CN2534182Y - Resin film and plate with reflection & illumination function - Google Patents

Resin film and plate with reflection & illumination function Download PDF

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Publication number
CN2534182Y
CN2534182Y CN 01264792 CN01264792U CN2534182Y CN 2534182 Y CN2534182 Y CN 2534182Y CN 01264792 CN01264792 CN 01264792 CN 01264792 U CN01264792 U CN 01264792U CN 2534182 Y CN2534182 Y CN 2534182Y
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China
Prior art keywords
combination
resin
plate
elements
layer
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Expired - Lifetime
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CN 01264792
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Chinese (zh)
Inventor
吕朝阳
孙淼鑫
姚增硕
胡煜宁
肖志国
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Dalian Luminglight Co Ltd
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Dalian Luminglight Co Ltd
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Priority to CN 01264792 priority Critical patent/CN2534182Y/en
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Abstract

A resin film and a resin plate respectively provided with a function of light reflection and irradiation is composed of a light reflection layer and an irradiation layer, wherein the light reflection layer is made of a micro glass ball, which can reflect the light, and the resin, alternatively made of crystal lattice resin light reflection film; the irradiation layer is made of the irradiation materials including silicate, aluminate and sulfide which are all activated by a variety of ions, and the resin. A variety of identifications and patterns made of the resin film and the resin plate are equipped with the functions of light reflection and irradiation. In the dark, the light irradiation can cause the light reflection layer to show clearly the identification and the pattern; after the light disappears, a self luminous function of the irradiation layer can perform an indication, suitable to be applied at safety fields of police garment, traffic mark, safety mark and life saving appliance, etc.

