CN106497703A - A kind of plant abluent containing Gemini surface active agent and preparation method thereof - Google Patents

A kind of plant abluent containing Gemini surface active agent and preparation method thereof Download PDF

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Publication number
CN106497703A
CN106497703A CN201610928985.3A CN201610928985A CN106497703A CN 106497703 A CN106497703 A CN 106497703A CN 201610928985 A CN201610928985 A CN 201610928985A CN 106497703 A CN106497703 A CN 106497703A
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China
Prior art keywords
surface active
sodium
active agent
gemini surface
abluent
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CN201610928985.3A
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Chinese (zh)
Inventor
焦伟丽
元晓琪
徐奇清
陈静虹
林孝崇
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Foshan Nanhai Eastern Along Pharmaceutical Co Ltd
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Foshan Nanhai Eastern Along Pharmaceutical Co Ltd
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Priority to CN201610928985.3A priority Critical patent/CN106497703A/en
Publication of CN106497703A publication Critical patent/CN106497703A/en
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0094—High foaming compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/046—Salts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/06—Phosphates, including polyphosphates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/28—Heterocyclic compounds containing nitrogen in the ring
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/30—Amines; Substituted amines ; Quaternized amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/32—Amides; Substituted amides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/008—Polymeric surface-active agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C11D1/24—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds containing ester or ether groups directly attached to the nucleus
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/667—Neutral esters, e.g. sorbitan esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C11D1/721—End blocked ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups

Abstract

A kind of plant abluent containing Gemini surface active agent and preparation method thereof, abluent includes the component of following mass percent：3 30% Gemini surface active agents, 1 15% nonionic surfactant, 0.01 10% corrosion inhibiter and 0.1 3% halogen contained compound, balance of water, its preparation method are to comprise the following steps：By the Gemini surface active agent in proportioning, nonionic surfactant, sequentially add in purified water, heated and stirred is subsequently added corrosion inhibiter, halogen contained compound, is stirred well to and is completely dissolved to being completely dissolved, adjust ph to 7～13, you can obtain alkaline cleaner.The present invention proposes a kind of decontamination efficiency height, plant's alkaline cleaner of resting period length, and it is low to the corrosivity of the hardware in plant, safety coefficient can effectively be improved, in addition the preparation method of above-mentioned alkaline cleaner is also proposed, method is simple, environmental requirement is low, and the alkaline cleaner of acquisition has good stability.

Description

A kind of plant abluent containing Gemini surface active agent and preparation method thereof
Technical field
The present invention relates to plant's cleaning technique field, more particularly to a kind of plant is with clear containing Gemini surface active agent Lotion and preparation method thereof.
Background technology
Biomembrane is forms being combined for bacterial aggregate and extracellular matrix at which in the mucus (mucopolysaccharide) secreted by antibacterial Body, its close adhesion in body surface (ground) and are difficult to remove.Conventional high pressure rinse means are made to bacterial biof iotalm With limited, need which to be carried out disintegrating destruction using suitable surfactant, assist follow-up disinfectant to kill remaining bacteria Go out.
And existing abluent has many kinds, but the formula seldom for plant's Environment Design, plant's environment is complicated, The residual of organic dirt such as the Excreta of cultivated animals, secretions and food debriss can cause the growth of bacterial biof iotalm so that Antibacterial is difficult to clean up.Caustic soda as original cleaning means is big to people and animals and instrument and equipment corrosion, is not suitable for large-scale use, And most cleaning agent formula lacks anti-inhibition ingredient, the especially formula of meta-alkalescence, it is impossible to alleviate cleaning process to instrument The loss brought by equipment.
In addition, plant's cleaning will produce large amount of sewage, it is desirable to cleaning agent formula environmental protection low stain, it is to avoid the sewage of outflow Pollution surrounding enviroment.
