CN107254222A - A kind of traffic paint and its production technology - Google Patents
A kind of traffic paint and its production technology Download PDFInfo
- Publication number
- CN107254222A CN107254222A CN201710434192.0A CN201710434192A CN107254222A CN 107254222 A CN107254222 A CN 107254222A CN 201710434192 A CN201710434192 A CN 201710434192A CN 107254222 A CN107254222 A CN 107254222A
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- traffic paint
- ketone
- paint according
- methoxyl group
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/22—Luminous paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to a kind of traffic paint and its production technology, its drip irrigation device is that in terms of mass fraction, its raw material includes：15~20 parts of acrylic resin, 50~55 parts of filler, 3.5~5 parts of titanium dioxide, 20~25 parts of bead, 0.8~1.2 part of PE resins, 0.6~1.1 part of EVA resin, 4~10 parts of luminescent material, 5,6,715 parts of trihydroxyflavones, 4', 715 parts of dihydroxy isoflavones, 4 methoxyl group 7H furans simultaneously 15 parts of 7 ketone of [3,2 g] chromene, 0.5 1.0 parts of auxiliary agent.The present invention not only have the advantages that illuminating at night, adhesive force are good, and its light do not influenceed by rainwater and moisture, stability of photoluminescence is good.This production technology improves the compression strength and wearability of the present invention.
Description
Technical field
The present invention relates to chemical industry paint vehicle technical field, in particular, it is related to a kind of traffic paint and its production work
Skill.
Background technology
Traffic paint is also referred to as pavement marker paint, to driving safely, relieving traffic congestion, judging that traffic accident responsibility etc. is played
Important function, it can also be used to playground runway, the occasion such as facility floor region division.But the traffic paint majority used at present is
Solvent-borne type or heat reflow paint with reflection function, such as point-like rainy night reflector marking material and novel wear resistant reflective road mark
Paint, the general function of not having noctilucence.But, if without street lamp on road, can only be to there be gaffer at paint marking night
The vehicle of tool plays a role, and can not then play its effect substantially for pedestrian and cyclist without illuminations.
The traffic paint of noctilucence is one kind of luminous paint.Luminous paint is also referred to as light-accumulated luminous coating, and it is in visible ray
Energy is absorbed when irradiation, in the dark can self-luminescence.So in dark evening, the visuality of luminescent coating is much higher than
Common gage mark coating.
Existing authorized announcement date be 2017.01.04, Authorization Notice No. be CV104263153B disclose a kind of accumulating type from
Illuminant nanometer coating (hereinafter referred to as documents), it separates nano material or groups of nanostructures into organic coating, comprehensive
The advantage of both organic polymer and inorganic structure component, make coating property have wear-resisting, service life length and while have to
The effect of imperial bacterium.
But, the accumulating type self-luminous nano paint in documents is in use due to the influence of rainwater and moisture
Sometimes become clear sometimes dim, deficient in stability.
The content of the invention
The purpose of the present invention one is to provide a kind of traffic paint not only have the advantages that illuminating at night, adhesive force are good,
And its it is luminous do not influenceed by rainwater and moisture, stability of photoluminescence is good.
The present invention above-mentioned purpose one technical scheme is that：
A kind of traffic paint, in terms of mass fraction, its raw material includes：15~20 parts of acrylic resin, 50~55 parts of filler, titanium
3.5~5 parts of white powder, 20~25 parts of bead, 0.8~1.2 part of PE resins, 0.6~1.1 part of EVA resin, luminescent material 4~10
Part, 1-5 parts of 5,6,7- trihydroxyflavones, 4', 1-5 parts of 7- dihydroxy isoflavones, 4- methoxyl group -7H- furans simultaneously [3,2-g] benzo
1-5 parts of pyrans -7- ketone, 0.5-1.0 parts of auxiliary agent.
