CN107474470A - Cold-resistant ABS tank materials of a kind of high-impact and preparation method thereof - Google Patents
Cold-resistant ABS tank materials of a kind of high-impact and preparation method thereof Download PDFInfo
- Publication number
- CN107474470A CN107474470A CN201710754541.7A CN201710754541A CN107474470A CN 107474470 A CN107474470 A CN 107474470A CN 201710754541 A CN201710754541 A CN 201710754541A CN 107474470 A CN107474470 A CN 107474470A
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- CN
- China
- Prior art keywords
- abs
- parts
- cold
- tank materials
- impact
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The present invention relates to ABS tank materials, more particularly to cold-resistant ABS tank materials of a kind of high-impact and preparation method thereof.ABS resin, maleic anhydride are grafted POE, ABS high glue powder, brominated flame retardant, antistatic additive, inorganic nano-particle, surface conditioning agent, antioxidant, lubricant and toughener and added in high mixer by formula, after mixing 5 10min at room temperature, its batch mixing is extruded using double screw extruder melt blending, pelletizing is carried out after water cooled, dry, finally pass through injection machine injection molding, on the basis of retaining the original rigidity of ABS, intensity, cold-resistant ABS tank materials of high-impact of reinforcing material ductility, splitting resistance and lower temperature resistance and preparation method thereof.
Description
Technical field
The present invention relates to ABS tank materials, more particularly to cold-resistant ABS tank materials of a kind of high-impact and preparation method thereof.
Background technology
The material used in luggage case on the market is typically all nylon material or plastic material at present, including PP, ABS, PC etc..
Wherein, ABS resin refers to acrylonitrile, BS, and ABS resin is a kind of intensity height, good toughness, is easy to add
The thermoplastic macromolecule material of work shaping, is widely used in all kinds of suitcases.
During prior art prepares ABS tank materials, other add generally is added on the basis of casing main material ABS material
Work auxiliary agent, is modified to ABS, but because these auxiliary agents and ABS resin have physics, the difference in chemical property in itself,
Also ABS resin is destroyed while modified from the advantage in aspect of performance.In addition, ABS resin is easily in high temperature or high shear
Under the conditions of easily decompose, and in process, if screw combinations, draw ratio, technology controlling and process are unreasonable, easily cause material
Degraded, the features such as having a strong impact on ABS material modified mechanical properties.
The content of the invention
Retaining ABS original rigidity, intensity it is an object of the invention to overcome the deficiencies of the prior art and provide a kind of
On the basis of, cold-resistant ABS tank materials of high-impact of reinforcing material ductility, splitting resistance and lower temperature resistance and preparation method thereof.
The present invention to achieve the above object and the technical scheme taken is：
A kind of cold-resistant ABS tank materials of high-impact, it is made up of the component of following parts by weight：
ABS resin 50-60 parts；
Maleic anhydride is grafted POE10-15 parts；
ABS rubber powder 10-15 parts；
Brominated flame retardant 5-10 parts；
Antistatic additive 2-4 parts；
Inorganic nano-particle 3-5 parts；
Surface conditioning agent 0.1-0.2 parts；
Antioxidant 0.5-1 parts；
Lubricant 1-2 parts；
Toughener 1-2 parts.
As a further improvement, the inorganic nano-particle is nano-calcium carbonate, nano barium sulfate or nanomete talc powder.
As a further improvement, the surface conditioning agent is silane coupler, aluminate coupling agent or titanate esters coupling
Agent.
As a further improvement, the antioxidant is antioxidant 1010, antioxidant 168 or antioxidant 264.
As a further improvement, the lubricant is Tissuemat E, stearic acid or oxidized wax.
The preparation method of the cold-resistant ABS tank materials of high-impact of the present invention, comprises the following steps：
ABS resin, maleic anhydride are grafted POE, ABS high glue powder, brominated flame retardant, antistatic additive, inorganic nano by formula
Particle, surface conditioning agent, antioxidant, lubricant and toughener are added in high mixer, after mixing 5-10min at room temperature, by it
Batch mixing is extruded using double screw extruder melt blending, is carried out pelletizing after water cooled, dry, is finally molded into by injection machine
Type, and injection temperature is arranged to 200-220 DEG C.
As a further improvement, maleic anhydride is grafted into POE, ABS rubber powder drying to water content before mixing is less than 2%.
The present invention uses above technical scheme, and using ABS resin as matrix resin, POE is grafted as shock resistance using maleic anhydride
Auxiliary agent, using ABS rubber powders as cold-resistant agent, by the combination of physical method and chemical method, modified ABS resin, retaining
On the basis of the original rigidity of ABS, intensity, ductility, splitting resistance and the lower temperature resistance of material are enhanced, is had better
Toughness and bearing capacity.Maleic anhydride grafting POE, ABS rubber powder has with solubility parameter similar in ABS resin, therefore and ABS
Blending has good compatibility and has the glass transition temperature lower compared with ABS, easily forms the blend of two phase structure.To ABS
The chemical modification of resin, the content for the butadiene for playing toughness in former ABS is improved, when modified ABS material is impacted
Amorphous fraction in material molecule structure forms plastic deformation stress concentration point with matrix, forms a large amount of local deformation cores herein
The heart, it can be formed and effectively absorb outer impact energy, and destructive rupture will not be formed, and add Elastic component in molecule to make
The increase of intermolecular Van der Waals force and intramolecular chemical bonding force obtain while improve Impact Properties of Materials so as to reach it is excellent
Cold tolerance.
