CN102330383B - Fog face release paper and preparation method thereof - Google Patents
Fog face release paper and preparation method thereof Download PDFInfo
- Publication number
- CN102330383B CN102330383B CN 201110194615 CN201110194615A CN102330383B CN 102330383 B CN102330383 B CN 102330383B CN 201110194615 CN201110194615 CN 201110194615 CN 201110194615 A CN201110194615 A CN 201110194615A CN 102330383 B CN102330383 B CN 102330383B
- Authority
- CN
- China
- Prior art keywords
- cloudy
- coating
- acrylate
- layer
- surface coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 239000011248 coating agent Substances 0.000 claims abstract description 70
- 238000000576 coating method Methods 0.000 claims abstract description 60
- 239000010410 layer Substances 0.000 claims abstract description 53
- 229920000728 polyester Polymers 0.000 claims abstract description 21
- 239000012790 adhesive layer Substances 0.000 claims abstract description 15
- 239000000178 monomer Substances 0.000 claims abstract description 12
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 7
- 238000001816 cooling Methods 0.000 claims abstract description 4
- -1 acrylic ester Chemical class 0.000 claims description 43
- 238000002386 leaching Methods 0.000 claims description 16
- 239000012528 membrane Substances 0.000 claims description 16
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 12
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 10
- 239000004698 Polyethylene Substances 0.000 claims description 9
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 8
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 8
- 239000000654 additive Substances 0.000 claims description 8
- 230000000996 additive effect Effects 0.000 claims description 8
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 claims description 8
- 239000011347 resin Substances 0.000 claims description 8
- 229920005989 resin Polymers 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 8
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 7
- 229920000573 polyethylene Polymers 0.000 claims description 7
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 6
- 239000004743 Polypropylene Substances 0.000 claims description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Natural products CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- 229920001155 polypropylene Polymers 0.000 claims description 6
- 244000028419 Styrax benzoin Species 0.000 claims description 5
- 235000000126 Styrax benzoin Nutrition 0.000 claims description 5
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 5
- 239000000292 calcium oxide Substances 0.000 claims description 5
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 5
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 5
- 239000004800 polyvinyl chloride Substances 0.000 claims description 5
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 claims description 5
- LMYRWZFENFIFIT-UHFFFAOYSA-N toluene-4-sulfonamide Chemical compound CC1=CC=C(S(N)(=O)=O)C=C1 LMYRWZFENFIFIT-UHFFFAOYSA-N 0.000 claims description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 4
- 235000008411 Sumatra benzointree Nutrition 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 4
- 229960002130 benzoin Drugs 0.000 claims description 4
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical group C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 4
- 239000012965 benzophenone Substances 0.000 claims description 4
- 230000000694 effects Effects 0.000 claims description 4
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims description 4
- 235000019382 gum benzoic Nutrition 0.000 claims description 4
- 229920001427 mPEG Polymers 0.000 claims description 4
- 239000000395 magnesium oxide Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 4
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 claims description 4
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 claims description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 3
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 3
- 230000003746 surface roughness Effects 0.000 claims description 3
- 125000003944 tolyl group Chemical group 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract description 11
- 229910052710 silicon Inorganic materials 0.000 abstract description 11
- 239000010703 silicon Substances 0.000 abstract description 11
- 239000010409 thin film Substances 0.000 abstract description 6
- 239000003795 chemical substances by application Substances 0.000 abstract description 5
- 238000000034 method Methods 0.000 abstract description 5
- 239000007788 liquid Substances 0.000 abstract description 3
- 238000010030 laminating Methods 0.000 abstract 2
- 239000003999 initiator Substances 0.000 abstract 1
- 230000001678 irradiating effect Effects 0.000 abstract 1
- 239000012466 permeate Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000010408 film Substances 0.000 description 17
- 239000000853 adhesive Substances 0.000 description 5
