CN105542379B - A kind of high-impact resists cold ABS tank materials and the preparation method and application thereof - Google Patents
A kind of high-impact resists cold ABS tank materials and the preparation method and application thereof Download PDFInfo
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- CN105542379B CN105542379B CN201511027989.6A CN201511027989A CN105542379B CN 105542379 B CN105542379 B CN 105542379B CN 201511027989 A CN201511027989 A CN 201511027989A CN 105542379 B CN105542379 B CN 105542379B
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/9258—Velocity
- B29C2948/9259—Angular velocity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
Abstract
The invention discloses cold-resistant ABS tank materials of a kind of high-impact and the preparation method and application thereof, and the ABS tank materials are grouped as by the group of following parts by weight：62 76 parts of ABS resin, 15 parts of POE10 of maleic anhydride grafting, 10 15 parts of ABS high glue powders, 35 parts of inorganic nano-particle, 0.1~0.2 part of surface conditioning agent, 0.5 1 parts of antioxidant, 12 parts of lubricant；The ABS tank materials squeeze out plastics sucking moulding by injection molding machine injection molding or by squeezing out Packing Machine, obtain ABS babinets.The present invention by the physics in terms of raw material, chemical method be combined and machining process in specific process parameter modified ABS, the ABS tank materials of preparation not only have high shock resistance and cold-resistant function, ABS resin itself is also retained the aspect of performance the advantages of, has many advantages, such as that resistance to punching, cold-resistant, processing and forming is convenient.
Description
Technical field
The present invention relates to ABS tank materials, and in particular to a kind of high-impact resist cold ABS tank materials and preparation method thereof with
Using.
Background technology
The material used in luggage case on the market is typically all nylon material or plastic material at present, including PP, ABS, PC etc..
Wherein, ABS resin refers to acrylonitrile, butadiene-styrene copolymer, ABS resin is a kind of intensity height, good toughness, be easy to plus
The molding thermoplastic macromolecule material of work, is widely used in all kinds of suitcases.
During prior art preparation ABS tank materials, other add usually is added on the basis of babinet main material ABS material
Work auxiliary agent, is modified ABS, but since these auxiliary agents and ABS resin itself are there are the difference in physics, chemical property,
Also ABS resin is destroyed while modified from the advantage in aspect of performance.In addition, ABS resin is easy in high temperature or high shear
Under the conditions of be easy to decompose, and in process, if screw combinations, draw ratio, technology controlling and process are unreasonable, be easy to cause material
The features such as degrading, seriously affecting the mechanical property of ABS modified materials.
Invention content
Retaining ABS original rigidity, intensity it is an object of the invention to overcome the deficiencies of the prior art and provide a kind of
On the basis of, the high-impact of reinforcing material ductility, splitting resistance and lower temperature resistance resist cold ABS tank materials and preparation method thereof with
Using.
To achieve the above object, the present invention uses following technical scheme：
A kind of cold-resistant ABS tank materials of high-impact, are grouped as by the group of following parts by weight：
The inorganic nano-particle is nano-calcium carbonate, nano barium sulfate or nanomete talc powder.
The surface conditioning agent is silane coupling agent, aluminate coupling agent or titanate coupling agent.
The antioxidant is antioxidant 1010, antioxidant 168 or antioxidant 264.
The lubricant is polyethylene wax, stearic acid or oxidized wax.
The preparation method of the cold-resistant ABS tank materials of high-impact of the present invention, includes the following steps：
1) inorganic nano-particle and surface conditioning agent are weighed by weight and is added in high-speed mixer, in 125 DEG C of following tables
Surface treatment 10-15min；
2) ABS resin, maleic anhydride grafting POE, ABS high glue powder, antioxidant and lubricant are weighed by weight, is added
In above-mentioned high-speed mixer, it is sufficiently mixed uniformly, mixture is made；
3) above-mentioned mixture is put into double screw extruder extruding pelletization, obtains the cold-resistant ABS tank materials of high-impact；
The extruding pelletization process, 190-200 DEG C of head temperature, Ith area of machine barrel, IIth area of machine barrel, III area's temperature of machine barrel are
170-180 DEG C, IVth area of machine barrel, Vth area of machine barrel, VIth area of machine barrel, VII area's temperature of machine barrel are 180-190 DEG C, and screw slenderness ratio is
36-40:1, screw speed 230-250r/min, feeding manner are using segmentation feeding, and the segmentation feeding refers in host
The mixture of spout feeding 50%, it is two defeated to force the mixture of charging 50%, screw combinations element in glass charge door
It send element and mediates (shearing) element, in feeding section, plastics section, equal to empty exhaust section, mixing section, vacuum exhaust section, extruding zone
Using suitable kneading member and kneading member quantity.