Embodiment
The present invention to achieve the above object and the technical scheme taken is：
A kind of cold-resistant ABS tank materials of high-impact, it is made up of the component of following parts by weight：
ABS resin 50-60 parts；
Maleic anhydride is grafted POE10-15 parts；
ABS rubber powder 10-15 parts；
Brominated flame retardant 5-10 parts；
Antistatic additive 2-4 parts；
Inorganic nano-particle 3-5 parts；
Surface conditioning agent 0.1-0.2 parts；
Antioxidant 0.5-1 parts；
Lubricant 1-2 parts；
Toughener 1-2 parts.
The inorganic nano-particle is nano-calcium carbonate, nano barium sulfate or nanomete talc powder.
The surface conditioning agent is silane coupler, aluminate coupling agent or titanate coupling agent.
The antioxidant is antioxidant 1010, antioxidant 168 or antioxidant 264.
The lubricant is Tissuemat E, stearic acid or oxidized wax.
The preparation method of the cold-resistant ABS tank materials of high-impact of the present invention, comprises the following steps：
ABS resin, maleic anhydride are grafted POE, ABS high glue powder, brominated flame retardant, antistatic additive, inorganic nano by formula
Particle, surface conditioning agent, antioxidant, lubricant and toughener are added in high mixer, after mixing 5-10min at room temperature, by it
Batch mixing is extruded using double screw extruder melt blending, is carried out pelletizing after water cooled, dry, is finally molded into by injection machine
Type, and injection temperature is arranged to 200-220 DEG C.
Maleic anhydride is grafted POE, ABS rubber powder drying to water content before mixing and is less than 2%.
Claims (7)
- The ABS tank materials 1. a kind of high-impact resists cold, it is characterised in that：It is made up of the component of following parts by weight：ABS resin 50-60 parts；Maleic anhydride is grafted POE10-15 parts；ABS rubber powder 10-15 parts；Brominated flame retardant 5-10 parts；Antistatic additive 2-4 parts；Inorganic nano-particle 3-5 parts；Surface conditioning agent 0.1-0.2 parts；Antioxidant 0.5-1 parts；Lubricant 1-2 parts；Toughener 1-2 parts.
- A kind of 2. cold-resistant ABS tank materials of high-impact according to claim 1, it is characterised in that：The inorganic nano-particle For nano-calcium carbonate, nano barium sulfate or nanomete talc powder.
- A kind of 3. cold-resistant ABS tank materials of high-impact according to claim 1, it is characterised in that：The surface conditioning agent is Silane coupler, aluminate coupling agent or titanate coupling agent.
- A kind of 4. cold-resistant ABS tank materials of high-impact according to claim 1, it is characterised in that：The antioxidant is antioxygen Agent 1010, antioxidant 168 or antioxidant 264.
- A kind of 5. cold-resistant ABS tank materials of high-impact according to claim 1, it is characterised in that：The lubricant is poly- second Alkene wax, stearic acid or oxidized wax.
- 6. the preparation method for the ABS tank materials that resisted cold according to a kind of high-impact described in claim 1-5 any one, its feature exist In the preparation method specifically includes following steps：ABS resin, maleic anhydride are grafted POE, ABS high glue powder, bromine by formula Based flame retardant, antistatic additive, inorganic nano-particle, surface conditioning agent, antioxidant, lubricant and toughener are added in high mixer, After mixing 5-10min at room temperature, its batch mixing is extruded using double screw extruder melt blending, carried out after water cooled, dry Pelletizing, finally by injection machine injection molding, and injection temperature is arranged to 200-220 DEG C.
- The preparation method of ABS tank materials 7. a kind of high-impact according to claim 6 resists cold, it is characterised in that：Mixed Maleic anhydride is grafted POE, ABS rubber powder drying to water content before conjunction and is less than 2%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710754541.7A CN107474470A (en) | 2017-08-29 | 2017-08-29 | Cold-resistant ABS tank materials of a kind of high-impact and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710754541.7A CN107474470A (en) | 2017-08-29 | 2017-08-29 | Cold-resistant ABS tank materials of a kind of high-impact and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107474470A true CN107474470A (en) | 2017-12-15 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710754541.7A Pending CN107474470A (en) | 2017-08-29 | 2017-08-29 | Cold-resistant ABS tank materials of a kind of high-impact and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107474470A (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105542379A (en) * | 2015-12-31 | 2016-05-04 | 祥兴(福建)箱包集团有限公司 | ABS box material with high impact resistance and cold resistance and preparing method and application thereof |
-
2017
- 2017-08-29 CN CN201710754541.7A patent/CN107474470A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105542379A (en) * | 2015-12-31 | 2016-05-04 | 祥兴(福建)箱包集团有限公司 | ABS box material with high impact resistance and cold resistance and preparing method and application thereof |
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| PB01 | Publication | ||
| PB01 | Publication | ||
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171215 |
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| RJ01 | Rejection of invention patent application after publication |