- 230000001070 adhesive effect Effects 0.000 description 5
- 229920003002 synthetic resin Polymers 0.000 description 4
- 239000000057 synthetic resin Substances 0.000 description 4
- 239000000025 natural resin Substances 0.000 description 3
- 229920002545 silicone oil Polymers 0.000 description 3
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 2
- 239000002390 adhesive tape Substances 0.000 description 2
- 239000005025 cast polypropylene Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003595 mist Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 2
- PJAKWOZHTFWTNF-UHFFFAOYSA-N (2-nonylphenyl) prop-2-enoate Chemical compound CCCCCCCCCC1=CC=CC=C1OC(=O)C=C PJAKWOZHTFWTNF-UHFFFAOYSA-N 0.000 description 1
- XDFYLDYPTBNHRY-UHFFFAOYSA-N C(CCCCCCCCCCCCCCCCC)C(C(=O)OCCCCCCCCCCCCCCCCCC)=C.C(C=C)(=O)O Chemical compound C(CCCCCCCCCCCCCCCCC)C(C(=O)OCCCCCCCCCCCCCCCCCC)=C.C(C=C)(=O)O XDFYLDYPTBNHRY-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 235000015511 Liquidambar orientalis Nutrition 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 229920001800 Shellac Polymers 0.000 description 1
- 239000004870 Styrax Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000007766 curtain coating Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- FYIBGDKNYYMMAG-UHFFFAOYSA-N ethane-1,2-diol;terephthalic acid Chemical compound OCCO.OC(=O)C1=CC=C(C(O)=O)C=C1 FYIBGDKNYYMMAG-UHFFFAOYSA-N 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- XPJRQAIZZQMSCM-UHFFFAOYSA-N heptaethylene glycol Polymers OCCOCCOCCOCCOCCOCCOCCO XPJRQAIZZQMSCM-UHFFFAOYSA-N 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 1
- 239000004208 shellac Substances 0.000 description 1
- 229940113147 shellac Drugs 0.000 description 1
- 235000013874 shellac Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Images
Landscapes
- Laminated Bodies (AREA)
- Adhesive Tapes (AREA)
Abstract
The invention relates to fog face release paper and a preparation method thereof. The preparation method comprises the following steps of: laminating a laminated layer on one lateral surface of body paper of the release paper by a laminating machine and then cooling; coating an adhesive layer on the other lateral surface of the body paper of the release paper and attaching a thin film layer to the surface of the adhesive layer; coating a layer of fog face coating agent with the thickness of 0.2 to 2 microns on the surface of the thin film layer; irradiating the fog face coating agent by ultraviolet rays, so that multifunctional acrylate monomers are subjected to polymerization under the action of an initiator to obtain a fog face coating; and coating a layer of release agent on the surface of the fog face coating. In the method, firstly, the surface of the thin film layer is coated with the polyester fog face coating, so that after being processed, the surface of the thin film layer coated with the polyester fog face coating is provided with a plurality of uniform concave-convex structures; then the surface of the thin film layer coated with the polyester fog face coating is coated with a silicon release agent coating; the bottom surface of the silicon release agent coating permeates the positions of notches on the surface of the polyester fog face coating in a liquid state; and after being solidified, the silicon release agent coating is fixedly connected with the polyester fog face coating through the notches, so the bonding force is more firm and reliable.
Description
Technical field
The present invention relates to a kind of cloudy-surface release paper and preparation method thereof, cloudy-surface release paper that particularly a kind of adhesion strength is high, peeling force is adjustable and preparation method thereof.
Background technology
Release liners claims again barrier paper, separate paper, is mainly used in pasting on the surface of adhesive tape for the protection of the adhesive layer of tape surface.Existing release liners generally is the surperficial film one deck leaching membrane layer (material of employing mainly contains polyethylene) at the release liners ground paper layer, and then the surface-coated one deck parting agent layer (material of employing is mainly silicone oil) at leaching membrane layer obtains release liners.But because the leaching membrane layer flatness is high, poor adhesive force between mould release coating and the leaching membrane layer, when release liners attaches with the pad pasting that is coated with trowel adhesive, cause easily the mould release coating on the release liners to be taken away by the larger adhesive of adhesion, thereby the local surfaces at pad pasting forms the mould release coating area that is difficult to clean out, and has destroyed pure, the uniformity of pad pasting integral body.
Summary of the invention
The invention provides a kind of cloudy-surface release paper and preparation method thereof, purpose is to solve the not high problem of the leaching membrane layer of release liners and mould release coating binding force.
