxiliary agent by the proportioning weighing of forming, under 120 ℃～200 ℃ temperature, banburying, are opened refining, rolled into the thick batten of 1.5～2.5mm.Be cut into certain width as required.
2, incandescnet particle production:
Incandescnet particle is the solids that contain silicate that different kinds of ions activates, aluminate, sulfide luminescent material, and particle diameter is 10～140 orders.Except luminescent material, carrier can be a resin in the incandescnet particle, can be silicate such as glass, pottery also, also can be its potpourri.(w%) is advisable with following composition:
Vector resin 20～95
Luminescent material 5～80
Filler 0～60
Auxiliary agent 0～30
Described vector resin is the one or more combination in polypropylene, tygon, polystyrene, ABS, nylon, polyester, the polycarbonate;
Described filler is one or more in titanium dioxide, zinc white, lithopone, lime carbonate, talcum powder, calcium sulphate, wollastonite in powder, the barium sulphate;
Described auxiliary agent is one or more in benzophenone, triazines, metallic soap class, silane coupling agent, titanate coupling agent, aluminate coupling agent, oleamide, erucyl amide, Tissuemat E, antioxidant T215, antioxidant 1010, dioctyl phthalate, dibutyl phthalate, epoxidised soybean oil, the decanedioic acid two (2-Octyl Nitrite);
From Process Technology of Polymer technology, processing aid used during different process of resin can be different.For example: during the processing Polyvinylchloride, must use plasticizer phthalic acid dioctyl ester, dibutyl phthalate.And generally other resin such as polypropylene, tygon, polystyrene add man-hour without these plastifier.When rubber, when fleut is filled in plastic processing, often need fleut to be carried out surface activation process with coupling agent, fill processing again.Tygon, polypropylene add man-hour, need add oleamide, erucyl amide for improving processing characteristics or surface-brightening, can certainly not add.So the processing aid described in this instructions is meant the processing aid general commonly used of used rubber or plastics.
The incandescnet particle method for making is: with luminescent material and other raw material by above prescription weighing and mix, through open refining, extrude, methods such as banburying, granulation, pulverizing, screening make.
3, light-reflecting particles is a reflecting glass Bead, meets the regulation of beaded glass among transportation industry standard " pavement marking paint " JT/T280-1995; The particle diameter of light-reflecting particles is 30-100 order, refractive index 〉=1.5, one-tenth circle rate 〉=82%;
4, tackifier is one or more in polyurethane adhesive, acrylate adhesive, epoxyn, the neoprene tackifier.
The used luminescent material of the present invention is silicate, aluminate, sulfide luminescent material or its potpourri that different kinds of ions activates, and its main expression and luminous twilight sunset color are as follows respectively:
1, the chemical composition expression of the silicate luminescent material of different kinds of ions activation is:
αMO·βM’O·γSiO
2·δR:Eu
xLn
y
Wherein: M is the combination of one or more elements among Sr, Ca, Ba, the Zn;
M ' is the combination of one or more elements among Mg, Cd, the Be;
R is B
2O
3, P
2O
5In one or both combination of compounds;
Ln is the combination of one or more elements among Nd, Dy, Ho, Tm, La, Pr, Tb, Ce, Er, Mn, Bi, Sn, the Sb:
α, β, γ, δ, x, y are mole coefficient:
0.6≤α≤6；0≤β≤5；1≤γ≤9；
0≤δ≤0.7；0.00001≤x≤0.2；0≤y≤0.3。
Further experiment shows that in the preferred above-mentioned silicate luminescent material, the luminescent material of following 2 classes can be made the luminescent film of higher brightness, and main chemical composition expression is:
1-1.(Sr
1-zCa
z)
2MgSi
2O
7:Eu
xLn
y
1-2.(Sr
1-zCa
z)
3MgSi
2O
8:Eu
xLn
y
Wherein: Ln is one or more element combinations among La, Ce, Dy, Tm, Ho, Nd, Er, Sb, the Bi;
Z is coefficient: 0≤z≤1;
X, y are mole coefficient: 0.0001≤x≤0.2; 0.0001≤y≤0.3.
The preferred long persistence luminescent silicate material of above-mentioned 2 classes is with the difference of z value, can send orchid, blue green, green, yellowish green, sodium yellow respectively, for example during z=0, sends out coloured light blue; During z=0.5, glow green.
