CN105860421A - High-impact-resistant ABS composite material - Google Patents
High-impact-resistant ABS composite material Download PDFInfo
- Publication number
- CN105860421A CN105860421A CN201610406634.6A CN201610406634A CN105860421A CN 105860421 A CN105860421 A CN 105860421A CN 201610406634 A CN201610406634 A CN 201610406634A CN 105860421 A CN105860421 A CN 105860421A
- Authority
- CN
- China
- Prior art keywords
- composite material
- abs composite
- impact
- acrylonitrile
- styrene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a high-impact-resistant ABS composite material which is prepared from an acrylonitrile-butadiene-styrene grafted copolymer, styrene-acrylonitrile, inorganic filler, additive and the like in a mixed mode. According to the high-impact-resistant ABS composite material, the acrylonitrile-butadiene-styrene grafted copolymer is selected as the main material, nano calcium carbonate and titanium dioxide are added as the additive of the composite material, the surface of the titanium dioxide is treated, and the composite material capable of being better dispersed can be obtained. The composite material has higher impact strength and whiteness and meets application requirements of the market for white household appliances.
Description
Technical field
The present invention relates to Material Field, be specifically related to a kind of high-impact ABS composite material.
Background technology
In recent years, the market demand of white domestic appliances has been promoted along with the update of household appliances.ABS resin conduct
The fifth-largest general-purpose plastics in the world and widest Plastics Toughening by Rubber are due to butadiene styrene and the knot of 3 kinds of components of acrylonitrile
Close, have complementary advantages so that ABS resin can carry out the adjustment of the multiple trade mark because producing actual needs, HI high impact,
High glaze, the several functions shaped material such as heat-resisting and fire-retardant are widely used.
Titanium dioxide has the features such as stable physics, chemical property and excellent whiteness, tinting strength, tinting power, covering power and heat resistance,
It is widely used in the industry such as coating, plastics, papermaking, printing-ink, chemical fibre, rubber, cosmetics.The appearance of composite, will
The inorganic nano-particle with rigidity is filled in polymer substrate, be a kind of improve polymer resin material performance have efficacious prescriptions
Method.But, substantial amounts of experimental fact proves, simply inorganic filler and organic matter is blended the improvement to polymer performance and fails to understand
Aobvious, the most also can reduce the toughness of polymer.
Summary of the invention
Present invention aim at, it is provided that a kind of high-impact ABS composite material, the technical solution adopted in the present invention is:
A kind of high-impact ABS composite material, it is characterised in that be mixed with by weight percentage by following components and form:
Butadiene-styrene-acrylonitrile graft copolymer 30-50 part
Styrene-acrylonitrile 5-10 part
Inorganic filler 50-70 part
Auxiliary agent 2-5 part.
One of preferably, described inorganic filler is by nano-calcium carbonate, nanometer titanium dioxide, ultra-fine sulfuric acid
Barium is 5:1:2 mixing composition according to percentage by weight.
One of preferably, described inorganic filler processes through titanate coupling agent surface.
One of preferably, described auxiliary agent includes ethylene bis stearamide, magnesium stearate.
The present invention provides the benefit that relative to prior art: the high-impact ABS composite material of the present invention, selects fourth two
Alkene-styrene-acrylonitrile graft copolymer is as main material, and adds nano-calcium carbonate, and titanium dioxide is as composite
Dose, and the surface of titanium dioxide is processed, can obtain disperseing more preferable composite, this composite has
Higher impact strength and whiteness, adapt to the market application needs to white household appliances.
Detailed description of the invention
Below with reference to embodiment, the design of the present invention and the technique effect of generation are clearly and completely described, with
It is completely understood by the purpose of the present invention, feature and effect.Obviously, described embodiment is the part enforcement of the present invention
Example rather than all embodiment, based on embodiments of the invention, those skilled in the art is not before paying creative work
Put other embodiments obtained, belong to the scope of protection of the invention.
Embodiment 1: a kind of high-impact ABS composite material, it is characterised in that mixed system by following components by weight percentage
For forming:
Butadiene-styrene-acrylonitrile graft copolymer 35 parts
Styrene-acrylonitrile 7 parts
Inorganic filler 55 parts
Auxiliary agent 3 parts.
Embodiment 2: a kind of high-impact ABS composite material, it is characterised in that mixed system by following components by weight percentage
For forming:
Butadiene-styrene-acrylonitrile graft copolymer 33 parts
Styrene-acrylonitrile 7 parts
Nano-calcium carbonate 40 parts
Nanometer titanium dioxide 8 parts
Ultra-fine barium sulfate 16 parts
Ethylene bis stearamide 1 part
Magnesium stearate 3 parts.
Above the better embodiment of the present invention is illustrated, but the invention is not limited to described
Embodiment, those of ordinary skill in the art also can make all equivalent changes on the premise of spirit of the present invention
Type or replacement, modification or the replacement of these equivalents are all contained in the application claim limited range.
Claims (4)
1. a high-impact ABS composite material, it is characterised in that be mixed with by weight percentage by following components and form:
Butadiene-styrene-acrylonitrile graft copolymer 30-50 part
Styrene-acrylonitrile 5-10 part
Inorganic filler 50-70 part
Auxiliary agent 2-5 part.
High-impact ABS composite material the most according to claim 1, it is characterised in that described inorganic filler is by nano-sized carbon
Acid calcium, nanometer titanium dioxide, ultra-fine barium sulfate is 5:1:2 mixing composition according to percentage by weight.
High-impact ABS composite material the most according to claim 1, it is characterised in that described inorganic filler is even through titanate esters
Connection agent surface processes.
High-impact ABS composite material the most according to claim 1, it is characterised in that described auxiliary agent includes that ethylene is double hard
Acyl amine, magnesium stearate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610406634.6A CN105860421A (en) | 2016-06-12 | 2016-06-12 | High-impact-resistant ABS composite material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610406634.6A CN105860421A (en) | 2016-06-12 | 2016-06-12 | High-impact-resistant ABS composite material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105860421A true CN105860421A (en) | 2016-08-17 |
Family
ID=56677435
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610406634.6A Pending CN105860421A (en) | 2016-06-12 | 2016-06-12 | High-impact-resistant ABS composite material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105860421A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018187616A1 (en) * | 2017-04-06 | 2018-10-11 | Sabic Global Technologies B.V. | Improved abs resin composition for additive manufacturing |
| CN110372986A (en) * | 2019-07-10 | 2019-10-25 | 铜陵新港塑胶制品有限公司 | A kind of preparation method of flame-proof ABS alloy |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104910539A (en) * | 2015-05-18 | 2015-09-16 | 中国石油天然气股份有限公司吉林石化分公司 | High-impact while household electrical appliance ABS composite material and preparation method therefor |
-
2016
- 2016-06-12 CN CN201610406634.6A patent/CN105860421A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104910539A (en) * | 2015-05-18 | 2015-09-16 | 中国石油天然气股份有限公司吉林石化分公司 | High-impact while household electrical appliance ABS composite material and preparation method therefor |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018187616A1 (en) * | 2017-04-06 | 2018-10-11 | Sabic Global Technologies B.V. | Improved abs resin composition for additive manufacturing |
| CN110372986A (en) * | 2019-07-10 | 2019-10-25 | 铜陵新港塑胶制品有限公司 | A kind of preparation method of flame-proof ABS alloy |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160817 |
|
| WD01 | Invention patent application deemed withdrawn after publication |