CN105860738A - Self-luminous road sign marking coating and application thereof - Google Patents
Self-luminous road sign marking coating and application thereof Download PDFInfo
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- CN105860738A CN105860738A CN201610420997.5A CN201610420997A CN105860738A CN 105860738 A CN105860738 A CN 105860738A CN 201610420997 A CN201610420997 A CN 201610420997A CN 105860738 A CN105860738 A CN 105860738A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D157/00—Coating compositions based on unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D157/02—Copolymers of mineral oil hydrocarbons
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/22—Luminous paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
Abstract
The invention provides a self-luminous road sign marking coating. The self-luminous road sign marking coating is prepared from, by weight, 0-30 parts of a road marking coating body I, 55-96 parts of a road marking coating body II and 4-15 parts of self-luminous microbeads. The self-luminous microbeads are prepared from, by weight, 70-95 parts of a microbead substrate and 5-30 parts of a self-luminous material, and the self-luminous material is an aluminate steady persistence material. The self-luminous microbeads have the advantage of being good in wear resistance and weather resistance due to the fact that the self-luminous material and the microbead substrate are integrally formed, the self-luminous material is dispersed in the microbead substrate, the microbead substrate has good mobility, and it is convenient to construct sign marking surfaces of various types.
Description
Technical field
The invention belongs to traffic engineering traffic paint preparing technical field, particularly to a kind of self-luminous road signs mark
Line coating and application thereof.
Background technology
In recent years, self-luminous road signs gage mark coating obtains in fields such as traffic signs, urban beautification, article of everyday use
Arrived promotion and application, but existing self-luminous road signs gage mark coating commonly exist pliability and wear-resisting,
The shortcoming of weatherability difference, is especially sprayed at plank or the road surface traffic mark as night traffic warning function
Will, as disclosed a kind of Green environment-friendlymultifunctional multifunctional energy-night-storagenano-grade nano-grade luminescent paint in Chinese patent literature
(CN102898880A).Under the conditions of being exposed to sunlight or sleet for a long time due to luminescent material, easily lose
Remove luminescent properties, and the film on surface is easy to cracking and occurs coming off.In order to solve Self-illumination road road sign
This shortcoming of will gage mark coating, the necessary self-luminous developing pliability, wearability and good weatherability
Highway sign and marking coating products.
Summary of the invention
To this end, the present invention is directed to the deficiency of the problems referred to above, it is provided that a kind of self-luminous function admirable self-luminous road
Identifier marking coating, containing low cost, is prone to industrialized production, has excellent pliability, wearability and resistance to
The self-luminous microballon that marquis's property is good.
The self-luminous road signs gage mark coating that the present invention provides, its component includes 0-30 part road by weight
Marking lines coating I, 55-96 part road mark paint II, and 4-15 part self-luminous microballon, wherein, described
The component of self-luminous microballon includes by weight: microballon substrate 58-135 part, self-luminescent material 5-30 part；
Described self-luminescent material is aluminate long afterglow materials, and described aluminate long afterglow materials is selected from
SrAl2O4: Eu, Dy and Sr4Al14O25: the one in Eu, Dy.
Preferably, described road mark paint I includes 5-30 part self-luminescent material, 15-40 by weight
Part resin I, 15-18 part quartz sand, 25-50 part Paris white, 2-6 part titanium dioxide, 1-2 part EVA hot melt
Glue, 15-18 part glass microballoon；
Described resin I is in C 5 petroleum resin, C 9 petroleum resin, epoxy resin or acrylic resin
One.
Preferably, described microballon substrate is high molecular polymer, and described self-luminous microballon includes following weight portion
The composition of number: high molecular polymer 70-95 part, self-luminescent material 5-30 part, wherein, described polyphosphazene polymer
Compound be polyethylene, polypropylene, polystyrene, polymethacrylates, thermoelastic one or more.
It is highly preferred that the preparation method of described self-luminous microballon is by described high molecular polymer and spontaneous finish
Material mixes in proportion, and then extrudes through double screw extruder, and pelletizing obtains.