2, the chemical composition expression of the aluminate luminescent material of different kinds of ions activation is:
αMO·βAL
2O
3·γB
2O
3:Eu
xLn
y
Wherein: M is the combination of one or more elements among Mg, Ca, Sr, Ba, Zn, the Cd;
Ln is the combination of one or more elements among Nd, Dy, Ho, Tm, La, Ce, Er, Pr, the Bi;
α, β, γ, x, y are mole coefficient:
0.5≤α≤6；0.5≤β≤9；0.0≤γ≤0.3；
0.00001≤x≤0.25；0.00001≤y≤0.3。
Further experiment shows, preferred above-mentioned aluminate luminescent material, and the luminescent material of following 2 classes can be made the incandescnet particle of higher brightness, and main chemical composition expression is:
2-1.MAl
2O
4:Eu
xLn
y
Wherein: Ln is the combination of one or more elements among La, Ce, Dy, Ho, Nd, the Er;
M is the combination of one or more elements among Sr, Ca, Mg, Ba, the Zn;
X, y are mole coefficient: 0.0001≤x≤0.25; 0.0001≤y≤0.3.
This material is with the difference of M, the glow color difference, during as M=Sr, for yellow green luminous; During M=Ca, be blue violet light.
2-2.M
4Al
14O
25:Eu
xLn
y
Wherein: Ln is the combination of one or more elements among Pr, Ce, Dy, Ho, Nd, the Er;
M is the combination of one or more elements among Sr, Ca, Mg, Ba, the Zn;
X, y are mole coefficient: 0.0001≤x≤0.25; 0.0001≤y≤0.3.
3. the main chemical composition expression of the sulfide luminescent material of different kinds of ions activation is:
3-1.(Ca
1-zSr
z)S:Eu
xLn
y
Wherein: Ln is the combination of one or more elements among Er, Dy, La, Tm, the Y;
Z is coefficient: 0≤z≤1;
X, y are mole coefficient: 0.00001≤x≤0.2; 0.00001≤y≤0.15.
This material is different with the z value, can present red, orange luminescence.
3-2.R
2O
2S:Eu
xLn
y
Wherein: R is the combination of one or more elements among Y, La, the Gd;
Ln is the combination of one or more elements among Er, Cr, Bi, Dy, Tm, Ti, Mg, Sr, Ca, Ba, the Mn;
X, y are mole coefficient: 0.00001≤x≤0.2; 0.00001≤y≤0.6.
Further test shows that kind, the content of incandescnet particle in whole luminous reflecting colored belt of vector resin of briliancy, after time and incandescnet particle of luminous-reflecting mark band is relevant.
The luminous-reflecting mark band that the present invention makes, the glorious degrees height reaches 12 hours after time, and glow color is colorful, and weatherability, wearing quality, rebound resilience, oil resistant, chemical resistance are good, do not have be full of cracks, anti-skidding, antifog, and serviceable life is more than 5 years.Easy to use, can finish construction, and not block traffic in 15 minutes.The simple reflecting mark band of security performance is better.
Below further specify the manufacture method of luminous-reflecting mark band with example:
Example one
1, the manufacturing of incandescnet particle:
Vector resin polystyrene 5.0Kg
Luminescent material aluminate SrAL
2O
4: Eu
0.05, Dy
0.184.5Kg
Filler-calcium carbonate 10Kg
Auxiliary agent calcium stearate 0.3Kg
Oleamide 0.2Kg
By the described starting material that take by weighing of prescription, add in the high-speed mixer, under 120 ℃, mix 20min, under 60 ℃, mix 20min again, be uniformly dispersed, by extruding, granulation is pulverized with mixed raw materials, and the method for screening is produced 10-140 order incandescnet particle.
2. the manufacturing of base material
Rubber natural rubber 240Kg
Plastics acrylic resin 50Kg
Filler-calcium carbonate 50Kg
Talcum powder 200Kg
Barium sulphate 200Kg
Beaded glass 200Kg
Pigment titanium white 90Kg
Zinc white 10Kg
Auxiliary agent white carbon 70Kg
Antioxidant 1010 0.3Kg
Benzophenone 0.15Kg
By the described starting material that take by weighing of prescription, other component except the rubber is put into high-speed mixer mixing 20min under 120 ℃, mix 20min in 60 ℃ and be uniformly dispersed.In 150 ℃ down and rubber mixing 10min in Banbury mixer, under 160 ℃ in mill mixing 10min, calendering formation is the thick batten of 1.5-2.5mm in calender under 160 ℃-100 ℃.
