CN105832577B - A kind of sun-proof rose nail polish and preparation method thereof - Google Patents
A kind of sun-proof rose nail polish and preparation method thereof Download PDFInfo
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- CN105832577B CN105832577B CN201610178175.0A CN201610178175A CN105832577B CN 105832577 B CN105832577 B CN 105832577B CN 201610178175 A CN201610178175 A CN 201610178175A CN 105832577 B CN105832577 B CN 105832577B
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- nail polish
- proof
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- rose
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/35—Ketones, e.g. benzophenone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q3/00—Manicure or pedicure preparations
- A61Q3/02—Nail coatings
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
- A61K2800/436—Interference pigments, e.g. Iridescent, Pearlescent
Abstract
The invention discloses a kind of nail polish and preparation method thereof, belong to filed of daily-use chemical industry.Nail polish disclosed by the invention removes first synephrine and Rosa Damascana including the trans asafoetide acyl groups of natural amides compound N.The nail polish of the present invention includes the trans asafoetide acyl groups of natural amides compound N and removes first synephrine and Rosa Damascana; so that the nail polish can not only play beautification modification to nail; with rose scent, while it can stop that ultraviolet injures to caused by nail, the chemical sunscreen single better than composition.
Description
Technical field
The present invention relates to a kind of nail polish and preparation method thereof, belongs to filed of daily-use chemical industry.
Background technology
Nail polish belongs to the product of color make-up series, has the function that beautification modification nail, but to the ultraviolet protection work(of nail
Can be poor.Due to environment, sunscreen product is increasingly subject to the welcome of consumer, but draws sun-proof simultaneous with fragrance concept
Enter in nail polish, at present domestic and international market or a blank.Maintenance of the people to nail is except products such as nail polish, nail savers
Almost have no option outside, if nail polish products of the increase with sun-proof and fragrant function, not only play beautification to nail
Modification, while reduce the access times of perfume, it is also possible to stop that ultraviolet injures to caused by nail.
The fragrance of rose can bring happiness, can mitigate the fatigue and regulation sentiment of people.In the prior art
Nail polish be applied on nail after, it is necessary to can just be washed off using organic solvent or special nail polish remover, so not only
Inconvenience, and health can be damaged when with being engaged in the related works such as food and drink and dining.Thus, it is easy to clean and have
The nail polish of fragrance is increasingly pursued by people.It is strong, wear-resisting, water-fast, easy that nail polish must possess quick-drying, gloss, adhesive force
The features such as applying and easily removing.Though oneself reaches certain effect to existing product in use, its protection energy to ultraviolet
Power is poor.Product of the present invention is easy to completely be removed with hand after can also drying, and reaches purpose easy to use.
Therefore the present invention enriches the function of nail polish, meets a variety of demands of people, allows user to be happy to use.
The content of the invention
In view of the shortcomings of the prior art, the technical problems to be solved by the invention carry rose fragrant after being to provide a kind of smear
Taste, and easily remove and have the nail polish of sun-screening function.
The present invention also solves the firmness of existing nail polish and the technical problem of glossiness difference simultaneously, there is provided one kind tool
There is the nail polish of good gloss degree and firmness.
The present invention is achieved by the following technical solutions：
The sun-proof rose nail polish removes first synephrine, Rosa Damascana including the trans asafoetide acyl groups of N-.
Wherein, by weight, it is 0.2-0.6 parts that the trans asafoetide acyl groups of described N-, which remove first synephrine, Rosa Damascana 2-6
Part.
In addition, described sun-proof rose nail polish includes pharmaceutically acceptable carrier or composition.
Preferably, by weight, described sun-proof rose nail polish also includes the ethyl acetate of 20-40 parts, 5-15 parts
NC Nitroncellulose, the camphor of 0.5-1.5 parts, the pearl essence of 0.1-0.3 parts, the pigment of 1-3 parts.
