Background technique
Waste water zero emission, English Zero Liquid Disge, abbreviation ZLD, i.e. liquid zero emission.Though conventional ZLD technology
It so may be implemented, however, being used to from the point of view of investment, or from operating cost, be intended to pay quite high cost.Using normal
The thermal method technique of rule evaporates the high slat-containing wastewater of concentration, and corrosivity is extremely strong, it is necessary to evaporator is made with titanium, so equipment
Investment is abnormal expensive.Waste water is flashed into distilled water, energy consumption is high, and unfavorable to energy conservation, recycle-water cost obtained is also very high,
Reduce the cost performance of waste water recycling.Having for complexity will be increased using the high organic wastewater of the high saliferous of reverse osmosis membrane concentration
Machine object pre-processes facility, and investment is big, and operation energy consumption is high, and membrane lifetime is short.It is simple and practical that this patent uses one kind, and utilizes the sun
The normal pressure technology that can be evaporated, can be concentrated to 10%(concentration 100000ppm for the high organic wastewater of high saliferous), distilled water reuse,
Concentrate can be directly entered the zero-emission that crystallization apparatus realizes waste water.The core technology of this patent is solar energy film evaporator.
Patent content
The purpose of this patent is to provide a kind of solar energy film waste water evaporation concentration device, existing using steam to solve
Thermal method enrichment facility cost is high, energy consumption is high, the problem high to the pre-processing requirements of waste water.This patent, can compared with similar technique
The operating cost of initial investment expense and system is effectively reduced.
This patent adopts the technical scheme that solve above-mentioned technical problem: the device by connecting in order from top to bottom
Waste water tank (1), solar energy film evaporator (2), fresh-water tank (3), concentrated water case (4), concentrated water circulating pump (5) composition, are specifically detailed in
Patent figures.Solar energy film evaporator (2) is the core component of the present apparatus.The high high organic wastewater of saliferous is passing through water flow
Distributor enters the vaporization chamber bottom inclined plate of tilt angle arrangement, forms the moisture film being evenly distributed, is evaporated by solar energy film
The film and sunlight of device form sufficiently large evaporation contact surface, to sufficiently be evaporated, the water vapour by thermal evaporation rises
To film inner surface, and it is agglomerated into drop, the surface tension and gravity of drop make it from top to bottom along film inner surface stream
It moves to fresh water collecting slot, fresh water is recyclable to be recycled.Waste water constantly evaporates and flows downward to steaming along bottom inclined plate in vaporization chamber
Room lower end is sent out, is collected into concentrated water case through concentrated water collecting pipe.Concentrated water can be beaten again by concentrated water circulating pump according to concentration requirement
Return to constantly circulation concentration in the waste water tank being arranged at the top of evaporator.
Solar energy film evaporator above-mentioned is the core of the present apparatus.It is by waterflow distributor (2-1), solar energy film
(2-2), waste water vaporization chamber (2-3), fresh water collecting slot (2-4) and concentrated water collecting pipe (2-5) composition.Solar energy film sealing covering
On waste water vaporization chamber (2-3) film skeleton.Waste water vaporization chamber (2-3) is obliquely installed, and it is thin that wastewater inlet pipe is threaded through solar energy
The lower part of film, is connected with waterflow distributor, and concentrated water collecting pipe is threaded through the lower part of vaporization chamber.The fresh water collecting slot (2-4)
It is arranged between the solar energy film and vaporization chamber bottom plate of solar energy film evaporator lower end, the fresh water collected is received by fresh water
Collect slot and introduces fresh-water tank.To reach Waste water concentrating, the purpose of fresh water reuse.
Waterflow distributor (2-1) is the important component of solar energy film evaporator, it is characterised in that: it is a uniform cloth
The PE pipe of full aperture (pore diameter range is 0.5 ~ 1mm), can be evenly distributed in the oblique of thin film evaporator bottom by its waste water
On plate, water membrane is formed, to achieve the effect that evaporation of sufficiently absorbing heat.
Waste water vaporization chamber (2-3) is that waste water receives sunlight heat radiation, completes the carrier body of evaporative effect, feature exists
In its tilt angle and its bottom inclined plate length by experiment and scientific algorithm.Wherein α angle as shown in drawings should be controlled
Within the scope of 30 ~ 80 degree, inclined plate projected length in the horizontal direction should control within the scope of 1000 ~ 4000mm system, thin to guarantee
The vaporizer residence time of waste water in film evaporator, generated water vapour, which can condense, is attached to table in its smooth film
Face, drop flow into fresh-water tank after going downstream to the collection of fresh water collecting slot.
