CN103074819B - Anti scuffing cloudy surface anti-static release paper - Google Patents

Anti scuffing cloudy surface anti-static release paper Download PDF

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Publication number
CN103074819B
CN103074819B CN201210556464.1A CN201210556464A CN103074819B CN 103074819 B CN103074819 B CN 103074819B CN 201210556464 A CN201210556464 A CN 201210556464A CN 103074819 B CN103074819 B CN 103074819B
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Prior art keywords
static
coating
layer
cloudy surface
surface anti
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CN201210556464.1A
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CN103074819A (en
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金闯
张庆杰
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Sidike New Materials Jiangsu Co Ltd
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Sidike New Materials Jiangsu Co Ltd
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Priority to CN201610084402.3A priority Critical patent/CN105839460B/en
Priority to CN201610084834.4A priority patent/CN105838277A/en
Priority to CN201610084700.2A priority patent/CN105837844A/en
Priority to CN201210556464.1A priority patent/CN103074819B/en
Priority to CN201610084833.XA priority patent/CN105839461B/en
Priority to CN201510982658.1A priority patent/CN105603824A/en
Priority to CN201510982397.3A priority patent/CN105586806A/en
Priority to CN201510973218.XA priority patent/CN105625093A/en
Application filed by Sidike New Materials Jiangsu Co Ltd filed Critical Sidike New Materials Jiangsu Co Ltd
Priority to CN201510979627.0A priority patent/CN105567111A/en
Publication of CN103074819A publication Critical patent/CN103074819A/en
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Abstract

The present invention discloses a kind of anti scuffing cloudy surface anti-static release paper, comprises release liners body paper and thin layer, and another surface coating a layer thickness of this thin layer is the cloudy surface anti-static coating of 0.2 ~ 2 micron, and another surface of cloudy surface anti-static coating is coated with silicon layer; The surface that described cloudy surface anti-static coating contacts with silicon layer has some sags and crests, this cloudy surface anti-static coating is silica granule 2 ~ 6%, mean molecule quantity is the acrylic polyol 20 ~ 30% of 500 ~ 2000, mean molecule quantity is the resin 35 ~ 45% of the polyoxyalkylene series polyalcohol of 200 ~ 2500, polyethylene glycol 15 ~ 20%, cyclomethicone 4 ~ 8%, 1-hydroxycyclohexyl phenyl ketone-light trigger 184 is 5 ~ 10%.The present invention had both solved the leaching membrane layer of release liners and mould release coating binding force is not high, peeling force is unstable, turn improves film surface anti-static performance, and also improves scratch resistance performance simultaneously.