Preferably, described microballon substrate is by 20-50 part titanium dioxide, 8-40 part zirconium dioxide and 30-45 part
Silicon dioxide forms.
It is highly preferred that described self-luminous microballon includes the composition of following parts by weight: 30 parts of titanium dioxide, 25-30
Part zirconium dioxide, 30-33 part silicon dioxide and 5-12 part self-luminescent material.
It is highly preferred that the preparation method of described self-luminous microballon is: by titanium dioxide, zirconium dioxide, dioxy
After SiClx and self-luminescent material are respectively through crushing, sieve, measuring, mix in proportion formation compound,
Mixed material heating is melted, continuously stirred in fusion process, sieve, i.e. obtain described self-luminous microballon.
Preferably, described road mark paint II is hot-melt traffic coatings, described road mark paint II
Component includes by weight: resin II 15-40 part, quartz sand 15-18 part, Paris white 25-50 part,
Titanium dioxide 2-6 part, EVA hot-melt adhesive 1-2 part, glass microballoon 15-18 part；
Described resin II is in C 5 petroleum resin, C 9 petroleum resin, epoxy resin or acrylic resin
One.
Preferably, described road mark paint II includes the matter of component A and B component, component A and B component
Amount ratio is 1-2:2-1,
Described component A includes the composition of following parts by weight: resin III 30-45 part, dispersant 0.2-0.6
Part, pigment 15-35 part, filler 10-35 part, UV absorbent 1-3 part, toughener 1-2.5 part；
Described B component includes the composition of following parts by weight: resin IV 30-45 part, dispersant 0.3-0.5
Part, pigment 25-45 part, filler 10-15 part, UV absorbent 1-3 part, toughener 1-2.5 part, Gu
Agent 0.5-5 part；
Described resin III is alkyl acrylate；Described resin IV is alkyl methacrylate；Described solidification
Agent is dibenzoyl peroxide；Described dispersant is unsaturated carboxylic acid polymer；Described pigment is rutile titanium
At least one in white lead, zinc oxide, Griffith's zinc white., chrome yellow, titan yellow；Described filler is calcium carbonate, sulphuric acid
At least one in barium, Pulvis Talci, Cab-O-sil；Described toughener is dioctyl phthalate or adjacent benzene
Dibutyl carboxylic acid；Described UV absorbent is Benzotriazole Ultraviolet Stabilizer.
The present invention provide self-luminous road signs gage mark coating be widely used, be mainly used in roadmarking,
The making of the mark of any one in tunnel inner wall, Bridge guardrail, anti-collision wall, traffic signs label.
The present invention also provides for the construction method of this self-luminous road signs gage mark coating, specifically includes following steps:
First determine that mark makes region, then determining that mark makes region and sprays described road mark paint
II, and described self-luminous microballon uniform spreading is spread on described road mark paint II, it is possible to spray the most again
It is coated with one layer of road mark paint I.
Time specifically used, it is possible to directly self-luminous microballon is added in bi-component road mark paint and use.
Self-luminous road signs gage mark coating, its yellow and the chromaticity of white self-luminous road signs gage mark coating
Coordinate table 1 below surrounded polygon in.
Each angle point chromaticity coordinate of table 1 self-luminescent material
The self-luminous microballon that the present invention provides, owing to self-luminescent material is one-body molded with microballon substrate, has resistance to
Mill property and the advantage of good weatherability, and self-luminescent material is scattered in microballon, and microballon has good flowing
Property, it is simple to construct in various types of highway sign and marking coating surfaces.This self-luminous microballon is applied to
In road sign will gage mark coating, efficiently solve traditional road identifier marking, cost height, wearability, weatherability
Difference, luminescent material is difficult to shortcomings such as mixing homogeneously, preparation and construction technology simply with coating, and cost of material is low,
It is prone to industrial scale produce.