3. the manufacturing of luminous-reflecting mark band
At the one side spraying acrylic acid adhesive of flat substrates, spreading incandescnet particle and reflective glass beads on tackifier are dried by drying tunnel.At base material back coated acrylic acid adhesive, compound again release liners is cut into certain width, baling on request.
This luminous reflecting colored belt weather resistance is good, anti-wear performance is good, chemical resistance is good, and service time is more than 3 years.The glorious degrees height reaches 12 hours after time.The autoluminescence color is green.
This luminous reflecting colored belt is easy to use, tears release liners and sticks on the assigned address roll extrusion and get final product, and just can finish construction, and not influence traffic in 15 minutes.
Example two
1. the manufacturing of incandescnet particle
Vector resin polycarbonate 84.5Kg
Filler talcum powder 10Kg
Auxiliary agent oleamide 0.3Kg
Erucyl amide 0.2Kg
Luminescent material strontium sulfide calcium: Sr
0.5CaS
0.5: Eu
0.001, Y
0.0055.0Kg
By the described starting material that take by weighing of prescription, add in the high-speed mixer, under 120 ℃, mix 20min, under 60 ℃, mix 20min again, be uniformly dispersed, by extruding, granulation is pulverized with mixed raw materials, and the method for screening is produced 10-140 order incandescnet particle.
2. the manufacturing of base material
Rubber polyurethane rubber 25Kg
Nitrile rubber 25Kg
Plastic polyethylene 250Kg
Filler-calcium carbonate 100Kg
Talcum powder 100Kg
Wollastonite in powder 200Kg
Beaded glass 200Kg
Pigment
Chrome yellow 100Kg
Auxiliary agent oleamide 0.7Kg
White carbon 20Kg
Aging resister 1010 0.1Kg
Benzophenone 0.025Kg
By the described starting material that take by weighing of prescription, other component except the rubber is put into high-speed mixer mixing 20min under 120 ℃, mix 20min in 60 ℃ again and be uniformly dispersed.In 150 ℃ down and rubber mixing 10min in Banbury mixer, under 160 ℃ in mill mixing 10min, calendering formation is the thick batten of 1.5-2.5mm in calender under 160 ℃-100 ℃.
3. the manufacturing of luminous-reflecting mark band
At substrate surface spraying polyurethane tackifier, spreading incandescnet particle and reflective glass beads on tackifier are dried by drying tunnel.At base material back coated polyurethane adhesive,, be cut into certain width on request, baling in compound release liners.
This luminous reflecting colored belt weather resistance is good, anti-wear performance is good, oil resistant, chemical resistance are good, and service time is more than 3 years.The glorious degrees height reaches 12 hours after time.The autoluminescence color is green.This luminous reflecting colored belt is easy to use, tears release liners and sticks on the assigned address roll extrusion and get final product, and just can finish construction, and not influence traffic in 15 minutes.
Example three
1, the manufacturing of incandescnet particle:
Vector resin nylon 66 39.5Kg
Luminescent material silicate (Sr
0.5Ca
0.5)
2MgSi
2O
7: Eu
0.01Nd
0.150Kg
Filler-calcium carbonate 10Kg
Auxiliary agent oleamide 0.5Kg
By the described starting material that take by weighing of prescription, add in the high-speed mixer, under 120 ℃, mix 20min, under 60 ℃, mix 20min again, be uniformly dispersed, by extruding, granulation is pulverized with mixed raw materials, and the method for screening is produced 10-140 order incandescnet particle.