Description

Anti scuffing cloudy surface anti-static release paper
Technical field
The present invention relates to a kind of cloudy surface anti-static release paper, particularly a kind of anti scuffing cloudy surface anti-static release paper.
Background technology
Release liners, also known as barrier paper, separate paper, is mainly used in being covered in the adhesive layer of surface for the protection of tape surface of adhesive tape.Existing release liners is generally the surperficial film one deck leaching membrane layer (material of employing mainly contains polyethylene) at release liners ground paper layer, is then coated with one deck mould release coating (material of employing is mainly silicone oil) on the surface of leaching membrane layer and obtains release liners.But because leaching membrane layer flatness is high, poor adhesive force between mould release coating and leaching membrane layer, when release liners attaches with the pad pasting being coated with trowel adhesive, the mould release coating in release liners is easily caused to be taken away by the adhesive that adhesion is larger, thus form in the local surfaces of pad pasting the mould release coating area being difficult to clean out, destroy pure, the uniformity of pad pasting entirety.And due to production process electrostatic excessive, causes the local out-of-flatness of release coating layer, not only affect product peeling force stability, and easily generation electrostatic spark causes fire.
Summary of the invention
The object of the invention is to provide a kind of anti scuffing cloudy surface anti-static release paper, this anti scuffing cloudy surface anti-static release paper had both solved the leaching membrane layer of release liners and mould release coating binding force is not high, peeling force is unstable, turn improve film surface anti-static performance, and also improve scratch resistance performance simultaneously.
For achieving the above object, the technical solution used in the present invention is: a kind of anti scuffing cloudy surface anti-static release paper, described anti scuffing cloudy surface anti-static release paper comprises the release liners body paper that a surperficial film has leaching membrane layer, another surface coating one adhesive layer of this release liners body paper, another surface adhesive of this adhesive layer has thin layer, another surface coating a layer thickness of this thin layer is the cloudy surface anti-static coating of 0.2 ~ 2 micron, and another surface of cloudy surface anti-static coating is coated with silicon layer; The surface that described cloudy surface anti-static coating contacts with silicon layer has some sags and crests;
Described cloudy surface anti-static coating is made up of the component of following masses percentage composition:
Silica granule 2 ~ 6%,
Mean molecule quantity is the acrylic polyol 20 ~ 30% of 500 ~ 2000,
Mean molecule quantity is the resin 30 ~ 40% of the polyoxyalkylene series polyalcohol of 200 ~ 2500,
Polyethylene glycol 15 ~ 20%,
Cyclomethicone 4 ~ 8%,
1-hydroxycyclohexyl phenyl ketone-light trigger 1845 ~ 10%;
The particle diameter of described silica granule is that in the size distribution measured by laser diffraction and scattering method, particle diameter has peak value respectively and average grain diameter is 4um or following in the scope of 0.1 ~ 2um and 1.5 ~ 5um.
In technique scheme, further improved plan is as follows:
1, in such scheme, described cloudy surface anti-static coating adopts ultra-violet bands to be 280nm ~ 350nm, and illumination is 1200mW/cm 2, described cloudy surface anti-static coating is irradiated, makes described component under the effect of 1-hydroxycyclohexyl phenyl ketone-light trigger 184, carry out polymerisation and obtain cloudy surface anti-static coating.
2, in such scheme, the material of described leaching membrane layer is polyethylene terephthalate, polypropylene, polyethylene or polyvinyl chloride.
3, in such scheme, described thin layer is pet film layer, layer of polypropylene foil, film layer, polyvinyl chloride layer or cast polypropylene film layer.
Because technique scheme is used, the present invention compared with prior art has following advantages and effect:
1, anti scuffing cloudy surface anti-static release paper of the present invention, its adopt 20 ~ 30% mean molecule quantities be 500 ~ 2000 acrylic polyol and 30 ~ 40% mean molecule quantities be 200 ~ 2500 polyoxyalkylene series polyalcohol resin polymerization polyurethane resin after and mix with cyclomethicone 4 ~ 8%, mean molecule quantity be 500 ~ 2000 acrylic polyol and mean molecule quantity be that chain in the resin of the polyoxyalkylene series polyalcohol of 200 ~ 2500 improves film surface anti-static performance, and also improve scratch resistance performance simultaneously; Its polyalcohol acrylate monomer has the mean molecule quantity of 500 ~ 2000, if molecular weight is less than 500, the ABRASION RESISTANCE of film is tending towards reducing, if mean molecule quantity is more than 2000, during film-forming, applicability is deteriorated.If polyalcohol acrylate monomer is in particular ethylene glycol, consider water absorbing capacity, the present invention select mean molecule quantity be 200 ~ 1000 polyethylene glycol, make use of the ability of its superior absorption Bound moisture, further increase anti-static effect.Have the ability of the water of absorption Bound moisture form superior especially due to this acrylic polyol monomer, have anti-static effect, polyalcohol acrylate monomer all can use this monomer.
2, the present invention is first to the surface coating cloudy surface anti-static coating of thin layer, by the surface after composition and engineering process, there is some even concaveconvex structures and anti-static effect through cloudy surface anti-static coating, then in this surperficial silicon-coating mould release coating coating, the bottom surface of silicon mould release coating coating infiltrates the notch place on described cloudy surface anti-static coating surface in the liquid state, silicon mould release coating coating is fixedly linked by notch place and cloudy surface anti-static coating after solidification, therefore, adhesion more firmly, reliably.And due to antistatic process, can eliminate electrostatic to the unstable impact brought of silicone oil coating, release peeling force can be very stable, also avoids the generation of production process electrostatic spark.
3, adopt light trigger 1-hydroxycyclohexyl phenyl ketone to cause in the present invention, mainly consider that it is under wave band is 320-400nm UV-irradiation, can instantaneous solidification film forming, can deep cure be reached, there is good planarization and intensity.Described light trigger is 1-hydroxycyclohexyl phenyl ketone-light trigger 184, is a kind of ultraviolet initiator of efficient non yellowing, and for causing the UV polymerisation of unsaturated prepolymerization system, its mass content is 5 ~ 10%.