Detailed description of the invention
In order to make those skilled in the art be more fully understood that, technical scheme can be practiced, below knot
The invention will be further described to close specific embodiment, but illustrated embodiment is not as a limitation of the invention.
Used below to for preparing self-luminous microballon and each composition of self-luminous road signs gage mark coating
It is commercially available in market.
Embodiment 1
A kind of marking lines self-luminous microballon, by by mass fraction ratio be: 30 parts of titanium dioxide, 30 parts of dioxies
Change zirconium, 30 parts of silicon dioxide and 10 parts of self-luminescent materials to make.
It is luminous that self-luminescent material therein uses rare earth aluminate long-afterglow material, also referred to as overlength afterglow
Powder, it irradiates about 10 minutes under the light sources such as natural light, daylight, light, and night or dark place are sustainable
Luminous more than 12 hours, concrete, this self-luminescent material was SrAl2O4: Eu, Dy, self-luminous intensity is high,
Its luminous angle point chromaticity coordinate is (0.420,0.540).
Concrete preparation method is as follows: by titanium dioxide, zirconium dioxide, silicon dioxide and self-luminescent material respectively
After crushing, sieve, measuring, mixing in proportion formation compound, compound heats in melting furnaces
Fusing, continuously stirred in fusion process, it is ensured that self-luminescent material is dispersed in vitreous humour, cross 60
Mesh number vibrosieve shapes, and i.e. obtains self-luminous microballon of the present invention.
Embodiment 2
A kind of marking lines self-luminous microballon, by by mass fraction ratio be: 30 parts of titanium dioxide, 25 parts of dioxies
Change zirconium, 33 parts of silicon dioxide and 12 parts of self-luminescent materials to make.This self-luminescent material is SrAl2O4: Eu, Dy,
Its luminous angle point chromaticity coordinate is (0.400,0.530).
Concrete preparation method is as follows: by titanium dioxide, zirconium dioxide, silicon dioxide and self-luminescent material respectively
After crushing, sieve, measuring, mixing in proportion formation compound, compound heats in melting furnaces
Fusing, continuously stirred in fusion process, it is ensured that self-luminescent material is dispersed in vitreous humour, cross 80
Mesh number vibrosieve shapes, and i.e. obtains self-luminous microballon of the present invention.
Embodiment 3
A kind of marking lines self-luminous microballon, by by mass fraction ratio be: 20 parts of titanium dioxide, 8 parts of dioxies
Change zirconium, 30 parts of silicon dioxide and 5 parts of self-luminescent materials to make.This self-luminescent material is SrAl2O4: Eu, Dy,
Its luminous angle point chromaticity coordinate is (0.450,0.490), and specific solution is with embodiment 1.
Embodiment 4
A kind of marking lines self-luminous microballon, by by mass fraction ratio be: 50 parts of titanium dioxide, 40 parts of dioxies
Change zirconium, 45 parts of silicon dioxide and 30 parts of self-luminescent materials to make.This self-luminescent material is SrAl2O4: Eu, Dy,
Its luminous angle point chromaticity coordinate is (0.275,0.300), and concrete preparation method is with embodiment 2.
Embodiment 5
A kind of marking lines self-luminous microballon, by by mass fraction ratio be: 95 parts of polymethacrylates and 5
Part self-luminescent material is made.This self-luminescent material is Sr4Al14O25: Eu, Dy, its luminous angle point chromaticity coordinate is
(0.265,0.290), concrete preparation method is: mixed in proportion with self-luminescent material by polymethacrylates
Close uniformly, then extrude through double screw extruder, pelletizing (pelletizing size and Semen setariae are suitable or less)
Arrive.
Embodiment 6
A kind of marking lines self-luminous microballon, by by mass fraction ratio be: 70 parts of polyethylene and 30 parts spontaneous
Luminescent material is made.This self-luminescent material be rare earth self-luminescent material be SrAl2O4: Eu, Dy, its luminous angle point color
Product coordinate is (0.390,0.545), and concrete preparation method is: mixed in proportion with self-luminescent material by polyethylene
Closing uniformly, then extrude through double screw extruder, pelletizing obtains.
