CN105849175B - 由包含巯基官能化硅氧烷的组合物制备的硫化橡胶和轮胎组件 - Google Patents
由包含巯基官能化硅氧烷的组合物制备的硫化橡胶和轮胎组件 Download PDFInfo
- Publication number
- CN105849175B CN105849175B CN201480071361.3A CN201480071361A CN105849175B CN 105849175 B CN105849175 B CN 105849175B CN 201480071361 A CN201480071361 A CN 201480071361A CN 105849175 B CN105849175 B CN 105849175B
- Authority
- CN
- China
- Prior art keywords
- poly
- diene
- elastomer
- isoprene
- hydrosulphonyl functionalized
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- -1 hydrosulphonyl Chemical group 0.000 title claims abstract description 157
- 239000004636 vulcanized rubber Substances 0.000 title claims abstract description 31
- 239000000203 mixture Substances 0.000 title claims description 59
- 238000002360 preparation method Methods 0.000 title description 7
- 229920001971 elastomer Polymers 0.000 claims abstract description 94
- 239000000806 elastomer Substances 0.000 claims abstract description 55
- 150000001875 compounds Chemical class 0.000 claims abstract description 44
- 239000000945 filler Substances 0.000 claims abstract description 34
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 28
- 239000004594 Masterbatch (MB) Substances 0.000 claims abstract description 17
- 238000000034 method Methods 0.000 claims abstract description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 57
- 150000001993 dienes Chemical class 0.000 claims description 46
- 239000000377 silicon dioxide Substances 0.000 claims description 28
- 229920000578 graft copolymer Polymers 0.000 claims description 21
- 229920001577 copolymer Chemical class 0.000 claims description 17
- 239000000463 material Substances 0.000 claims description 16
- 239000002243 precursor Substances 0.000 claims description 9
- 239000000376 reactant Substances 0.000 claims description 7
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 7
- 229920003051 synthetic elastomer Polymers 0.000 claims description 7
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Natural products CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 6
- 244000043261 Hevea brasiliensis Species 0.000 claims description 5
- 239000005062 Polybutadiene Substances 0.000 claims description 5
- 229920003052 natural elastomer Polymers 0.000 claims description 5
- 229920001194 natural rubber Polymers 0.000 claims description 5
- 229920001084 poly(chloroprene) Polymers 0.000 claims description 5
- 229920002857 polybutadiene Polymers 0.000 claims description 5
- 229920003244 diene elastomer Polymers 0.000 claims description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 3
- 239000005977 Ethylene Substances 0.000 claims 3
- 239000005060 rubber Substances 0.000 description 39
- 229920000642 polymer Polymers 0.000 description 25
- 238000002156 mixing Methods 0.000 description 23
- 229920001296 polysiloxane Polymers 0.000 description 21
- 239000005864 Sulphur Substances 0.000 description 14
- 238000006243 chemical reaction Methods 0.000 description 14
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 13
- 239000003921 oil Substances 0.000 description 13
- 235000019198 oils Nutrition 0.000 description 13
- 239000006229 carbon black Substances 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 9
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 8
- 125000003396 thiol group Chemical group [H]S* 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
- 229910052799 carbon Inorganic materials 0.000 description 7
- 230000002708 enhancing effect Effects 0.000 description 7
- 125000000962 organic group Chemical group 0.000 description 7