Waste water vaporization chamber (2-3) above-mentioned, it is characterised in that solar energy film and its bottom inclined plate inner surface at the top of it
The distance between h should control within the scope of 100 ~ 200mm, to guarantee sunlight to the caloradiance of waste water.
Solar energy film is the important carrier for completing photothermal conversion, it is characterised in that it uses PVC or PE material, outer surface
Nanometer heat absorbing coating is applied, collecting efficiency is high, flexibility is strong, corrosion-resistant, anti-aging, price is low, easy acquisition.The film material light
It is sliding, there is very strong hydrophily, thermal resistance is small and can guarantee water vapour that is hydrophobic smooth, therefore being generated in package unit by thermal evaporation
It is easily attached to its surface and condenses into water droplet, and along its smooth gravity flow in smooth surface, enter after the collection of fresh water collecting slot
Fresh-water tank achievees the purpose that fresh water is separated with concentrated water.
Solar energy film waste water evaporation concentration device above-mentioned, it is characterised in that: waste water tank is arranged in a whole set of enrichment facility
Top, outlet pipe be connected to water tank bottom and with the evaporator connection that is positioned below, waste water is by self gravity through water flow
Distributor, along vaporization chamber bottom, inclined plate uniformly goes downstream, and reaches energy-saving effect.
Solar energy film waste water evaporation concentration device above-mentioned, it is characterised in that: fresh-water tank is arranged in solar energy film steaming
Device lower end is sent out, fresh water outlet mouth is not less than fresh-water tank apical side height, and fresh-water tank is arranged in the upper surface of concentrated water case, therefore fresh water can
To be delivered to by gravity with water spot, fresh water transfer pump equipment is not only saved, and effectively reduce device electricity consumption.
Solar energy film waste water evaporation concentration device above-mentioned, it is characterised in that: be arranged in the dense of package unit bottommost
Water tank is connected by being threaded through the concentrated water collecting pipe of vaporization chamber lower part with solar energy film evaporator, dense waterbox design equipped with
Concentrated water circulating pump allows concentrated water to recycle repeatedly evaporation according to concentration rate requirement, achievees the purpose that be concentrated by evaporation repeatedly.
This patent having the beneficial effect that compared with the existing technology:
1, this patent realizes Waste water concentrating using solar energy resources, and low energy consumption, low to the pre-processing requirements of waste water;
2, list covering device processing water is 0.5-1m3/d;
3, the high organic wastewater of high saliferous can be handled, the dissolved solid (TDS) in waste water has up within 50000ppm
Machine object (COD) is up within 30000ppm;
4, this patent is light-weight, is readily transported, mounts and dismounts;
5, this patent has the advantages of simple structure and easy realization, and production cost is low, and it is smaller to be especially suitable for waste water water, waste water
The water quality of complicated component.
Specific embodiment 5: illustrating in conjunction with Fig. 1, the folder between present embodiment rectangular film skeleton and vertical direction
Angle is 30 ° -80 °.Present embodiment is arranged such, convenient for realizing Waste water concentrating using solar energy resources, enhances water vapour
It generates, improves the thermal efficiency and concentrated effect of device.
For this patent in implementation process, concrete condition is as follows:
The film of present embodiment be polyethylene, 30 ° of setting angle, evaporator tank volume 2m3,Effective surface area 4m2, inside
Illiteracy Chifeng City's summer test process water is 0.7 m3/d;
The film of present embodiment be polyvinyl chloride, 45 ° of setting angle, evaporator tank volume 2m3, effective surface area 4m2,
Chifeng city summer test process water is 0.75 m3/d。
The working principle of this patent is: using the thermoradiation efficiency of sunlight, the evaporation of water heat being made to become water vapour rising
To solar energy film inner surface, residual waste water, which is constantly concentrated, achievees the purpose that Waste water concentrating is reduced.
This patent irradiates evaporator by sunlight and heats to vaporization chamber, and evaporation room temperature increases, in waste water tank
Water be distributed evenly on base of evaporator inclined plate through the waterflow distributor of evaporator, with sunlight formed adequately contact by
Hot face, since evaporation room temperature is higher than outside air temperature, water vapour is moved upwards in vaporization chamber, hydrophobic thin encountering
Drop is formed when film, since hydrophobic film has very strong hydrophily, water droplet leans on the surface tension edge of self gravity and water
Hydrophobic film inner surface goes downstream, and flow in fresh-water tank after the collection of fresh water collecting slot.Evaporate indoor waste water from top to bottom
Uniform Flow, and with continuous evaporation, waste strength is higher and higher, collects after flowing to bottom to concentrated water case, is wanted according to concentration
Concentration can constantly be recycled by the overhead waste water case that concentrated water delivery pump returns evaporator again concentrated water by asking.