CN105829396B - 通过反应性挤出的方式制备含硅氧烷的嵌段共聚碳酸酯 - Google Patents

通过反应性挤出的方式制备含硅氧烷的嵌段共聚碳酸酯 Download PDF

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Publication number
CN105829396B
CN105829396B CN201480055080.9A CN201480055080A CN105829396B CN 105829396 B CN105829396 B CN 105829396B CN 201480055080 A CN201480055080 A CN 201480055080A CN 105829396 B CN105829396 B CN 105829396B
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polycarbonate
process according
bis
reactor
carbonate
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Chinese (zh)
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CN105829396A (zh
Inventor
A.迈尔
K.霍恩
R.鲁道夫
U.利森费尔德
T.克尼希
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Covestro Deutschland AG
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Covestro Deutschland AG
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/18—Block or graft polymers
    • C08G64/186—Block or graft polymers containing polysiloxane sequences
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/022—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/365—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using pumps, e.g. piston pumps
    • B29C48/37—Gear pumps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/78—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling
    • B29C48/80—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling at the plasticising zone, e.g. by heating cylinders
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/20—General preparatory processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/06—Preparatory processes
    • C08G77/08—Preparatory processes characterised by the catalysts used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/42—Block-or graft-polymers containing polysiloxane sequences
    • C08G77/445—Block-or graft-polymers containing polysiloxane sequences containing polyester sequences
    • C08G77/448—Block-or graft-polymers containing polysiloxane sequences containing polyester sequences containing polycarbonate sequences
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/50—Phosphorus bound to carbon only

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Silicon Polymers (AREA)
CN201480055080.9A 2013-10-08 2014-10-06 通过反应性挤出的方式制备含硅氧烷的嵌段共聚碳酸酯 Active CN105829396B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP13187752.4 2013-10-08
EP13187752 2013-10-08
PCT/EP2014/071293 WO2015052110A1 (en) 2013-10-08 2014-10-06 Preparation of siloxane-containing block copolycarbonates by means of reactive extrusion

Publications (2)

Publication Number Publication Date
CN105829396A CN105829396A (zh) 2016-08-03
CN105829396B true CN105829396B (zh) 2019-12-20

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CN201480055080.9A Active CN105829396B (zh) 2013-10-08 2014-10-06 通过反应性挤出的方式制备含硅氧烷的嵌段共聚碳酸酯

Country Status (7)

Country Link
US (1) US9828462B2 (enExample)
EP (1) EP3055341B1 (enExample)
JP (1) JP6675978B2 (enExample)
KR (1) KR102277384B1 (enExample)
CN (1) CN105829396B (enExample)
ES (1) ES2751459T3 (enExample)
WO (1) WO2015052110A1 (enExample)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102294921B1 (ko) * 2013-10-08 2021-08-30 코베스트로 도이칠란트 아게 약산의 염을 이용하는 폴리실록산-폴리카보네이트 블록 공축합물의 제조 방법
US10287402B2 (en) 2016-04-29 2019-05-14 Exxonmobil Chemical Patents Inc. Polycarbonate-polyolefin block copolymers and methods of making them
US11130321B2 (en) 2016-06-03 2021-09-28 Covestro Deutschland Ag Multi-layer composite material containing special copolycarbonates as a matrix material
KR20190042578A (ko) 2016-08-24 2019-04-24 코베스트로 도이칠란트 아게 활석을 포함하는 폴리카르보네이트 조성물
EP3555179B1 (en) 2016-12-19 2021-07-07 Covestro Intellectual Property GmbH & Co. KG Production of siloxane-containing block copolycarbonates by means of compatibilizers
JP6895778B2 (ja) * 2017-03-17 2021-06-30 帝人株式会社 ポリカーボネート樹脂組成物およびそれからなる成形品
EP3502306B1 (de) 2017-12-19 2022-03-02 Covestro Deutschland AG Mehrschichtkörper, umfassend eine substratschicht enthaltend polycarbonat, talk und wachs
WO2020065536A1 (en) 2018-09-24 2020-04-02 Sabic Global Technologies B.V. Flame-retardant polycarbonate resin compositions
ES2933516T3 (es) * 2019-04-02 2023-02-09 Covestro Deutschland Ag Co-policarbonatos en bloque que contienen siloxano con un tamaño de dominio pequeño
US20230052441A1 (en) 2019-12-06 2023-02-16 Idemitsu Kosan Co.,Ltd. Polycarbonate/polyorganosiloxane copolymer and resin composition including said copolymer
JP7659503B2 (ja) 2019-12-06 2025-04-09 出光興産株式会社 ポリカーボネート－ポリオルガノシロキサン共重合体及び該共重合体を含む樹脂組成物
EP4071194A4 (en) 2019-12-06 2023-09-13 Idemitsu Kosan Co.,Ltd. POLYCARBONATE/POLYORGANOSILOXANE COPOLYMER AND RESIN COMPOSITION COMPRISING SAID COPOLYMER
EP3957672A1 (en) 2020-08-20 2022-02-23 Idemitsu Kosan Co.,Ltd. Polycarbonate-polyorganosiloxane copolymer, method for producing the same, and resin composition comprising the copolymer
EP3957674A1 (en) 2020-08-20 2022-02-23 Idemitsu Kosan Co.,Ltd. Polycarbonate-polyorganosiloxane copolymer, method for producing the same, and resin composition comprising the copolymer
EP3957673A1 (en) 2020-08-20 2022-02-23 Idemitsu Kosan Co.,Ltd. Polycarbonate-polyorganosiloxane copolymer, method for producing the same, and resin composition comprising the copolymer
JPWO2022065329A1 (enExample) * 2020-09-23 2022-03-31
KR20240017830A (ko) 2021-06-09 2024-02-08 이데미쓰 고산 가부시키가이샤 폴리카보네이트계 수지 조성물 및 성형체
US20240287258A1 (en) 2021-06-09 2024-08-29 Idemitsu Kosan Co., Ltd. Polycarbonate resin composition and molded article
KR20240017831A (ko) 2021-06-09 2024-02-08 이데미쓰 고산 가부시키가이샤 폴리카보네이트계 수지 조성물 및 성형체
DE112022002973T5 (de) 2021-06-09 2024-03-21 Idemitsu Kosan Co., Ltd. Polycarbonat-Harzzusammensetzung und Formkörper
KR20240017829A (ko) 2021-06-09 2024-02-08 이데미쓰 고산 가부시키가이샤 폴리카보네이트계 수지 조성물 및 성형체
US20240368403A1 (en) 2021-06-09 2024-11-07 Idemitsu Kosan Co.,Ltd. Polycarbonate resin composition and molded article
US20240287251A1 (en) 2021-06-09 2024-08-29 Idemitsu Kosan Co.,Ltd. Polycarbonate resin composition and molded article
JP2023137245A (ja) * 2022-03-18 2023-09-29 帝人株式会社 成形品
EP4606841A1 (de) 2024-02-22 2025-08-27 Covestro Deutschland AG Blockcopolymer und verfahren zu dessen herstellung unter verwendung eines speziellen katalysators