For achieving the above object, the first technical scheme that the present invention adopts is: a kind of cloudy-surface release paper, stacked gradually by six layers of leaching membrane layer, release liners original paper layer, adhesive layer, thin layer, cloudy surface coating and mould release coatings and to consist of, the surface roughness of described cloudy surface coating towards the surface of described mould release coating is 2.821um～3.324um.
For achieving the above object, the second technical scheme that the present invention adopts is: a kind of preparation method of cloudy-surface release paper mainly is comprised of the following step:
The first step: at a side surface of release liners body paper, with film machine film one deck leaching membrane layer, then cooling;
Second step: at opposite side surface-coated one deck adhesive layer of described release liners body paper;
The 3rd step: to described adhesive layer surface label unification layer film layer;
The 4th step: be 0.2～2 micron cloudy surface coating agent in surface-coated a layer thickness of described thin layer, this cloudy surface coating agent is comprised of the compound of following quality percentage composition:
Cloudy surface additive 2～6%;
Polyfunctional acrylic ester monomer 30～50%;
Initator 0.1～1%;
Solvent 45～66%;
Described cloudy surface additive is that particle diameter is at least a in the resin particle, aluminium oxide, magnesia, calcium oxide of 20 nanometers～2 micron;
Described polyfunctional acrylic ester monomer is at least a in methyl acrylate, ethyl acrylate, 2-methyl methacrylate, ethyl 2-methacrylate, methoxy poly (ethylene glycol) mono acrylic ester, alkoxide lauryl acrylate, acrylic acid stearyl, alkoxide nonyl phenol acrylate, epoxy acrylate, polyester acrylate, the polyfunctional group aliphatic urethane acrylate;
Described initator is benzophenone, para toluene sulfonamide, triphenyl phosphate or benzoin dimethylether;
Described solvent is toluene, ethyl acetate or positive butanone;
The 5th step: adopt ultraviolet ray that described cloudy surface coating agent is shone, make described polyfunctional acrylic ester monomer under the effect of initator, carry out polymerisation and obtain the cloudy surface coating;
The 6th step: the surface in described cloudy surface coating applies one deck mould release.
Related content in the technique scheme is explained as follows:
1, in the such scheme, described mould release coating is to isolate adhesive on the adhesive tape to make it and the release liners bonding, thus require its not with adhesive generation cross-linking reaction, the material of its use is mainly silicone oil.
2, in the such scheme, described ultraviolet ray (UV) mainly refers to UVA, UVB and UVC.
3, in the such scheme, methoxy poly (ethylene glycol) mono acrylic ester (Methoxy Glycol 350 Monoacrylate; Methoxy Polyethylene Glycol 350 Monoacrylate; CH
3O(CH
2CH
2O)
nOCCH=CH
2N=8～33), alkoxide lauryl acrylate (Alkoxylated Lauryl Acrylate), acrylic acid stearyl (Stearyl Acrylate), alkoxide nonyl phenol acrylate (Alkoxylated Nonyl Phenol Acrylate), epoxy acrylate (Epoxy Acrylate), polyester acrylate (Polyester Acrylate), the polyfunctional group aliphatic urethane acrylate can be available from the chemical Co., Ltd of Sartomer (Guangzhou).
4, in the such scheme, resin can be the natural resins such as rosin, styrax; Phenolic resins, Corvic etc. are synthetic resin.Resin has dividing of natural resin and synthetic resin.Natural resin refers to the amorphous organic substance by occurring in nature animals and plants secretion gained, such as rosin, amber, shellac etc.Synthetic resin refers to the resin product that obtained through chemical reaction through chemical synthesis or some natural products by simple organic.Synthetic resin is the main component of plastics.
5, in the such scheme, the material of described leaching membrane layer is polyethylene terephthalate, polypropylene, polyethylene or polyvinyl chloride.
6, in the such scheme, described film is pet film, polypropylene film, polyethylene film, polyvinyl chloride or cast polypropylene film.