Description

Have reflective and resin molding, plate lighting function
What the utility model was related is functional resin film, the plate with photoluminescence effect and reflection action.
Use reflector at present in a large number as caution, sign, sign in traffic, security fields, under rayed, has catoptrical function, pattern shown in can very clearly seeing like this, but in the dark that illumination is removed, just be difficult to distinguish or cannot see at all pattern, also just do not have the effect of caution, safety; And the luminous mark of being made by the light-accumulating material that uses in security fields in recent years after irradiate light, has self light emission function in the dark, but when illumination owing to there is not reflection action can not clearly immediately manifest sign.
The purpose of this utility model is with existing reflective, functional resin film, plate that lighting function combines, makes this functional product have reflection function in irradiate light, has lighting function after irradiate light in the dark.
The utility model is a kind of functional tree adipose membrane that has the light sensation effect and have sign or pattern, plate, this functional membrane, the plate surface, the sign that constitutes by reflector layer and luminescent layer, pattern, in sign, the different sites of pattern, after illumination, its different sites has luminous or reflection function in the dark, it is by reflector layer (1) basically, photoluminescence layer (2) and basic unit (3) constitute, reflector layer and luminescent layer are by light reflecting material, luminescent material and resin are made, and the resin of use is: PVC, PE, PP, PET, one or more of PC etc.
The effect of reflector layer (1) is after this one deck is arrived in illumination, can reflect consumingly according to the light that comes, and be to make with reflective glass beads and resin, it consists of:
Reflective glass beads 5～80%
Resin 20～95% glass microballon particle diameters are very little, have only 1～200 μ m, if use the aluminized glass microballon of hemisphere face, its reflector layer reflecting effect of making is better.
The meticulous embossing lattice tapetum lucidum that the reflecting layer also can be made of resin reaches reflective purpose, and effect is fine, and especially the embossing lattice film reflecting effect of PVC material is good.
Luminescent layer (2) is to make with embedded photoluminescent material and resin, and it consists of
Embedded photoluminescent material 5～80%
Resin 20～95%
Embedded photoluminescent material is different kinds of ions activated silicate, aluminate, sulfide luminescent material or its mixture, and its main chemical constitution expression is respectively:
1, the chemical constitution expression of different kinds of ions activated silicate luminescent material is:
α?MO·βMO·γSiO 2·δR：Eu xLn y
Wherein M is a kind of element among Sr, Ca, Ba, the Zn or the combination of multiple element;
M is the combination of one or more elements among Mg, Cd, the Be;
R is B 2O 3, P 2O 5In one or both combination of compounds;
Ln is the combination of one or more elements among Nd, Dy, Ho, Tm, La, Pr, Tb, Ce, Er, Mn, Bi, Sn, the Sb:
α, β, γ, δ, x, y are mole coefficient,
0.6≤α≤6；0≤β≤5；1≤γ≤9；
0≤δ≤0.7；0.00001≤x≤0.2；0≤y≤0.3。
2, the main chemical constitution expression of different kinds of ions activated silicate luminescent material is:
(Sr 1-zCa z) 2MgSi 2O 7：Eu xLn y
Ln is the combination of one or more elements among La, Ce, Dy, Tm, Ho, Nd, Er, Sb, the Bi;
Z is coefficient: 0≤z≤1;
X, y are mole coefficient: 0.0001≤x≤0.2; 0.0001≤y≤0.3.
3, the main chemical constitution expression of different kinds of ions activated silicate luminescent material is:
(Sr 1-zCa z) 3MgSi 2O 8：Eu xLn y
Ln is the combination of one or more elements among La, Ce, Dy, Tm, Ho, Nd, Er, Sb, the Bi;
Z is coefficient: 0≤z≤1;
X, y are mole coefficient: 0.0001≤x≤0.2; 0.0001≤y≤0.3.
4, the main chemical constitution expression of different kinds of ions activated aluminate luminescent material is:
αMO·βAl 2O 3·γB 2O 3：Eu xLn y
Wherein M is the combination of one or more elements among Mg, Ca, Sr, Ba, Zn, the Cd;
Ln is the combination of one or more elements among Nd, Dy, Ho, Tm, La, Ce, Er, Pr, the Bi;
α, β, γ, x, y are mole coefficient,
0.5≤α≤6；0.5≤β≤9；0.0≤γ≤0.3；
0.00001≤x≤0.15；0.00001≤y≤0.2。
