CN104774415A - Road light-reflecting marking line belt and preparation process thereof - Google Patents
Road light-reflecting marking line belt and preparation process thereof Download PDFInfo
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- CN104774415A CN104774415A CN201510225602.1A CN201510225602A CN104774415A CN 104774415 A CN104774415 A CN 104774415A CN 201510225602 A CN201510225602 A CN 201510225602A CN 104774415 A CN104774415 A CN 104774415A
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Abstract
The invention discloses a road light-reflecting marking line belt and a preparation process thereof. The road light-reflecting marking line belt is prepared through homemade PS resin, homemade water-based adhesive glue, vinyl, acrylic resin, titanium dioxide, talcum powder, glass beads, ethyl acetate and dioctyl phthalate. The road marking line belt is prepared through the raw materials low in price and replaces a hot-melt road light-reflecting coating and a road light-reflecting marking line belt which are prepared through polymer resin and natural rubber high in price, and the aims of high quality, long service life, no pollution and low cost are achieved.
Description
technical field:
The present invention relates to a kind of Chemicals, especially relate to a kind of reflecting reticle of road band and preparation technology thereof of low cost.
technical background:
Along with the development of national economy, modern transportation cause have also been obtained fast development, simultaneously also proposes higher level requirement one by one to relevant auxiliary facility thereupon.Reflecting reticle of road, the road is clear, the marker of driving safety, life security, happy family life for a direct relation, in the development of communication, serve very important effect.In the evolution of communication, be the identifier marking that motorway, modern city rail are supporting, from the life-span used, use value to beautiful and clean reflecting effect, be proposed higher requirement.Traditional roadmarking is white or yellow paint, and namely paint brushing and move ahead or left and right turning etc. to show on road surface, this method uses trouble, and not wear-resisting, the life-span is short.The thermally melting roadmarking of current use, reflecting marking band make traffic sign character and graphic, exist seriously polluted, work-ing life is short, actual building cost high in cost of production shortcoming.Thus find that a kind of quality is good, pollution-free, cost value is low, road marking-line band easy to manufacture, be a kind of instant problem, being that user only needs, is also needed for era development.
summary of the invention:
Technical problem to be solved by this invention is: prepare road marking-line band with the raw material of cheapness, instead of the hot-melt type road reflective coating and reflecting reticle of road band that manufacture with expensive macromolecule resin and natural rubber, achieve the object of high quality, long lifetime, pollution-free, low cost.
A kind of reflecting reticle of road band, is made by following raw materials according:
Self-control PS resin, self-control aqueous assembly glue, ethenoid resin, acrylic resin, titanium dioxide, talcum powder, glass microballon, ethyl acetate, dioctyl ester.
Self-control PS resin utilizes waste foam to be prepared from;
Self-control aqueous assembly glue instead of original toluene tackiness agent;
A kind of preparation technology of reflecting reticle of road band is: the first step: self-control PS resin, self-control aqueous assembly glue, ethenoid resin, acrylic resin, titanium dioxide, talcum powder, glass microballon, ethyl acetate, dioctyl ester are added successively in fine material mixer, fully stir; Second step: the raw materials technology that the first step is completed add in mill carry out mixing, be pressed into slug; 3rd step: by the slug of second step feeding rolling press, continuous calendering becomes the basic finished product of desired thickness; 4th step: the basic finished product of the 3rd step is gone on netted rail automatically and send band, through paint spray booth high pressure airless spray equipment, is sprayed on basic finished surface uniformly by self-control aqueous assembly glue; 5th step: by rail send band the basic finished product of the 4th step is delivered to ball-planting machine under, reflective glass beads is planted in glue on the surface uniformly, rail send band the finished product reflective tape of planting upper rear reflector is sent to dryer, by cut after drying reel, vanning be finished product.
