CN102350846A - Preparation method of novel cloudy-surface release paper - Google Patents
Preparation method of novel cloudy-surface release paper Download PDFInfo
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- CN102350846A CN102350846A CN201110194532XA CN201110194532A CN102350846A CN 102350846 A CN102350846 A CN 102350846A CN 201110194532X A CN201110194532X A CN 201110194532XA CN 201110194532 A CN201110194532 A CN 201110194532A CN 102350846 A CN102350846 A CN 102350846A
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- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 239000011248 coating agent Substances 0.000 claims abstract description 57
- 238000000576 coating method Methods 0.000 claims abstract description 45
- 229920000728 polyester Polymers 0.000 claims abstract description 17
- 239000000758 substrate Substances 0.000 claims abstract description 11
- 150000001875 compounds Chemical class 0.000 claims abstract description 3
- 239000010410 layer Substances 0.000 claims description 56
- -1 acrylic ester Chemical class 0.000 claims description 31
- 239000010408 film Substances 0.000 claims description 23
- 239000012528 membrane Substances 0.000 claims description 18
- 238000002386 leaching Methods 0.000 claims description 17
- 239000012790 adhesive layer Substances 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 10
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 9
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 9
- 239000004698 Polyethylene Substances 0.000 claims description 9
- 239000000178 monomer Substances 0.000 claims description 9
- 229920000573 polyethylene Polymers 0.000 claims description 7
- 239000011347 resin Substances 0.000 claims description 7
- 229920005989 resin Polymers 0.000 claims description 7
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 6
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 6
- 239000004743 Polypropylene Substances 0.000 claims description 6
- 239000000654 additive Substances 0.000 claims description 6
- 230000000996 additive effect Effects 0.000 claims description 6
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 claims description 6
- 229920001155 polypropylene Polymers 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 5
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 5
- 239000004800 polyvinyl chloride Substances 0.000 claims description 5
- VBHDMJVUPJVYJZ-UHFFFAOYSA-N 2-nonylphenol;prop-2-enoic acid Chemical compound OC(=O)C=C.CCCCCCCCCC1=CC=CC=C1O VBHDMJVUPJVYJZ-UHFFFAOYSA-N 0.000 claims description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 4
- 244000028419 Styrax benzoin Species 0.000 claims description 4
- 235000000126 Styrax benzoin Nutrition 0.000 claims description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Natural products CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 4
- 150000004703 alkoxides Chemical class 0.000 claims description 4
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 4
- 239000000292 calcium oxide Substances 0.000 claims description 4
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 claims description 4
- LMYRWZFENFIFIT-UHFFFAOYSA-N toluene-4-sulfonamide Chemical compound CC1=CC=C(S(N)(=O)=O)C=C1 LMYRWZFENFIFIT-UHFFFAOYSA-N 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 3
- 235000008411 Sumatra benzointree Nutrition 0.000 claims description 3
- 125000001931 aliphatic group Chemical group 0.000 claims description 3
- 229960002130 benzoin Drugs 0.000 claims description 3
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical group C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 3
- 239000012965 benzophenone Substances 0.000 claims description 3
- 239000005025 cast polypropylene Substances 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims description 3
- 235000019382 gum benzoic Nutrition 0.000 claims description 3
- 229920001427 mPEG Polymers 0.000 claims description 3
- 239000000395 magnesium oxide Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 3
- 229920005644 polyethylene terephthalate glycol copolymer Polymers 0.000 claims description 3
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 claims description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 2
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 claims description 2
- 125000003944 tolyl group Chemical group 0.000 claims description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract description 11
- 229910052710 silicon Inorganic materials 0.000 abstract description 11
- 239000010703 silicon Substances 0.000 abstract description 11
- 239000003795 chemical substances by application Substances 0.000 abstract description 4
- 239000007788 liquid Substances 0.000 abstract description 3