The invention also discloses the preparation method of the sun-proof rose nail polish, the preparation side of the sun-proof rose nail polish
Method is as follows：
By ethyl acetate and Rosa Damascana, after being mixed evenly, NC Nitroncellulose is added under stirring in above-mentioned
In mixed liquor, 10min is stirred at 1500 rpm；Then the trans asafoetide acyl groups of N- are added and remove first synephrine, are stirred under 1500rpm
10min.Finally camphor, pearl essence, pigment are added thereto, stir 10min at 1500 rpm；200 mesh screens are made molten
Liquid, 4-5 hours are refrigerated in 0-4 DEG C, finally encapsulates and produces sun-proof rose nail polish.
The present invention is compared with prior art：The nail polish is free of formaldehyde, organic solvent and poisonous heavy metal, environmentally friendly nothing
Pollution, and it is easy to user to remove；It is fragrant without adding and the addition of Rosa Damascana improves nail polish to nail bond properties
Material, just it is provided with the faint scent of rose；Simultaneously can complete barrier ultraviolet injury, make nail polish that there is outstanding sun-proof work(
Effect, the SPF of nail polish is improved, better than the effect of single chemicals, very effective protection is played to nail and is repaired and is made
With.And preparation technology simplifies, practical function highly significant, and it is suitable to industrialized production.
Brief description of the drawings
Fig. 1 is the measurement result of sun-proof rose nail polish UVResistant effect.
Embodiment
Technical scheme is described in further detail with reference to specific embodiment, but protection scope of the present invention is not
It is confined to the embodiment.
The trans asafoetide acyl groups of embodiment 1N- go the preparation of first synephrine
Synthetic method forms acid amides first to synthesize Ferulic acid, then with chapter amine by amido link, specifically
Step is with reference to journal article：Zhengrong Wu, Lifang Zheng, Yang Li, et al.Synthesis and
structure-activity relationships and effects of phenylpropanoid amides of
octopamine and dopamine on tyrosinase inhibition and antioxidation,Food
Chemistry.134(2012)1128-1131。
Spectral data is as follows：The trans asafoetide acyl groups of N- remove first synephrine：Pale yellow powder, fusing point：183-185℃；
IR(KBr,cm-l):3361,3020-2930,1653,1594-1514,1268-1213；1H NMR(CD30D-d4,
400MHz).δ:3.43 (dd, J=13.6,8.OHz, 1H), 3.52 (dd, J=13.6,5.2Hz, 1H), 3.88 (s, 3H), 4.72
(dd, J=7.6,5.2Hz, 1H), 6.46 (d, J=15.6Hz, 1H), 6.76 (d, J=8.8Hz, 2H) 6.78 (d, J=8.5Hz,
1H), 7.02 (dd, J=8.4,1.2Hz, 1H), 7.12 (s, 1H), 7.23 (d, J=8.5Hz, 2H), 7.44 (d, J=15.6Hz,
1H):13C NMR(CD30D-d4,1OOMHz)δ:169.5,158.1,149.9,149.3,142.2,134.7,128.5,128.3,
123.3,118.7,116.5,116.1,111.6,73.4,56.4,48.3；HRMS:m/z 352.1149(calcd for
C18H19NO5+Na,352.1155)。
The preparation of the sun-proof rose nail polish of embodiment 2
1. the formula of sun-proof rose nail polish
Formula 1
The 2g trans asafoetide acyl groups of N- remove first synephrine, 20g Rosa Damascana, 200g ethyl acetate, 50g nitro fibre
Dimension element, 5g camphor, 1g pearl essence, 10g pigment.
Formula 2
The 4g trans asafoetide acyl groups of N- remove first synephrine, 40g Rosa Damascana, 300g ethyl acetate, 100g nitro
Cellulose, 10g camphor, 2g pearl essence, 20g pigment.
Formula 3
The 6g trans asafoetide acyl groups of N- remove first synephrine, 60g Rosa Damascana, 400g ethyl acetate, 150g nitro
Cellulose, 15g camphor, 3g pearl essence, 30g pigment.
