CN103275454A - Enhanced highlight ABS (Acrylonitrile-Butadiene-Styrene) composite material and preparation method thereof - Google Patents
Enhanced highlight ABS (Acrylonitrile-Butadiene-Styrene) composite material and preparation method thereof Download PDFInfo
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- CN103275454A CN103275454A CN2013101882847A CN201310188284A CN103275454A CN 103275454 A CN103275454 A CN 103275454A CN 2013101882847 A CN2013101882847 A CN 2013101882847A CN 201310188284 A CN201310188284 A CN 201310188284A CN 103275454 A CN103275454 A CN 103275454A
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- matrix material
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- resin
- abs matrix
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- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 title claims abstract description 46
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 239000002131 composite material Substances 0.000 title claims abstract description 9
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 title abstract 7
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 title abstract 7
- 239000011521 glass Substances 0.000 claims abstract description 26
- 239000007822 coupling agent Substances 0.000 claims abstract description 19
- 239000011347 resin Substances 0.000 claims abstract description 9
- 229920005989 resin Polymers 0.000 claims abstract description 9
- 239000000314 lubricant Substances 0.000 claims abstract description 8
- 238000001125 extrusion Methods 0.000 claims abstract description 6
- 238000002156 mixing Methods 0.000 claims abstract description 6
- 239000003381 stabilizer Substances 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 5
- 239000011159 matrix material Substances 0.000 claims description 24
- 238000003756 stirring Methods 0.000 claims description 16
- 230000004913 activation Effects 0.000 claims description 14
- 230000002708 enhancing effect Effects 0.000 claims description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- 239000003112 inhibitor Substances 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 10
- 230000003647 oxidation Effects 0.000 claims description 10
- 238000007254 oxidation reaction Methods 0.000 claims description 10
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 6
- 230000000694 effects Effects 0.000 claims description 5
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 4
- IHBCFWWEZXPPLG-UHFFFAOYSA-N [Ca].[Zn] Chemical compound [Ca].[Zn] IHBCFWWEZXPPLG-UHFFFAOYSA-N 0.000 claims description 4
- AGXUVMPSUKZYDT-UHFFFAOYSA-L barium(2+);octadecanoate Chemical compound [Ba+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AGXUVMPSUKZYDT-UHFFFAOYSA-L 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 4
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 4
- 229960004756 ethanol Drugs 0.000 claims description 4
- 238000005469 granulation Methods 0.000 claims description 4
- 230000003179 granulation Effects 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- RKISUIUJZGSLEV-UHFFFAOYSA-N n-[2-(octadecanoylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCNC(=O)CCCCCCCCCCCCCCCCC RKISUIUJZGSLEV-UHFFFAOYSA-N 0.000 claims description 4
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical group CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 claims description 3
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 claims description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- -1 Zinic stearas Chemical compound 0.000 claims description 2
- 150000004645 aluminates Chemical class 0.000 claims description 2
- SHLNMHIRQGRGOL-UHFFFAOYSA-N barium zinc Chemical compound [Zn].[Ba] SHLNMHIRQGRGOL-UHFFFAOYSA-N 0.000 claims description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 2
- 239000008116 calcium stearate Substances 0.000 claims description 2
- 235000013539 calcium stearate Nutrition 0.000 claims description 2
- 239000006084 composite stabilizer Substances 0.000 claims description 2
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 claims description 2
- 229940113162 oleylamide Drugs 0.000 claims description 2
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 230000032683 aging Effects 0.000 abstract description 2
- 230000007797 corrosion Effects 0.000 abstract description 2
- 238000005260 corrosion Methods 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 239000011324 bead Substances 0.000 abstract 3
- 239000003963 antioxidant agent Substances 0.000 abstract 2
- 230000003078 antioxidant effect Effects 0.000 abstract 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 1
- 230000003213 activating effect Effects 0.000 abstract 1