- 239000006082 mold release agent Substances 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 description 5
- 230000001070 adhesive effect Effects 0.000 description 5
- 229920003002 synthetic resin Polymers 0.000 description 4
- 239000000057 synthetic resin Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 3
- 239000000025 natural resin Substances 0.000 description 3
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 2
- 239000002390 adhesive tape Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000003595 mist Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 2
- PJAKWOZHTFWTNF-UHFFFAOYSA-N (2-nonylphenyl) prop-2-enoate Chemical compound CCCCCCCCCC1=CC=CC=C1OC(=O)C=C PJAKWOZHTFWTNF-UHFFFAOYSA-N 0.000 description 1
- XDFYLDYPTBNHRY-UHFFFAOYSA-N C(CCCCCCCCCCCCCCCCC)C(C(=O)OCCCCCCCCCCCCCCCCCC)=C.C(C=C)(=O)O Chemical compound C(CCCCCCCCCCCCCCCCC)C(C(=O)OCCCCCCCCCCCCCCCCCC)=C.C(C=C)(=O)O XDFYLDYPTBNHRY-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 235000015511 Liquidambar orientalis Nutrition 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 229920001800 Shellac Polymers 0.000 description 1
- 239000004870 Styrax Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000007766 curtain coating Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- XPJRQAIZZQMSCM-UHFFFAOYSA-N heptaethylene glycol Polymers OCCOCCOCCOCCOCCOCCOCCO XPJRQAIZZQMSCM-UHFFFAOYSA-N 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 1
- 239000004208 shellac Substances 0.000 description 1
- 229940113147 shellac Drugs 0.000 description 1
- 235000013874 shellac Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
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- Laminated Bodies (AREA)
- Adhesive Tapes (AREA)
Abstract
The invention relates to a preparation method of novel cloudy-surface release paper, which comprises the following steps that: a film-coated layer is coated on one side surface of a base release paper, a cementing compound layer is coated on the other side surface of the base release paper after being cooled to obtain a substrate layer to standby use; a layer of cloudy-surface coating agent with the thickness of 0.2 micrometer to 2 micrometers is coated on the surface of a film layer; the cloudy-surface coating agent is radiated by ultraviolet rays to obtain a cloudy-surface coating, and then a layer of mold release agent is coated on the surface of the cloudy-surface coating to obtain a cloudy-surface release layer for standby use; and the cloudy-surface release layer is bonded with the substrate layer. Sine the polyester cloudy-surface coating is firstly coated on the surface of the film layer, a plurality of convex-concave structures are obtained on the surface of the film layer after being processed; and then the silicon release agent coating is coated on the surface of the cloudy-surface coating, the bottom surface of the silicon release agent coating at a liquid state penetrates into concaves on the surface of the polyester cloudy-surface coating and the silicon release agent coating is fixedly connected with the polyester cloudy-surface coating through the concaves after being solidified, so the bonding force is firmer and more reliable.
Description
Technical field
The present invention relates to a kind of preparation method of novel cloudy surface release liners, the preparation method of a kind of novel cloudy surface release liners that particularly a kind of adhesion strength is high, peeling force is adjustable.
Background technology
Release liners is claimed barrier paper, separate paper again, is mainly used in to paste the adhesive layer that is used for the protective tapes surface on the surface of adhesive tape.Existing release liners generally is to drench film one deck leaching membrane layer (material of employing mainly contains polyethylene) on the surface of release liners ground paper layer, and the surface coated one deck parting agent layer (material of employing is mainly silicone oil) at leaching membrane layer obtains release liners then.But because the leaching membrane layer flatness is high; Poor adhesive force between mould release coating and the leaching membrane layer; When release liners attaches with the pad pasting that is coated with trowel adhesive; Cause the mould release coating on the release liners to be taken away easily, thereby form the mould release coating area that is difficult to clean out, destroyed whole pure, the uniformity of pad pasting in the local surfaces of pad pasting by the bigger adhesive of adhesion.
Summary of the invention
The present invention provides a kind of preparation method of novel cloudy surface release liners, and purpose is leaching membrane layer and the not high problem of mould release coating adhesion that solves release liners.