2. the manufacturing of base material
Rubber powder nitrile rubber 120Kg
Plastic polyvinyl chloride resin 150Kg
Filler
Lime carbonate 200Kg
Barium sulphate 200Kg
Beaded glass 200Kg
Pigment titanium white 90Kg
Zinc white 10Kg
Auxiliary agent white carbon 40Kg
Antioxidant 1010 0.3Kg
Benzophenone 0.15Kg
Dioctyl phthalate 60Kg
Disalt 0.6Kg
Three salt 0.3Kg
By the described starting material that take by weighing of prescription, other component except the rubber is put into high-speed mixer mixing 20min under 120 ℃, mix 20min in 60 ℃ and be uniformly dispersed.In 150 ℃ down and rubber mixing 10min in Banbury mixer, under 160 ℃ in mill mixing 10min, calendering formation is the thick batten of 1.5-2.5mm in calender under 160 ℃-100 ℃.
3. the manufacturing of luminous-reflecting mark band
At the one side spraying acrylic acid adhesive of flat substrates, spreading incandescnet particle and reflective glass beads on tackifier are dried by drying tunnel.At base material back coated acrylic acid adhesive, compound again release liners is cut into certain width, baling on request.
This luminous reflecting colored belt weather resistance is good, anti-wear performance is good, chemical resistance is good, and service time is more than 3 years.The glorious degrees height reaches 12 hours after time.The autoluminescence color is a blue-green.
This luminous reflecting colored belt is easy to use, tears release liners and sticks on the assigned address roll extrusion and get final product, and just can finish construction, and not influence traffic in 15 minutes.
Claims (13)
1. luminous-reflecting mark band that contains embedded photoluminescent material, reflectorized material,
The structure that it is characterized in that colored belt is covered with photoluminescence particle (3) and light-reflecting particles (4) for scribbling one deck adhesive layer (2) in base material (1) one side on the adhesive layer, at base material another side coating gum layer (5), compound off-style paper layer (6) under glue-line;
Wherein, base material is film, the sheet that rubber, plastics or its potpourri are made, and its thickness is 1.0～5.0mm;
Incandescnet particle is the solids that contain luminescent material, and its particle diameter is 10～140 orders, and weight percent consists of:
Vector resin 20～95
Luminescent material 5～80
Filler 0～60
Auxiliary agent 0～30
Described vector resin is the one or more combination in polypropylene, tygon, polystyrene, ABS, nylon, polyester, the polycarbonate;
Described luminescent material is silicate, aluminate, the sulfide that different kinds of ions activates;
Described filler is one or more in titanium dioxide, zinc white, lithopone, lime carbonate, talcum powder, calcium sulphate, wollastonite in powder, the barium sulphate;
Described auxiliary agent is one or more in benzophenone, triazines, metallic soap class, silane coupling agent, titanate coupling agent, aluminate coupling agent, oleamide, erucyl amide, Tissuemat E, antioxidant T215, antioxidant 1010, dioctyl phthalate, dibutyl phthalate, epoxidised soybean oil, the decanedioic acid two;
Described light-reflecting particles is a reflecting glass Bead, and particle diameter is 30-100 order, refractive index 〉=1.5, one-tenth circle rate 〉=82%;
Described adhesive layer is one or more in polyurethane adhesive, acrylate adhesive, epoxyn, the neoprene tackifier.
2, luminous-reflecting mark band as claimed in claim 1 is characterized in that base material is rubber, plastic hybrid, and thickness is 1.5～2.5mm, and its weight percent consists of:
Rubber 5～50
Plastics 5～50
Filler 10～80
Pigment 5～30
Auxiliary agent 0～60
Described rubber is: the one or more combination in cis-butadiene cement, butadiene-styrene rubber, natural gum, polyurethane adhesive, ACM, nitrile rubber, EP rubbers, the chlorinated rubber;
Described plastics are: the one or more combination in tygon, polypropylene, Polyvinylchloride, ABS, nylon, polyester, polycarbonate, polyacrylate, the haloflex;
Described filler is: the one or more combination in lime carbonate, talcum powder, lithopone, wollastonite in powder, calcium sulphate, barium sulphate, the beaded glass;
Described auxiliary agent is: one or more in white carbon, antioxidant H, antioxidant DSTP, benzophenone, triazines, metallic soap class, silane coupling agent, titanate coupling agent, aluminate coupling agent, oleamide, erucyl amide, Tissuemat E, antioxidant T215, antioxidant 1010, dioctyl phthalate, dibutyl phthalate, epoxidised soybean oil, the decanedioic acid two;
3, luminous-reflecting mark band as claimed in claim 1 is characterized in that the main chemical composition expression of the silicate luminescent material that described different kinds of ions activates is:
αMO·βM’O·γSiO2·δR:Eu
xLn
y
Wherein: M is a kind of element among Sr, Ca, Ba, the Zn or the combination of multiple element;
M ' is the combination of one or more elements among Mg, Cd, the Be;
R is B
2O
3, P
2O
5In one or both combination of compounds;
Ln is the combination of one or more elements among Nd, Dy, Ho, Tm, La, Pr, Tb, Ce, Er, Mn, Bi, Sn, the Sb;
α, β, γ, δ, x, y are mole coefficient:
0.6≤α≤6；0≤β≤5；1≤γ≤9；
0≤δ≤0.7；0.00001≤x≤0.2；0≤y≤0.3。
4, luminous-reflecting mark band as claimed in claim 3 is characterized in that the main chemical composition expression of luminescent material is:
(Sr
1-zCa
z)
2MgSi
2O
7:Eu
xLn
y
Wherein: Ln is one or more element combinations among La, Ce, Dy, Tm, Ho, Nd, Er, Sb, the Bi;
Z is coefficient: 0≤z≤1;
X, y are mole coefficient: 0.0001≤x≤0.2; 0.0001≤y≤0.3.
