CN105839463A - Release paper with stable peel strength - Google Patents
Release paper with stable peel strength Download PDFInfo
- Publication number
- CN105839463A CN105839463A CN201610126835.0A CN201610126835A CN105839463A CN 105839463 A CN105839463 A CN 105839463A CN 201610126835 A CN201610126835 A CN 201610126835A CN 105839463 A CN105839463 A CN 105839463A
- Authority
- CN
- China
- Prior art keywords
- coating
- cloudy surface
- antistatic agent
- film
- release paper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000011248 coating agent Substances 0.000 claims abstract description 49
- 238000000576 coating method Methods 0.000 claims abstract description 48
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 17
- -1 acrylic polyol Chemical class 0.000 claims abstract description 16
- 239000002216 antistatic agent Substances 0.000 claims abstract description 13
- 229920005862 polyol Polymers 0.000 claims abstract description 7
- 229920005989 resin Polymers 0.000 claims abstract description 6
- 239000011347 resin Substances 0.000 claims abstract description 6
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 5
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 5
- 239000010410 layer Substances 0.000 claims description 17
- 239000002245 particle Substances 0.000 claims description 12
- 230000000694 effects Effects 0.000 claims description 10
- 239000008187 granular material Substances 0.000 claims description 8
- 239000000377 silicon dioxide Substances 0.000 claims description 8
- 150000005846 sugar alcohols Polymers 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- 229920002799 BoPET Polymers 0.000 claims description 5
- 239000004698 Polyethylene Substances 0.000 claims description 4
- 239000011247 coating layer Substances 0.000 claims description 4
- 238000009826 distribution Methods 0.000 claims description 4
- 238000005286 illumination Methods 0.000 claims description 4
- 238000007561 laser diffraction method Methods 0.000 claims description 4
- 238000000790 scattering method Methods 0.000 claims description 4
- IUMSDRXLFWAGNT-UHFFFAOYSA-N Dodecamethylcyclohexasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 IUMSDRXLFWAGNT-UHFFFAOYSA-N 0.000 claims description 3
- 238000009503 electrostatic coating Methods 0.000 claims 1
- 229920000139 polyethylene terephthalate Polymers 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 229920002545 silicone oil Polymers 0.000 abstract description 4
- 230000005611 electricity Effects 0.000 abstract description 2
- 238000006116 polymerization reaction Methods 0.000 abstract description 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 abstract 1
- 150000003077 polyols Chemical class 0.000 abstract 1
- 230000003068 static effect Effects 0.000 abstract 1
- 239000000178 monomer Substances 0.000 description 5
- 238000002386 leaching Methods 0.000 description 4
- 239000012528 membrane Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 238000007711 solidification Methods 0.000 description 3
- 230000008023 solidification Effects 0.000 description 3
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 239000002390 adhesive tape Substances 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical compound C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 231100000241 scar Toxicity 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000002788 crimping Methods 0.000 description 1
- 229940086555 cyclomethicone Drugs 0.000 description 1
- 230000005686 electrostatic field Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/16—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising curable or polymerisable compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/001—Release paper
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4063—Mixtures of compounds of group C08G18/62 with other macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4804—Two or more polyethers of different physical or chemical nature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/22—Polyalkenes, e.g. polystyrene
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/32—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming a linkage containing silicon in the main chain of the macromolecule
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
- Paints Or Removers (AREA)
- Adhesive Tapes (AREA)
Abstract
The invention discloses a release paper with stable peel strength. A matt antistatic agent comprises, by mass, 4% of silica particles, 27.5% of acrylic polyol with an average molecular weight of 500 to 2000, 36.5% of polyoxyalkylene series polyol resin with an average molecular weight of 200 to 2500, 18.5% of polyethylene glycol, 6% of cyclomethyl siloxane and 7.5% of 1-hydroxycyclohexylphenyl ketone-photoinitiator 184. Ultraviolet rays with a wave band of 280 to 350 nm and illuminance of 1200 mW/cm<2> are employed for irradiation of the matt antistatic agent so as to allow components of the matt antistatic agent to undergo polymerization reaction under the action of 1-hydroxycyclohexylphenyl ketone-photoinitiator 184 so as to obtain the matt antistatic agent. The release paper provided by the invention can eliminate influence of static electricity on instable coating of silicone oil, has stable release peel strength and can prevent generation of electrostatic sparks in the process of production.