2. the preparation method of sun-proof rose nail polish
By ethyl acetate and Rosa Damascana, after being mixed evenly, NC Nitroncellulose is added under stirring in above-mentioned
In mixed liquor, lOmin is stirred at 1500 rpm；Then the trans asafoetide acyl groups of sun-screening agent N- are added and remove first synephrine, 1500rpm
Lower stirring 10min.Finally camphor, pearl essence, pigment are added thereto, stir 10min at 1500 rpm:200 mesh screen systems
Into solution, 4-5 hours are refrigerated in 0-4 DEG C, finally encapsulates and produces sun-proof rose nail polish finished product.
The performance test of the sun-proof rose nail polish of embodiment 3
1. the preparation of laboratory sample
(1) sun-proof rose nail polish
Formula：The 2g trans asafoetide acyl groups of N- remove first synephrine, 20g Rosa Damascana, 200g ethyl acetate, 50g's
NC Nitroncellulose, 5g camphor, 1g pearl essence, 10g pigment.
Preparation method：
By ethyl acetate and Rosa Damascana, after being mixed evenly, NC Nitroncellulose is incorporated under stirring
State in mixed liquor, stir 10min at 1500 rpm；Then the trans asafoetide acyl groups of N- are added and remove first synephrine, are stirred under 1500rpm
Mix 10min.Finally camphor, pearl essence, pigment are added thereto according to the above ratio, stir 10min at 1500 rpm；200 mesh sieves
Solution is made in filtering, refrigerates 4-5 hours in 0-4 DEG C, finally encapsulates and produce sun-proof rose nail polish finished product.
(2) Rosa Damascana group
Formula：20g Rosa Damascana, 200g ethyl acetate, 50g NC Nitroncellulose, 5g camphor, lg pearly-lustre
Powder, 10g pigment.
Preparation method：By ethyl acetate and Rosa Damascana, after being mixed evenly, nitrocellulose is added under stirring
Element stirs lOmin at 1500 rpm in above-mentioned mixed liquor.Finally camphor according to the above ratio, pearl essence, pigment are added
Wherein, lOmin is stirred at 1500 rpm；200 mesh screens, produced in 0-4 DEG C of refrigeration 4-5 hour.
(3) the trans asafoetide acyl groups of N- go first synephrine group
Formula：The 2g trans asafoetide acyl groups of N- remove first synephrine, 200g ethyl acetate, 50g NC Nitroncellulose, 5g's
Camphor, 1g pearl essence, 10g pigment.
Preparation method：Ethyl acetate is added into NC Nitroncellulose to mix, stirs lOmin at 1500 rpm；Then N- is added
Trans asafoetide acyl group removes first synephrine, and lOmin is stirred under 1500rpm.Finally camphor, pearl essence, pigment are added according to the above ratio
Enter wherein, stir lOmin at 1500 rpm；200 mesh screens, produced in 0-4 DEG C of refrigeration 4-5 hour.
2. the preparation of control
Formula：200g ethyl acetate, 50g NC Nitroncellulose, 5g camphor, 1g pearl essence, 10g pigment.
Preparation method：
Ethyl acetate is mixed with NC Nitroncellulose, stirs lOmin at 1500 rpm；Again by camphor, pearl essence, pigment
It is proportionally added into above-mentioned solution, stirs lOmin at 1500 rpm；200 mesh screens, produced in 0-4 DEG C of refrigeration 4-5 hour.
3. sun-proof rose nail polish performance test
(l) outward appearance：Full color, it is bright, there is moist feeling.
(2) smell and removal easy degree：With rose scent taste, easily removed with hand.
(3) 3M adhesive tapes method determines its UVResistant effect.
The present embodiment determines the sun-proof result of manufactured sun-proof rose nail polish using 3M adhesive tapes method.