5, luminous-reflecting mark band as claimed in claim 3 is characterized in that the main chemical composition expression of luminescent material is:
(Sr
1-zCa
z)
3MgSi
2O
8:Eu
xLn
y
Wherein: Ln is one or more element combinations among La, Ce, Dy, Tm, Ho, Nd, Er, Sb, the Bi;
Z is coefficient: 0≤z≤1;
X, y are mole coefficient: 0.0001≤x≤0.2; 0.0001≤y≤0.3.
6, luminous-reflecting mark band as claimed in claim 1 is characterized in that the main chemical composition expression of the aluminate luminescent material that described different kinds of ions activates is:
αMO·βAL
2O
3·γB
2O
3:Eu
xLn
y
Wherein: M is the combination of one or more elements among Mg, Ca, Sr, Ba, Zn, the Cd;
Ln is the combination of one or more elements among Nd, Dy, Ho, Tm, La, Ce, Er, Pr, the Bi;
α, β, γ, x, y are mole coefficient:
0.5≤α≤6；0.5≤β≤9；0.0≤γ≤0.3；
0.00001≤x≤0.25；0.00001≤y≤0.3。
7, luminous-reflecting mark band as claimed in claim 6 is characterized in that the main chemical composition expression of luminescent material is:
MAl
2O
4:Eu
xLn
y
Wherein: Ln is the combination of one or more elements among La, Ce, Dy, Ho, Nd, the Er;
M is the combination of one or more elements among Sr, Ca, Mg, Ba, the Zn;
X, y are mole coefficient: 0.0001≤x≤0.25; 0.0001≤y≤0.3.
8, luminous-reflecting mark band as claimed in claim 6 is characterized in that the main chemical composition expression of luminescent material is:
M
4Al
14O
25:Eu
xLn
y
Wherein: Ln is the combination of one or more elements among Pr, Ce, Dy, Ho, Nd, the Er;
M is the combination of one or more elements among Sr, Ca, Mg, Ba, the Zn;
X, y are mole coefficient: 0.0001≤x≤0.25; 0.0001≤y≤0.3.
9, luminous-reflecting mark band as claimed in claim 1 is characterized in that the main chemical composition expression of the sulfide luminescent material that described different kinds of ions activates is:
(Ca
1-zSr
z)S:Eu
xLn
y
Wherein: Ln is the combination of one or more elements among Er, Dy, La, Tm, the Y;
Z is a coefficient, 0≤z≤1;
X, y are mole coefficient: 0.00001≤x≤0.2; 0.00001≤y≤0.15.
10, luminous-reflecting mark band as claimed in claim 1 is characterized in that the main chemical composition expression of the sulfide luminescent material that described different kinds of ions activates is:
R
2O
2S:Eu
xLn
y
Wherein: R is the combination of one or more elements among Y, La, the Gd;
Ln is the combination of one or more elements among Er, Cr, Bi, Dy, Tm, Ti, Mg, Sr, Ca, Ba, the Mn;
X, y are mole coefficient: 0.00001≤x≤0.2; 0.00001≤y≤0.6.