The self-luminous road signs gage mark coating that the present invention provides, the group of this self-luminous road signs gage mark coating
Divide and include by weight: 0-30 part road mark paint I, 55-96 part road mark paint II, and 4-15
The self-luminous microballon that part embodiment 1-6 provides.
The product that above-mentioned road mark paint II can be existing purchase is used, i.e. in district to be identified
Territory first sprays one layer of existing road mark paint II, then self-luminous microballon is spread on road mark paint II
Surface.Can also directly spray after self-luminous microballon and road mark paint II mix homogeneously.
Bilayer can be used if desired, i.e. on the basis of above-mentioned construction completes, then spray one layer of roadmarking painting
Material I, concrete, road mark paint I can be by existing road mark paint and self-luminescent material mixing
Become.
It is used as road mark paint I and the component of road mark paint II that the present invention provides, the most such as
Shown in embodiment 7-9.
Embodiment 7
A kind of self-luminous road signs gage mark coating, its component includes by weight: road mark paint II
90 parts and self-luminous microballon 10 parts, wherein, described self-luminous microballon is obtained by embodiment 1.
Concrete, the component of this road mark paint II includes resin II 17 parts, quartz sand by weight
16 parts, Paris white 38 parts, glass microballoon 15 parts, titanium dioxide 2.5 parts, EVA hot-melt adhesive 1.5 parts；
Described resin II is commercially available C5 class road mark paint resin dedicated (C 5 petroleum resin).
During Specific construction, first construction line on roadmarking, then above-mentioned each raw material is put into blender
In, after heated scorification, continue to be uniformly mixed, carry out spraying preparation and there is the road surface of self-luminous performance
Graticule.Or other components in addition to self-luminous microballon are uniformly mixed, spray, then will be from
Luminous microballon uniform spreading is spread on described road mark paint also possible.
This pavement strip is faint yellow, flat appearance self-luminous intensity height.
Embodiment 8
A kind of self-luminous road signs gage mark coating, its component includes by weight: 20 parts of roadmarkings are coated with
Material I, 90 parts of road mark paints II and 10 parts of self-luminous microballons, wherein, described self-luminous microballon is for implementing
Obtained by example 2.
Wherein, described road mark paint I includes 20 parts of self-luminescent materials, 30 parts of acrylic acid by weight
Resin, 15 parts of quartz sand, 25 parts of Paris whites, 4 parts of titanium dioxides, 1EVA PUR, 15 parts of glass are micro-
Pearl.
Described road mark paint II is double-component (A+B), concrete,
Component A includes the composition of following parts by weight: resin III 45 parts, dispersant 0.6 part, pigment 35
Part, filler 35 parts, UV absorbent 3 parts, toughener 2.5 parts；
B component includes the composition of following parts by weight: resin IV 45 parts, dispersant 0.5 part, pigment 45
Part, filler 15 parts, UV absorbent 3 parts, toughener 2.5 parts, 5 parts of firming agent；
Above-mentioned component A is 1:1 with the mass ratio of B component.
Concrete, the concrete material for component A and B component selects, and resin III is alkyl acrylate；
Resin IV is alkyl methacrylate；Firming agent is dibenzoyl peroxide；Dispersant is unsaturated carboxylic acid
Polymer；Pigment is rutile titanium white lead；Filler is calcium carbonate；Toughener is dioctyl phthalate；
UV absorbent is Benzotriazole Ultraviolet Stabilizer.
During Specific construction, other compositions of firming agent and B component are mixed, is sufficiently stirred for, then component A
Mix with the B component proportioning with weight ratio as 1:1 and be sprayed at road surface, then self-luminous microballon is spread on road
The surface of gage mark coating；And the component of resin I is put in blender, after heated scorification, continue stirring
Mix homogeneously, is sprayed on the surface of pavement strip sprinkled with self-luminous microballon.