- 238000009776 industrial production Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 238000002791 soaking Methods 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 9
- 238000001746 injection moulding Methods 0.000 description 8
- 230000035939 shock Effects 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 2
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/04—Particle-shaped
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/022—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
Abstract
The invention discloses an enhanced highlight ABS (Acrylonitrile-Butadiene-Styrene) composite material and a preparation method thereof. The enhanced highlight ABS composite material comprises the following raw materials in percentage by weight: 50%-75% of ABS resin, 10%-25% of AS (acrylonitrile) resin, 10%-25% of nanoscale glass beads, 1%-3% of a coupling agent, 1%-3% of a compatibilizer, 0.5%-2% of a lubricating agent, 0.5%-3% of a stabilizer and 0.5%-2% of an antioxidant. The preparation method comprises the following steps of: soaking and activating sub-nanoscale glass beads by using a coupling agent, uniformly mixing the sub-nanoscale glass beads with the ABS resin, the compatibilizer, the lubricating agent, the stabilizer, the antioxidant and the like in a high-speed mixer, and finally carrying out melt blending and extrusion on a twin-screw extrusion machine. The prepared ABS composite material has the characteristics of good high-low temperature resistance, ageing resistance and chemical corrosion resistance, excellent glossiness, high strength, impact resistance and the like, and is easy to process. The production processes of the ABS composite material are simple and easy to control and low in cost; and the preparation method is suitable for industrial production.
Description
Technical field
The present invention relates to field of material preparation, be specifically related to a kind of high-light ABS matrix material and preparation method thereof that obtains to strengthen.
Background technology
Along with the development of advancing by leaps and bounds of China's household electrical appliance refrigerator, refrigerator handle panel has also obtained developing rapidly with the high-light ABS material.Refrigerator handle panel is as the important appearance component of the especially high-end refrigerator of domestic refrigerator, require high strength, high gloss and attractive in appearance, common ABS material is difficult to satisfy this requirement, ABS sprays paint and has problems such as cost height, contaminate environment and very difficult recycling, and the exploitation high light of enhancing and lower-cost refrigerator handle panel have become the hot issue of industry with the ABS material.
Summary of the invention
The object of the present invention is to provide a kind of high strength, high gloss and lower-cost refrigerator handle panel ABS matrix material and preparation method thereof.
Technical scheme provided by the invention is:
A kind of enhancing high-light ABS matrix material is made by the raw material of following weight ratio: ABS resin 50-75%, AS resin 10-25%, Subnano-class glass microballon 10-25%, coupling agent 1-3%, expanding material 1-3%, lubricant 0.5-2%, stablizer 0.5-3%, oxidation inhibitor 0.5-2%.
A kind of preparation method who strengthens the high-light ABS matrix material may further comprise the steps:
(1) coupling agent is diluted by 1:1 with dehydrated alcohol, then the Subnano-class glass microballon that weighs up is put in the homogenizer and stirred, stirring velocity is 1500-2000r/min, pour the coupling agent/ethanol solution that configures while stirring into, treat to continue to stir 10-15min after solution is all poured into, make solution soak into the effect that glass microballon reaches activation as far as possible, with the dry 2-3h under 120-150 ℃ of the glass microballon after the activation treatment, be cooled to normal temperature, stand-by;
(2) glass microballon with ABS resin, AS resin, expanding material, lubricant, stablizer, oxidation inhibitor and step (1) activation treatment places homogenizer, be that 500-1000r/min, temperature are to stir 10-20min under the 80-90 ℃ of condition at rotating speed, then compound is sent into carry out in the twin screw extruder that melt blending is extruded, cooling, granulation, namely get and strengthen the high-light ABS matrix material.
Described coupling agent can be in silane coupling agent, titanate coupling agent, the aluminate coupling agent one or more.
Described solubilizing agent can be in EVA grafted maleic anhydride multipolymer, POE grafted maleic anhydride multipolymer, the phenylethylene-maleic anhydride-glytidyl methacrylate multipolymer one or more.