For achieving the above object, the technical scheme that the present invention adopts is: a kind of preparation method of novel cloudy surface release liners, mainly be made up of the following step:
(1) at a side surface of a release liners body paper, drench film one deck leaching membrane layer with drenching the film machine, wait said leaching membrane layer cooling after, obtain substrate layer at opposite side surface coated one deck adhesive layer of said release liners body paper, subsequent use;
(2) at surface coated one layer thickness of a thin layer be 0.2～2 micron cloudy surface coating agent, this cloudy surface coating agent is made up of the compound of following quality percentage composition:
Polyfunctional acrylic ester monomer 30～50%;
Initator 0.1～1%;
Solvent 45～66%;
Said cloudy surface additive is that particle diameter is at least a in the resin particle, aluminium oxide, magnesia, calcium oxide of 20 nanometers～2 micron;
Said polyfunctional acrylic ester monomer is at least a in methyl acrylate, ethyl acrylate, 2-methyl methacrylate, ethyl 2-methacrylate, methoxy poly (ethylene glycol) mono acrylic ester, alkoxide lauryl acrylate, acrylic acid stearyl, alkoxide nonyl phenol acrylic acid ester, epoxy acrylate, polyester acrylate, the polyfunctional group aliphatic urethane acrylate;
Said initator is benzophenone, para toluene sulfonamide, triphenyl phosphate or benzoin dimethylether;
Said solvent is toluene, ethyl acetate or positive butanone;
Adopt ultraviolet ray that said cloudy surface coating agent is shone, make said polyfunctional acrylic ester monomer under action of evocating, carry out polymerisation and obtain the cloudy surface coating, the surface-coated one deck mould release in said cloudy surface coating obtains the cloudy surface release layer again, and is subsequent use;
(3), said cloudy surface release layer and said substrate layer are fitted with the thin layer of said cloudy surface release layer adhesive layer towards said substrate layer.
Related content in the technique scheme is explained as follows:
1, in the such scheme, said mould release coating is to be used for isolating adhesive on the adhesive tape to make it and the release liners bonding, thus require its not with adhesive generation cross-linking reaction, the material of its use is mainly silicone oil.
2, in the such scheme, said ultraviolet ray (UV) mainly is meant UVA, UVB and UVC.
3, in the such scheme, methoxy poly (ethylene glycol) mono acrylic ester (Methoxy Glycol 350 Monoacrylate; Methoxy Polyethylene Glycol 350 Monoacrylate; CH
3O (CH
2CH
2O)
nOCCH=CH
2N=8～33), alkoxide lauryl acrylate (Alkoxylated Lauryl Acrylate), acrylic acid stearyl (Stearyl Acrylate), alkoxide nonyl phenol acrylic acid ester (Alkoxylated Nonyl Phenol Acrylate), epoxy acrylate (Epoxy Acrylate), polyester acrylate (Polyester Acrylate), the polyfunctional group aliphatic urethane acrylate can be available from the chemical Co., Ltd of Sartomer (Guangzhou).
4, in the such scheme, resin can be natural resins such as rosin, styrax; Phenolic resins, Corvic etc. are synthetic resin.Resin has the branch of natural resin and synthetic resin.Natural resin is meant the amorphous organic substance by occurring in nature animals and plants secretion gained, like rosin, amber, shellac etc.Synthetic resin is meant the resin product that is obtained through chemical reaction through chemical synthesis or some natural products by simple organic.Synthetic resin is the main component of plastics.
5, in the such scheme, the material of said leaching membrane layer is PETG, polypropylene, polyethylene or polyvinyl chloride.
6, in the such scheme, said film is pet film, polypropylene film, polyethylene film, polyvinyl chloride or cast polypropylene film.
Because the technique scheme utilization, the present invention compared with prior art has advantage and effect:
The present invention is at first to the surface coated polyester cloudy surface coating (material is a polyester) of thin layer; The surface has some even concaveconvex structures after treatment; In this surface coated silicon mould release coating, the notch place of said polyester cloudy surface coating surface is infiltrated in the bottom surface of silicon mould release coating under liquid state then, and silicon mould release coating is fixedly linked through notch and polyester cloudy surface coating after solidifying; Therefore, adhesion more firmly, reliably.But also can freely adjust the size of peeling force between silicon mould release coating and the release liners body paper through regulating the mist degree (being roughness) of cloudy surface coating.
Description of drawings
Accompanying drawing 1 is a sketch map of the present invention.
In the above accompanying drawing: 1, leaching membrane layer; 2, release liners original paper layer; 3, adhesive layer; 4, thin layer; 5, cloudy surface coating; 6, mould release coating.