Existing patent (aqueous foam abluent, 201510098659.X) discloses a kind of plant's environment abluent, Under alkaline environment, using the quaternary amine salt surfactant of cation, there is unstability easily to decompose, the resting period is short, and decontamination is imitated Can not be high, and erosion is easily caused to metal instrument and equipment in plant, make equipment rusty stain easily occur.
Content of the invention
It is an object of the invention to proposing the plant of a kind of decontamination efficiency height, resting period length with containing Gemini surface active The abluent of agent, is alkaline cleaner, and the corrosivity to the hardware in plant are low, can effectively improve safety coefficient.
Further object is that proposing a kind of preparation of plant with the abluent containing Gemini surface active agent Method, method are simple, and environmental requirement is low, and the alkaline cleaner for preparing has good stability.
It is that the present invention is employed the following technical solutions up to this purpose：
A kind of abluent of plant containing Gemini surface active agent, including the component of following mass percent：3-30% Gemini surface active agent, 1-15% nonionic surfactants, 0.01-10% corrosion inhibiter and 0.1-3% halogen contained compounds, remaining Measure as water.
Further description, the Gemini surface active agent be N, the bimonthly osmanthus Ethylene Diamine dipropionic acids of N'-, dioxane One or more in yl diphenyl ether sodium disulfonate or the double cocoyl ethylenediamine diethyl sodium sulfonates of N, N'-.
Further description, the nonionic surfactant are alkylolamideses polyethenoxy ether class, block polyoxy One or more of ethylene-polyoxypropylene ethers, alkylolamideses class, alkyl poly glucoside class and polyol ester apoplexy due to endogenous wind, excellent Choosing for alkylolamideses class.
Further description, the corrosion inhibiter be ethylenediamine, triethanolamine, carbamide, heptadecanoyl amine, sodium hexameta phosphate, One or more in tertiary sodium phosphate, sodium tripolyphosphate, sodium dihydrogen phosphate or sodium aluminate.Preferably, the corrosion inhibiter is trimerization In sodium phosphate, triethanolamine one or two.
Further description, the halogen contained compound are any one in sodium chloride, sodium bromide or sodium iodide.Excellent Choosing, the halogen contained compound is sodium chloride.
Further description, also includes the builder that mass percent is 0.05-2%.
Further description, the builder are sodium carbonate, sodium sulfate, nitrilotriacetic acid salt, sodium citrate or second two One or more in amine tetraacethyl disodium.
Further description, prepares a kind of method of the above-mentioned plant with the abluent containing Gemini surface active agent, bag Include following steps：
By the Gemini surface active agent in proportioning, nonionic surfactant, sequentially add in purified water, heated and stirred is extremely It is completely dissolved, is subsequently added corrosion inhibiter, halogen contained compound, stirs to being completely dissolved, adjust ph to 7～13, you can obtain alkali Property abluent.
Beneficial effects of the present invention：
1st, for the residual of organic dirts such as plant's environment complexity, the Excreta of cultivated animals, secretions and food debriss Stay and derivative antibacterial, select Gemini surface active agent and nonionic surfactant to be arranged in pairs or groups, corrosion inhibiter with there is anti-corruption There is synergism in the Gemini surface active agent and nonionic surfactant of erosion effect, make foam fine and smooth persistently, tool to each other There are good stability, detergency ability high；
2nd, corrosivity of the base formulation to hardware in plant are reduced, corrosivity are low, reduce the loss of equipment, improve Safety coefficient；
3rd, add hard water resistance builder, reduce the impact of the product effect of different regions Water quality；
3rd, the resting period effectively can extend, and abluent itself has more stable solution property.
Specific embodiment
Technical scheme is further illustrated below by specific embodiment.
A kind of abluent of plant containing Gemini surface active agent, including the component of following mass percent：3-30% Gemini surface active agent, 1-15% nonionic surfactants, 0.01-10% corrosion inhibiter and 0.1-3% halogen contained compounds, remaining Measure as water.