4, anti scuffing cloudy surface anti-static release paper of the present invention, to be particle diameter be described silica granule in the size distribution measured by laser diffraction and scattering method that particle diameter has peak value respectively in the scope of 0.1 ~ 2um and 1.5 ~ 5um and average grain diameter is 4um or following silica granule, both substantially increase atomized surface effect, in turn ensure that solidification effect.
5, the power of medium ultraviolet light of the present invention adopts 1200mW/cm 2if mainly power is lower than 1200mW/cm 2, film not exclusively solidifies, and ABRASION RESISTANCE reduces; If if power is higher than 1200mW/cm 2, affect film flatness, applicability declines.Employing ultra-violet bands is 320 ~ 400nm, and illumination is 1200mW/cm 2described cloudy surface coating agent is irradiated, make described component carry out polymerisation under the effect of the specific 1-hydroxycyclohexyl phenyl ketone as light trigger of the present invention and obtain cloudy surface coating, thickness is 4 ~ 10um, there is anti-static effect, then apply one deck mould release coating on the surface of described cloudy surface coating and obtain cloudy surface release layer.
Accompanying drawing explanation
Accompanying drawing 1 is the present invention's novel anti scuffing cloudy surface anti-static release paper structural representation.
In above accompanying drawing: 1, release liners body paper; 2, leaching membrane layer; 3, adhesive layer; 4, thin layer; 5, cloudy surface anti-static coating; 6, silicon layer; 61, sags and crests.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described:
Embodiment 1 ~ 5: a kind of anti scuffing cloudy surface anti-static release paper, described anti scuffing cloudy surface anti-static release paper comprises the release liners body paper 1 that a surperficial film has leaching membrane layer 2, another surface coating one adhesive layer 3 of this release liners body paper 1, this another surface adhesive of adhesive layer 3 has thin layer 4, another surface coating a layer thickness of this thin layer 4 is the cloudy surface anti-static coating 5 of 0.2 ~ 2 micron, and another surface of cloudy surface anti-static coating 5 is coated with silicon layer 6; The surface that described cloudy surface anti-static coating 5 contacts with silicon layer 6 has some sags and crests 61;
Described cloudy surface anti-static coating 5 is made up of the component of following masses percentage composition:
Silica granule 2 ~ 6%,
Mean molecule quantity is the acrylic polyol 20 ~ 30% of 500 ~ 2000,
Mean molecule quantity is the resin 30 ~ 40% of the polyoxyalkylene series polyalcohol of 200 ~ 2500,
Polyethylene glycol 15 ~ 20%,
Cyclomethicone 4 ~ 8%,
1-hydroxycyclohexyl phenyl ketone-light trigger 1845 ~ 10%;
The particle diameter of described silica granule is that in the size distribution measured by laser diffraction and scattering method, particle diameter has peak value respectively and average grain diameter is 4um or following in the scope of 0.1 ~ 2um and 1.5 ~ 5um.
Obtained cloudy-surface release paper is see shown in accompanying drawing 1, stacked gradually by leaching membrane layer 2, release liners body paper 1, adhesive layer 3, thin layer 4, cloudy surface anti-static coating 5 and mould release coating 6 six layers and form, the surface roughness on the surface that described cloudy surface anti-static coating 5 contacts with mould release coating 6 is 2.821um ~ 3.324um.Testing standard: ISO4287:1998.Roughness tester: the TR200 Manual roughness devices of Beijing epoch peak Science and Technology Ltd. production.
Described cloudy surface anti-static coating 5 is polyester cloudy surface coating.First be the leaching membrane layer 2 of PE to the one side film material of release liners body paper 1, another side is coated with one deck adhesive layer 3, to fit on adhesive layer 3 again thin film layer 4, then being coated with cloudy surface anti-static coating 5(material on the surface of thin layer 4 is polyester), surface has some even concaveconvex structures after treatment, then in the release mould release coating 6 of this surperficial silicon-coating, the bottom surface of silicon release mould release coating 6 infiltrates the notch place on described cloudy surface anti-static coating 5 surface in the liquid state, the release mould release coating 6 of silicon is fixedly linked by notch and cloudy surface anti-static coating 5 after solidification, therefore, adhesion is more firm, reliably.But also by regulating the mist degree (i.e. roughness) of cloudy surface anti-static coating 5, can freely adjust the size of peeling force between the release mould release coating 6 of silicon and release liners body paper.
1, method is with embodiment two.
2, the related materials of embodiment two ~ five use is as follows:
(1) material of leaching membrane layer: embodiment three, polyvinyl chloride; Embodiment four, polyethylene terephthalate; Embodiment five, polyethylene; Embodiment six, polypropylene.
(2) thin layer: embodiment three, polypropylene film; Embodiment four, polyethylene film; Embodiment five, cast polypropylene film; Embodiment six pet film.
3, the formula of cloudy surface coating agent is in table 1.
Table 1
Performance indications are as shown in table 2:
Table two
(1), ocular estimate: evaluated by the existence of visual observation to outward appearance, transparency and crackle.No problem film is rated as satisfactory (O), and problematic film is rated as unsatisfactory (X);
(2), private seal by release aspect private seal 10 times, be qualified without delustring, delustring is defective;
(3), hundred lattice test cross-cut testers tests without coming off for qualified products, come off for substandard product;
(4) (1 kilogram back and forth by adhesive tape crimping, to peel off voltage roller, speed 0.3m/min) in release face, thereafter, (10m/min) is peeled off by quick-moving speed, the maximum that adhesive tape glues the stripping electrostatic pressure of release face is read with electrostatic field tester (model: SIMCOFMX-003), it is qualified products that electrostatic pressure is less than 0.3KV, and it is substandard product that electrostatic pressure is greater than 0.3KV;
(5), surface resistance value sheet resistance tester G two, face parallel copper electrodes is placed in the arbitrary place of sample surfaces, presses black A key, waits about 30 seconds, and LED shows test place resistance, and ambient temperature and humidity, notes down.Display surface resistance <1.0E+10 Ω/sq, (65%RH, 23 DEG C) are for qualified; Display surface resistance >1.0E+10 Ω/sq, (65%RH, 23 DEG C) are defective.
(6) wearability test is at the 500g/cm of steel wire face (#0000) 2the pressure that adds rub after 30 times to hard conating face, to not having scar to be denoted as O, be denoted as X to there being scar.
(7) pencil hardness test evaluates the pencil hardness of hard coating film according to GB/T6739-2006.
Above-described embodiment, only for technical conceive of the present invention and feature are described, its object is to person skilled in the art can be understood content of the present invention and implement according to this, can not limit the scope of the invention with this.All equivalences done according to Spirit Essence of the present invention change or modify, and all should be encompassed within protection scope of the present invention.