Because technique scheme is used, the present invention compared with prior art has following advantages and effect:
The present invention is at first to the surface-coated polyester cloudy surface coating (material is polyester) of thin layer, the surface has some even concaveconvex structures after treatment, then in this surface-coated silicon mould release coating, the notch place of described polyester cloudy surface coating surface is infiltrated in the bottom surface of silicon mould release coating under liquid state, silicon mould release coating is fixedly linked by notch and polyester cloudy surface coating after solidifying, therefore, adhesion more firmly, reliably.But also can by regulating the mist degree (being roughness) of cloudy surface coating, freely adjust the size of peeling force between silicon mould release coating and the release liners body paper.
Description of drawings
Accompanying drawing 1 is schematic diagram of the present invention.
In the above accompanying drawing: 1, leaching membrane layer; 2, release liners original paper layer; 3, adhesive layer; 4, thin layer; 5, cloudy surface coating; 6, mould release coating.
The specific embodiment
The invention will be further described below in conjunction with drawings and Examples:
Embodiment one: cloudy-surface release paper
Shown in accompanying drawing 1, a kind of cloudy-surface release paper, stacked gradually by 6 six layers of leaching membrane layer 1, release liners original paper layer 2, adhesive layer 3, thin layer 4, cloudy surface coating 5 and mould release coatings and to consist of, the surface roughness of described cloudy surface coating 5 towards the surface of described mould release coating 6 is 2.821um～3.324um.Testing standard: ISO4287:1998.Roughness tester: the TR200 Manual roughness devices of Beijing epoch peak Science and Technology Ltd. production.Described cloudy surface coating 5 is polyester cloudy surface coating.At first to the common paper of release liners original paper layer 2() one side film material be the first leaching membrane layer 1 of PE, another side coating one deck adhesive layer 3, applying thin film layer 4 on adhesive layer 3 again, then be polyester in the surface-coated polyester cloudy surface coating 5(of thin layer 4 material), the surface has some even concaveconvex structures after treatment, then in this surface-coated silicon mould release coating 6, the notch place on described polyester cloudy surface coating 5 surfaces is infiltrated in the bottom surface of silicon mould release coating 6 under liquid state, silicon mould release coating 6 is fixedly linked by notch and polyester cloudy surface coating 5 after solidifying, therefore, adhesion is more firm, reliably.But also can by regulating the mist degree (being roughness) of cloudy surface coating 5, freely adjust the size of peeling force between silicon mould release coating 6 and the release liners body paper.
The preparation method of embodiment two, cloudy-surface release paper
Shown in accompanying drawing 1, a kind of preparation method of cloudy-surface release paper, making step is as follows:
The first step: first to the surface treatment of release liners body paper, make its surface not have paper scrap, stains.
Second step: at a side surface of release liners body paper, with film machine film one deck PE leaching membrane layer 1, then cooling; The high speed extrusion single face curtain coating compounding machine group A type that the film machine can come adopted plastics machinery Co., Ltd to produce with Changzhou.
The 3rd step: at opposite side surface-coated one deck adhesive layer 3 of described release liners body paper;
The 4th step: to described adhesive layer 3 surface labels unification strata ethylene glycol terephthalate thin layer 4;
The 5th step: be 0.2～2 micron cloudy surface coating agent in surface-coated a layer thickness of described thin layer 4, the prescription of this cloudy surface coating agent sees Table 1.
The 6th step: adopt ultraviolet ray that described cloudy surface coating agent is shone, make described polyfunctional acrylic ester monomer under the effect of initator, carry out polymerisation and obtain cloudy surface coating 5;
The 7th step: apply one deck silicone oil mould release coating 6 on the surface of described cloudy surface coating.
Embodiment three～six: a kind of its preparation method of cloudy-surface release paper
1, method is with embodiment two.
2, the related materials of embodiment three～six uses is as follows:
(1) material of leaching membrane layer: embodiment three, polyvinyl chloride; Embodiment four, polyethylene terephthalate; Embodiment five, polyethylene; Embodiment six, polypropylene.
(2) thin layer: embodiment three, polypropylene film; Embodiment four, polyethylene film; Embodiment five, cast polypropylene film; Embodiment six pet films.
3, the prescription of cloudy surface coating agent sees Table 1.