Described lubricant can be in EVA wax, butyl stearate, oleylamide, ethylene bis stearamide, the sodium stearate one or more.
Described stablizer can be in calcium stearate, Zinic stearas, barium stearate, calcium-zinc composite stabilizing agent, the barium zinc composite stabilizer one or more.
Described oxidation inhibitor can be antioxidant 1076, oxidation inhibitor 168, one or more in the antioxidant 264.
The blend extrusion temperature of described twin screw extruder is: a district 195-205 ℃, and two district 215-225 ℃, three district 220-230 ℃, four district 220-235 ℃, five district 225-235 ℃, head 230-240 ℃; Screw speed 180-220 r/min.
Beneficial effect of the present invention:
ABS is general injection grade material in the present invention's prescription, has satisfactory stability, intensity and shock resistance, AS has glossiness and rigidity preferably, the Subnano-class glass microballon has enhancing, the effect of blast, the three has good synergy, can improve the tensile strength of matrix material, performance such as shock resistance and glossiness, the present invention utilizes coupling agent to come the activation treatment glass microballon, make it to strengthen with the ABS resin coupling better, utilize expanding material to increase ABS, consistency between AS and activation glass microballon, thereby the over-all properties of raising matrix material.The ABS matrix material that the present invention prepares has good high and low temperature resistance, ageing-resistant performance and resistance to chemical corrosion, good glossiness, intensity height, shock resistance is good, be easy to characteristics such as processing, its production process is simple and easy to control, and cost is low, is applicable to suitability for industrialized production.
Embodiment
Embodiment 1
A kind of enhancing high-light ABS matrix material is made by the raw material of following weight ratio: ABS resin 65%, AS resin 15%, Subnano-class glass microballon 15%, silane coupling agent KH550 1.5%, EVA grafted maleic anhydride copolymer 1 %, EVA wax 1%, barium stearate 1%, antioxidant 1076 0.5%.
A kind of preparation method who strengthens the high-light ABS matrix material may further comprise the steps:
(1) coupling agent is diluted by 1:1 with dehydrated alcohol, then the Subnano-class glass microballon that weighs up is put in the homogenizer and stirred, stirring velocity is 2000r/min, pour the coupling agent/ethanol solution that configures while stirring into, treat to continue to stir 10min after solution is all poured into, make solution soak into the effect that glass microballon reaches activation as far as possible, with the dry 3h under 125 ℃ of the glass microballon after the activation treatment, be cooled to normal temperature, stand-by;
(2) glass microballon with ABS resin, AS resin, EVA grafted maleic anhydride multipolymer, EVA wax, barium stearate, antioxidant 1010 and step (1) activation treatment places homogenizer, be that 800r/min, temperature are to stir 15min under 85 ℃ of conditions at rotating speed, then compound is sent into carry out in the twin screw extruder that melt blending is extruded, cooling, granulation, namely get and strengthen the high-light ABS matrix material.
The blend extrusion temperature of described twin screw extruder is: 200 ℃ in a district, 210 ℃ in two districts, 225 ℃ in three districts, 230 ℃ in four districts, 230 ℃ in five districts, 235 ℃ of heads; Screw speed 200 r/min.
With extruded stock injection moulding machine injection molding standard testing batten and injection moulding model, after testing, the batten tensile strength is 55.3MPa, and elongation at break is 12%, and Young's modulus is 3353MPa, injection moulding model glossiness height.
Embodiment 2
A kind of enhancing high-light ABS matrix material is made by the raw material of following weight ratio: ABS resin 55%, AS resin 20%, Subnano-class glass microballon 20%, silane coupling agent DL602 1.5%, POE grafted maleic anhydride copolymer 1 %, ethylene bis stearamide 1.5%, calcium-zinc composite stabilizing agent 0.5%, oxidation inhibitor 168 1%.