Claims (3)

1. an anti scuffing cloudy surface anti-static release paper, it is characterized in that: described anti scuffing cloudy surface anti-static release paper comprises the release liners body paper (1) that a surperficial film has leaching membrane layer (2), another surface coating one adhesive layer (3) of this release liners body paper (1), this adhesive layer (3) another surface adhesive has thin layer (4), another surface coating a layer thickness of this thin layer (4) is the cloudy surface anti-static coating (5) of 0.2 ~ 2 micron, and cloudy surface anti-static coating (5) another surface is coated with silicon layer (6); The surface that described cloudy surface anti-static coating (5) contacts with silicon layer (6) has some sags and crests (61);
Described cloudy surface anti-static coating (5) is made up of the component of following masses percentage composition:
Silica granule 2 ~ 6%,
Mean molecule quantity is the acrylic polyol 20 ~ 30% of 500 ~ 2000,
Mean molecule quantity is the resin 30 ~ 40% of the polyoxyalkylene series polyalcohol of 200 ~ 2500,
Polyethylene glycol 15 ~ 20%,
Cyclomethicone 4 ~ 8%,
1-hydroxycyclohexyl phenyl ketone-light trigger 1845 ~ 10%;
The particle diameter of described silica granule is that in the size distribution measured by laser diffraction and scattering method, particle diameter has peak value respectively and average grain diameter is 4 μm or following in the scope of 0.1 ~ 2 μm and 1.5 ~ 5 μm;
Described cloudy surface anti-static coating (5) adopts ultra-violet bands to be 280nm ~ 350nm, and illumination is 1200mW/cm 2, described cloudy surface anti-static coating is irradiated, makes described component under the effect of 1-hydroxycyclohexyl phenyl ketone-light trigger 184, carry out polymerisation and obtain cloudy surface anti-static coating (5).
2. anti scuffing cloudy surface anti-static release paper according to claim 1, is characterized in that: the material of described leaching membrane layer is polyethylene terephthalate, polypropylene, polyethylene or polyvinyl chloride.
3. anti scuffing cloudy surface anti-static release paper according to claim 1, is characterized in that: described thin layer is pet film layer, layer of polypropylene foil, film layer or polyvinyl chloride layer.
CN201210556464.1A 2012-12-20 2012-12-20 Anti scuffing cloudy surface anti-static release paper Active CN103074819B (en)