Complicated for plant's environment, the residual of organic dirt such as the Excreta of cultivated animals, secretions and food debriss And derivative antibacterial, the application selects Gemini surface active agent, nonionic surfactant and corrosion inhibiter to be arranged in pairs or groups, strong basicity Under environment, while surfactant is carried out disintegrating destruction to bacterial biof iotalm, the addition of corrosion inhibiter can effectively avoid alkalescence Abluent in the pond of plant or the corrosion phenomenon that causes of equipment occurs, corrosion inhibiter and the Shuangzi surface with anticorrosive effect There is synergism to each other in activating agent and nonionic surfactant, make foam fine and smooth persistently, with good stability, go Dirty performance is high, and raw material is friendly to people and animals, with good biological degradability, while adding corrosion inhibiter in formula, is different from The Caustic soda abluent used in traditional plant, the corrosion inhibiter in the application formula are used for reducing base formulation to plant's Endothelium corneum The corrosivity of category equipment, pH value are determined that by raw material corrosivity are low, reduce the loss of equipment, improve safety coefficient.
Further description, the Gemini surface active agent be N, the bimonthly osmanthus Ethylene Diamine dipropionic acids of N'-, dioxane One or more in yl diphenyl ether sodium disulfonate or the double cocoyl ethylenediamine diethyl sodium sulfonates of N, N'-.Preferably, it is N, The double cocoyl ethylenediamine diethyl sodium sulfonates of N'-, dirt-removing power are high, and storage is stable.
Further description, the nonionic surfactant are alkylolamideses polyethenoxy ether class, block polyoxy One or more of ethylene-polyoxypropylene ethers, alkylolamideses class, alkyl poly glucoside class and polyol ester apoplexy due to endogenous wind, excellent Choosing for alkylolamideses class.
Further description, for the abluent used in plant, which uses N, the bimonthly osmanthus Ethylene Diamines two of N'- One or more in sodium propionate or dialkyl diphenyl ether sodium disulfonate or the double cocoyl ethylenediamine diethyl sodium sulfonates of N, N'-, Its decontamination efficiency under the synergism of nonionic surfactant is greatly improved, and the resting period can extend, abluent itself There is more stable solution property.
Further description, the corrosion inhibiter be ethylenediamine, triethanolamine, carbamide, heptadecanoyl amine, sodium hexameta phosphate, One or more in tertiary sodium phosphate, sodium tripolyphosphate, sodium dihydrogen phosphate or sodium aluminate.Preferably, the corrosion inhibiter is trimerization In sodium phosphate, triethanolamine one or two.
Further description, the halogen contained compound are any one in sodium chloride, sodium bromide or sodium iodide.Excellent Choosing, the halogen contained compound is sodium chloride.
Further description, also include mass percent be 0.05-2% builder, the builder be sodium carbonate, One or more in sodium sulfate, nitrilotriacetic acid salt, sodium citrate or disodiumedetate.Make in the formula of the application Used additives consumption is few, but in order that the range of application increase of abluent, can add hard water resistance builder, reduce different regions Impact of the water body to product effect, improves the range of application of abluent.
A kind of method of the above-mentioned plant with the abluent containing Gemini surface active agent is prepared, is comprised the following steps：
By the Gemini surface active agent in proportioning, nonionic surfactant, sequentially add in purified water, heating is fully stirred Mix to being completely dissolved, be subsequently added corrosion inhibiter, halogen contained compound, be stirred well to and be completely dissolved, adjust ph to 7～13, i.e., Alkaline cleaner can be obtained.
Preferably, purified water is heated, water temperature is 40-60 DEG C.
Embodiment 1
Formula：Component including following mass percent：3% is N, bimonthly osmanthus Ethylene Diamine dipropionic acids of N'-, 1% Alkylolamideses polyethenoxy ether class, 0.01% ethylenediamine, 0.01% sodium chloride, balance of water.