The specific embodiment
Below in conjunction with accompanying drawing and embodiment the present invention is further described:
The preparation method of embodiment one, a kind of novel cloudy surface release liners
Shown in accompanying drawing 1, a kind of preparation method of novel cloudy surface release liners, making step is following:
At first, to the surface treatment of release liners body paper, make its surface not have paper scrap, stains.
(1) at a side surface of release liners body paper, drench film one deck PE leaching membrane layer 1 with drenching the film machine, wait said leaching membrane layer 1 cooling after, obtain substrate layer at opposite side surface coated one deck adhesive layer 3 of said release liners body paper, subsequent use.Drenching the film machine can use the high speed of Changzhou next adopted plastics machinery Co., Ltd production to extrude single face curtain coating compounding machine group A type.
(2) at surface coated one layer thickness of pet film layer be 0.2～2 micron cloudy surface coating agent, the prescription of this cloudy surface coating agent is seen table 1.
Adopt ultraviolet ray that said cloudy surface coating agent is shone, make said polyfunctional acrylic ester monomer under action of evocating, carry out polymerisation and obtain the cloudy surface coating, the surface-coated one deck mould release in said cloudy surface coating obtains the cloudy surface release layer again, and is subsequent use;
(3), said cloudy surface release layer and said substrate layer are fitted with the thin layer 4 of said cloudy surface release layer adhesive layer 3 towards said substrate layer.
The cloudy surface release liners that makes is referring to shown in the accompanying drawing 1; Stacked gradually for 6 six layers by leaching membrane layer 1, release liners original paper layer 2, adhesive layer 3, thin layer 4, cloudy surface coating 5 and mould release coating and to constitute, the surface roughness of said cloudy surface coating 5 towards the surface of said mould release coating 6 is 2.821um～3.324um.Testing standard: ISO4287:1998.Roughness tester: the TR200 hand-held roughmeter of Beijing epoch peak Science and Technology Ltd. production.Said cloudy surface coating 5 is a polyester cloudy surface coating.At first the one side of release liners original paper layer 2 (common paper) being drenched membrane material is first leaching membrane layer 1 of PE; Another side coating one deck adhesive layer 3, applying thin film layer 4 on adhesive layer 3 again is then in the surface coated polyester cloudy surface coating 5 (material is a polyester) of thin layer 4; The surface has some even concaveconvex structures after treatment; In this surface coated silicon mould release coating 6, the notch place on said polyester cloudy surface coating 5 surfaces is infiltrated in the bottom surface of silicon mould release coating 6 under liquid state then, and silicon mould release coating 6 is fixedly linked through notch and polyester cloudy surface coating 5 after solidifying; Therefore, adhesion more firmly, reliably.But also can freely adjust the size of peeling force between silicon mould release coating 6 and the release liners body paper through regulating the mist degree (being roughness) of cloudy surface coating 5.
Embodiment two～five: a kind of its preparation method of cloudy surface release liners
1, method is with embodiment two.
2, the relevant material of embodiment two～five uses is following:
(1) material of leaching membrane layer: embodiment three, polyvinyl chloride; Embodiment four, PETG; Embodiment five, polyethylene; Embodiment six, polypropylene.
(2) thin layer: embodiment three, polypropylene film; Embodiment four, polyethylene film; Embodiment five, cast polypropylene film; Embodiment six pet films.
3, the prescription of cloudy surface coating agent is seen table 1.
Table 1
| ? | Embodiment one | Embodiment two | Embodiment three | Embodiment four | Embodiment five |
| The cloudy surface additive | 4% | 5% | 2% | 2.5% | 6% |
| The polyfunctional acrylic ester monomer | 34.5% | 30% | 43% | 45% | 44.3% |
| Initator | 0.2% | 0.5% | 0.7% | 1% | 0.7% |
| Solvent | 61.3% | 64.5% | 54.3% | 51.5% | 49% |
Annotate: in the table 1:
1, cloudy surface additive: embodiment one, magnesia; Embodiment two, organic resin; Embodiment three, aluminium oxide; Embodiment four, calcium oxide and organic resin are according to the mass ratio of 1:1; Embodiment five, calcium oxide.