Description
Technical field
The present invention relates to a kind of release paper, stablize peeling force type release paper particularly to one.
Background technology
Existing release paper is usually at one layer of leaching membrane layer of surface film of release paper ground paper layer that (material of employing mainly has
Polyethylene), then obtain release paper the surface of leaching membrane layer one layer of mould release coating (material of employing is mainly silicone oil) of coating.
But owing to leaching membrane layer flatness is high, poor adhesive force between mould release coating and leaching membrane layer, when release paper be coated with high viscosity
When the pad pasting of binding agent attaches, the binding agent that the mould release coating being easily caused in release paper is attached power bigger is taken away, thus
Local surfaces at pad pasting forms the mould release coating area being difficult to clean out, and destroys pure, concordance that pad pasting is overall.And
And owing to production process electrostatic is excessive, cause the local out-of-flatness of release coating layer, not only affect product peeling force stability, and
Easily produce electrostatic spark and cause fire.
Summary of the invention
It is an object of the present invention to provide one and stablize peeling force type release paper, this stable peeling force type release paper can eliminate quiet
The impact that silicone oil coating instability is brought by electricity, release peeling force can be the most stable, also avoids the generation of production process electrostatic spark.
For reaching above-mentioned purpose, the technical solution used in the present invention is: one stablizes peeling force type release paper, described release
Film includes that upper and lower surface film respectively has the original paper layer of PE film and PET film, another surface-coated of the PET film of original paper layer to have
Cloudy surface anti-static coating, this another surface-coated of cloudy surface anti-static coating has mould release coating；Described cloudy surface anti-static coating with
The roughness on the surface of mould release coating layer touch is 2.83 μm～3.32 μm, and it is convex that this another surface of mould release coating has several
The portion of rising；
Described cloudy surface anti-static coating is formed by the coating of cloudy surface antistatic agent, and this cloudy surface antistatic agent is by following masses percentage composition
Component composition:
Silica granule 4%,
Mean molecule quantity is the acrylic polyol 27.5% of 500 ~ 2000,
Mean molecule quantity is resin 36.5 % of the polyoxyalkylene series polyhydric alcohol of 200 ~ 2500,
Polyethylene Glycol 18.5%,
Cyclomethicone 6%,
1-hydroxycyclohexyl phenyl ketone-light trigger 184 7.5%；
The particle diameter of described silica granule be in the particle size distribution measured by laser diffraction and scattering method particle diameter 0.1 ~ 2 μm and 1.5 ~
It is respectively provided with peak value in the range of 5 μm and mean diameter is 4 μm or following.
In technique scheme, further improved plan is as follows:
In such scheme, described cloudy surface antistatic agent uses ultra-violet bands to be 280nm ~ 350nm, and illumination is 1200mW/cm2,
Described cloudy surface anti-static coating is irradiated, makes described component at the work of 1-hydroxycyclohexyl phenyl ketone-light trigger 184
Carry out polyreaction under with and obtain cloudy surface anti-static coating.
Owing to technique scheme is used, the present invention compared with prior art has following advantages and an effect:
1, the present invention stablizes peeling force type release paper, and it uses the acrylic acid that mean molecule quantity is 500 ~ 2000 of certain content many
After the polyurethane resin of the resin polymerization of unit's alcohol and polyoxyalkylene series polyhydric alcohol that mean molecule quantity is 200 ~ 2500 also
Mix with cyclomethicone, mean molecule quantity be 500 ~ 2000 acrylic polyol and mean molecule quantity be 200 ~ 2500
Chain in the resin of polyoxyalkylene series polyhydric alcohol improves film surface anti-static performance, and also improves scratch resistance performance simultaneously；
Its polyalcohol acrylate monomer has the mean molecule quantity of 500 ~ 2000, if molecular weight is less than 500, the wearability of film tends to
Reducing, if mean molecule quantity is more than 2000, during film-forming, the suitability is deteriorated.If polyalcohol acrylate monomer specifically for
Ethylene glycol, it is contemplated that water absorbing capacity, the Polyethylene Glycol that the present invention selects mean molecule quantity to be 200 ~ 1000, make use of it superior
Absorb the ability combining water, further increase anti-static effect.Owing to this acrylic polyol monomer has especially advantageous
Absorption combine the ability of water of water form, there is anti-static effect, polyalcohol acrylate monomer all can use this
Monomer.
