CN105838514A - Liquid detergent containing gemini surfactant - Google Patents

Liquid detergent containing gemini surfactant Download PDF

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Publication number
CN105838514A
CN105838514A CN201610186566.7A CN201610186566A CN105838514A CN 105838514 A CN105838514 A CN 105838514A CN 201610186566 A CN201610186566 A CN 201610186566A CN 105838514 A CN105838514 A CN 105838514A
Authority
CN
China
Prior art keywords
liquid detergent
parts
sodium
surface active
active agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610186566.7A
Other languages
Chinese (zh)
Inventor
许虎君
李晓邦
徐凯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangnan University
Original Assignee
Jiangnan University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangnan University filed Critical Jiangnan University
Priority to CN201610186566.7A priority Critical patent/CN105838514A/en
Publication of CN105838514A publication Critical patent/CN105838514A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/34—Organic compounds containing sulfur
    • C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C11D1/721—End blocked ethers

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The present invention discloses a liquid detergent, in particular a liquid detergent containing a gemini surfactant N,N'-bisododecylethylene diamine di-propionate sodium, and belongs to the field of detergent. The liquid detergent comprises the following raw materials by weight: 3-10 portions of N,N'-bisododecylethylene diamine di-propionate sodium, 3-8 portions of sodium dodecyl benzene sulfonate, 6-9 parts of fatty alcohol-polyoxyethylene ether (9) (AEO9), 6-9 parts of sodium alcohol ether sulphate, 0.05-0.2 parts of kathon, 0.1-0.2 parts of essence and the balance of deionized water. The detergent of the present invention has the characteristics of strong detergency, hard water washing resistance, simple production process and usage at room temperature or low temperature.

Description

A kind of liquid detergent containing Gemini surface active agent
Technical field
The present invention relates to a kind of liquid detergent, be specifically related to a kind of containing Gemini surface active agent, strong detergency, The liquid detergent of hard water resistance washing.
Background technology
Gemini surface active agent is efficient, the multifunctional novel kind that a class is different from conventional surfactant, Such surfactant breaches the single-stranded structure of conventional surfactant, has two long hydrophobic chains and two Hydrophilic group, and the compound being formed by connecting by chemical bond by linking group.This of Gemini surface active agent Plant unique structure so that it is there is excellent surface chemistry and application performance, the most become surface and lived Property agent research in a field the most active.But the double type surfactant owing to having researched and developed produces Cost is high, therefore its industrialization product is the fewest.
Wherein Gemini surface active agent N, N '-bis-dodecanoyl ethylene diamine dipropionic acid sodium solutions have excellent resistance to firmly Water scourability, also has good emulsifying and foaming properties simultaneously, and therefore it is in liquid detergent field Have a extensive future.
The liquid detergent market development of recent year is rapid, along with consumer's washing habits change and Consumer group's rejuvenation trend is obvious so that liquid detergent market development space is huge.
Though liquid detergent currently on the market is of a great variety, but it is strong not generally to there is dirt-removing power, hard water The problem of clean result difference, it is difficult to meet consumer demand.
Summary of the invention
The defect existed in view of above-mentioned prior art, the purpose of the present invention is to propose to a kind of containing Gemini surface active The liquid detergent of agent, solves dirt-removing power present in liquid detergent poor, hard water clean result difference Problem.
The purpose of the present invention is achieved by the following technical programs:
A kind of liquid detergent of the present invention, comprises the raw material of following mass fraction: N, N '-bis-12 Ethylene Diamine dipropionic acid 3-10 part, dodecylbenzene sodium sulfonate 3-8 part, fatty alcohol-polyoxyethylene ether (9) (AEO9) 6-9 part, polyoxyethylenated alcohol sodium sulfate 6-9 part, Kazon 0.05-0.2 part, essence 0.1-0.2 Part, surplus is deionized water.
Above-mentioned a kind of liquid detergent containing Gemini surface active agent, making step is: first, by the moon from Sub-surface activating agent, Gemini surface active agent add in metering water, and heating adds poly alkyl alcohol after being sufficiently stirred for Oxygen vinyl Ether (9) (AEO9), it being eventually adding Kazon, essence, stirring is to being completely dissolved.
The prominent effect of the present invention is:
Above-mentioned a kind of liquid detergent containing Gemini surface active agent has strong detergency, the spy of hard water resistance washing Point.And processing technology is simple, can use under room temperature or low temperature.
Detailed description of the invention
Below in conjunction with specific embodiment, embodiments of the present invention are described in further detail.
Embodiment 1
A kind of liquid detergent, comprises the raw material of following mass fraction: N, N '-bis-dodecanoyl ethylenediamines two Sodium propionate 5 parts, dodecylbenzene sodium sulfonate 3 parts, fatty alcohol-polyoxyethylene ether (9) (AEO9) 8 parts, Polyoxyethylenated alcohol sodium sulfate 8 parts, Kazon 0.05 part, 0.1 part of essence, surplus is deionized water.
Concrete preparation process: first, adds metering water by anion surfactant, Gemini surface active agent In, heating adds fatty alcohol-polyoxyethylene ether (9) (AEO after being sufficiently stirred for9), it is eventually adding Kazon, perfume (or spice) Essence, stirring is to being completely dissolved.
Embodiment 2
A kind of liquid detergent, comprises the raw material of following mass fraction: N, N '-bis-dodecanoyl ethylenediamines two Sodium propionate 3 parts, dodecylbenzene sodium sulfonate 6 parts, fatty alcohol-polyoxyethylene ether (9) (AEO9) 9 parts, Polyoxyethylenated alcohol sodium sulfate 9 parts, Kazon 0.1 part, 0.2 part of essence, surplus is deionized water.
This example preparation process is with embodiment 1.
Embodiment 3
A kind of liquid detergent, comprises the raw material of following mass fraction: N, N '-bis-dodecanoyl ethylenediamines two Sodium propionate 8 parts, dodecylbenzene sodium sulfonate 8 parts, fatty alcohol-polyoxyethylene ether (9) (AEO9) 5 parts, Polyoxyethylenated alcohol sodium sulfate 6 parts, Kazon 0.2 part, 0.1 part of surplus of essence are deionized water.
This example preparation process is with embodiment 1.
Above-described is only the preferred embodiment of the present invention, the invention is not restricted to above example.Permissible Understanding, those skilled in the art the most directly derive or associate Oher improvements and changes, within being all considered as being included in protection scope of the present invention.