3M medical air-permeable adhesive tapes are cut into lcm × 4cm sizes, are pasted onto quartz colorimetric utensil printing opacity side surface.It is accurate to claim
Test sample 35mg, test sample is uniformly applied on quartz colorimetric utensil transparent surface, be placed in 35 DEG C of drying boxes, dried 30 minutes.
Then it is 285nm, 290nm, 295nm, 300nm, 305nm, 310nm, 315nm in Detection wavelength with ultraviolet specrophotometer,
320nm is detected, and each test sample setting five is parallel, determines OD values, OD values are bigger, better to UVB protection effect.
It can be seen from Fig. 1 results under same concentration, the OD values of sun-proof rose nail polish disclosed by the invention are obvious
First synephrine group is gone higher than control group, Rosa Damascana group and the trans asafoetide acyl groups of N-, shows to contain N-trans asafoetide acyl simultaneously
Base goes sun-proof rose nail polish prescription uvioresistant effect/anti-sunlight function of first synephrine and Rosa Damascana to be significantly higher than and individually contain
There is Rosa Damascana experimental group and the effect of first synephrine experimental group is individually gone containing the trans asafoetide acyl groups of N-, Rosa Damascana is anti-with N-
Formula asafoetide acyl group goes between first synephrine have the function that Synergistic.
Claims (5)
1. a kind of sun-proof rose nail polish, it is characterised in that described sun-proof rose nail polish is gone including the trans asafoetide acyl groups of N-
First synephrine, Rosa Damascana.
2. sun-proof rose nail polish according to claim 1, it is characterised in that by weight, the trans asafoetides of described N-
It is 0.2-0.6 parts that acyl group, which removes first synephrine, and Rosa Damascana is 2-6 parts.
3. sun-proof rose nail polish according to claim 1 or 2, it is characterised in that described sun-proof rose nail polish bag
Include pharmaceutically acceptable carrier or composition.
4. sun-proof rose nail polish according to claim 3, it is characterised in that by weight, described sun-proof rose refers to
Nail polish also includes the ethyl acetate of 20-40 parts, the NC Nitroncellulose of 5-15 parts, the camphor of 0.5-1.5 parts, the pearl of 0.1-0.3 parts
Light powder, the pigment of 1-3 parts.
5. sun-proof rose nail polish according to claim 4, it is characterised in that the preparation side of the sun-proof rose nail polish
Method is as follows：
By ethyl acetate and Rosa Damascana, after being mixed evenly, NC Nitroncellulose is added under stirring in above-mentioned mixing
In liquid, 10min is stirred at 1500 rpm；Then the trans asafoetide acyl groups of N- are added and remove first synephrine, are stirred under 1500rpm
10min, finally camphor, pearl essence, pigment are added thereto, stir 10min at 1500 rpm；200 mesh screens are made molten
Liquid, 4-5 hours are refrigerated in 0-4 DEG C, finally encapsulates and produces sun-proof rose nail polish.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610178175.0A CN105832577B (en) | 2016-03-25 | 2016-03-25 | A kind of sun-proof rose nail polish and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610178175.0A CN105832577B (en) | 2016-03-25 | 2016-03-25 | A kind of sun-proof rose nail polish and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105832577A CN105832577A (en) | 2016-08-10 |
| CN105832577B true CN105832577B (en) | 2018-01-05 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610178175.0A Active CN105832577B (en) | 2016-03-25 | 2016-03-25 | A kind of sun-proof rose nail polish and preparation method thereof |
Country Status (1)
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Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1301705C (en) * | 2003-09-17 | 2007-02-28 | 杜洪良 | Formula of sun screen fingernail oil |
| JP2005154361A (en) * | 2003-11-27 | 2005-06-16 | Shiseido Co Ltd | Manicure preparation |
| CN103655277A (en) * | 2013-11-20 | 2014-03-26 | 青岛晨讯通商贸有限公司 | Light fragrance long-acting nail polish |
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2016
- 2016-03-25 CN CN201610178175.0A patent/CN105832577B/en active Active
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| Publication number | Publication date |
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| CN105832577A (en) | 2016-08-10 |
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