In the step 2), before mixing, first maleic anhydride grafting POE, ABS high glue powder is dried to water content and is less than
2%.
The cold-resistant ABS tank materials of high-impact of the present invention are used to prepare ABS babinets, and the ABS babinets are by ABS babinets
Material squeezes out plastics sucking moulding by injection molding machine injection molding or by squeezing out Packing Machine.
The present invention uses above technical scheme, and using ABS resin as matrix resin, POE is grafted as shock resistance using maleic anhydride
Auxiliary agent, using ABS high glue powders as cold-resistant agent, by the combination of physical method and chemical method, modified ABS resin is retaining
On the basis of the original rigidity of ABS, intensity, ductility, splitting resistance and the lower temperature resistance of material are enhanced, is had more good
Toughness and bearing capacity.Maleic anhydride, which is grafted POE, ABS high glue powder, to be had with solubility parameter similar in ABS resin, therefore with
ABS blendings have good compatibility and with compared with the lower glass transition temperatures of ABS, are easy to form the blend of two phase structure.It is right
The chemical modification of ABS resin improves the content for the butadiene for playing toughness in former ABS, when modified ABS material is impacted
When material molecule structure in amorphous fraction with matrix formed plastic deformation stress concentration point, form a large amount of local deformation cores herein
The heart can form and effectively absorb outer impact energy, and will not form destructive rupture, and increases Elastic component in molecule and make
Intermolecular Van der Waals force and intramolecular chemical bonding force increase to reach the while of improving Impact Properties of Materials obtain it is excellent
Cold tolerance.
Common inorganic materials are added to the impact property that material is often influenced in ABS material, especially low temperature
Brittleness can increase with the increase of dosage.The present invention uses micro mist chemistry process for treating surface, by inorganic nano material and table
Surface treatment agent mixes, and is surface-treated, inorganic nano material is enable preferably to be combined with ABS material, be evenly dispersed into
In organic molecule, improves mobility, particle connecting and the particle adhesive force of polymer particles and relevant physical characteristic, avoid
Agglomeration occurs in high molecular material for inorganic nano-particle, and the physical blending capitally realized between obstructed component combines,
Each component is uniformly distributed, and greatly improves mobility, the inter-molecular binding force of material, to enable inorganic nano material maximum limit
In the gap of the insertion ABS strands of degree or filling molecule interchain, plays and increase intermolecular distance and make system toughness, cold resistance
Increase and reduce the cost of material.
It is easy to be easy decomposition under high temperature or shear conditions for ABS resin, and in process, if screw rod group
Conjunction, draw ratio, technology controlling and process are unreasonable, be easy to cause material degradation, seriously affect the spies such as the mechanical property of ABS modified materials
Point.The present invention studies the screw combinations of double screw extruder, feeding manner, determines best technological parameter, solves
The problem of ABS poor mechanical properties, and analyze the shadow of adjustment screw combination and segmentation feeding to ABS modified material mechanical properties
It rings.
The present invention can be achieved low temperature and squeeze out, reduce heat and concentrate, avoid object as far as possible in this way by the way of being segmented feeding
Material degradation, ensures the mechanical property of material.
To sum up, the present invention by the physics in terms of raw material, chemical method be combined and machining process in tool
The ABS tank materials of body technology parametric modifier ABS, preparation not only have high shock resistance and cold-resistant function, also retain
ABS resin itself has many advantages, such as that resistance to punching, cold-resistant, processing and forming is convenient, design freedom is high the aspect of performance the advantages of.This
After ABS tank materials prepared by invention are molded into standard batten, mechanical test performance is as follows：Melt flow rate (MFR) (220 DEG C,
5Kg) >=2.0g/10min, notch impact strength >=200J/M, tensile strength >=25Mpa, elongation at break >=30%, low temperature are crisp
Change temperature≤- 20 DEG C.