Table 1
| ? | Embodiment two | Embodiment three | Embodiment four | Embodiment five | Embodiment six |
| The |
4% | 5% | 2% | 2.5% | 6% |
| The polyfunctional acrylic ester monomer | 34.5% | 30% | 43% | 45% | 44.3% |
| Initator | 0.2% | 0.5% | 0.7% | 1% | 0.7% |
| Solvent | 61.3% | 64.5% | 54.3% | 51.5% | 49% |
Annotate: in the table 1:
1, cloudy surface additive: embodiment two, magnesia; Embodiment three, organic resin; Embodiment four, aluminium oxide; Embodiment five, calcium oxide and organic resin are according to the mass ratio of 1:1; Embodiment six, calcium oxide.
2, polyfunctional acrylic ester monomer: embodiment two, alkoxide lauryl acrylate; Embodiment three, ethyl acrylate and acrylic acid stearyl mix according to the mass ratio of 1:5 between the two; Embodiment four, polyester acrylate; Embodiment five, alkoxide nonyl phenol acrylate; Embodiment six, alkoxide lauryl acrylate.
3, initator: embodiment two, para toluene sulfonamide; Embodiment three, triphenyl phosphate; Embodiment four, benzoin dimethylether; Embodiment five, benzophenone; Embodiment six, para toluene sulfonamide.
4, solvent: embodiment two～three, ethyl acetate; Embodiment four～six, methyl acetone.
Above-described embodiment only is explanation technical conceive of the present invention and characteristics, and its purpose is to allow the personage who is familiar with technique can understand content of the present invention and according to this enforcement, can not limit protection scope of the present invention with this.All equivalences that Spirit Essence is done according to the present invention change or modify, and all should be encompassed within protection scope of the present invention.
Claims (4)
1. cloudy-surface release paper, it is characterized in that: stacked gradually by six layers of leaching membrane layer, release liners original paper layer, adhesive layer, thin layer, cloudy surface coating and mould release coatings and consist of, the surface roughness of described cloudy surface coating towards the surface of described mould release coating is 2.821 μ m～3.324 μ m;
Described cloudy surface coating is polyester cloudy surface coating, and this cloudy surface coating agent is comprised of the compound of following quality percentage composition:
Cloudy surface additive 2～6%;
Polyfunctional acrylic ester monomer 30～50%;
Initator 0.1～1%;
Solvent 45～66%;
Described cloudy surface additive is that particle diameter is at least a in the resin particle, aluminium oxide, magnesia, calcium oxide of 20 nanometers～2 micron; Described polyfunctional acrylic ester monomer is at least a in methyl acrylate, ethyl acrylate, 2-methyl methacrylate, ethyl 2-methacrylate, methoxy poly (ethylene glycol) mono acrylic ester, alkoxide lauryl acrylate, acrylic acid stearyl, alkoxide nonyl phenol acrylate, epoxy acrylate, polyester acrylate, the polyfunctional group aliphatic urethane acrylate; Described initator is benzophenone, para toluene sulfonamide, triphenyl phosphate or benzoin dimethylether; Described solvent is toluene, ethyl acetate or positive butanone.
2. the preparation method of a cloudy-surface release paper is characterized in that: mainly be comprised of the following step:
The first step: at a side surface of release liners body paper, with film machine film one deck leaching membrane layer, then cooling;
Second step: at opposite side surface-coated one deck adhesive layer of described release liners body paper;
The 3rd step: to described adhesive layer surface label unification layer film layer;
The 4th step: be 0.2～2 micron cloudy surface coating agent in surface-coated a layer thickness of described thin layer, this cloudy surface coating agent is comprised of the compound of following quality percentage composition:
Cloudy surface additive 2～6%;
Polyfunctional acrylic ester monomer 30～50%;
Initator 0.1～1%;
Solvent 45～66%;
Described cloudy surface additive is that particle diameter is at least a in the resin particle, aluminium oxide, magnesia, calcium oxide of 20 nanometers～2 micron;
Described polyfunctional acrylic ester monomer is at least a in methyl acrylate, ethyl acrylate, 2-methyl methacrylate, ethyl 2-methacrylate, methoxy poly (ethylene glycol) mono acrylic ester, alkoxide lauryl acrylate, acrylic acid stearyl, alkoxide nonyl phenol acrylate, epoxy acrylate, polyester acrylate, the polyfunctional group aliphatic urethane acrylate;
Described initator is benzophenone, para toluene sulfonamide, triphenyl phosphate or benzoin dimethylether;
Described solvent is toluene, ethyl acetate or positive butanone;
The 5th step: adopt ultraviolet ray that described cloudy surface coating agent is shone, make described polyfunctional acrylic ester monomer under the effect of initator, carry out polymerisation and obtain the cloudy surface coating;
The 6th step: the surface in described cloudy surface coating applies one deck mould release.