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CN201610084700.2A CN105837844A (en) 2012-12-20 2012-12-20 Antistatic release film for protection adhesive tape
CN201210556464.1A CN103074819B (en) 2012-12-20 2012-12-20 Anti scuffing cloudy surface anti-static release paper
CN201610084833.XA CN105839461B (en) 2012-12-20 2012-12-20 Adhesive tape cloudy surface anti-static coating
CN201510982658.1A CN105603824A (en) 2012-12-20 2012-12-20 Antistatic release film for pressure sensitive adhesive tape
CN201610084402.3A CN105839460B (en) 2012-12-20 2012-12-20 Adhesive tape high-bond cloudy surface coating material
CN201510973218.XA CN105625093A (en) 2012-12-20 2012-12-20 Scratch-resistant coating material
CN201610084834.4A CN105838277A (en) 2012-12-20 2012-12-20 High-reliability matte release material for adhesive tape
CN201510979627.0A CN105567111A (en) 2012-12-20 2012-12-20 High stable-peel-force antiadherent film
CN201510982397.3A CN105586806A (en) 2012-12-20 2012-12-20 Anti-static matte coating material

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CN201510973218.XA Division CN105625093A (en) 2012-12-20 2012-12-20 Scratch-resistant coating material
CN201610084833.XA Division CN105839461B (en) 2012-12-20 2012-12-20 Adhesive tape cloudy surface anti-static coating
CN201610084834.4A Division CN105838277A (en) 2012-12-20 2012-12-20 High-reliability matte release material for adhesive tape
CN201510982658.1A Division CN105603824A (en) 2012-12-20 2012-12-20 Antistatic release film for pressure sensitive adhesive tape
CN201610084700.2A Division CN105837844A (en) 2012-12-20 2012-12-20 Antistatic release film for protection adhesive tape
CN201610084402.3A Division CN105839460B (en) 2012-12-20 2012-12-20 Adhesive tape high-bond cloudy surface coating material
CN201510979627.0A Division CN105567111A (en) 2012-12-20 2012-12-20 High stable-peel-force antiadherent film
CN201510982397.3A Division CN105586806A (en) 2012-12-20 2012-12-20 Anti-static matte coating material

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CN201510973218.XA Pending CN105625093A (en) 2012-12-20 2012-12-20 Scratch-resistant coating material
CN201610084402.3A Active CN105839460B (en) 2012-12-20 2012-12-20 Adhesive tape high-bond cloudy surface coating material
CN201510982397.3A Pending CN105586806A (en) 2012-12-20 2012-12-20 Anti-static matte coating material
CN201210556464.1A Active CN103074819B (en) 2012-12-20 2012-12-20 Anti scuffing cloudy surface anti-static release paper
CN201610084833.XA Active CN105839461B (en) 2012-12-20 2012-12-20 Adhesive tape cloudy surface anti-static coating
CN201610084700.2A Pending CN105837844A (en) 2012-12-20 2012-12-20 Antistatic release film for protection adhesive tape
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CN201510973218.XA Pending CN105625093A (en) 2012-12-20 2012-12-20 Scratch-resistant coating material
CN201610084402.3A Active CN105839460B (en) 2012-12-20 2012-12-20 Adhesive tape high-bond cloudy surface coating material
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