Preferably, the Noroxylin,5,6,7-Trihydroxy flavone, 4', 7- dihydroxy isoflavones and 4- methoxyl group -7H- furans are simultaneously
The weight ratio of [3,2-g] chromene -7- ketone is 2：2~3：3~2.
Preferably, the Noroxylin,5,6,7-Trihydroxy flavone, 4', 7- dihydroxy isoflavones and 4- methoxyl group -7H- furans are simultaneously
The weight ratio of [3,2-g] chromene -7- ketone is 2：2.5：2.5.
Preferably, the luminescent material is accumulating type self-luminescent material.
Preferably, the auxiliary agent includes thickener, coalescents, dispersant, defoamer and bactericide, the thickening
Agent, coalescents, dispersant, the weight ratio of defoamer and bactericide are 1:1:1:1:1.
Preferably, the defoamer is SP-01 defoamers, and the dispersant is P-01 dispersants, the coalescents
For Lauryl Alcohol fat, the bactericide is many clever bacterium, and the thickener is polyacrylic acid.
Preferably, the filler is bentonite.
Preferably, the particle diameter of the glass microballoon is 0.3~0.35mm.
The purpose of the present invention two is the preparation method for providing above-mentioned traffic paint, can improve traffic paint of the present invention
Compression strength and wearability.
The present invention above-mentioned purpose two technical scheme is that：
A kind of technique for producing traffic paint described above, comprises the following steps：
Step a：By luminescent material, 5,6,7- trihydroxyflavones, 4', 7- dihydroxy isoflavones and 4- methoxyl group -7H- furans are simultaneously
[3,2-g] chromene -7- ketone is well mixed, and obtains mixture；
Step b：After the filler of 1/3 parts by weight, acrylic resin, PE resins, EVA resin are well mixed with auxiliary agent first, stirring
Titanium dioxide, mixture, bead and remaining filler are added sequentially under the conditions of mixing again, is stirred.
Compared with prior art, the invention has the advantages that：
1st, traffic paint of the present invention not only has the advantages that illuminating at night, adhesive force are good, and it is luminous not by rainwater and wet
The influence of gas, stability of photoluminescence is good.Wherein, Noroxylin,5,6,7-Trihydroxy flavone, 4', 7- dihydroxy isoflavones and 4- methoxyl group -7H- furans
Simultaneously [3,2-g] chromene -7- ketone of muttering can improve the stability of photoluminescence of traffic paint of the present invention, and be produced during three's compounding
Cooperative effect.
2nd, 5,6,7- trihydroxyflavones, 4', 7- dihydroxy isoflavones and 4- methoxyl group -7H- furans simultaneously [3,2-g] benzo pyrrole
- 7- ketone of muttering can improve the compression strength and wearability of traffic paint of the present invention, and produce cooperative effect during three's compounding.
3rd, 5,6,7- trihydroxyflavones, 4', 7- dihydroxy isoflavones and 4- methoxyl group -7H- furans simultaneously [3,2-g] benzo
After the premixing of pyrans -7- ketone, then mixed with luminescent material, can further improve the pressure resistance of traffic paint of the present invention
Degree and wearability.
Embodiment
The present invention is described in further detail with reference to embodiments.It should be understood that described in the embodiment of the present invention
Preparation method is only used for the explanation present invention, rather than limitation of the present invention, to this hair under the concept thereof of the present invention
The simple modifications of bright preparation method belong to the scope of protection of present invention.
The raw material sources of table 1
List of ingredients (the unit of the embodiment of table 2：Kg)
The traffic paint of embodiment 1 to 6, is obtained using following technique productions.
The preparation method of traffic paint, comprises the following steps：Step a：By 5,6,7- trihydroxyflavones, 4', 7- dihydroxies
Simultaneously [3,2-g] chromene -7- ketone is well mixed for base isoflavones and 4- methoxyl group -7H- furans, adds luminescent material mixing equal
It is even, obtain mixture；Step b：The filler of 1/3 parts by weight, acrylic resin, PE resins, EVA resin are well mixed with auxiliary agent first
Afterwards, titanium dioxide, mixture, bead and remaining filler are added sequentially again under agitation, is stirred.