2, polyfunctional acrylic ester monomer: embodiment one, alkoxide lauryl acrylate; Embodiment two, ethyl acrylate and acrylic acid stearyl mix according to the mass ratio of 1:5 between the two; Embodiment three, polyester acrylate; Embodiment four, alkoxide nonyl phenol acrylic acid ester; Embodiment five, alkoxide lauryl acrylate.
3, initator: embodiment one, para toluene sulfonamide; Embodiment two, triphenyl phosphate; Embodiment three, benzoin dimethylether; Embodiment four, benzophenone; Embodiment five, para toluene sulfonamide.
4, solvent: embodiment one～two, ethyl acetate; Embodiment three～five, methyl acetone.
The foregoing description only is explanation technical conceive of the present invention and characteristics, and its purpose is to let the personage who is familiar with this technology can understand content of the present invention and enforcement according to this, can not limit protection scope of the present invention with this.All equivalences that spirit is done according to the present invention change or modify, and all should be encompassed within protection scope of the present invention.
Claims (3)
1. the preparation method of a novel cloudy surface release liners is characterized in that: mainly be made up of the following step:
(1) at a side surface of a release liners body paper, drench film one deck leaching membrane layer with drenching the film machine, wait said leaching membrane layer cooling after, obtain substrate layer at opposite side surface coated one deck adhesive layer of said release liners body paper, subsequent use;
(2) at surface coated one layer thickness of a thin layer be 0.2～2 micron cloudy surface coating agent, this cloudy surface coating agent is made up of the compound of following quality percentage composition:
Cloudy surface additive 2～6%;
Polyfunctional acrylic ester monomer 30～50%;
Initator 0.1～1%;
Solvent 45～66%;
Said cloudy surface additive is that particle diameter is at least a in the resin particle, aluminium oxide, magnesia, calcium oxide of 20 nanometers～2 micron;
Said polyfunctional acrylic ester monomer is at least a in methyl acrylate, ethyl acrylate, 2-methyl methacrylate, ethyl 2-methacrylate, methoxy poly (ethylene glycol) mono acrylic ester, alkoxide lauryl acrylate, acrylic acid stearyl, alkoxide nonyl phenol acrylic acid ester, epoxy acrylate, polyester acrylate, the polyfunctional group aliphatic urethane acrylate;
Said initator is benzophenone, para toluene sulfonamide, triphenyl phosphate or benzoin dimethylether;
Said solvent is toluene, ethyl acetate or positive butanone;
Adopt ultraviolet ray that said cloudy surface coating agent is shone, make said polyfunctional acrylic ester monomer under action of evocating, carry out polymerisation and obtain the cloudy surface coating, the surface-coated one deck mould release in said cloudy surface coating obtains the cloudy surface release layer again, and is subsequent use;
(3), said cloudy surface release layer and said substrate layer are fitted with the thin layer of said cloudy surface release layer adhesive layer towards said substrate layer.
2. the preparation method of novel cloudy surface release liners according to claim 1 is characterized in that: the material of said leaching membrane layer is PETG, polypropylene, polyethylene or polyvinyl chloride.