Claims (3)

1. a liquid detergent, it is characterised in that: comprise the raw material of following mass fraction: N, N '-bis-dodecanoyls Ethylene diamine dipropionic acid sodium 3-10 part, dodecylbenzene sodium sulfonate 3-8 part, fatty alcohol-polyoxyethylene ether (9) (AEO9) 6-9 part, polyoxyethylenated alcohol sodium sulfate 6-9 part, Kazon 0.05-0.2 part, essence 0.1-0.2 Part, surplus is deionized water.
A kind of liquid detergent containing Gemini surface active agent, it is characterised in that make Step is: first, anion surfactant, Gemini surface active agent is added in metering water, and heating is filled Fatty alcohol-polyoxyethylene ether (9) (AEO is added after dividing stirring9), it being eventually adding Kazon, essence, stirring is extremely It is completely dissolved.
The application in detergent of a kind of liquid detergent containing Gemini surface active agent.
CN201610186566.7A 2016-03-29 2016-03-29 Liquid detergent containing gemini surfactant Pending CN105838514A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610186566.7A CN105838514A (en) 2016-03-29 2016-03-29 Liquid detergent containing gemini surfactant

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610186566.7A CN105838514A (en) 2016-03-29 2016-03-29 Liquid detergent containing gemini surfactant

Publications (1)

Publication Number Publication Date
CN105838514A true CN105838514A (en) 2016-08-10

Family

ID=56583917

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610186566.7A Pending CN105838514A (en) 2016-03-29 2016-03-29 Liquid detergent containing gemini surfactant

Country Status (1)

Country Link
CN (1) CN105838514A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106497703A (en) * 2016-10-31 2017-03-15 佛山市南海东方澳龙制药有限公司 A kind of plant abluent containing Gemini surface active agent and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101033434A (en) * 2007-03-28 2007-09-12 常熟市亚德实业有限公司 Clothes detergent
ZA201104027B (en) * 2008-12-22 2012-08-29 Unilever Plc Laundry compositions
CN103146501A (en) * 2013-03-22 2013-06-12 于文 Environment-friendly high-efficiency laundry detergent and preparation method thereof
WO2014105366A1 (en) * 2012-12-28 2014-07-03 The Dial Corporation Laundry detergents and methods for making laundry detergents containing methyl ester ethoxylates

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101033434A (en) * 2007-03-28 2007-09-12 常熟市亚德实业有限公司 Clothes detergent
ZA201104027B (en) * 2008-12-22 2012-08-29 Unilever Plc Laundry compositions
WO2014105366A1 (en) * 2012-12-28 2014-07-03 The Dial Corporation Laundry detergents and methods for making laundry detergents containing methyl ester ethoxylates
CN103146501A (en) * 2013-03-22 2013-06-12 于文 Environment-friendly high-efficiency laundry detergent and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
许虎君等: "N,N’-双月桂酰基乙二胺二丙酸钠的制备与性能", 《精细石油化工》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106497703A (en) * 2016-10-31 2017-03-15 佛山市南海东方澳龙制药有限公司 A kind of plant abluent containing Gemini surface active agent and preparation method thereof

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PB01 Publication
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WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20160810

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