The preparation technology of self-control PS resin: the waste foam claiming to make, wilkinite, aluminum oxide are added gas making tank successively, is warmed to 300 ~ ~ 400C °, is oxidized, flows out for subsequent use through cooling liquid; Then same methyl methacrylate, ethyl propenoate, butyl acrylate add in the reactor of belt stirrer, are warmed to 60 ~ ~ 80C °, start agitator, drip ethyl acetate and peroxidation toluyl molten thing altogether again, be warming up to 80 ~ ~ 85C °, be incubated 3 ~ ~ 4 hours, barrelling is for subsequent use.
The preparation technology of self-control aqueous assembly glue: the first step; 424 maleic resins that make and ethyl acetate mix and blend, dissolving will be claimed; Second step: raw material made for the first step claiming to make is added homogenizer, dispersing and mixing successively with benzene emulsion; 3rd step: second step is sent into sand mill through the material of dispersion, and through fine grinding, barrelling is for subsequent use.
positive beneficial effect:raw material of the present invention have employed homemade PS resin and aqueous assembly glue is prepared from.Its beneficial effect is: instead of expensive macromolecule resin and natural rubber with the waste foam of cheapness, the pollution waste not only reasonably utilized, and decreases the discharge of polluting waste; Next is in propyl benzene emulsion, add ethyl acetate and 424 maleic resins, and that aqueous assembly glue is possessed is aseptic, dry, feature that adhesive property is excellent.
Embodiment
Below in conjunction with specific embodiment, the present invention is described further:
A kind of reflecting reticle of road band, is made by following raw materials according:
Self-control PS resin, self-control aqueous assembly glue, ethenoid resin, acrylic resin, titanium dioxide, talcum powder, glass microballon, ethyl acetate, dioctyl ester.
Self-control PS resin utilizes waste foam to be prepared from;
Self-control aqueous assembly glue instead of original toluene tackiness agent;
A kind of preparation technology of reflecting reticle of road band is: the first step: self-control PS resin, self-control aqueous assembly glue, ethenoid resin, acrylic resin, titanium dioxide, talcum powder, glass microballon, ethyl acetate, dioctyl ester are added successively in fine material mixer, fully stir; Second step: the raw materials technology that the first step is completed add in mill carry out mixing, be pressed into slug; 3rd step: by the slug of second step feeding rolling press, continuous calendering becomes the basic finished product of desired thickness; 4th step: the basic finished product of the 3rd step is gone on netted rail automatically and send band, through paint spray booth high pressure airless spray equipment, is sprayed on basic finished surface uniformly by self-control aqueous assembly glue; 5th step: by rail send band the basic finished product of the 4th step is delivered to ball-planting machine under, reflective glass beads is planted in glue on the surface uniformly, rail send band the finished product reflective tape of planting upper rear reflector is sent to dryer, by cut after drying reel, vanning be finished product.
The preparation technology of self-control PS resin: the waste foam claiming to make, wilkinite, aluminum oxide are added gas making tank successively, is warmed to 300 ~ ~ 400C °, is oxidized, flows out for subsequent use through cooling liquid; Then same methyl methacrylate, ethyl propenoate, butyl acrylate add in the reactor of belt stirrer, are warmed to 60 ~ ~ 80C °, start agitator, drip ethyl acetate and peroxidation toluyl molten thing altogether again, be warming up to 80 ~ ~ 85C °, be incubated 3 ~ ~ 4 hours, barrelling is for subsequent use.
The preparation technology of self-control aqueous assembly glue: the first step; 424 maleic resins that make and ethyl acetate mix and blend, dissolving will be claimed; Second step: raw material made for the first step claiming to make is added homogenizer, dispersing and mixing successively with benzene emulsion; 3rd step: second step is sent into sand mill through the material of dispersion, and through fine grinding, barrelling is for subsequent use.