Pavement strip prepared by dual-component coating is the thinnest, and intensity is good, is particularly suitable for cold district such as China
The pavement strip of the Northeast makes.
Embodiment 9
A kind of self-luminous road signs gage mark coating, its component includes by weight: road mark paint II
85 parts and self-luminous microballon 10 parts, wherein, described self-luminous microballon is obtained by embodiment 5.
Wherein, component A includes the composition of following parts by weight: resin III 30 parts, dispersant 0.2 part, face
Expect 15 parts, filler 10 parts, UV absorbent 1 part, toughener 1 part；
B component includes the composition of following parts by weight: resin IV 30 parts, dispersant 0.3 part, pigment 25
Part, filler 10 parts, UV absorbent 1 part, toughener 1 part, 0.5 part of firming agent；
Above-mentioned component A is 1:2 with the mass ratio of B component.
Concrete, the concrete material for component A and B component selects, and resin III is alkyl acrylate；
Resin IV is alkyl methacrylate；Firming agent is dibenzoyl peroxide；Dispersant is unsaturated carboxylic acid
Polymer；Pigment is zinc oxide；Filler is barium sulfate；Toughener is dibutyl phthalate；Ultraviolet
Absorbent is Benzotriazole Ultraviolet Stabilizer.
During Specific construction, self-luminous microballon, component A are mixed homogeneously with B component and is sprayed at road surface.
Also first at one layer of existing traffic paint of road surface spray coating, then self-luminous microballon, component A can be mixed with B component
Uniformly and be sprayed at road surface.
Embodiment described above is only the preferred embodiment lifted by absolutely proving the present invention, and it protects model
Enclose and be not limited to this.The equivalent that those skilled in the art are made on the basis of the present invention substitutes or conversion,
All within protection scope of the present invention, protection scope of the present invention is as the criterion with claims.
Claims (10)
1. a self-luminous road signs gage mark coating, it is characterised in that described self-luminous highway sign and marking
The component of coating includes by weight: 0-30 part road mark paint I, 55-96 part road mark paint II,
And 4-15 part self-luminous microballon, wherein, the component of described self-luminous microballon includes by weight: microballon
Substrate 58-135 part, self-luminescent material 5-30 part；
Described self-luminescent material is aluminate long afterglow materials, and described aluminate long afterglow materials is selected from
SrAl2O4: Eu, Dy and Sr4Al14O25: the one in Eu, Dy.
Self-luminous road signs gage mark coating the most according to claim 1, it is characterised in that
Described road mark paint I includes 5-30 part self-luminescent material by weight, 15-40 part resin I,
15-18 part quartz sand, 25-50 part Paris white, 2-6 part titanium dioxide, 1-2 part EVA hot-melt adhesive, 15-18
Part glass microballoon；
Described resin I is in C 5 petroleum resin, C 9 petroleum resin, epoxy resin or acrylic resin
One.
Self-luminous road signs gage mark coating the most according to claim 2, it is characterised in that described micro-
Pearl substrate is high molecular polymer, and described self-luminous microballon includes the composition of following parts by weight: polyphosphazene polymer
Compound 70-95 part, self-luminescent material 5-30 part, wherein, described high molecular polymer be polyethylene, poly-third
Alkene, polystyrene, polymethacrylates, thermoelastic one or more.
Self-luminous road signs gage mark coating the most according to claim 2, it is characterised in that described micro-
Pearl substrate is made up of 20-50 part titanium dioxide, 8-40 part zirconium dioxide and 30-45 part silicon dioxide.
Self-luminous road signs gage mark coating the most according to claim 4, it is characterised in that described from
Luminous microballon includes the composition of following parts by weight: 30 parts of titanium dioxide, 25-30 part zirconium dioxide, 30-33
Part silicon dioxide and 5-12 part self-luminescent material.