- 238000009991 scouring Methods 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 238000004073 vulcanization Methods 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 6
- 239000000178 monomer Substances 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- 235000021355 Stearic acid Nutrition 0.000 description 5
- 239000007822 coupling agent Substances 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 5
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 5
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 5
- 238000005096 rolling process Methods 0.000 description 5
- 238000007711 solidification Methods 0.000 description 5
- 230000008023 solidification Effects 0.000 description 5
- 239000008117 stearic acid Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 150000001721 carbon Chemical group 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 239000006231 channel black Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 229920001021 polysulfide Polymers 0.000 description 4
- 239000005077 polysulfide Substances 0.000 description 4
- 150000008117 polysulfides Polymers 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 125000005369 trialkoxysilyl group Chemical group 0.000 description 4
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
- 230000003078 antioxidant effect Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 125000005842 heteroatom Chemical group 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 3
- 238000011065 in-situ storage Methods 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 3
- 239000000391 magnesium silicate Substances 0.000 description 3
- 235000019792 magnesium silicate Nutrition 0.000 description 3
- 229910052919 magnesium silicate Inorganic materials 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 229910000077 silane Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 229920005573 silicon-containing polymer Polymers 0.000 description 3
- 230000010148 water-pollination Effects 0.000 description 3
- 239000001993 wax Substances 0.000 description 3
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 2
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical compound C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 description 2
- SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 description 2
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
- 239000006238 High Abrasion Furnace Substances 0.000 description 2
- 239000006057 Non-nutritive feed additive Substances 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 125000001118 alkylidene group Chemical group 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 238000000429 assembly Methods 0.000 description 2
- 230000000712 assembly Effects 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 229920001400 block copolymer Polymers 0.000 description 2
- 235000012241 calcium silicate Nutrition 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 150000001924 cycloalkanes Chemical class 0.000 description 2
- 125000000392 cycloalkenyl group Chemical group 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 description 2
- 238000005984 hydrogenation reaction Methods 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- VDGJOQCBCPGFFD-UHFFFAOYSA-N oxygen(2-) silicon(4+) titanium(4+) Chemical compound [Si+4].[O-2].[O-2].[Ti+4] VDGJOQCBCPGFFD-UHFFFAOYSA-N 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000005061 synthetic rubber Substances 0.000 description 2
- ZDHXKXAHOVTTAH-UHFFFAOYSA-N trichlorosilane Chemical compound Cl[SiH](Cl)Cl ZDHXKXAHOVTTAH-UHFFFAOYSA-N 0.000 description 2