2, first the present invention is coated with cloudy surface anti-static coating to the surface of thin layer, passes through formula through cloudy surface anti-static coating
With the surface after PROCESS FOR TREATMENT, there is some uniform concaveconvex structures and anti-static effect, be then coated with at this surface silicon-coating mould release
Layer coating, the bottom surface of silicon mould release coating coating is penetrated at the notch on described cloudy surface anti-static coating surface in the liquid state, silicon from
Type agent coating coating is after solidification by being fixedly linked with cloudy surface anti-static coating at notch, therefore, adhesion more firmly, can
Lean on.And owing to antistatic processes, the impact that silicone oil coating instability is brought by electrostatic can be eliminated, release peeling force can be the most steady
Fixed, also avoid the generation of production process electrostatic spark.
3, the present invention uses light trigger 1-hydroxycyclohexyl phenyl ketone cause, mainly consider that it at wave band is
320-400nm ultraviolet light irradiate under, can instantaneous solidification film forming, can reach deep cure, there is good planarization and intensity.Institute
Stating light trigger is 1-hydroxycyclohexyl phenyl ketone-light trigger 184, is the ultraviolet initiator of a kind of efficient non yellowing,
For causing the UV polyreaction of unsaturated prepolymerization system, its mass content is 5～10 %.
4, the present invention stablizes peeling force type release paper, described silica granule be particle diameter be to be measured by laser diffraction and scattering method
Particle size distribution in particle diameter in the range of 0.1 ~ 2 μm and 1.5 ~ 5 μm, be respectively provided with peak value and mean diameter is 4 μm or following
Silica granule, both substantially increased atomized surface effect, in turn ensure that solidification effect.
5, the power of medium ultraviolet light of the present invention uses 1200mW/cm2If mainly power is less than 1200mW/cm2, film is the completeest
All solidstate, wearability reduces；If if power is higher than 1200mW/cm2, affecting film flatness, the suitability declines.Use ultraviolet ripple
Section is 320 ~ 400nm, and illumination is 1200mW/cm2, described cloudy surface coating agent is irradiated, makes described component special in the present invention
It being set for obtaining cloudy surface coating for carrying out polyreaction under the effect of the 1-hydroxycyclohexyl phenyl ketone of light trigger, thickness is 4 ~
10 μm, have an anti-static effect, then obtain cloudy surface release layer in one layer of mould release coating of surface-coated of described cloudy surface coating.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described:
Embodiment: one stablizes peeling force type release paper, and described release paper includes that upper and lower surface film respectively has PE film
With the original paper layer of PET film, another surface-coated of the PET film of original paper layer has cloudy surface anti-static coating, and this cloudy surface anti-static coating is another
One surface-coated has mould release coating；Described cloudy surface anti-static coating is 2.83 with the roughness on the surface of mould release coating layer touch
μm～3.32 μm, this another surface of mould release coating has several lobe；
Described cloudy surface anti-static coating is formed by the coating of cloudy surface antistatic agent, and this cloudy surface antistatic agent is by following masses percentage composition
Component composition:
Silica granule 4%,
Mean molecule quantity is the acrylic polyol 27.5% of 500 ~ 2000,
Mean molecule quantity is resin 36.5 % of the polyoxyalkylene series polyhydric alcohol of 200 ~ 2500,
Polyethylene Glycol 18.5%,
Cyclomethicone 6%,
1-hydroxycyclohexyl phenyl ketone-light trigger 184 7.5%；
The particle diameter of described silica granule be in the particle size distribution measured by laser diffraction and scattering method particle diameter 0.1 ~ 2 μm and 1.5 ~
It is respectively provided with peak value in the range of 5 μm and mean diameter is 4 μm or following.