A kind of preparation method who strengthens the high-light ABS matrix material may further comprise the steps:
(1) coupling agent is diluted by 1:1 with dehydrated alcohol, then the Subnano-class glass microballon that weighs up is put in the homogenizer and stirred, stirring velocity is 1500r/min, pour the coupling agent/ethanol solution that configures while stirring into, treat to continue to stir 15min after solution is all poured into, make solution soak into the effect that glass microballon reaches activation as far as possible, with the dry 2h under 150 ℃ of the glass microballon after the activation treatment, be cooled to normal temperature, stand-by;
(2) ABS resin, AS resin, POE grafted maleic anhydride multipolymer, ethylene bis stearamide, calcium-zinc composite stabilizing agent, oxidation inhibitor 168 are placed homogenizer with the glass microballon of step (1) activation treatment, be that 1000r/min, temperature are to stir 10min under 90 ℃ of conditions at rotating speed, then compound is sent into carry out in the twin screw extruder that melt blending is extruded, cooling, granulation, namely get and strengthen the high-light ABS matrix material.
The blend extrusion temperature of described twin screw extruder is: 205 ℃ in a district, 220 ℃ in two districts, 225 ℃ in three districts, 230 ℃ in four districts, 235 ℃ in five districts, 240 ℃ of heads; Screw speed 180r/min.
With extruded stock injection moulding machine injection molding standard testing batten and injection moulding model, after testing, the batten tensile strength is 62.4MPa, and elongation at break is 13%, and Young's modulus is 3553MPa, injection moulding model glossiness height.
Claims (8)
1. one kind strengthens the high-light ABS matrix material, it is characterized in that, made by the raw material of following weight ratio: ABS resin 50-75%, AS resin 10-25%, Subnano-class glass microballon 10-25%, coupling agent 1-3%, expanding material 1-3%, lubricant 0.5-2%, stablizer 0.5-3%, oxidation inhibitor 0.5-2%.
2. the preparation method of an enhancing high-light ABS matrix material as claimed in claim 1 is characterized in that may further comprise the steps:
(1) coupling agent is diluted by 1:1 with dehydrated alcohol, then the Subnano-class glass microballon that weighs up is put in the homogenizer and stirred, stirring velocity is 1500-2000r/min, pour the coupling agent/ethanol solution that configures while stirring into, treat to continue to stir 10-15min after solution is all poured into, make solution soak into the effect that glass microballon reaches activation as far as possible, with the dry 2-3h under 120-150 ℃ of the glass microballon after the activation treatment, be cooled to normal temperature, stand-by;
(2) glass microballon with ABS resin, AS resin, expanding material, lubricant, stablizer, oxidation inhibitor and step (1) activation treatment places homogenizer, be that 500-1000r/min, temperature are to stir 10-20min under the 80-90 ℃ of condition at rotating speed, then compound is sent into carry out in the twin screw extruder that melt blending is extruded, cooling, granulation, namely get and strengthen the high-light ABS matrix material.
3. enhancing high-light ABS matrix material according to claim 1 and 2 is characterized in that, described coupling agent can be in silane coupling agent, titanate coupling agent, the aluminate coupling agent one or more.
4. enhancing high-light ABS matrix material according to claim 1 and 2, it is characterized in that described solubilizing agent can be in EVA grafted maleic anhydride multipolymer, POE grafted maleic anhydride multipolymer, the phenylethylene-maleic anhydride-glytidyl methacrylate multipolymer one or more.
5. enhancing high-light ABS matrix material according to claim 1 and 2 is characterized in that, described lubricant can be in EVA wax, butyl stearate, oleylamide, ethylene bis stearamide, the sodium stearate one or more.
6. enhancing high-light ABS matrix material according to claim 1 and 2 is characterized in that, described stablizer can be in calcium stearate, Zinic stearas, barium stearate, calcium-zinc composite stabilizing agent, the barium zinc composite stabilizer one or more.