Preparation method：N in formula, N'- bimonthly osmanthus Ethylene Diamine dipropionic acid and alkane are successively added in purified water Base alkylolamides polyethenoxy ether class, sequentially adds ethylenediamine, sodium chloride after dissolving completely, notes dissolving complete one of them into / after, another is added, is stirred to dissolving completely, subpackage.
Embodiment 2
Formula：Component including following mass percent：The bimonthly osmanthus Ethylene Diamine dipropionic acid of 15%N, N'-, 6% embedding Section polyoxyethylene polyoxypropylene ether class, 2% triethanolamine, 2% sodium chloride, balance of water.
Preparation method successively adds the N in formula, the bimonthly osmanthus Ethylene Diamine dipropionic acids of N'- and block in purified water Polyoxyethylene polyoxypropylene ether class, sequentially adds triethanolamine, sodium chloride after dissolving completely, notes dissolving completely wherein After individual composition, another is added, stirred to dissolving completely, subpackage.
Embodiment 3
Formula：Component including following mass percent：The bimonthly osmanthus Ethylene Diamine dipropionic acid of 8%N, N'- and 15% Alkyl poly glucoside class, 5% heptadecanoyl amine, 3% sodium bromide, balance of water.
Preparation method：N in formula, N'- bimonthly osmanthus Ethylene Diamine dipropionic acid, alkyl are successively added in purified water Polydextrose glycoside, heptadecanoyl amine, sodium bromide, after noting the completely one of composition of dissolving, add another, stir to Dissolving is complete, subpackage.
Embodiment 4
Formula：Component including following mass percent：The double cocoyl ethylenediamine diethyl sodium sulfonates of 17%N, N'-, 10% alkylolamideses class, 1% triethanolamine, 1.5% sodium chloride, balance of water.
Preparation method：N in formula is successively added in purified water, and the double cocoyl ethylenediamine diethyl sodium sulfonates of N'- are complete After CL, triethanolamine, sodium chloride is sequentially added, after noting the completely one of composition of dissolving, adds another, Stir to dissolving completely, carry out middle product and product inspection, check qualified, subpackage.
Embodiment 5
Formula：Component including following mass percent：The bimonthly osmanthus Ethylene Diamine dipropionic acid of 10%N, N'-, 5%N, The double cocoyl ethylenediamine diethyl sodium sulfonates of N'-, 7% polyhydric alcohol esters surface active agent, 3% sodium tripolyphosphate, 2% chlorination Sodium, balance of water.
Preparation method：N in formula successively added in purified water, the bimonthly osmanthus Ethylene Diamine dipropionic acids of N'-, N, The double cocoyl ethylenediamine diethyl sodium sulfonates of N'- and polyhydric alcohol esters surface active agent, sequentially add trimerization after being completely dissolved Sodium phosphate and sodium chloride, after noting the completely one of composition of dissolving, add another, stir to dissolving completely, subpackage ?.
Embodiment 6
Formula：Component including following mass percent：15% dialkyl diphenyl ether sodium disulfonate, 15%N, the double coconut palms of N'- Two ethyl sulfonic acid of oleoyl ethylenediamine, 7% alkyl poly glucoside class surfactant, 3% sodium tripolyphosphate, 2% sodium chloride, remaining Measure as water.
Preparation method：Dialkyl diphenyl ether sodium disulfonate in formula, N, N'- double cocos nucifera oil acyl are successively added in purified water Base ethylenediamine diethyl sodium sulfonate and alkyl poly glucoside class surfactant, sequentially add sodium tripolyphosphate after being completely dissolved And sodium chloride, after noting the completely one of composition of dissolving, another is added, stirred to dissolving completely, subpackage.
Embodiment 7
Formula：Component including following mass percent：The bimonthly osmanthus Ethylene Diamine dipropionic acid of 10%N, N'-, 7%0 Dialkyl benzene sulfonic acids sodium, 1% hexamethylenetetramine, balance of water.