Self-luminous road signs gage mark coating the most according to claim 4, it is characterised in that described from
The preparation method of luminous microballon is: by titanium dioxide, zirconium dioxide, silicon dioxide and self-luminescent material respectively
After crushing, sieve, measuring, mix in proportion formation compound, mixed material heating melted,
In fusion process continuously stirred, sieve, i.e. obtain described self-luminous microballon.
Self-luminous road signs gage mark coating the most according to claim 1, it is characterised in that described road
Marking lines coating II is hot-melt traffic coatings, and the component of described hot-melt traffic coatings includes by weight:
Resin II 15-40 part, quartz sand 15-18 part, Paris white 25-50 part, titanium dioxide 2-6 part, EVA heat
Melten gel 1-2 part, glass microballoon 15-18 part；
Described resin II is in C 5 petroleum resin, C 9 petroleum resin, epoxy resin or acrylic resin
One.
Self-luminous road signs gage mark coating the most according to claim 1, it is characterised in that described road
Marking lines coating II includes that component A and B component, component A are 1-2:2-1 with the mass ratio of B component,
Described component A includes the composition of following parts by weight: resin III 30-45 part, dispersant 0.2-0.6
Part, pigment 15-35 part, filler 10-35 part, UV absorbent 1-3 part, toughener 1-2.5 part；
Described B component includes the composition of following parts by weight: resin IV 30-45 part, dispersant 0.3-0.5
Part, pigment 25-45 part, filler 10-15 part, UV absorbent 1-3 part, toughener 1-2.5 part, Gu
Agent 0.5-5 part；
Described resin III is alkyl acrylate；Described resin IV is alkyl methacrylate；Described solidification
Agent is dibenzoyl peroxide；Described dispersant is unsaturated carboxylic acid polymer；Described pigment is rutile titanium
At least one in white lead, zinc oxide, Griffith's zinc white., chrome yellow, titan yellow；Described filler is calcium carbonate, sulphuric acid
At least one in barium, Pulvis Talci, Cab-O-sil；Described toughener is dioctyl phthalate or adjacent benzene
Dibutyl carboxylic acid；Described UV absorbent is Benzotriazole Ultraviolet Stabilizer.
Self-luminous road signs gage mark coating the most according to claim 1, it is characterised in that described from
Luminescent road identifier marking coating is applied to roadmarking, tunnel inner wall, Bridge guardrail, anti-collision wall, traffic
The making of the mark of any one in sign label.
The construction method of self-luminous road signs gage mark coating the most according to claim 1, its feature
It is, comprises the steps:
First determine that mark makes region, then make region in mark and spray described road mark paint II,
And described self-luminous microballon uniform spreading is spread on described road mark paint II, it is possible to spray one the most again
Layer road mark paint I.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610420997.5A CN105860738B (en) | 2016-06-13 | 2016-06-13 | A kind of self-luminous road sign gage mark coating and its application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610420997.5A CN105860738B (en) | 2016-06-13 | 2016-06-13 | A kind of self-luminous road sign gage mark coating and its application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105860738A true CN105860738A (en) | 2016-08-17 |
| CN105860738B CN105860738B (en) | 2018-03-23 |
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| CN107217581A (en) * | 2017-04-28 | 2017-09-29 | 长安大学 | A kind of construction technology of pavement marker or graticule |
| CN107254222A (en) * | 2017-06-09 | 2017-10-17 | 北京路安交通科技发展有限公司 | A kind of traffic paint and its production technology |