Above-mentioned cloudy surface antistatic agent uses ultra-violet bands to be 280nm ~ 350nm, and illumination is 1200mW/cm2, to described mist
Face anti-static coating is irradiated, and makes described component carry out under the effect of 1-hydroxycyclohexyl phenyl ketone-light trigger 184
Polyreaction obtains cloudy surface anti-static coating.
Performance indications are as shown in table 1:
Table 1
(1), ocular estimate: the existence of outward appearance, transparency and crackle is evaluated by visual observation.No problem film
Being rated as satisfactory (O), problematic film is rated as unsatisfactory (X)；
(2), private seal by release aspect private seal 10 times, be qualified without delustring, delustring is defective；
(3), hundred lattice test cross-cut testers tests without coming off for qualified products, come off for substandard product；
(4), peel off voltage roller and adhesive tape crimping (1 kilogram back and forth, speed 0.3m/min), in release face, thereafter, is used hands
Quickly peel off (10m/min), read adhesive tape with electrostatic field tester (model: SIMCO FMX-003) and glue the stripping of release face
The maximum of electrostatic pressure, electrostatic pressure is qualified products less than 0.3KV, and electrostatic pressure is substandard product more than 0.3KV；
(5), two, face of surface resistance value sheet resistance tester G parallel copper electrodes be placed in the arbitrary place of sample surfaces, press black
Color A key, waits about 30 seconds, resistance at LED display test, and ambient temperature and humidity is noted down.Display surface resistance < 1.0E+10
Ω/sq, (65%RH, 23 DEG C) is qualified；Display surface resistance > 1.0E+10 Ω/sq, (65%RH, 23 DEG C) is defective.
(6) wearability test is at the 500g/cm of steel wire face (#0000)2The pressure that adds hard conating face is rubbed after 30 times,
To not having scar to be denoted as O, it is denoted as X to there being scar.
(7) pencil hardness test evaluates the pencil hardness of hard coating film according to GB/T 6739-2006.
Above-described embodiment, only for technology design and the feature of the explanation present invention, its object is to allow person skilled in the art
Scholar will appreciate that present disclosure and implements according to this, can not limit the scope of the invention with this.All according to the present invention
The equivalence that spirit is made changes or modifies, and all should contain within protection scope of the present invention.
Claims (1)
1. stablize peeling force type release paper for one kind, it is characterised in that: include that upper and lower surface film respectively has PE film and PET
The original paper layer of film, another surface-coated of the PET film of original paper layer has cloudy surface anti-static coating, this another surface of cloudy surface anti-static coating
It is coated with mould release coating；The roughness on the surface of described cloudy surface anti-static coating and mould release coating layer touch be 2.83 μm～
3.32 μm, this another surface of mould release coating has several lobe；
Described cloudy surface anti-static coating is formed by the coating of cloudy surface antistatic agent, and this cloudy surface antistatic agent is by following masses percentage composition
Component composition:
Silica granule 4%,
Mean molecule quantity is the acrylic polyol 27.5% of 500 ~ 2000,
Mean molecule quantity is resin 36.5 % of the polyoxyalkylene series polyhydric alcohol of 200 ~ 2500,
Polyethylene Glycol 18.5%,
Cyclomethicone 6%,
1-hydroxycyclohexyl phenyl ketone-light trigger 184 7.5%；
The particle diameter of described silica granule be in the particle size distribution measured by laser diffraction and scattering method particle diameter 0.1 ~ 2 μm and 1.5 ~
It is respectively provided with peak value in the range of 5 μm and mean diameter is 4 μm or following；
Described cloudy surface antistatic agent uses ultra-violet bands to be 280nm ~ 350nm, and illumination is 1200mW/cm2, described cloudy surface is prevented