11, the method for making of luminous-reflecting mark band according to claim 1, it is characterized by in the spray of the one side of the film of making by rubber, plastics or its potpourri, flat substrates or be coated with one deck tackifier, spreading contains the solid luminescence particle and the reflective glass beads of the luminescent material of silicate that different kinds of ions activates, aluminate, sulfide on adhesive layer, and is then dry; At the another side spray or the coating binder of base material, and compound release liners.
12, as the method for making of luminous-reflecting mark band as described in the claim 11, it is characterized by: the raw materials used weight percent proportioning of incandescnet particle is:
Vector resin 20～95
Luminescent material 5～80
Filler 0～60
Auxiliary agent 0～30
The incandescnet particle manufacturing process is: luminescent material and other raw material are mixed, through open refining, extrude, banburying, granulation, pulverizing, screening and make.
13, as the method for making of luminous-reflecting mark band as described in the claim 11, it is characterized by: the raw materials used weight percent proportioning of base material is:
Rubber 5～50
Plastics 5～50
Filler 10～80
Pigment 5～30
Auxiliary agent 0～60
The base material manufacture craft:
With the ratio weighing on demand of rubber, plastics, filler, pigment, auxiliary agent, under 120 ℃～200 ℃ temperature, through banburying, open refining, roll into the thick batten of 1.5～2.5mm, be cut into certain width as required.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 01125038 CN1220169C (en) | 2001-08-04 | 2001-08-04 | Luminous-reflecting mark band and its making method |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 01125038 CN1220169C (en) | 2001-08-04 | 2001-08-04 | Luminous-reflecting mark band and its making method |
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|---|---|
| CN1400573A CN1400573A (en) | 2003-03-05 |
| CN1220169C true CN1220169C (en) | 2005-09-21 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100429352C (en) * | 2005-11-16 | 2008-10-29 | 辽宁警官高等专科学校 | Light-light reflecting road traffic marker band |
| CN101418110B (en) * | 2007-10-26 | 2010-04-21 | 中国石油化工股份有限公司 | Laser marked resin composite and preparation method thereof |
| CN102020819A (en) * | 2009-09-16 | 2011-04-20 | 大连路明发光科技股份有限公司 | Plastic light-conversion fluorescent granules and application thereof |
| CN102911491A (en) * | 2012-11-19 | 2013-02-06 | 邓文 | Thermoplastic composition, preparation method and application thereof |
| CN103242616B (en) * | 2013-04-27 | 2018-06-15 | 上海锦湖日丽塑料有限公司 | Aesthetic resin composition with illusion-colour and preparation method thereof |
| CN104774415A (en) * | 2015-05-06 | 2015-07-15 | 赵继福 | Road light-reflecting marking line belt and preparation process thereof |
| CN105860738B (en) * | 2016-06-13 | 2018-03-23 | 张悦 | A kind of self-luminous road sign gage mark coating and its application |
| CN106349877B (en) * | 2016-08-31 | 2018-10-02 | 沈阳顺风新材料有限公司 | A kind of roadmarking patch and preparation method thereof |
| CN106760966A (en) * | 2016-11-28 | 2017-05-31 | 尤晓丽 | A kind of lockhole is visually pasted |
| CN108118537A (en) * | 2018-02-07 | 2018-06-05 | 海宁市现代汽车座套有限公司 | A kind of Reflection fabric and preparation method thereof |
| CN109355923B (en) * | 2018-09-06 | 2020-12-08 | 福建新隆上超纤有限公司 | Preparation method of flame-retardant polyurethane artificial leather |
| CN111592779A (en) * | 2020-05-18 | 2020-08-28 | 苏州拓博琳新材料科技有限公司 | Self-luminous raised marking paint and preparation method and use method thereof |
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2001
- 2001-08-04 CN CN 01125038 patent/CN1220169C/en not_active Expired - Lifetime
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| CN1400573A (en) | 2003-03-05 |
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Address after: 116025 No. 32, high energy street, hi tech Zone, Liaoning, Dalian Patentee after: Dalian Luming Light Emitting Sci-Tech Co., Ltd. Address before: 116025 Liaoning city of Dalian province high tech Zone Qixianling Torch Road No. 10 Patentee before: Dalian Luming Light Emitting Sci-Tech Co., Ltd. |
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Granted publication date: 20050921 |