Comparative example 1：The difference of comparative example 1 and embodiment 4 is, is not added with Noroxylin,5,6,7-Trihydroxy flavone.
Comparative example 2：The difference of comparative example 2 and embodiment 4 is, is not added with 4', 7- dihydroxy isoflavones.
Comparative example 3：The difference of comparative example 2 and embodiment 4 is, is not added with 4- methoxyl group -7H- furans simultaneously [3,2-g] benzene
And pyrans -7- ketone.
Comparative example 4：The difference of comparative example 4 and embodiment 4 is that both technique productions are different, and the road of comparative example 4 is drawn
The production technology of line paint：Comprise the following steps：Step a：By 5,6,7- trihydroxyflavones, 4', 7- dihydroxy isoflavones, 4- methoxies
Simultaneously [3,2-g] chromene -7- ketone and luminescent material are well mixed for base -7H- furans, obtain mixture A；
Step b：After the filler of 1/3 parts by weight, acrylic resin, PE resins, EVA resin are well mixed with auxiliary agent first, stirring
Titanium dioxide, mixture A, bead and remaining filler are added sequentially under the conditions of mixing again, is stirred.
Comparative example 5：The difference of comparative example 5 and embodiment 4 is that both technique productions are different, and the road of comparative example 5 is drawn
The production technology of line paint：Step a：By 5,6,7- trihydroxyflavones, 4', 7- dihydroxy isoflavones and 4- methoxyl group -7H- furans are simultaneously
[3,2-g] chromene -7- ketone is well mixed, and obtains mixture B；Step b：First the filler of 1/3 parts by weight, acrylic resin,
After PE resins, EVA resin are well mixed with auxiliary agent, be added sequentially again under agitation titanium dioxide, mixture B, luminescent material,
Bead and remaining filler, stir.
Comparative example 6：The difference of comparative example 6 and embodiment 4 is that both technique productions are different, and the road of comparative example 6 is drawn
The production technology of line paint：Step a：By 5,6,7- trihydroxyflavones, 4', 7- dihydroxy isoflavones and 4- methoxyl group -7H- furans are simultaneously
[3,2-g] chromene -7- ketone is well mixed, and obtains mixture B；Step b：First the filler of 1/3 parts by weight, acrylic resin,
After PE resins, EVA resin are well mixed with auxiliary agent, be added sequentially again under agitation titanium dioxide, luminescent material, mixture B,
Bead and remaining filler, stir.
Comparative example 7：Embodiment 1 in documents (CV104263153B), a kind of accumulating type self-luminous nano paint, bag
Include the component of following parts by weight：35 parts of perforate expanded perlite, 65 parts of calcium titanate, 35 parts of rosin, 18 parts of glass microballoon, crust
15 parts of element, 18 parts of chitosan, 30 parts of nanometer titanium dioxide, 18 parts of nano zine oxide, 13 parts of nano silicon oxide, 35 parts of styrene-acrylic emulsion
(particle diameter is 0.15 μm) and 18 parts of Nano Rare soil nature self-luminescent material.Its preparation method is as follows：The perforate of formula ratio is expanded precious
Zhu Yan, calcium titanate, rosin, chitin and chitosan are mixed to join in mixer, and 1h is stirred at 35 DEG C, obtain A mixed liquors；
The glass microballoon of formula ratio, nanometer titanium dioxide, nano zine oxide, nano silicon oxide, styrene-acrylic emulsion and Nano Rare soil nature is spontaneous
Luminescent material is mixed to join in mixer, and 1h is stirred under normal temperature, obtains B liquid, and obtained A liquid is added in B liquid, stirring
0.5h, obtains accumulating type self-luminous nano paint.