embodiment 1
A kind of reflecting reticle of road band:
Take self-control PS resin 40 kilograms, self-control aqueous assembly glue 40 kilograms, ethenoid resin 10 kilograms, acrylic resin 2 kilograms, titanium dioxide 7 kilograms, talcum powder 45 kilograms, glass microballon 20 kilograms, ethyl acetate 15 kilograms, dioctyl ester 1.5 kilograms;
Preparation technology:
The first step: self-control PS resin, self-control aqueous assembly glue, ethenoid resin, acrylic resin, titanium dioxide, talcum powder, glass microballon, ethyl acetate, dioctyl ester are added in fine material mixer successively, fully stirs;
Second step: the raw materials technology that the first step is completed add in 400 type mills carry out mixing, be pressed into slug;
3rd step: by the slug of second step feeding rolling press, continuous calendering becomes thickness to be the basic finished product of 1-2mm;
4th step: the basic finished product of the 3rd step is gone on netted rail automatically and send band, through paint spray booth high pressure airless spray equipment, is sprayed on basic finished surface uniformly by self-control aqueous assembly glue;
5th step: by rail send band the basic finished product of the 4th step is delivered to ball-planting machine under, reflective glass beads is planted in glue on the surface uniformly, rail send band the finished product reflective tape of planting upper rear reflector is sent to dryer, by cut after drying reel, vanning be finished product.
Self-control PS resin:
Waste foam 95 kilograms, wilkinite 2 kilograms, 3 kilograms, aluminum oxide;
Preparation technology: the waste foam claiming to make, wilkinite, aluminum oxide are added gas making tank successively, is warmed to 300C ° of oxidation, flows out for subsequent use through cooling liquid; Then by above-mentioned raw material weighing 80 kilograms, methyl methacrylate 7 kilograms, ethyl propenoate 10 kilograms, butyl acrylate 3 kilograms add in the reactor of belt stirrer, be warmed to 60C °, start agitator, drip ethyl acetate and peroxidation toluyl molten thing altogether again, be warming up to 80C °, be incubated 3 hours, barrelling is for subsequent use.
Self-control aqueous assembly glue:
Benzene emulsion 60 kilograms, 424 maleic resin 5 kilograms, ethyl acetate 10.5 kilograms, deionized water 20 kilograms;
Preparation technology: the first step; 424 maleic resins that make and ethyl acetate mix and blend, dissolving will be claimed; Second step: raw material made for the first step claiming to make is added homogenizer, dispersing and mixing successively with benzene emulsion; 3rd step: second step is sent into sand mill through the material of dispersion, and through fine grinding 2 times, barrelling is for subsequent use.
embodiment 2
A kind of reflecting reticle of road band:
Take self-control PS resin 16 kilograms, self-control aqueous assembly glue 20 kilograms, ethenoid resin 21 kilograms, acrylic resin 3 kilograms, titanium dioxide 7 kilograms, talcum powder 80 kilograms, glass microballon 25 kilograms, ethyl acetate 14 kilograms, dioctyl ester 1.5 kilograms;
Preparation technology:
The first step: self-control PS resin, self-control aqueous assembly glue, ethenoid resin, acrylic resin, titanium dioxide, talcum powder, glass microballon, ethyl acetate, dioctyl ester are added in fine material mixer successively, fully stirs;
Second step: the raw materials technology that the first step is completed add in mill carry out mixing, be pressed into slug;
3rd step: by the slug of second step feeding rolling press, continuous calendering becomes thickness to be the basic finished product of 1-2mm;
4th step: the basic finished product of the 3rd step is gone on netted rail automatically and send band, through paint spray booth high pressure airless spray equipment, is sprayed on basic finished surface uniformly by self-control aqueous assembly glue;
5th step: by rail send band the basic finished product of the 4th step is delivered to ball-planting machine under, reflective glass beads is planted in glue on the surface uniformly, rail send band the finished product reflective tape of planting upper rear reflector is sent to dryer, by cut after drying reel, vanning be finished product.
Self-control PS resin:
Waste foam 100 kilograms, wilkinite 3 kilograms, 2 kilograms, aluminum oxide;
Preparation technology: the waste foam claiming to make, wilkinite, aluminum oxide are added gas making tank successively, be warmed to 400C ° dissolve after gasification, flow out for subsequent use through cooling, liquefaction; Then by above-mentioned raw material weighing 100 kilograms, methyl methacrylate 10 kilograms, ethyl propenoate 13 kilograms, butyl acrylate 4 kilograms add in the reactor of belt stirrer, be warmed to 80
C °, starts agitator, then drips ethyl acetate and peroxidation toluyl molten thing altogether, and be warming up to 85C °, be incubated 4 hours, barrelling is for subsequent use.