5, the main chemical constitution expression of different kinds of ions activated aluminate luminescent material is:
MAl 2O 4：Eu xLn y
Wherein Ln is the combination of one or more elements among La, Ce, Dy, Ho, Nd, the Er;
M is the combination of one or more elements among Sr, Ca, Mg, Ba, the Zn;
X, y are mole coefficient: 0.0001≤x≤0.15; 0.0001≤y≤0.2.
6, the main chemical constitution expression of different kinds of ions activated aluminate luminescent material is:
M 4Al 14O 25：Eu xLn y
Wherein Ln is the combination of one or more elements among Pr, Ce, Dy, Ho, Nd, the Er;
M is the combination of one or more elements among Sr, Ca, Mg, Ba, the Zn;
X, y are mole coefficient: 0.0001≤x≤0.15; 0.0001≤y≤0.2.
7, the main chemical constitution expression of different kinds of ions activated sulfide luminescent material is:
(Ca 1-zSr z)S：Eu xLn y
Wherein Ln is the combination of one or more elements among Er, Dy, La, Tm, the Y;
Z is a coefficient, 0≤z≤1;
X, y are mole coefficient: 0.00001≤x≤0.2; 0.00001≤y≤0.15.
8, the main chemical constitution expression of different kinds of ions activated sulfide luminescent material is:
R 2O 2S：Eu xLn y
Wherein R is the combination of one or more elements among Y, La, the Gd;
Wherein Ln is the combination of one or more elements among Er, Cr, Bi, Dy, Tm, Ti, Mg, Sr, Ca, Ba, the Mn; X, y are mole coefficient, wherein:
0.00001≤x≤0.2；0.0001≤y≤0.6
The structure of this functional membrane, plate can be: basic unit (resin molding, plate, leather, paper, fabric, wood, sheet metal etc.) on one deck luminescent layer is arranged, be the reflector layer that constitutes decorative pattern, pattern or sign as required on the luminescent layer, following luminescent layer (or transparent layer be covered with luminescent layer) is exposed in the part outside decorative pattern, pattern, the sign or its gap; Certainly, conversely, reflector layer before this in the basic unit is that the luminescent layer that has decorative pattern, pattern or sign also can be obtained same effect again; Also can be at above-mentioned wounded in the battle line, be coated with and cover not sign or the pattern made of luminescent material of one deck on the plate of case; Perhaps constitute the part of decorative pattern, pattern or sign in basic unit with luminescent material and resin, another part then constitutes with light reflecting material.If, can cover the layer of transparent film in the foreign side of this feature board in order to improve life-span and effect.
Sign, the pattern made with this functional membrane, plate have strong reflection light and lighting function, and a part that promptly constitutes sign, pattern is a reflector layer, can reflect when rayed according to the light that comes; And another part is a luminescent layer, and absorb light during illumination can be sent light when light is removed.As the indication of a kind of highway communication, sign board, its background is light luminescent layer, makes the main body pattern with the black reflector layer on it, and label plays common indicative function daytime; At night, when garage approached near label, the car headlight impinged upon on the label, and main body pattern energy strong reflection light shows its indicating graphic.When garage crossed label and do not have light-illuminating, the background parts of label was sent light, also can demonstrate its figure.The vehicle that travels after following or other vehicles do not have big light irradiation can see its sign clearly yet.Otherwise master pattern and background material therefor effect are as the same in the label.Because different luminescent materials can send the light of different colours, light of multiple colors such as that so the luminescent layer made from different luminescent materials can send respectively after illumination is red, orange, yellow, yellowish green, green, blue, bluish-green, purple, make functional membrane, plate more colorful, allow the user that more selection is arranged.This functional membrane, plate can be widely used in caution clothes, warning mark, traffic sign, safe life-saving, escape sign, and be underground or multistoried garage is capable, stop sign etc.
The utility model product has reflective and lighting function simultaneously, can be widely used in multiple field more, and its DEVELOPMENT PROSPECT is very wide, and this is that currently available products can't phase.