- 239000005052 trichlorosilane Substances 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- APPOKADJQUIAHP-GGWOSOGESA-N (2e,4e)-hexa-2,4-diene Chemical compound C\C=C\C=C\C APPOKADJQUIAHP-GGWOSOGESA-N 0.000 description 1
- AHAREKHAZNPPMI-AATRIKPKSA-N (3e)-hexa-1,3-diene Chemical compound CC\C=C\C=C AHAREKHAZNPPMI-AATRIKPKSA-N 0.000 description 1
- QOVCUELHTLHMEN-UHFFFAOYSA-N 1-butyl-4-ethenylbenzene Chemical compound CCCCC1=CC=C(C=C)C=C1 QOVCUELHTLHMEN-UHFFFAOYSA-N 0.000 description 1
- NVZWEEGUWXZOKI-UHFFFAOYSA-N 1-ethenyl-2-methylbenzene Chemical compound CC1=CC=CC=C1C=C NVZWEEGUWXZOKI-UHFFFAOYSA-N 0.000 description 1
- CBXRMKZFYQISIV-UHFFFAOYSA-N 1-n,1-n,1-n',1-n',2-n,2-n,2-n',2-n'-octamethylethene-1,1,2,2-tetramine Chemical compound CN(C)C(N(C)C)=C(N(C)C)N(C)C CBXRMKZFYQISIV-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- IGLWCQMNTGCUBB-UHFFFAOYSA-N 3-methylidenepent-1-ene Chemical compound CCC(=C)C=C IGLWCQMNTGCUBB-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 1
- 241000790917 Dioxys <bee> Species 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 description 1
- 239000005662 Paraffin oil Substances 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229910003978 SiClx Inorganic materials 0.000 description 1
- 229910020175 SiOH Inorganic materials 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000006230 acetylene black Substances 0.000 description 1
- 229920000800 acrylic rubber Polymers 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000004450 alkenylene group Chemical group 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 125000000304 alkynyl group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 239000010692 aromatic oil Substances 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- HRHBQGBPZWNGHV-UHFFFAOYSA-N azane;bromomethane Chemical compound N.BrC HRHBQGBPZWNGHV-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 description 1
- 229940008099 dimethicone Drugs 0.000 description 1
- 125000001891 dimethoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 229920005558 epichlorohydrin rubber Polymers 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- 239000006232 furnace black Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 235000003642 hunger Nutrition 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000005660 hydrophilic surface Effects 0.000 description 1
- 230000005661 hydrophobic surface Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000006233 lamp black Substances 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N naphthalene-acid Natural products C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 125000005702 oxyalkylene group Chemical group 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 125000004437 phosphorous atom Chemical group 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920003225 polyurethane elastomer Polymers 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 239000012763 reinforcing filler Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000010458 rotten stone Substances 0.000 description 1
- 238000010058 rubber compounding Methods 0.000 description 1
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- NGHMEZWZOZEZOH-UHFFFAOYSA-N silicic acid;hydrate Chemical compound O.O[Si](O)(O)O NGHMEZWZOZEZOH-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 125000003107 substituted aryl group Chemical group 0.000 description 1
- 125000005649 substituted arylene group Chemical group 0.000 description 1
- 238000005486 sulfidation Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 125000004354 sulfur functional group Chemical group 0.000 description 1