Self-control aqueous assembly glue:
Benzene emulsion 65 kilograms, 424 maleic resin 3 kilograms, ethyl acetate 7 kilograms, deionized water 15 kilograms;
Preparation technology: the first step; 424 maleic resins that make and ethyl acetate mix and blend, dissolving will be claimed; Second step: raw material made for the first step claiming to make is added homogenizer, dispersing and mixing successively with benzene emulsion; 3rd step: second step is sent into sand mill through the material of dispersion, and through fine grinding 3 times, barrelling is for subsequent use.
Raw material of the present invention have employed homemade PS resin and aqueous assembly glue is prepared from.Its beneficial effect is: instead of expensive macromolecule resin and natural rubber with the waste foam of cheapness, the pollution waste not only reasonably utilized, and decreases the discharge of polluting waste; Next is in propyl benzene emulsion, add ethyl acetate and 424 maleic resins, and that aqueous assembly glue is possessed is aseptic, dry, feature that adhesive property is excellent.
Above case study on implementation is only for illustration of the preferred embodiment of the present invention; but the present invention is not limited to above-mentioned embodiment; in the ken that described exercising ordinary skill possesses; the any amendment done within the spirit and principles in the present invention, equivalent to substitute and improvement etc., the protection domain of the application all should be considered as.
Claims (8)
1. a reflecting reticle of road band, it is characterized in that being made by following raw materials according:
Self-control PS resin, ethenoid resin, acrylic resin, titanium dioxide, talcum powder, glass microballon, ethyl acetate, dioctyl ester.
2. a kind of reflecting reticle of road band according to claim 1, is characterized in that: described self-control PS resin is made by following raw materials according, waste foam, wilkinite, aluminum oxide.
3. a kind of reflecting reticle of road band according to claim 1, is characterized in that: described self-control PS resin utilizes waste foam to be prepared from.
4. a kind of reflecting reticle of road band according to claim 1, is characterized in that: described self-control aqueous assembly glue is made by following raw materials according, benzene emulsion, 424 maleic resins, ethyl acetate, deionized water 20 kilograms.
5. a kind of reflecting reticle of road band according to claim 1, is characterized in that: described self-control aqueous assembly glue instead of original toluene tackiness agent.
6. a preparation technology for reflecting reticle of road band, is characterized in that, is to be prepared from by following method:
The first step: self-control PS resin, self-control aqueous assembly glue, ethenoid resin, acrylic resin, titanium dioxide, talcum powder, glass microballon, ethyl acetate, dioctyl ester are added in fine material mixer successively, fully stirs; Second step: the raw materials technology that the first step is completed add in mill carry out mixing, be pressed into slug; 3rd step: by the slug of second step feeding rolling press, continuous calendering becomes the basic finished product of desired thickness; 4th step: the basic finished product of the 3rd step is gone on netted rail automatically and send band, through paint spray booth high pressure airless spray equipment, is sprayed on basic finished surface uniformly by self-control aqueous assembly glue; 5th step: by rail send band the basic finished product of the 4th step is delivered to ball-planting machine under, reflective glass beads is planted in glue on the surface uniformly, rail send band the finished product reflective tape of planting upper rear reflector is sent to dryer, by cut after drying reel, vanning be finished product.
7. the preparation technology of a kind of reflecting reticle of road band according to claim 6, is characterized in that, described self-control PS resin is made by following method:
The waste foam claiming to make, wilkinite, aluminum oxide are added gas making tank successively, is warmed to 300 ~ ~ 400C °, is oxidized, flows out for subsequent use through cooling liquid; Then same methyl methacrylate, ethyl propenoate, butyl acrylate add in the reactor of belt stirrer, are warmed to 60 ~ ~ 80C °, start agitator, drip ethyl acetate and peroxidation toluyl molten thing altogether again, be warming up to 80 ~ ~ 85C °, be incubated 3 ~ ~ 4 hours, barrelling is for subsequent use.