Accompanying drawing 1-8 is the luminescent film of various structures, the composition that hardens, and figure top is divided into regular figure, and the bottom is a sectional view.
Wherein, 1 is reflector layer, and 2 is luminescent layer, and 3 is basic unit, and 4 is non-luminous identification pattern.A is a soot layer among Fig. 6, and b is the lining aluminium lamination.
Example 1
A kind of reflective luminescent screen that has tartan, wherein the box-shaped grid has reflection function, and the square spacer bar has lighting function.Its structure is: material is one deck to be arranged by 50% aluminate luminescent material (SrAl in the basic unit of PVC 2O 4: Eu 0.05Dy 0.05) with the luminescent layer that the 50%PVC resin constitutes, be to be pressed with the reflector layer that quadrate is made with PVC lattice tapetum lucidum on the luminescent layer, the square spacer pieces partly is the transparent PVC film, what be covered with exposes luminescent layer.
This reflective luminescent screen because square partly has the strong reflect light effect, makes that decorative pattern very clearly displays on the whole plate during with light-illuminating in the dark; After closing lamp, parting bead partly sends the luminous decorative pattern that makes of stronger yellow-green colour and displays.Still high-visible after 2 hours.This routine product such as Fig. 1 example 2
With the reflective luminescent screen of example 1, there is the warning mark of the no turn of an avy blue at the position therebetween.As shown in Figure 2.Lamp according to the time or light reflective after moving or luminously can both show this sign fully aware ofly.Still obviously show after 2 hours.Example 3
The traffic mark plate.Material is one deck to be arranged by 25% aluminate luminescent material (Sr in the basic unit of PE plate 4Al 4O 25: Eu 0.05.Dy 0.05) and the luminescent layer that constitutes of 75%PVC resin, the reflective traffic sign that useful thereon 25% hemisphere face aluminum plating glass microballon and 75%PVC resin are made.As shown in Figure 3.Lamp according to the time and light can both know display mark after removing.Example 4
The reflective luminescent screen of tartan.Its structure is that the luminescent layer on the basal plate of PVC is by 85% sulfide luminescent material (Y 2O 2S:Eu 0.05Er 0.05) and the luminescent layer made of 15%PE resin, square partly is the reflector layer made from 75% hemisphere face aluminum plating glass microballon and 25%PE resin.Parting bead partly is that the luminescent layer of transparent film constitutes by revealing not between reflective square.Shown in accompanying drawing four.Square can be reflective strongly during illumination in the dark; And after light removed, parting bead presented orange-red fluorescent, also can show its decorative pattern.Example 5
The reflective luminescent screen of tartan, the square on the basal plate partly are by 75% silicate luminescent material (Sr 2MgSi 2O 7: Eu 0.05Dy 0.05) and 25%PP resin formation; Parting bead part then is the reflector layer that is made of 75% hemisphere face aluminum plating glass microballoon and 25%PP resin.As shown in Figure 5.Example 6
The reflective luminescent screen of tartan, material is to be the luminescent layer of being made by the PP material of 55% aluminate luminescent material and 45% in the basic unit of PP plate, constitute at the reflector layer of luminescent layer upper block by the glass microsphere of lining aluminium, the luminescent layer that reveals between square becomes parting bead, as shown in Figure 6.The luminous reflecting effect also can be satisfactory.Example 7
The light-emitting reflecting film of escape sign.Have one deck to make luminescent film by 50% aluminate luminescent material and 50%PVC on the adhesive tape of separating shaped paper having, having one deck that the tapetum lucidum of escape sign is arranged on the film is PVC lattice tapetum lucidum, and this tunic is except that the escape sign, and other positions all are transparent films.As shown in Figure 7.Example 8
Hexagonal Christmas tree pattern, reflective luminous zone.Wherein the hexagon blocky is a PVC lattice tapetum lucidum, and other parts are the luminescent layer that aluminate and resin constitute.As shown in Figure 8:

Claims (14)

1, a kind of functional resin film, plate that has the light sensation effect and have sign or pattern, it is characterized in that surface at film, plate, the sign that constitutes by reflector layer and luminescent layer, pattern is at its different sites, after illumination, have reflective or lighting function in the dark, it is made of reflector layer (1) luminescent layer (2) and basic unit (3) substantially:
Reflector layer is made up of reflective glass beads and resin, and proportion is: reflective glass beads is 5～80%, and resin is 20～95%;
Luminescent layer is made up of embedded photoluminescent material and resin, and proportion is: embedded photoluminescent material is 5～80%, and resin is 20～95%;
Embedded photoluminescent material is different kinds of ions activated silicate, aluminate, sulfide luminescent material or its miscellany, and used resin is one or more of PVC, PE, PP, PET, PC.
2, functional resin film as claimed in claim 1, plate is characterized in that glass microballon or the hemisphere face aluminized glass microballon of described reflective glass beads for lining aluminium.
3, functional resin film as claimed in claim 1, plate is characterized in that described reflector layer is the lattice resin tapetum lucidum with meticulous embossing, and this tapetum lucidum is with a kind of the making in PVC, PP, PE, PET, the PC material.
4, lattice resin tapetum lucidum as claimed in claim 3 is characterized in that it being the lattice tapetum lucidum of PVC type.
5, functional resin film as claimed in claim 1, plate is characterized in that described layer has luminescent material not to make outside reflector layer or luminescent layer sign or pattern.
6, as claim 1 or 5 described functional resin films, plate, it is characterized in that its skin has the resin molding of layer of transparent.
7, functional membrane as claimed in claim 1, plate is characterized in that the chemical constitution expression of described different kinds of ions activated silicate luminescent material is:
αMO·βMO·γSiO 2·δR：Eu xLn y
Wherein M is a kind of element among Sr, Ca, Ba, the Zn or the combination of multiple element:
M is the combination of one or more elements among Mg, Cd, the Be;
R is B 2O 3, P 2O 5In one or both combination of compounds;
Ln is the combination of one or more elements among Nd, Dy, Ho, Tm, La, Pr, Tb, Ce, Er, Mn, Bi, the Sn:
α, β, γ, δ, x, y are mole coefficient,
0.6≤α≤6；0≤β≤5；1≤γ≤9；
0≤δ≤0.7；0.00001≤x≤0.2；0≤y≤0.3。
8, different kinds of ions activated silicate luminescent material as claimed in claim 7 is characterized in that the chemical constitution expression is:
(Sr 1-zCa z) 2MgSi 2O 7：Eu xLn y
Ln is the combination of one or more elements among La, Ce, Dy, Tm, Ho, Nd, Er, Sb, the Bi;
Z is coefficient: 0≤z≤1;
X, y are mole coefficient: 0.0001≤x≤0.2; 0.0001≤y≤0.3.
9, different kinds of ions activated silicate luminescent material as claimed in claim 7 is characterized in that the chemical constitution expression is:
(Sr 1-zCa z) 3MgSi 2O 8：Eu xLn y
Ln is the combination of one or more elements among La, Ce, Dy, Tm, Ho, Nd, Er, Sb, the Bi;
Z is coefficient: 0≤z≤1;
X, y are mole coefficient: 0.0001≤x≤0.2; 0.0001≤y≤0.3.
10, functional membrane as claimed in claim 1, plate, its feature at the chemical constitution expression of described different kinds of ions activated aluminate luminescent material is:
αMO·βAL 2O 3·γB 2O 3：Eu xLn y
Wherein M is the combination of one or more yuan among Mg, Ca, Sr, Ba, Zn, the Cd;
Ln is the combination of one or more elements among Nd, Dy, Ho, Tm, La, Ce, Er, Pr, the Bi;
α, β, γ, x, y are mole coefficient,
0.5≤α≤6；0.5≤β≤9；0.0≤γ≤0.3；
0.00001≤x≤0.15；0.00001≤y≤0.2。
11, functional membrane as claimed in claim 1, plate is characterized in that the chemical constitution expression of described different kinds of ions activated aluminate luminescent material is:
MAl 2O 4：Eu xLn y
Wherein Ln is the combination of one or more elements among La, Ce, Dy, Ho, Nd, the Er;
M is the combination of one or more elements among Sr, Ca, Mg, Ba, the Zn;
X, y are mole coefficient: 0.0001≤x≤0.15; 0.0001≤y≤0.2.
12, functional membrane as claimed in claim 1, plate is characterized in that described different kinds of ions activated aluminate luminescent material, and its feature chemical constitution expression is:
M 4Al 14O 25：Eu xLn y
Wherein Ln is the combination of one or more elements among Pr, Ce, Dy, Ho, Nd, the Er;
M is the combination of one or more elements among Sr, Ca, Mg, Ba, the Zn;
X, y are mole coefficient: 0.0001≤x≤0.15; 0.0001≤y≤0.2.
13, functional membrane as claimed in claim 1, plate is characterized in that for the chemical constitution expression of different kinds of ions activated sulfide luminescent material being:
(Ca 1-zSr 2)S：Eu xLn y
Wherein Ln is the combination of one or more elements among Er, Dy, La, Tm, the Y;
Z is a coefficient, 0≤z≤1;
X, y are mole coefficient: 0.00001≤x≤0.2; 0.00001≤y≤0.15.
14, functional membrane as claimed in claim 1, plate is characterized in that it being that the chemical constitution expression of different kinds of ions activated sulfide is:
R 2O 2S：Eu xLn y
Wherein R is the combination of one or more elements among Y, La, the Gd;
Wherein Ln is the combination of one or more elements among Er, Cr, Bi, Dy, Tm, Ti, Mg, Sr, Ca, Ba, the Mn;
X, y are mole coefficient, wherein:
0.00001≤x≤0.2；0.0001≤y≤0.6
CN 01264792 2001-05-19 2001-09-14 Resin film and plate with reflection & illumination function Expired - Lifetime CN2534182Y (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 01264792 CN2534182Y (en) 2001-05-19 2001-09-14 Resin film and plate with reflection & illumination function

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CN01119136.8 2001-05-19
CN01119136 2001-05-19
CN 01264792 CN2534182Y (en) 2001-05-19 2001-09-14 Resin film and plate with reflection & illumination function

Publications (1)

Publication Number Publication Date
CN2534182Y true CN2534182Y (en) 2003-02-05

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104774415A (en) * 2015-05-06 2015-07-15 赵继福 Road light-reflecting marking line belt and preparation process thereof
CN105523720A (en) * 2015-12-28 2016-04-27 常熟市金亿复合材料有限公司 Heat insulation type hollow glass plate
CN109988569A (en) * 2019-05-08 2019-07-09 安徽中益新材料科技有限公司 Luminescent material, shine light-replenishing film, retroreflective light filling slice and road sign board

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104774415A (en) * 2015-05-06 2015-07-15 赵继福 Road light-reflecting marking line belt and preparation process thereof
CN105523720A (en) * 2015-12-28 2016-04-27 常熟市金亿复合材料有限公司 Heat insulation type hollow glass plate
CN109988569A (en) * 2019-05-08 2019-07-09 安徽中益新材料科技有限公司 Luminescent material, shine light-replenishing film, retroreflective light filling slice and road sign board

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Expiration termination date: 20110914

Granted publication date: 20030205