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5334358A (en) * 1990-06-06 1994-08-02 Bayer Aktiengesellschaft Self-cleaning reactor/mixer with large useful volume
US5344908A (en) * 1993-05-04 1994-09-06 General Electric Company Process for the manufacture of polycarbonate-oligomers without solvent
CN1150595A (zh) * 1995-09-20 1997-05-28 通用电气公司 聚碳酸酯-聚硅氧烷嵌段共聚物的制备方法
US6066700A (en) * 1997-03-12 2000-05-23 Bayer Aktiengesellschaft Process for the production of polysiloxane/polycarbonate block co-condensation products
CN102066494A (zh) * 2008-06-20 2011-05-18 沙伯基础创新塑料知识产权有限公司 聚硅氧烷-聚碳酸酯组合物,制造方法,及由其制成的制品
WO2013066002A1 (en) * 2011-10-31 2013-05-10 Samyang Corporation Polysiloxane-polycarbonate copolymer and method of manufacturing the same

Family Cites Families (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3189662A (en) 1961-01-23 1965-06-15 Gen Electric Organopolysiloxane-polycarbonate block copolymers
US3419634A (en) 1966-01-03 1968-12-31 Gen Electric Organopolysiloxane polycarbonate block copolymers
NL152889B (nl) 1967-03-10 1977-04-15 Gen Electric Werkwijze ter bereiding van een lineair polycarbonaatcopolymeer, alsmede orienteerbare textielvezel van dit copolymeer.
DE8233007U1 (de) 1982-11-25 1983-03-24 Röhm GmbH, 6100 Darmstadt Polycarbonat-kunststofftafel
DE3244953C2 (de) 1982-12-04 1984-11-29 Röhm GmbH, 6100 Darmstadt Verfahren zur Herstellung einer Hohlkammerkunststofftafel
DE3334782A1 (de) 1983-04-19 1984-10-25 Bayer Ag, 5090 Leverkusen Verfahren zur herstellung von polydiorganosiloxanen mit hydroxyaryloxy-endgruppen
DE3678900D1 (de) 1985-11-11 1991-05-29 Hitachi Ltd Vorrichtung zur kontinuierlichen behandlung von viskosem material.
CH680196A5 (enExample) 1988-02-16 1992-07-15 List Ag
NO170326C (no) 1988-08-12 1992-10-07 Bayer Ag Dihydroksydifenylcykloalkaner
DE3832396A1 (de) 1988-08-12 1990-02-15 Bayer Ag Dihydroxydiphenylcycloalkane, ihre herstellung und ihre verwendung zur herstellung von hochmolekularen polycarbonaten
CA1340125C (en) 1988-10-06 1998-11-10 Dieter Freitag Mixture of special new polycarbonates with other thermoplastics or with elastomers
DE3833953A1 (de) 1988-10-06 1990-04-19 Bayer Ag Mischungen von speziellen, neuen polycarbonaten mit anderen thermoplasten oder mit elastomeren
US5227449A (en) 1990-07-02 1993-07-13 Xerox Corporation Photoconductive imaging members with polycarbonate binders
TW222292B (enExample) 1991-02-21 1994-04-11 Ciba Geigy Ag
DE4118884A1 (de) 1991-06-07 1992-12-10 List Ag Mischkneter
DE4126425A1 (de) 1991-08-09 1993-02-11 Bayer Ag Vollstaendig selbstreinigender reaktor/mischer mit grossem nutzvolumen
US5519106A (en) * 1992-08-26 1996-05-21 Mitsubishi Chemical Corporation Process for the preparation of aromatic polycarbonate resins
DE4326807A1 (de) 1993-08-10 1995-02-16 Bayer Ag Vollständig selbstreinigender Mischer
US5414054A (en) 1994-06-01 1995-05-09 Miles Inc. Copolycarbonate having improved low-temperature impact strength
CN1046707C (zh) 1994-11-10 1999-11-24 巴斯福股份公司 2－氰基丙烯酸酯