- 238000010059 sulfur vulcanization Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 125000004665 trialkylsilyl group Chemical group 0.000 description 1
- 239000010913 used oil Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0016—Compositions of the tread
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/011—Crosslinking or vulcanising agents, e.g. accelerators
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/10—Block- or graft-copolymers containing polysiloxane sequences
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2309/00—Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons
- C08J2309/06—Copolymers with styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2351/00—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
- C08J2351/04—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2407/00—Characterised by the use of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2483/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
- C08J2483/04—Polysiloxanes
- C08J2483/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/06—Sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/548—Silicon-containing compounds containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201361921153P | 2013-12-27 | 2013-12-27 | |
| US61/921,153 | 2013-12-27 | ||
| PCT/US2014/072511 WO2015100449A2 (en) | 2013-12-27 | 2014-12-29 | Vulcanizates and tire components prepared from compositions including mercapto-functional siloxanes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105849175A CN105849175A (zh) | 2016-08-10 |
| CN105849175B true CN105849175B (zh) | 2019-09-24 |
Family
ID=52440821
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201480071361.3A Expired - Fee Related CN105849175B (zh) | 2013-12-27 | 2014-12-29 | 由包含巯基官能化硅氧烷的组合物制备的硫化橡胶和轮胎组件 |
Country Status (5)
| Country | Link |
|---|---|
| US (2) | US10150845B2 (de) |
| EP (1) | EP3086928B1 (de) |
| JP (1) | JP6591422B2 (de) |
| CN (1) | CN105849175B (de) |
| WO (1) | WO2015100449A2 (de) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3086928B1 (de) * | 2013-12-27 | 2019-09-11 | Bridgestone Corporation | Aus zusammensetzungen mit mercaptofunktionellen siloxanen hergestellte vulkanisate und reifenkomponenten |
| JP6753139B2 (ja) * | 2016-05-18 | 2020-09-09 | 横浜ゴム株式会社 | タイヤ用ゴム組成物の製造方法 |
| JP6874490B2 (ja) * | 2017-04-13 | 2021-05-19 | 住友ゴム工業株式会社 | タイヤ用ゴム組成物の製造方法 |
| JP6957126B2 (ja) * | 2017-07-19 | 2021-11-02 | コンパニー ゼネラール デ エタブリッスマン ミシュラン | シリコーンオイルに基づくゴム組成物 |
| CN110784807B (zh) * | 2019-10-31 | 2021-07-06 | 歌尔股份有限公司 | 一种发声装置的振膜以及发声装置 |
| US20230030838A1 (en) * | 2019-12-30 | 2023-02-02 | Bridgestone Corporation | Rubber compositions prepared with a polar polysulfide crosslinking agent |
| WO2023129997A1 (en) * | 2021-12-29 | 2023-07-06 | Bridgestone Corporation | Natural rubber compositions for pneumatic tires |
| WO2024101082A1 (ja) * | 2022-11-10 | 2024-05-16 | 信越化学工業株式会社 | ゴム組成物およびオルガノポリシロキサン |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1163285A (zh) * | 1996-01-11 | 1997-10-29 | 米什兰集团总公司 | 用于外胎的橡胶组合物 |
| US5994456A (en) * | 1998-04-09 | 1999-11-30 | Dow Corning Corporation | Compositions comprising mercapto-functional organosilicon compounds |
| CN1265126A (zh) * | 1997-07-11 | 2000-08-30 | 米什兰集团总公司 | 以聚有机硅氧烷为偶联剂及白色填料增强的二烯橡胶组合物 |
| EP1640183A1 (de) * | 2004-09-23 | 2006-03-29 | The Goodyear Tire & Rubber Company | Reifen mit Lauffläche aus Kautschuk mit geringer Emissionsrate an flüchtigem Alkohol |
| CN101668791A (zh) * | 2007-04-27 | 2010-03-10 | 3M创新有限公司 | 接枝有机硅聚合物以及用其制备的产品 |