Specific implementation mode
A kind of cold-resistant ABS tank materials of high-impact, are grouped as by the group of following parts by weight：
The inorganic nano-particle is nano-calcium carbonate, nano barium sulfate or nanomete talc powder, and surface conditioning agent is silane
Coupling agent, aluminate coupling agent or titanate coupling agent, antioxidant are antioxidant 1010, antioxidant 168 or antioxidant
264, lubricant is polyethylene wax, stearic acid or oxidized wax.
The preparation method of the cold-resistant ABS tank materials of the high-impact, includes the following steps：
1) inorganic nano-particle and surface conditioning agent are weighed by weight and is added in high-speed mixer, in 125 DEG C of following tables
Surface treatment 10-15min；
2) ABS resin, maleic anhydride grafting POE, ABS high glue powder, antioxidant and lubricant are weighed by weight, is added
In above-mentioned high-speed mixer, it is sufficiently mixed uniformly, mixture is made；
3) above-mentioned mixture is put into double screw extruder extruding pelletization, obtains the cold-resistant ABS tank materials of high-impact；
The extruding pelletization process, 190-200 DEG C of head temperature, Ith area of machine barrel, IIth area of machine barrel, III area's temperature of machine barrel are
170-180 DEG C, IVth area of machine barrel, Vth area of machine barrel, VIth area of machine barrel, VII area's temperature of machine barrel are 180-190 DEG C, and screw slenderness ratio is
(36~40):1, screw speed 230-250r/min, feeding manner are using segmentation feeding, and the segmentation feeding refers in master
The mixture of machine spout feeding 50%, it is two to force the mixture of charging 50%, screw combinations element in glass charge door
Delivery element and kneading (shearing) element, in feeding section, plastics section, to empty exhaust section, mixing section, vacuum exhaust section, extruding zone
It is all made of suitable kneading member and kneading member quantity.
A kind of preparation method of ABS babinets, the ABS babinets are molded by the ABS tank materials of the present invention by injection molding machine
Molding squeezes out plastics sucking moulding by squeezing out Packing Machine.
Embodiment 1
A kind of preparation method of the cold-resistant ABS tank materials of high-impact, includes the following steps：
1) following components by weight, is weighed：
The inorganic nano-particle is nano-calcium carbonate, and surface conditioning agent is silane coupling agent, and antioxidant is antioxidant
1010, lubricant is polyethylene wax, and maleic anhydride grafting POE, ABS high glue powder is dried to water content and is less than 2%；
2) inorganic nano-particle and surface conditioning agent are added in high-speed mixer, in 125 DEG C of following table surface treatment 12min；
3) above-mentioned mixed at high speed is added in ABS resin, maleic anhydride grafting POE, ABS high glue powder, antioxidant and lubricant
In machine, it is sufficiently mixed uniformly, mixture is made；
4) above-mentioned mixture is put into double screw extruder extruding pelletization, obtains the cold-resistant ABS tank materials of high-impact；
The extruding pelletization process, 190 DEG C of head temperature, Ith area of machine barrel, IIth area of machine barrel, III area's temperature of machine barrel are 170
DEG C, IVth area of machine barrel, Vth area of machine barrel, VIth area of machine barrel, VII area's temperature of machine barrel are 180 DEG C, screw slenderness ratio 36:1, screw speed
For 230r/min, feeding manner is using segmentation feeding, and the segmentation feeding refers to the mixing in host spout feeding 50%
Material forces the mixture of charging 50% in glass charge door, and screw combinations element is two delivery element and mediates (shearing) member
Part, feeding section, plastics section, to empty exhaust section, mixing section, be vacuum-evacuated section, extruding zone be all made of suitable kneading member and
Kneading member quantity.