EP0715882B1 (de) 1994-12-05 1998-02-25 Bayer Ag Selbstreinigender Reaktor/Mischer für hochviskoses und feststoffhaltiges Mischgut
EP0715881B1 (de) 1994-12-05 1998-02-25 Bayer Ag Vollständig selbstreinigender Mischer/Reaktor
DE4444868A1 (de) 1994-12-16 1996-06-20 Bayer Ag UV-geschützte, mehrschichtige Polycarbonatplatten
US5504177A (en) 1995-03-02 1996-04-02 General Electric Company Method for preparation of block copolysiloxanecarbonates
DE19539290A1 (de) 1995-10-23 1997-04-24 Bayer Ag Verfahren zur Herstellung von Poly-(diorganosiloxan)-Polycarbonat-Blockcopolymeren
DE19611852A1 (de) 1996-03-26 1997-10-02 Bayer Ag Selbstreinigender Reaktor/Mischer für hochviskose und kohäsive Mischgüter
EP0839623B1 (de) 1996-10-30 2001-01-31 Ciba SC Holding AG Stabilisatorkombination für das Rotomolding-Verfahren
US6258968B1 (en) * 1997-02-20 2001-07-10 Ge Bayer Silicones Gmbh & Co. Kg Method for producing organofunctional siloxanes and use of same
DE19710081A1 (de) 1997-03-12 1998-09-17 Bayer Ag Verfahren zur Herstellung von Polysiloxan-Polysiloxan-Polycarbonat-Blockcokondensaten
US5821321A (en) 1997-09-16 1998-10-13 Bayer Corporation Molding composition having improved impact strength
DE10150900C1 (de) 2001-10-18 2003-04-24 List Ag Mischkneter mit unterschiedlich dicken Tragelementen für Knetbarren
EP1308084A1 (en) 2002-10-02 2003-05-07 Ciba SC Holding AG Synergistic UV absorber combination
DE10311063A1 (de) 2003-03-13 2004-09-23 Basf Ag Verwendung einer Stabilisatormischung in thermoplastischen Formmassen
DE102007011069A1 (de) 2007-03-07 2008-09-11 Bayer Materialscience Ag Polycarbonatzusammensetzung enthaltend UV-Absorber
DE102008019503A1 (de) 2008-04-18 2009-10-22 Bayer Materialscience Ag Polycarbonate mit Umlagerungsstrukturen, cyclischen und linearen Oligomeren sowie verbessertem Fließverhalten

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5334358A (en) * 1990-06-06 1994-08-02 Bayer Aktiengesellschaft Self-cleaning reactor/mixer with large useful volume
US5344908A (en) * 1993-05-04 1994-09-06 General Electric Company Process for the manufacture of polycarbonate-oligomers without solvent
CN1150595A (zh) * 1995-09-20 1997-05-28 通用电气公司 聚碳酸酯-聚硅氧烷嵌段共聚物的制备方法
US6066700A (en) * 1997-03-12 2000-05-23 Bayer Aktiengesellschaft Process for the production of polysiloxane/polycarbonate block co-condensation products
CN102066494A (zh) * 2008-06-20 2011-05-18 沙伯基础创新塑料知识产权有限公司 聚硅氧烷-聚碳酸酯组合物,制造方法,及由其制成的制品
WO2013066002A1 (en) * 2011-10-31 2013-05-10 Samyang Corporation Polysiloxane-polycarbonate copolymer and method of manufacturing the same

Also Published As

Publication number Publication date
US20160244559A1 (en) 2016-08-25
JP6675978B2 (ja) 2020-04-08
ES2751459T3 (es) 2020-03-31
CN105829396A (zh) 2016-08-03
JP2016532733A (ja) 2016-10-20
EP3055341A1 (en) 2016-08-17
EP3055341B1 (en) 2019-10-02
KR20160067854A (ko) 2016-06-14
KR102277384B1 (ko) 2021-07-14
WO2015052110A1 (en) 2015-04-16
US9828462B2 (en) 2017-11-28

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