3. the preparation method of novel cloudy surface release liners according to claim 1 is characterized in that: said film is pet film, polypropylene film, polyethylene film, polyvinyl chloride or cast polypropylene film.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310032573.8A CN103103883B (en) | 2011-07-12 | 2011-07-12 | Preparation method of fog face release paper |
| CN 201110194532 CN102350846B (en) | 2011-07-12 | 2011-07-12 | Preparation method of novel cloudy-surface release paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110194532 CN102350846B (en) | 2011-07-12 | 2011-07-12 | Preparation method of novel cloudy-surface release paper |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310031882.3A Division CN103114498B (en) | 2011-07-12 | 2011-07-12 | Method for preparing matte release paper for adhesive tapes |
| CN201310032573.8A Division CN103103883B (en) | 2011-07-12 | 2011-07-12 | Preparation method of fog face release paper |
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| Publication Number | Publication Date |
|---|---|
| CN102350846A true CN102350846A (en) | 2012-02-15 |
| CN102350846B CN102350846B (en) | 2013-10-30 |
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| CN 201110194532 Active CN102350846B (en) | 2011-07-12 | 2011-07-12 | Preparation method of novel cloudy-surface release paper |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102704333A (en) * | 2012-05-14 | 2012-10-03 | 斯迪克新型材料（江苏）有限公司 | Coated mist release paper |
| CN102702883A (en) * | 2012-05-14 | 2012-10-03 | 斯迪克新型材料（江苏）有限公司 | Matte release agent |
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| CN103061207A (en) * | 2012-12-20 | 2013-04-24 | 苏州斯迪克新材料科技股份有限公司 | Preparation method of novel matte anti-static release paper |
| CN103074819A (en) * | 2012-12-20 | 2013-05-01 | 斯迪克新型材料（江苏）有限公司 | Anti-scuffing matt-surface antistatic release paper |
| CN103103875A (en) * | 2012-12-28 | 2013-05-15 | 斯迪克新型材料（江苏）有限公司 | Mist antistatic agent for release liner |
| CN104975536A (en) * | 2015-06-09 | 2015-10-14 | 东莞市尚鑫纸业有限公司 | Low density and soft release paper |
| CN104988803A (en) * | 2015-06-08 | 2015-10-21 | 东莞市尚鑫纸业有限公司 | Anti-microbial release paper used in medical field |
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| CN108049250A (en) * | 2017-12-18 | 2018-05-18 | 温州市新丰装饰材料有限公司 | A kind of shaggy special release paper preparation method |
| CN111993730A (en) * | 2020-08-28 | 2020-11-27 | 淄博金豪塑料新材料股份有限公司 | Research and development of 15 g light-stripping anti-yellowing isolation film |
| CN115536890A (en) * | 2022-11-04 | 2022-12-30 | 惠州市鑫亚凯立科技有限公司 | Optical fluorine release film with three-dimensional micro-nano structure and manufacturing method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11301096A (en) * | 1998-04-20 | 1999-11-02 | Konica Corp | Ink jet recording paper |
| EP1916569A1 (en) * | 2005-08-17 | 2008-04-30 | Nippon Paper Industries Co., Ltd. | Electrophotographic transfer paper |
| CN101565918A (en) * | 2009-06-05 | 2009-10-28 | 中国乐凯胶片集团公司 | High-light release paper for synthetic leather |
| CN101597874A (en) * | 2009-06-24 | 2009-12-09 | 朱锦佐 | A kind of manufacture craft of embossing laminating release paper |
| CN101709559A (en) * | 2009-09-15 | 2010-05-19 | 苏州斯迪克电子胶粘材料有限公司 | High-brightness release paper, and preparation method and applications thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101245153B (en) * | 2008-03-31 | 2010-06-23 | 四川东材科技集团股份有限公司 | Production method for transparent suboptical polyester film |
| JP5607337B2 (en) * | 2009-10-27 | 2014-10-15 | リンテック株式会社 | Water-dispersed acrylic pressure-sensitive adhesive composition, pressure-sensitive adhesive sheet and method for producing the same |
-
2011
- 2011-07-12 CN CN201310032573.8A patent/CN103103883B/en active Active
- 2011-07-12 CN CN 201110194532 patent/CN102350846B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11301096A (en) * | 1998-04-20 | 1999-11-02 | Konica Corp | Ink jet recording paper |
| EP1916569A1 (en) * | 2005-08-17 | 2008-04-30 | Nippon Paper Industries Co., Ltd. | Electrophotographic transfer paper |
| CN101565918A (en) * | 2009-06-05 | 2009-10-28 | 中国乐凯胶片集团公司 | High-light release paper for synthetic leather |
| CN101597874A (en) * | 2009-06-24 | 2009-12-09 | 朱锦佐 | A kind of manufacture craft of embossing laminating release paper |
| CN101709559A (en) * | 2009-09-15 | 2010-05-19 | 苏州斯迪克电子胶粘材料有限公司 | High-brightness release paper, and preparation method and applications thereof |
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| CN111993730A (en) * | 2020-08-28 | 2020-11-27 | 淄博金豪塑料新材料股份有限公司 | Research and development of 15 g light-stripping anti-yellowing isolation film |
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Also Published As
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|---|---|
| CN103103883A (en) | 2013-05-15 |
| CN102350846B (en) | 2013-10-30 |
| CN103103883B (en) | 2015-07-22 |
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