After ABS tank materials manufactured in the present embodiment are molded into standard batten, mechanical test performance is as follows：
Table 1
Embodiment 2
A kind of preparation method of the cold-resistant ABS tank materials of high-impact, includes the following steps：
1) following components by weight, is weighed：
The inorganic nano-particle is nano barium sulfate, and the surface conditioning agent is aluminate coupling agent, and antioxidant is anti-
Oxidant 168, lubricant are stearic acid；And maleic anhydride grafting POE, ABS high glue powder is dried to water content and is less than 2%；
2) inorganic nano-particle and surface conditioning agent are added in high-speed mixer, in 125 DEG C of following table surface treatment 15min；
3) above-mentioned mixed at high speed is added in ABS resin, maleic anhydride grafting POE, ABS high glue powder, antioxidant and lubricant
In machine, it is sufficiently mixed uniformly, mixture is made；
4) above-mentioned mixture is put into double screw extruder extruding pelletization, obtains the cold-resistant ABS tank materials of high-impact；
The extruding pelletization process, 190-200 DEG C of head temperature, Ith area of machine barrel, IIth area of machine barrel, III area's temperature of machine barrel are
180 DEG C, IVth area of machine barrel, Vth area of machine barrel, VIth area of machine barrel, VII area's temperature of machine barrel are 190 DEG C, screw slenderness ratio 40:1, screw rod
Rotating speed is 250r/min, and feeding manner is using segmentation feeding, and the segmentation feeding refers in host spout feeding 50%
Mixture, it is that two delivery elements and kneading (are cut to force the mixture of charging 50%, screw combinations element in glass charge door
Cut) element, in feeding section, plastics section, suitable kneading member is all made of to empty exhaust section, mixing section, vacuum exhaust section, extruding zone
Part and kneading member quantity.
After ABS tank materials manufactured in the present embodiment are molded into standard batten, mechanical test performance is as follows：
Table 2
Embodiment 3
A kind of preparation method of the cold-resistant ABS tank materials of high-impact, includes the following steps：
1) following components by weight, is weighed：
The inorganic nano-particle is nanomete talc powder, and the surface conditioning agent is titanate coupling agent, and antioxidant is anti-
Oxidant 264, lubricant are oxidized wax；And maleic anhydride grafting POE, ABS high glue powder is dried to water content and is less than 2%；
2) inorganic nano-particle and surface conditioning agent are added in high-speed mixer, in 125 DEG C of following table surface treatment 12min；
3) above-mentioned mixed at high speed is added in ABS resin, maleic anhydride grafting POE, ABS high glue powder, antioxidant and lubricant
In machine, it is sufficiently mixed uniformly, mixture is made；
4) above-mentioned mixture is put into double screw extruder extruding pelletization, obtains the cold-resistant ABS tank materials of high-impact；
The extruding pelletization process, 195 DEG C of head temperature, Ith area of machine barrel, IIth area of machine barrel, III area's temperature of machine barrel are 175
DEG C, IVth area of machine barrel, Vth area of machine barrel, VIth area of machine barrel, VII area's temperature of machine barrel are 185 DEG C, screw slenderness ratio 38:1, screw speed
For 230-250r/min, feeding manner is using segmentation feeding, and the segmentation feeding refers in host spout feeding 50%
Mixture, it is that two delivery elements and kneading (are cut to force the mixture of charging 50%, screw combinations element in glass charge door
Cut) element, in feeding section, plastics section, suitable kneading member is all made of to empty exhaust section, mixing section, vacuum exhaust section, extruding zone
Part and kneading member quantity.
After ABS tank materials manufactured in the present embodiment are molded into standard batten, mechanical test performance is as follows：
Table 3
Embodiment 4
A kind of preparation method of ABS babinets, the ABS babinets are molded by the ABS tank materials of the present invention by injection molding machine
Molding squeezes out plastics sucking moulding by squeezing out Packing Machine.
Claims (7)
- The preparation method of ABS tank materials 1. a kind of high-impact resists cold, it is characterised in that：The ABS tank materials are by following heavy The group of amount part is grouped as：62-76 parts of ABS resin；Maleic anhydride is grafted 10-15 parts of POE；10-15 parts of ABS high glue powders；3-5 parts of inorganic nano-particle；0.1-0.2 parts of surface conditioning agent；0.5-1 parts of antioxidant；1-2 parts of lubricant；The preparation method of the ABS tank materials, includes the following steps：1）Inorganic nano-particle and surface conditioning agent are weighed by weight and are added in high-speed mixer, at 125 DEG C of lower surfaces Manage 10-15min；2）ABS resin, maleic anhydride grafting POE, ABS high glue powder, antioxidant and lubricant are weighed by weight, are added above-mentioned In high-speed mixer, it is sufficiently mixed uniformly, mixture is made；3）Above-mentioned mixture is put into double screw extruder extruding pelletization, obtains the cold-resistant ABS tank materials of high-impact；The extruding pelletization process, 190-200 DEG C of head temperature, Ith area of machine barrel, IIth area of machine barrel, III area's temperature of machine barrel are 170- 180 DEG C, IVth area of machine barrel, Vth area of machine barrel, VIth area of machine barrel, VII area's temperature of machine barrel are 180-190 DEG C, screw slenderness ratio 36-40: 1, screw speed 230-250r/min, feeding manner are using segmentation feeding, and the segmentation feeding refers in host spout The mixture of feeding 50% forces the mixture of charging 50% in glass charge door, screw combinations element be two delivery elements and Kneading member.