Preparation method：Dodecylbenzene sodium sulfonate in formula, N, N'- double lauroyl second are successively added in purified water Diamidogen dipropionic acid, hexamethylenetetramine, after noting the completely one of composition of dissolving, add another, stir to molten Solution is complete, subpackage.
The test of proof property：
First, stability test
The abluent that embodiment 1-6 is obtained is placed 24h in -18 DEG C of refrigerator, is taken out and is recovered to observation nothing during room temperature Crystallization, without precipitation；24h is placed in the couveuse of (40 scholar 1) DEG C, take out observe immediately not stratified, haze-free, and do not change gas Taste, when subsequently using, detergency ability does not significantly decrease, and embodiment 7 places 24h in -18 DEG C of refrigerator, takes out and recovers extremely Nodeless mesh is observed during room temperature, without precipitation；24h is placed in the couveuse of (40 scholar 1) DEG C, take out observe immediately not stratified, haze-free, Abnormal smells from the patient slightly becomes, and when subsequently using, detergency ability declines.
2nd, detergency experiment
1. method summary
Standard intraocular's dirt is made to be evenly affixed on stainless steel substrates, with the dishwashing detergent agent solution of normal concentration, in regulation Under the conditions of wash, determine dirt removal percentage rate.
2. reagent
A) 150mg/kg hard water；
B) vegetable oil；
C) liquid paraffin；
D) attapulgite；
E) arabic gum.
3. instrument
A) analytical balance, sensibility reciprocal 0.1mg, maximum capacity 200g；
B) Electromagnetic Heating agitator；
C) pendulum washing machine, rustless steel constant temperature water bath；
D) thermometer, 100 DEG C of range；
E) rustless steel test piece, 8cm × 7cm；
F) 250ml beakers；
G) 40 DEG C of calorstats.
4. determination step
1. the preparation of test piece
27 stainless steel substrates, specification are 8cm × 7cm, use ethanol soaked overnight, flushing to dry, be put in dry after cleaning up Stand-by in dry ware.
2. the preparation of artificial dirt
Prepare 10 parts of vegetable oil and 10 points of liquid paraffin, mix homogeneously adds 5 points of arabic gums after being heated to 65-75 DEG C With 50 parts of water.The attapulgite for amounting to 25 parts is dividedly in some parts after stirring.
3. the preparation of dirty piece
Ready test piece, three is one group, totally nine groups, weighs (being accurate to 0.1g), and now quality is represented with m0.To claim The test piece that measured is sandwiched in test piece frame one by one, immerses in ready 60 DEG C of artificial dirts, and liquid level is arrived from clip about 30mm, immersion 1 2s, after be slowly withdrawn, after under greasy dirt drop slow after, be suspended in 250ml sky beaker on, be sequentially prepared dirty piece.After be put into 40 3h is air-dried in DEG C calorstat.Take out, the weight of accurate weighing dirt piece is designated as m1.
4. test procedure
Using preprepared 150mg/kg hard water, test solution is configured to the solution that concentration is 1%, is poured into clean In 250ml beakers, each beaker is placed the dirty piece of one group of known weight and is fixed.(46 ± 2) DEG C pendulum is moved into after immersion 1min to wash In machine, adjustment pendulum wash frequency for (30 ± 2) secondary/min (coming and going as 1 time), pendulum washes 15min, takes out dirty piece afterwards, moves into 40 DEG C of constant temperature 3h being air-dried in case and being weighed, now quality is m2.
5. result is calculated
Detergency A is calculated by formula (1)：
In formula：
M0 defile before test piece quality, unit be gram (g)；
M1 defile after test piece quality, unit be gram (g)；
Test piece quality after m2 cleanings, unit are gram (g).