Electrostatic coating is irradiated, and makes described component be polymerized under the effect of 1-hydroxycyclohexyl phenyl ketone-light trigger 184
Reaction obtains cloudy surface anti-static coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201610126835.0A CN105839463A (en) | 2012-12-28 | 2012-12-28 | Release paper with stable peel strength |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210584167.8A CN103103875B (en) | 2012-12-28 | 2012-12-28 | For the cloudy surface antistatic agent of mould release membrance |
| CN201610126835.0A CN105839463A (en) | 2012-12-28 | 2012-12-28 | Release paper with stable peel strength |
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| CN201210584167.8A Division CN103103875B (en) | 2012-12-28 | 2012-12-28 | For the cloudy surface antistatic agent of mould release membrance |
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| CN105839463A true CN105839463A (en) | 2016-08-10 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610127830.XA Pending CN105839454A (en) | 2012-12-28 | 2012-12-28 | Rapidly-cured release film |
| CN201610126835.0A Pending CN105839463A (en) | 2012-12-28 | 2012-12-28 | Release paper with stable peel strength |
| CN201610126036.3A Active CN105839462B (en) | 2012-12-28 | 2012-12-28 | Adhesive tape release paper cloudy surface coating agent |
| CN201610126898.6A Active CN105839464B (en) | 2012-12-28 | 2012-12-28 | For the antistatic coating agent of barrier paper |
| CN201210584167.8A Active CN103103875B (en) | 2012-12-28 | 2012-12-28 | For the cloudy surface antistatic agent of mould release membrance |
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| CN201610127830.XA Pending CN105839454A (en) | 2012-12-28 | 2012-12-28 | Rapidly-cured release film |
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| CN201610126036.3A Active CN105839462B (en) | 2012-12-28 | 2012-12-28 | Adhesive tape release paper cloudy surface coating agent |
| CN201610126898.6A Active CN105839464B (en) | 2012-12-28 | 2012-12-28 | For the antistatic coating agent of barrier paper |
| CN201210584167.8A Active CN103103875B (en) | 2012-12-28 | 2012-12-28 | For the cloudy surface antistatic agent of mould release membrance |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110254011A (en) * | 2019-06-28 | 2019-09-20 | 深圳泰源龙电子科技有限公司 | Transparent PET Anti-static release liner and preparation process |
| CN110904733A (en) * | 2019-12-04 | 2020-03-24 | 江苏双冠新材料科技有限公司 | Preparation method of matte PET release paper |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104988805A (en) * | 2015-06-08 | 2015-10-21 | 东莞市尚鑫纸业有限公司 | Release paper applied to electric field and manufacturing technology thereof |
| CN105274905A (en) * | 2015-09-14 | 2016-01-27 | 衢州五洲特种纸业有限公司 | White glassine and preparation method |
| CN108820588A (en) * | 2018-08-06 | 2018-11-16 | 杭州创嘉印刷文化有限公司 | Ice cream cylinder |
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- 2012-12-28 CN CN201610126835.0A patent/CN105839463A/en active Pending
- 2012-12-28 CN CN201610126036.3A patent/CN105839462B/en active Active
- 2012-12-28 CN CN201610126898.6A patent/CN105839464B/en active Active
- 2012-12-28 CN CN201210584167.8A patent/CN103103875B/en active Active
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| CN102587205A (en) * | 2011-01-11 | 2012-07-18 | 昆山福泰涂布科技有限公司 | Antistatic release paper and making method thereof |
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| CN110904733B (en) * | 2019-12-04 | 2022-03-01 | 江苏双冠新材料科技有限公司 | Preparation method of matte PET release paper |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105839462B (en) | 2018-06-19 |
| CN105839464A (en) | 2016-08-10 |
| CN105839454A (en) | 2016-08-10 |
| CN103103875A (en) | 2013-05-15 |
| CN105839462A (en) | 2016-08-10 |
| CN105839464B (en) | 2018-06-19 |
| CN103103875B (en) | 2016-04-27 |
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Application publication date: 20160810 |