3. the preparation method of cloudy-surface release paper according to claim 2, it is characterized in that: the material of described leaching membrane layer is polyethylene terephthalate, polypropylene, polyethylene or polyvinyl chloride.
4. the preparation method of cloudy-surface release paper according to claim 2, it is characterized in that: described film is pet film, polypropylene film, polyethylene film or polyvinyl chloride.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110194615 CN102330383B (en) | 2011-07-12 | 2011-07-12 | Fog face release paper and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110194615 CN102330383B (en) | 2011-07-12 | 2011-07-12 | Fog face release paper and preparation method thereof |
Related Child Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310046314.0A Division CN103147358B (en) | 2011-07-12 | 2011-07-12 | Preparation method of matte release paper |
| CN201310046313.6A Division CN103147357B (en) | 2011-07-12 | 2011-07-12 | Preparation method of matte release paper |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102330383A CN102330383A (en) | 2012-01-25 |
| CN102330383B true CN102330383B (en) | 2013-10-30 |
Family
ID=45482333
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110194615 Active CN102330383B (en) | 2011-07-12 | 2011-07-12 | Fog face release paper and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102330383B (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103061207B (en) * | 2012-12-20 | 2015-07-22 | 苏州斯迪克新材料科技股份有限公司 | Preparation method of novel matte anti-static release paper |
| CN105603824A (en) * | 2012-12-20 | 2016-05-25 | 斯迪克新型材料（江苏）有限公司 | Antistatic release film for pressure sensitive adhesive tape |
| CN104788637A (en) * | 2012-12-20 | 2015-07-22 | 苏州斯迪克新材料科技股份有限公司 | Release film with small release force |
| CN104975534A (en) * | 2015-06-08 | 2015-10-14 | 东莞市尚鑫纸业有限公司 | Manufacturing method for release paper used for flexible copper clad lamination |
| CN105002776A (en) * | 2015-07-16 | 2015-10-28 | 吉翔宝（太仓）离型材料科技发展有限公司 | High temperature-resistant antistatic release paper and preparation method therefor |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1916569A1 (en) * | 2005-08-17 | 2008-04-30 | Nippon Paper Industries Co., Ltd. | Electrophotographic transfer paper |
| CN101565918A (en) * | 2009-06-05 | 2009-10-28 | 中国乐凯胶片集团公司 | High-light release paper for synthetic leather |
| CN101709559A (en) * | 2009-09-15 | 2010-05-19 | 苏州斯迪克电子胶粘材料有限公司 | High-brightness release paper, and preparation method and applications thereof |
| CN201634951U (en) * | 2010-03-03 | 2010-11-17 | 苏州斯迪克电子胶粘材料有限公司 | Release paper |
| CN202169742U (en) * | 2011-07-12 | 2012-03-21 | 苏州斯迪克电子胶粘材料有限公司 | frosted-surface release paper |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3834998B2 (en) * | 1998-04-20 | 2006-10-18 | コニカミノルタホールディングス株式会社 | Inkjet recording paper |
-
2011
- 2011-07-12 CN CN 201110194615 patent/CN102330383B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1916569A1 (en) * | 2005-08-17 | 2008-04-30 | Nippon Paper Industries Co., Ltd. | Electrophotographic transfer paper |
| CN101565918A (en) * | 2009-06-05 | 2009-10-28 | 中国乐凯胶片集团公司 | High-light release paper for synthetic leather |
| CN101709559A (en) * | 2009-09-15 | 2010-05-19 | 苏州斯迪克电子胶粘材料有限公司 | High-brightness release paper, and preparation method and applications thereof |
| CN201634951U (en) * | 2010-03-03 | 2010-11-17 | 苏州斯迪克电子胶粘材料有限公司 | Release paper |
| CN202169742U (en) * | 2011-07-12 | 2012-03-21 | 苏州斯迪克电子胶粘材料有限公司 | frosted-surface release paper |
Non-Patent Citations (1)
| Title |
|---|