| CN102690449A (zh) * | 2012-06-21 | 2012-09-26 | 三角轮胎股份有限公司 | 含改性橡胶的充气轮胎橡胶组合物 |
Family Cites Families (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2008426A1 (de) * | 1969-02-27 | 1970-09-10 | ||
| US4066603A (en) * | 1976-03-03 | 1978-01-03 | Dow Corning Corporation | Sulfur containing silicone elastomer and method of preparation |
| US4279449A (en) * | 1978-07-20 | 1981-07-21 | The Goodyear Tire & Rubber Company | Slide surface compound for track-driven vehicle |
| US6022923A (en) | 1995-01-13 | 2000-02-08 | Bridgestone Corporation | Pneumatic tires |
| JP3555809B2 (ja) | 1995-06-19 | 2004-08-18 | 株式会社ブリヂストン | ラジアルタイヤ |
| DE69632512T2 (de) | 1995-08-31 | 2005-05-25 | The Yokohama Rubber Co., Ltd. | Polysiloxan-enthaltende Kautschukzusammensetzung |
| JP3606411B2 (ja) | 1996-07-10 | 2005-01-05 | 株式会社ブリヂストン | タイヤ加硫成型用金型およびその製造方法 |
| JP3117645B2 (ja) | 1996-09-03 | 2000-12-18 | 株式会社ブリヂストン | 空気入りラジアルタイヤ |
| JP3685572B2 (ja) | 1996-12-17 | 2005-08-17 | 住友ゴム工業株式会社 | タイヤトレッド用ゴム組成物 |
| JPH10176081A (ja) * | 1996-12-19 | 1998-06-30 | Yokohama Rubber Co Ltd:The | ゴム組成物 |
| US5723531A (en) | 1997-04-30 | 1998-03-03 | The Goodyear Tire & Rubber Company | Rubber composition and tire having tread thereof |
| ATE215578T1 (de) * | 1997-07-11 | 2002-04-15 | Rhodia Chimie Sa | Verfahren zur herstellung von thiolgruppen- enthaltenden polyorganosiloxanen, mit diesem verfahren hergestellte organopolysiloxane und deren anwendung in gummi |
| US5971046A (en) | 1997-09-17 | 1999-10-26 | Bridgestone/Firestone, Inc. | Method and apparatus for bonding an active tag to a patch and a tire |
| DE19905820A1 (de) * | 1998-10-27 | 2000-05-04 | Degussa | Schwefelfunktionelle Polyorganosilane |
| US6156822A (en) | 1998-11-12 | 2000-12-05 | The Goodyear Tire & Rubber Company | Prepared reinforced elastomer, elastomer composite and tire having component thereof |
| FR2802542A1 (fr) | 1999-12-20 | 2001-06-22 | Michelin Soc Tech | Composition de caoutchouc vulcanisable pour la fabrication d'un pneumatique et pneumatique dont la bande de roulement comprend une telle composition |
| US6313220B1 (en) | 2000-03-03 | 2001-11-06 | Thierry Florent Edme Materne | Preparation of reinforced elastomer, elastomer composite, and tire having component thereof |
| DE10132942A1 (de) | 2001-07-06 | 2003-01-23 | Degussa | Siloxan-Oligomere, Verfahren zu deren Herstellung und deren Verwendung |
| US7301042B2 (en) | 2002-04-23 | 2007-11-27 | Cruse Richard W | Blocked mercaptosilane hydrolyzates as coupling agents for mineral-filled elastomer compositions |
| NZ537861A (en) | 2002-07-09 | 2008-09-26 | Momentive Performance Mat Inc | Silica-rubber mixtures having improved hardness |
| JP5433233B2 (ja) * | 2005-03-24 | 2014-03-05 | 株式会社ブリヂストン | 揮発性有機化合物（ｖｏｃ）の放出が少ないシリカ補強ゴムの配合 |
| US20090126845A1 (en) | 2007-11-15 | 2009-05-21 | Hogan Terrence E | Siloxane modified elastomers |
| JP2009161598A (ja) | 2007-12-28 | 2009-07-23 | Three M Innovative Properties Co | （メタ）アクリルグラフトシリコーンポリマー処理粉体及びそれを用いた製品 |
| DE102008010111A1 (de) | 2008-02-20 | 2009-09-03 | Continental Aktiengesellschaft | Verfahren zur Herstellung einer Kautschukmischung |
| US8182626B2 (en) | 2008-10-30 | 2012-05-22 | Continental Ag | Tire composition with improved vulcanizing agent |
| KR101152663B1 (ko) | 2009-10-28 | 2012-06-15 | 한국과학기술연구원 | 기능성 보강 충전제 및 이의 제조 방법 |
| JP6113402B2 (ja) * | 2010-12-27 | 2017-04-12 | 日本ゼオン株式会社 | ニトリルゴム組成物およびゴム架橋物 |
| JP5614308B2 (ja) * | 2011-01-28 | 2014-10-29 | 横浜ゴム株式会社 | タイヤ用ゴム組成物の製造方法 |
| JP5339008B2 (ja) * | 2011-08-26 | 2013-11-13 | 横浜ゴム株式会社 | タイヤトレッド用ゴム組成物 |