The detection of traditional performance is carried out for embodiment 1~6, testing result is shown in Table 3.
The testing result of the traditional performance of 3 embodiment of table 1~6
The detection of traditional performance is carried out for comparative example 1~6, testing result is shown in Table 4.
The testing result of the traditional performance of 4 comparative example of table 1~6
According to the data analysis in table 3 and table 4, the traditional performance of embodiment 1~6 and comparative example 1~6 meets JT/T280-
2004《Pavement marking paint》Requirement.
Comparative example 4 and comparative example 1~3 understand, Noroxylin,5,6,7-Trihydroxy flavone, 4', 7- dihydroxy isoflavones and 4- first
Simultaneously [3,2-g] chromene -7- ketone can improve the compression strength and wearability of traffic paint of the present invention to epoxide -7H- furans,
And produce cooperative effect during three's compounding.
Comparative example 4 and comparative example 4~6 understand, Noroxylin,5,6,7-Trihydroxy flavone, 4', 7- dihydroxy isoflavones and 4-
Methoxyl group -7H- furans is mixed simultaneously after the premixing of [3,2-g] chromene -7- ketone, then with luminescent material, can be further
Improve the compression strength and wearability of traffic paint of the present invention.
Choose embodiment 4 and the luminous model of the coating of comparative example 1~7 carries out the experiment of noctilucence road mark coating, estimate it
Stability of photoluminescence, experimental result is shown in Table 5.
Painting method is：By paint heating to 200 DEG C, constructed after after coating melting using special hot melting scribing machine, construction
After spontaneously dry, you can film-forming, the thickness of film is 1500 μm.
The experimental result of the stability of photoluminescence of table 5
| Experimental project | Night is without rain | Rainy day at night |
| Embodiment 4 | Without significant change | Without significant change |
| Comparative example 1 | Without significant change | Sometimes become clear sometimes dim |
| Comparative example 2 | Without significant change | Sometimes become clear sometimes dim |
| Comparative example 3 | Without significant change | Sometimes become clear sometimes dim |
| Comparative example 4 | Without significant change | Without significant change |
| Comparative example 5 | Without significant change | Without significant change |
| Comparative example 6 | Without significant change | Without significant change |
| Comparative example 7 | Without significant change | Sometimes become clear sometimes dim |
It can be seen from the experimental result in table 5, the luminous of traffic paint of the present invention is not influenceed by rainwater and moisture, is lighted steady
It is qualitative good.
Comparative example 5 and comparative example 1~3 understand, Noroxylin,5,6,7-Trihydroxy flavone, 4', 7- dihydroxy isoflavones and 4- first
Simultaneously [3,2-g] chromene -7- ketone can improve the stability of photoluminescence of traffic paint of the present invention, and three to epoxide -7H- furans
Cooperative effect is produced during compounding.
Claims (9)
1. a kind of traffic paint, it is characterised in that in terms of mass fraction, its raw material includes：15~20 parts of acrylic resin, fill out
Material 50~55 parts, 3.5~5 parts of titanium dioxide, 20~25 parts of bead, 0.8~1.2 part of PE resins, 0.6~1.1 part of EVA resin,
4~10 parts of luminescent material, 1~5 part of Noroxylin,5,6,7-Trihydroxy flavone, 4', 1~5 part of 7- dihydroxy isoflavones, 4- methoxyl group -7H- furans
Mutter simultaneously 1~5 part of [3,2-g] chromene -7- ketone, 0.5~1.0 part of auxiliary agent.
2. traffic paint according to claim 1, it is characterised in that the Noroxylin,5,6,7-Trihydroxy flavone, 4', 7- dihydroxies
The weight ratio of base isoflavones and 4- methoxyl group -7H- furans simultaneously [3,2-g] chromene -7- ketone is 2：2~3：3~2.