8. the preparation technology of a kind of reflecting reticle of road band according to claim 6, is characterized in that, described self-control aqueous assembly glue is made by following method:
The first step; 424 maleic resins that make and ethyl acetate mix and blend, dissolving will be claimed; Second step: raw material made for the first step claiming to make is added homogenizer, dispersing and mixing successively with benzene emulsion; 3rd step: second step is sent into sand mill through the material of dispersion, and through fine grinding, barrelling is for subsequent use.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510225602.1A CN104774415A (en) | 2015-05-06 | 2015-05-06 | Road light-reflecting marking line belt and preparation process thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510225602.1A CN104774415A (en) | 2015-05-06 | 2015-05-06 | Road light-reflecting marking line belt and preparation process thereof |
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| Publication Number | Publication Date |
|---|---|
| CN104774415A true CN104774415A (en) | 2015-07-15 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510225602.1A Pending CN104774415A (en) | 2015-05-06 | 2015-05-06 | Road light-reflecting marking line belt and preparation process thereof |
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Citations (8)
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|---|---|---|---|---|
| CN1343815A (en) * | 2001-10-11 | 2002-04-10 | 郑国智 | Refective marker band prepared from waste or used plastics for road and its preparing process |
| CN2534182Y (en) * | 2001-05-19 | 2003-02-05 | 大连路明发光科技股份有限公司 | Resin film and plate with reflection & illumination function |
| CN1400573A (en) * | 2001-08-04 | 2003-03-05 | 大连路明发光科技股份有限公司 | Luminous-reflecting mark band and its making method |
| CN1604151A (en) * | 2004-11-05 | 2005-04-06 | 杨毅男 | Self-luminous fonts of various Chinese characters, Arabic numbers and English letters |
| CN1760458A (en) * | 2005-11-16 | 2006-04-19 | 辽宁警官高等专科学校 | Light-light reflecting road traffic marker band |
| CN101338152A (en) * | 2007-07-20 | 2009-01-07 | 潘东海 | Road reflective marker line coating |
| CN102675803A (en) * | 2012-05-23 | 2012-09-19 | 苏健 | Nanometer polymer composites traffic line mark |
| CN103694819A (en) * | 2013-11-29 | 2014-04-02 | 青岛科润塑料机械有限公司 | Road marking paint |
-
2015
- 2015-05-06 CN CN201510225602.1A patent/CN104774415A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2534182Y (en) * | 2001-05-19 | 2003-02-05 | 大连路明发光科技股份有限公司 | Resin film and plate with reflection & illumination function |
| CN1400573A (en) * | 2001-08-04 | 2003-03-05 | 大连路明发光科技股份有限公司 | Luminous-reflecting mark band and its making method |
| CN1343815A (en) * | 2001-10-11 | 2002-04-10 | 郑国智 | Refective marker band prepared from waste or used plastics for road and its preparing process |
| CN1604151A (en) * | 2004-11-05 | 2005-04-06 | 杨毅男 | Self-luminous fonts of various Chinese characters, Arabic numbers and English letters |
| CN1760458A (en) * | 2005-11-16 | 2006-04-19 | 辽宁警官高等专科学校 | Light-light reflecting road traffic marker band |
| CN101338152A (en) * | 2007-07-20 | 2009-01-07 | 潘东海 | Road reflective marker line coating |
| CN102675803A (en) * | 2012-05-23 | 2012-09-19 | 苏健 | Nanometer polymer composites traffic line mark |
| CN103694819A (en) * | 2013-11-29 | 2014-04-02 | 青岛科润塑料机械有限公司 | Road marking paint |
Non-Patent Citations (2)
| Title |
|---|
| 李和平 主编: "《精细化工原材料及中间体手册 胶黏剂》", 31 May 2005 * |
| 李子东 等编: "《胶黏剂助剂》", 28 February 2005 * |
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Application publication date: 20150715 |