6. result of the test
1 detergency result of the test of table
1 is shown in Table, the dirt-removing power of embodiments herein 1-6 is superior to clear water and competing product, 4 Gemini surface active of embodiment Agent selects Sodium Alcohol Ether Sulphate and Fatty acid methyl ester sodium sulfonate, amphoteric surfactant to aoxidize from dodecanamide propyl Amine, preferably, wherein, competing product refer to certain import plant rinse product domestic to the dirt-removing power for reaching.
Further description, would know that by embodiment 5-6, it is preferred that the addition of corrosion inhibiter is 0.01-2%, adds When dosage is excessive, detergency ability begins to decline.
3rd, corrosion inhibition for metal experiment
1. experiment material
Iron part, electronic balance (sensibility reciprocal 0.000lg), slide gauge, infrared drying oven, tweezers, 50ml tool plug test tube, 5ml graduated cylinders, test tube rack, filter paper.
Caustic soda, the abluent of the acquisition of embodiment 2, acetone, ethanol.
2. experimental procedure
1) by ferrous element 11：Acetone ethanol solution in wash away greasy dirt after, be placed on cleaning filter paper on, be placed in red Dry in outer drying baker, quality is accurately weighed with electronic balance by its numbering.(being accurate to 2 after arithmetic point).
2) 4 50ml tool plug test tubes are taken, 25ml30%H in first test tube, is added2O2, in second test tube, add 25ml 2%NaOH, adds 25ml 1 in the 3rd test tube:50 embodiments 2, add 25ml pure water in last test tube, cover bottle Plug shakes up.
3) ferrous element for weighing up quality is carefully placed in above-mentioned test tube, time and room temperature that accurate recording is added.Quiet After putting one week, ferrous element is taken out, wash away the liquid that remains in test piece immediately with tap water and portion is dipped in clean filter paper Divide tap water, be then placed in 11：Acetone ethanol solution in wash, be finally placed in infrared drying oven dry, claim its quality.
3. experimental result
Experimental result：30%H2O2Group, iron ring start rusty stain occur；2%NaOH, rustization are serious；Embodiment 2, without substantially rust Mark occurs, clear water group, occurs without obvious rusty stain.As a result show, the conventional 2%NaOH of plant has certain to apparatus made of iron Corrosivity, and the corrosivity of the embodiment of the present application 2 will be well below Caustic soda.It should be noted that under room temperature Caustic soda itself is not Chemical reaction can be produced with ferrum, but the H+ that highly basic brings, OH- are unbalance, can increase the oxidation activity of ironwork, cause rustization phenomenon Appearance.
Above-described embodiment 2 is replaced with any one its effect in embodiment 1 or embodiment 3-6 same as Example 2, no Obvious rusty stain occurs.
Above in association with the know-why that specific embodiment describes the present invention.These descriptions are intended merely to explain the present invention's Principle, and limiting the scope of the invention can not be construed to by any way.Based on explanation herein, the technology of this area Personnel associate other specific embodiments of the present invention by need not paying performing creative labour, these modes fall within Within protection scope of the present invention.

Claims (10)

1. a kind of plant with containing Gemini surface active agent abluent, it is characterised in that：Group including following mass percent Point：3-30% Gemini surface active agents, 1-15% nonionic surfactants, 0.01-10% corrosion inhibiter and 0.1-3% are halogen-containing Compound, balance of water.
2. a kind of plant according to claim 1 with containing Gemini surface active agent abluent, it is characterised in that：Described Gemini surface active agent is N, the double coconut palms of the bimonthly osmanthus Ethylene Diamine dipropionic acids of N'-, dialkyl diphenyl ether sodium disulfonate or N, N'- One or more in oleoyl ethylenediamine diethyl sodium sulfonate.
3. a kind of plant according to claim 1 with containing Gemini surface active agent abluent, it is characterised in that：Described Nonionic surfactant is alkylolamideses polyethenoxy ether class, Block polyoxyethylene-polyoxypropylene ethers, alkylolamideses One or more of class, alkyl poly glucoside class and polyol ester apoplexy due to endogenous wind.