3. traffic paint according to claim 2, it is characterised in that the Noroxylin,5,6,7-Trihydroxy flavone, 4', 7- dihydroxies
The weight ratio of base isoflavones and 4- methoxyl group -7H- furans simultaneously [3,2-g] chromene -7- ketone is 2：2.5：2.5.
4. traffic paint according to claim 1, it is characterised in that the luminescent material is the spontaneous finish of accumulating type
Material.
5. traffic paint according to claim 1, it is characterised in that the auxiliary agent includes thickener, coalescents, divided
Powder, defoamer and bactericide, the thickener, coalescents, dispersant, the weight ratio of defoamer and bactericide are 1:1:1:
1:1。
6. traffic paint according to claim 5, it is characterised in that the defoamer is SP-01 defoamers, described point
Powder is P-01 dispersants, and the coalescents are Lauryl Alcohol fat, and the bactericide is many clever bacterium, and the thickener is poly- third
Olefin(e) acid.
7. traffic paint according to claim 1, it is characterised in that the filler is bentonite.
8. traffic paint according to claim 1, it is characterised in that the particle diameter of the glass microballoon is 0.3~
0.35mm。
9. a kind of technique for producing the traffic paint in claim 1 to 8 described in any one, it is characterised in that including such as
Lower step：
Step a：By 5,6,7- trihydroxyflavones, 4', 7- dihydroxy isoflavones and 4- methoxyl group -7H- furans simultaneously [3,2-g] benzo
Pyrans -7- ketone is well mixed, and is added luminescent material and is well mixed, obtains mixture；
Step b：After the filler of 1/3 parts by weight, acrylic resin, PE resins, EVA resin are well mixed with auxiliary agent first, stirring
Titanium dioxide, mixture, bead and remaining filler are added sequentially under the conditions of mixing again, is stirred.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710434192.0A CN107254222A (en) | 2017-06-09 | 2017-06-09 | A kind of traffic paint and its production technology |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710434192.0A CN107254222A (en) | 2017-06-09 | 2017-06-09 | A kind of traffic paint and its production technology |
Publications (1)
| Publication Number | Publication Date |
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| CN107254222A true CN107254222A (en) | 2017-10-17 |
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ID=60023939
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710434192.0A Pending CN107254222A (en) | 2017-06-09 | 2017-06-09 | A kind of traffic paint and its production technology |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109251614A (en) * | 2018-08-24 | 2019-01-22 | 河北晨阳工贸集团有限公司 | A kind of aqueous road paint marking and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101016436A (en) * | 2007-02-28 | 2007-08-15 | 周鹏 | Hot melt type vibration gage mark coating |
| CN104629568A (en) * | 2015-02-04 | 2015-05-20 | 陕西世纪交通工程有限公司 | Full-color three-dimensional self-luminous road line paint and preparation method thereof |
| CN104845485A (en) * | 2015-04-15 | 2015-08-19 | 吉安市永安交通设施有限公司 | Formula and preparation method of road marked line coating |
| CN105860738A (en) * | 2016-06-13 | 2016-08-17 | 张悦 | Self-luminous road sign marking coating and application thereof |
-
2017
- 2017-06-09 CN CN201710434192.0A patent/CN107254222A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101016436A (en) * | 2007-02-28 | 2007-08-15 | 周鹏 | Hot melt type vibration gage mark coating |
| CN104629568A (en) * | 2015-02-04 | 2015-05-20 | 陕西世纪交通工程有限公司 | Full-color three-dimensional self-luminous road line paint and preparation method thereof |
| CN104845485A (en) * | 2015-04-15 | 2015-08-19 | 吉安市永安交通设施有限公司 | Formula and preparation method of road marked line coating |
| CN105860738A (en) * | 2016-06-13 | 2016-08-17 | 张悦 | Self-luminous road sign marking coating and application thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109251614A (en) * | 2018-08-24 | 2019-01-22 | 河北晨阳工贸集团有限公司 | A kind of aqueous road paint marking and preparation method thereof |
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Application publication date: 20171017 |