| JP特开平11-301096A 1999.11.02 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102330383A (en) | 2012-01-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102350846B (en) | Preparation method of novel cloudy-surface release paper | |
| CN102330382B (en) | Fog face release paper and preparation method thereof | |
| CN102330383B (en) | Fog face release paper and preparation method thereof | |
| CN106164200B (en) | Adhesive sheet and method for producing same | |
| CN103403115B (en) | Double-faced adhesive tape | |
| US10919276B2 (en) | Adhesive resin layer, adhesive resin film, laminate, and method of producing laminate | |
| CN102753344B (en) | Hard conating formation method | |
| JP5859942B2 (en) | Manufacturing method of laminate | |
| CN105839460B (en) | Adhesive tape high-bond cloudy surface coating material | |
| BR112014008458B1 (en) | PRESSURE-SENSITIVE ADHESIVE TAPE, E, PRESSURE-SENSITIVE ADHESIVE LAYER PREPARATION METHOD | |
| WO2013101693A1 (en) | Adhesive tape composition and adhesive tape prepared from same | |
| TWI798300B (en) | Release film and method for producing laminate | |
| CN106103617A (en) | There is structuring and the release liner of performance can be reapposed | |
| CN103201780A (en) | Label and method for producing same | |
| CN103147358B (en) | Preparation method of matte release paper | |
| CN103147357B (en) | Preparation method of matte release paper | |
| JP2016010947A (en) | Method for producing hard coat transfer film, hard coat transfer film and polymer resin plate or polymer resin film having hard coat layer | |
| CN103061207B (en) | Preparation method of novel matte anti-static release paper | |
| CN103114498B (en) | Method for preparing matte release paper for adhesive tapes | |
| CN112918145B (en) | Reusable UV transfer film and production method thereof | |
| CN106133085B (en) | Adhesive sheet | |
| HRP20141271T1 (en) | Use of a film for the lamination of printed matter and production method of such film | |
| CN211688892U (en) | Prevent cull protection film | |
| CN202169742U (en) | frosted-surface release paper | |
| CN202147456U (en) | Photochromic function film |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C53 | Correction of patent for invention or patent application | ||
| CB02 | Change of applicant information |
Address after: 215400 Taicang Economic Development Zone, Jiangsu, Qingdao West Road, No. 11, No. Applicant after: Suzhou Sidike New Material Science & Technology Co., Ltd. Address before: 215400 Luoyang, Jiangsu, Taicang Banqiao Town, East Road, No. 221, No. Applicant before: Suzhou Sidike Stickiness Electron Stuff Co., Ltd. |
|
| COR | Change of bibliographic data |
Free format text: CORRECT: APPLICANT; FROM: SUZHOU SIDIKET ELECTRONICS ADHESIVE MATERIAL CO., LTD. TO: SUZHOU SIDIKE NEW MATERIALS SCIENCE AND TECHNOLOGY CO., LTD. |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CP03 | Change of name, title or address | ||
| CP03 | Change of name, title or address |
Address after: 223900 Sihong Province Economic Development Zone, Suqian, West Ocean West Road, No. 6 Patentee after: Jiangsu Stick new materials Polytron Technologies Inc Address before: 215400 Taicang Economic Development Zone, Jiangsu, Qingdao West Road, No. 11, No. Patentee before: Suzhou Sidike New Material Science & Technology Co., Ltd. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170706 Address after: 215400 Taicang, Suzhou, Taicang Economic Development Zone, Qingdao West Road, No. 11, No. Patentee after: Taicang Stick new Mstar Technology Ltd Address before: 223900 Sihong Province Economic Development Zone, Suqian, West Ocean West Road, No. 6 Patentee before: Jiangsu Stick new materials Polytron Technologies Inc |