| JP6287324B2 (ja) * | 2013-02-25 | 2018-03-07 | 横浜ゴム株式会社 | スタッドレスタイヤ用ゴム組成物およびスタッドレスタイヤ |
| EP3086928B1 (de) * | 2013-12-27 | 2019-09-11 | Bridgestone Corporation | Aus zusammensetzungen mit mercaptofunktionellen siloxanen hergestellte vulkanisate und reifenkomponenten |
-
2014
- 2014-12-29 EP EP14833435.2A patent/EP3086928B1/de not_active Not-in-force
- 2014-12-29 CN CN201480071361.3A patent/CN105849175B/zh not_active Expired - Fee Related
- 2014-12-29 WO PCT/US2014/072511 patent/WO2015100449A2/en active Application Filing
- 2014-12-29 US US15/108,022 patent/US10150845B2/en active Active
- 2014-12-29 JP JP2016542908A patent/JP6591422B2/ja not_active Expired - Fee Related
-
2018
- 2018-12-07 US US16/213,496 patent/US10662298B2/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1163285A (zh) * | 1996-01-11 | 1997-10-29 | 米什兰集团总公司 | 用于外胎的橡胶组合物 |
| CN1265126A (zh) * | 1997-07-11 | 2000-08-30 | 米什兰集团总公司 | 以聚有机硅氧烷为偶联剂及白色填料增强的二烯橡胶组合物 |
| US5994456A (en) * | 1998-04-09 | 1999-11-30 | Dow Corning Corporation | Compositions comprising mercapto-functional organosilicon compounds |
| EP1640183A1 (de) * | 2004-09-23 | 2006-03-29 | The Goodyear Tire & Rubber Company | Reifen mit Lauffläche aus Kautschuk mit geringer Emissionsrate an flüchtigem Alkohol |
| CN101668791A (zh) * | 2007-04-27 | 2010-03-10 | 3M创新有限公司 | 接枝有机硅聚合物以及用其制备的产品 |
| CN102690449A (zh) * | 2012-06-21 | 2012-09-26 | 三角轮胎股份有限公司 | 含改性橡胶的充气轮胎橡胶组合物 |
Non-Patent Citations (1)
| Title |
|---|
| Click Chemistry: Diverse Chemical Function from a Few Good Reactions;sharpless 等;《angewandte chemie international edition》;20010828;第40卷(第11期);第2004-2021页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| US10662298B2 (en) | 2020-05-26 |
| WO2015100449A2 (en) | 2015-07-02 |
| EP3086928A2 (de) | 2016-11-02 |
| JP6591422B2 (ja) | 2019-10-16 |
| JP2017502149A (ja) | 2017-01-19 |
| WO2015100449A3 (en) | 2015-09-03 |
| EP3086928B1 (de) | 2019-09-11 |
| US20160333151A1 (en) | 2016-11-17 |
| CN105849175A (zh) | 2016-08-10 |
| US10150845B2 (en) | 2018-12-11 |
| US20190106546A1 (en) | 2019-04-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105849175B (zh) | 由包含巯基官能化硅氧烷的组合物制备的硫化橡胶和轮胎组件 | |
| JP6631254B2 (ja) | 空気入りタイヤ | |
| JP6627513B2 (ja) | 空気入りタイヤ | |
| JP6627294B2 (ja) | 空気入りタイヤ | |
| JP4451810B2 (ja) | ランフラットタイヤ | |
| WO2016039005A1 (ja) | 空気入りタイヤ | |
| JP6564882B2 (ja) | 有機リチウム化合物、これを利用した変性共役ジエン系重合体の製造方法及び変性共役ジエン系重合体 | |
| JP6627511B2 (ja) | 空気入りタイヤ | |
| BR102013024929B1 (pt) | Elastômero funcionalizado, composição de borracha, pneu pneumático e método para fabricar um elastômero funcionalizado | |
| KR20150024849A (ko) | 타이어 트레드용 고무 조성물 | |
| WO2016199915A1 (ja) | ゴム組成物およびそれを用いた空気入りタイヤ | |
| US8426515B2 (en) | Master batch elastometer containing organically modified silica and method of preparing the same | |
| JP2019116574A (ja) | トレッド用ゴム組成物及び空気入りタイヤ | |
| US20190389995A1 (en) | Rubber composition and tire | |
| JP5569226B2 (ja) | タイヤトレッド用ゴム組成物 | |
| WO2013058262A1 (ja) | タイヤ用ゴム組成物及び空気入りタイヤ | |
| JP5944778B2 (ja) | トレッド用ゴム組成物及び空気入りタイヤ | |
| JP4616550B2 (ja) | タイヤトレッド用ゴム組成物 | |
| CN108323168B (zh) | 改性单体、含有该改性单体的改性共轭二烯类聚合物及其制备方法 | |
| US11697305B2 (en) | Tire for a motorcycle | |
| KR102393234B1 (ko) | 고무 조성물 | |
| JP7375536B2 (ja) | トレッド用ゴム組成物およびタイヤ | |
| US20220403068A1 (en) | Modified Conjugated Diene-Based Polymer, Method for Preparing the Same and Rubber Composition Including the Same | |
| JP2021130800A (ja) | ゴム組成物及びタイヤ | |
| KR101005288B1 (ko) | 타이어 트레드용 고무 조성물 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20190924 |