- The preparation method of ABS tank materials 2. a kind of high-impact according to claim 1 resists cold, it is characterised in that：It is described Inorganic nano-particle is nano-calcium carbonate, nano barium sulfate or nanomete talc powder.
- The preparation method of ABS tank materials 3. a kind of high-impact according to claim 1 resists cold, it is characterised in that：It is described Surface conditioning agent is silane coupling agent, aluminate coupling agent or titanate coupling agent.
- The preparation method of ABS tank materials 4. a kind of high-impact according to claim 1 resists cold, it is characterised in that：It is described Antioxidant is antioxidant 1010, antioxidant 168 or antioxidant 264.
- The preparation method of ABS tank materials 5. a kind of high-impact according to claim 1 resists cold, it is characterised in that：It is described Lubricant is polyethylene wax, stearic acid or oxidized wax.
- The preparation method of ABS tank materials 6. a kind of high-impact according to claim 1 resists cold, it is characterised in that：It is described Step 2）In, before mixing, first maleic anhydride grafting POE, ABS high glue powder is dried to water content and is less than 2%.
- The ABS babinet materials that the preparation method of ABS tank materials obtains 7. a kind of high-impact according to claim 1 resists cold The application of material, it is characterised in that：The ABS tank materials are used to prepare ABS babinets, and the ABS babinets are by ABS tank materials Plastics sucking moulding is squeezed out by injection molding machine injection molding or by squeezing out Packing Machine.
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| CN105943258A (en) * | 2016-05-26 | 2016-09-21 | 夏放军 | A first-aid kit |
| CN106751382A (en) * | 2016-11-26 | 2017-05-31 | 滁州市天悦塑胶制品有限公司 | A kind of cold-resistant ABS inner container of icebox materials high and preparation method thereof |
| CN106543636A (en) * | 2016-11-26 | 2017-03-29 | 滁州市荣康塑料制品有限公司 | Cold-resistant ABS tank materials of a kind of high-impact and preparation method thereof |
| CN107474470A (en) * | 2017-08-29 | 2017-12-15 | 温州永立箱包有限公司 | Cold-resistant ABS tank materials of a kind of high-impact and preparation method thereof |
| CN108410117A (en) * | 2018-04-23 | 2018-08-17 | 林淑录 | A kind of babinet ABS composite material and preparation method thereof |
| CN112063097A (en) * | 2020-09-07 | 2020-12-11 | 海信（山东）冰箱有限公司 | Refrigerator, refrigerator drawer, injection molding material for refrigerator and preparation method of injection molding material |
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| CN101016401A (en) * | 2007-03-02 | 2007-08-15 | 浙江大学 | Injection moulding composition based on reclaiming ABS |
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- 2015-12-31 CN CN201511027989.6A patent/CN105542379B/en not_active Expired - Fee Related
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|---|---|---|---|---|
| CN101016401A (en) * | 2007-03-02 | 2007-08-15 | 浙江大学 | Injection moulding composition based on reclaiming ABS |
| CN103275454A (en) * | 2013-05-20 | 2013-09-04 | 合肥科拜耳新材料有限公司 | Enhanced highlight ABS (Acrylonitrile-Butadiene-Styrene) composite material and preparation method thereof |
| CN104140634A (en) * | 2014-07-04 | 2014-11-12 | 广东宾豪旅行用品有限公司 | Recycled ABS plastic for manufacturing traveling case shell and preparation method thereof |
| CN104140635A (en) * | 2014-07-04 | 2014-11-12 | 广东宾豪旅行用品有限公司 | Recycled ABS plastic reinforced and toughened by adopting micro-crosslinking method and preparation method thereof |
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