7. enhancing high-light ABS matrix material according to claim 1 and 2 is characterized in that, described oxidation inhibitor can be antioxidant 1076, oxidation inhibitor 168, one or more in the antioxidant 264.
8. enhancing high-light ABS matrix material according to claim 1 and 2 is characterized in that, the blend extrusion temperature of described twin screw extruder is: a district 195-205 ℃, two district 215-225 ℃, three district 220-230 ℃, four district 220-235 ℃, five district 225-235 ℃, head 230-240 ℃; Screw speed 180-220 r/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201310188284.7A CN103275454B (en) | 2013-05-20 | 2013-05-20 | A kind of enhancing high-light ABS matrix material and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310188284.7A CN103275454B (en) | 2013-05-20 | 2013-05-20 | A kind of enhancing high-light ABS matrix material and preparation method thereof |
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| Publication Number | Publication Date |
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| CN103275454A true CN103275454A (en) | 2013-09-04 |
| CN103275454B CN103275454B (en) | 2016-03-16 |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104845020A (en) * | 2015-04-27 | 2015-08-19 | 安徽海纳川塑业科技有限公司 | ABS/shell powder composite material and preparation method thereof |
| CN104845018A (en) * | 2015-04-27 | 2015-08-19 | 安徽海纳川塑业科技有限公司 | High-strength wear-resistant ABS composite material and preparation method thereof |
| CN104845021A (en) * | 2015-04-27 | 2015-08-19 | 安徽海纳川塑业科技有限公司 | ABS/waste porcelain powder composite material and preparation method thereof |
| CN104845016A (en) * | 2015-04-27 | 2015-08-19 | 安徽海纳川塑业科技有限公司 | Fly ash modified ABS composite material and preparation method thereof |
| CN105542379A (en) * | 2015-12-31 | 2016-05-04 | 祥兴(福建)箱包集团有限公司 | ABS box material with high impact resistance and cold resistance and preparing method and application thereof |
| CN108070197A (en) * | 2017-12-15 | 2018-05-25 | 广西汇智生产力促进中心有限公司 | Modified kaolin-ABS is corrosion-resistant, the preparation method of explosion-proof composite material |
| CN112961454A (en) * | 2021-02-04 | 2021-06-15 | 九牧厨卫股份有限公司 | ABS composite material and preparation method thereof |
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| CN104845020A (en) * | 2015-04-27 | 2015-08-19 | 安徽海纳川塑业科技有限公司 | ABS/shell powder composite material and preparation method thereof |
| CN104845018A (en) * | 2015-04-27 | 2015-08-19 | 安徽海纳川塑业科技有限公司 | High-strength wear-resistant ABS composite material and preparation method thereof |
| CN104845021A (en) * | 2015-04-27 | 2015-08-19 | 安徽海纳川塑业科技有限公司 | ABS/waste porcelain powder composite material and preparation method thereof |
| CN104845016A (en) * | 2015-04-27 | 2015-08-19 | 安徽海纳川塑业科技有限公司 | Fly ash modified ABS composite material and preparation method thereof |
| CN105542379A (en) * | 2015-12-31 | 2016-05-04 | 祥兴(福建)箱包集团有限公司 | ABS box material with high impact resistance and cold resistance and preparing method and application thereof |
| CN105542379B (en) * | 2015-12-31 | 2018-09-28 | 祥兴(福建)箱包集团有限公司 | A kind of high-impact resists cold ABS tank materials and the preparation method and application thereof |
| CN108070197A (en) * | 2017-12-15 | 2018-05-25 | 广西汇智生产力促进中心有限公司 | Modified kaolin-ABS is corrosion-resistant, the preparation method of explosion-proof composite material |
| CN112961454A (en) * | 2021-02-04 | 2021-06-15 | 九牧厨卫股份有限公司 | ABS composite material and preparation method thereof |
| CN112961454B (en) * | 2021-02-04 | 2023-10-03 | 九牧厨卫股份有限公司 | ABS composite material and preparation method thereof |
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