4. a kind of plant according to claim 1 with containing Gemini surface active agent abluent, it is characterised in that：Described Corrosion inhibiter is ethylenediamine, triethanolamine, carbamide, heptadecanoyl amine, sodium hexameta phosphate, tertiary sodium phosphate, sodium tripolyphosphate, biphosphate One or more in sodium or sodium aluminate.
5. a kind of plant according to claim 4 with containing Gemini surface active agent abluent, it is characterised in that：Described Corrosion inhibiter is sodium tripolyphosphate, in triethanolamine one or two.
6. a kind of plant according to claim 1 with containing Gemini surface active agent abluent, it is characterised in that：Described Halogen contained compound is any one in sodium chloride, sodium bromide or sodium iodide.
7. a kind of plant according to claim 6 with containing Gemini surface active agent abluent, it is characterised in that：Described Halogen contained compound is sodium chloride.
8. a kind of plant according to claim 1 with containing Gemini surface active agent abluent, it is characterised in that：Also wrap Include the builder that mass percent is 0.05-2%.
9. a kind of plant according to claim 8 with containing Gemini surface active agent abluent, it is characterised in that：Described Builder is one or more in sodium carbonate, sodium sulfate, nitrilotriacetic acid salt, sodium citrate or disodiumedetate.
10. the method for preparing a kind of abluent of the plant described in claim 1 containing Gemini surface active agent, its feature exist In：Comprise the following steps：
By the Gemini surface active agent in proportioning, nonionic surfactant, sequentially add in purified water, heated and stirred is to complete Dissolving, is subsequently added corrosion inhibiter, halogen contained compound, stirs to being completely dissolved, adjusts ph to 7～13, you can obtains alkalescence clear Lotion.
CN201610928985.3A 2016-10-31 2016-10-31 A kind of plant abluent containing Gemini surface active agent and preparation method thereof Pending CN106497703A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114752942A (en) * 2022-04-29 2022-07-15 泰伦特生物工程股份有限公司 Industrial cleaning agent containing gemini surfactant and preparation method thereof
CN116219444A (en) * 2023-03-01 2023-06-06 福建省佑达环保材料有限公司 Cleaning agent for new energy columnar battery aluminum shell

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Publication number Priority date Publication date Assignee Title
WO1998015345A1 (en) * 1996-10-04 1998-04-16 Rhodia Inc. Detergent compositions containing low concentration levels of gemini surfactants
CN1616627A (en) * 2004-09-30 2005-05-18 霍纪功 Dirt detergent
CN105838514A (en) * 2016-03-29 2016-08-10 江南大学 Liquid detergent containing gemini surfactant
CN105925395A (en) * 2016-05-19 2016-09-07 山东信得科技股份有限公司 Veterinary foam cleaning agent and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998015345A1 (en) * 1996-10-04 1998-04-16 Rhodia Inc. Detergent compositions containing low concentration levels of gemini surfactants
CN1616627A (en) * 2004-09-30 2005-05-18 霍纪功 Dirt detergent
CN105838514A (en) * 2016-03-29 2016-08-10 江南大学 Liquid detergent containing gemini surfactant
CN105925395A (en) * 2016-05-19 2016-09-07 山东信得科技股份有限公司 Veterinary foam cleaning agent and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114752942A (en) * 2022-04-29 2022-07-15 泰伦特生物工程股份有限公司 Industrial cleaning agent containing gemini surfactant and preparation method thereof
CN114752942B (en) * 2022-04-29 2023-09-22 泰伦特生物工程股份有限公司 Industrial cleaning agent containing gemini structure surfactant and preparation method thereof
CN116219444A (en) * 2023-03-01 2023-06-06 福建省佑达环保材料有限公司 Cleaning agent for new energy columnar battery aluminum shell

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Application publication date: 20170315