| CN107337904A (en) * | 2017-08-02 | 2017-11-10 | 上海浦兴路桥建设工程有限公司 | A kind of self-luminous ground surface material and compound method |
| CN107573777A (en) * | 2017-09-12 | 2018-01-12 | 天途路业集团有限公司 | A kind of hot melt type gage mark coating and preparation method thereof |
| CN108546506A (en) * | 2018-05-10 | 2018-09-18 | 重庆新康意安得达尔新材料有限公司 | A kind of anti-dazzle optical coating and preparation method thereof |
| CN109370323A (en) * | 2018-11-27 | 2019-02-22 | 浙江欧路德交通科技有限公司 | One kind highlighting reflective type hot-melt coating and preparation method thereof |
| CN109553330A (en) * | 2018-12-24 | 2019-04-02 | 上海同济检测技术有限公司 | Long-afterglow energy-accumulating luminescent road ground surface material and preparation method thereof |
| CN110452601A (en) * | 2019-08-24 | 2019-11-15 | 深圳市交通工程试验检测中心有限公司 | A kind of road mark paint and preparation method thereof |
| CN110564256A (en) * | 2019-09-20 | 2019-12-13 | 宁波职业技术学院 | Anti-cracking energy-storage self-luminous hot-melt road marking coating and preparation method and application thereof |
| CN110724431A (en) * | 2019-10-22 | 2020-01-24 | 厦门闽路通建设工程有限公司 | Road marking paint and preparation method thereof |
| CN113105804A (en) * | 2021-03-05 | 2021-07-13 | 广东美涂士建材股份有限公司 | Fluorescent colorful paint |
| CN115181486A (en) * | 2022-08-12 | 2022-10-14 | 武汉工程大学 | Long-afterglow self-luminous road marking paint and preparation method thereof |
| CN115975468A (en) * | 2022-12-09 | 2023-04-18 | 山东高速交通科技有限公司 | Durable hot-melt marking paint and preparation method thereof |
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Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107217581A (en) * | 2017-04-28 | 2017-09-29 | 长安大学 | A kind of construction technology of pavement marker or graticule |
| CN107254222A (en) * | 2017-06-09 | 2017-10-17 | 北京路安交通科技发展有限公司 | A kind of traffic paint and its production technology |
| CN107337904A (en) * | 2017-08-02 | 2017-11-10 | 上海浦兴路桥建设工程有限公司 | A kind of self-luminous ground surface material and compound method |
| CN107573777A (en) * | 2017-09-12 | 2018-01-12 | 天途路业集团有限公司 | A kind of hot melt type gage mark coating and preparation method thereof |
| CN108546506A (en) * | 2018-05-10 | 2018-09-18 | 重庆新康意安得达尔新材料有限公司 | A kind of anti-dazzle optical coating and preparation method thereof |
| CN109370323A (en) * | 2018-11-27 | 2019-02-22 | 浙江欧路德交通科技有限公司 | One kind highlighting reflective type hot-melt coating and preparation method thereof |
| CN109553330A (en) * | 2018-12-24 | 2019-04-02 | 上海同济检测技术有限公司 | Long-afterglow energy-accumulating luminescent road ground surface material and preparation method thereof |
| CN110452601A (en) * | 2019-08-24 | 2019-11-15 | 深圳市交通工程试验检测中心有限公司 | A kind of road mark paint and preparation method thereof |
| CN110564256A (en) * | 2019-09-20 | 2019-12-13 | 宁波职业技术学院 | Anti-cracking energy-storage self-luminous hot-melt road marking coating and preparation method and application thereof |
| CN110724431A (en) * | 2019-10-22 | 2020-01-24 | 厦门闽路通建设工程有限公司 | Road marking paint and preparation method thereof |
| CN110724431B (en) * | 2019-10-22 | 2021-06-01 | 厦门闽路通建设工程有限公司 | Road marking paint and preparation method thereof |
| CN113105804A (en) * | 2021-03-05 | 2021-07-13 | 广东美涂士建材股份有限公司 | Fluorescent colorful paint |
| CN115181486A (en) * | 2022-08-12 | 2022-10-14 | 武汉工程大学 | Long-afterglow self-luminous road marking paint and preparation method thereof |
| CN115975468A (en) * | 2022-12-09 | 2023-04-18 | 山东高速交通科技有限公司 | Durable hot-melt marking paint and preparation method thereof |
| CN115975468B (en) * | 2022-12-09 | 2023-10-31 | 山东高速交通科技有限公司 | Durable hot-melt marking paint and preparation method thereof |
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