CN105829396B - 通过反应性挤出的方式制备含硅氧烷的嵌段共聚碳酸酯 - Google Patents

通过反应性挤出的方式制备含硅氧烷的嵌段共聚碳酸酯 Download PDF

Info

Publication number
CN105829396B
CN105829396B CN201480055080.9A CN201480055080A CN105829396B CN 105829396 B CN105829396 B CN 105829396B CN 201480055080 A CN201480055080 A CN 201480055080A CN 105829396 B CN105829396 B CN 105829396B
Authority
CN
China
Prior art keywords
polycarbonate
process according
bis
reactor
carbonate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201480055080.9A
Other languages
English (en)
Chinese (zh)
Other versions
CN105829396A (zh
Inventor
A.迈尔
K.霍恩
R.鲁道夫
U.利森费尔德
T.克尼希
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Covestro Deutschland AG
Original Assignee
Covestro Deutschland AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Covestro Deutschland AG filed Critical Covestro Deutschland AG
Publication of CN105829396A publication Critical patent/CN105829396A/zh
Application granted granted Critical
Publication of CN105829396B publication Critical patent/CN105829396B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/18Block or graft polymers
    • C08G64/186Block or graft polymers containing polysiloxane sequences
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/022Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/36Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/365Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using pumps, e.g. piston pumps
    • B29C48/37Gear pumps
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/36Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/395Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/78Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling
    • B29C48/80Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling at the plasticising zone, e.g. by heating cylinders
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/20General preparatory processes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04Polysiloxanes
    • C08G77/06Preparatory processes
    • C08G77/08Preparatory processes characterised by the catalysts used
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/42Block-or graft-polymers containing polysiloxane sequences
    • C08G77/445Block-or graft-polymers containing polysiloxane sequences containing polyester sequences
    • C08G77/448Block-or graft-polymers containing polysiloxane sequences containing polyester sequences containing polycarbonate sequences
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/49Phosphorus-containing compounds
    • C08K5/50Phosphorus bound to carbon only

Landscapes

  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Silicon Polymers (AREA)
CN201480055080.9A 2013-10-08 2014-10-06 通过反应性挤出的方式制备含硅氧烷的嵌段共聚碳酸酯 Active CN105829396B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP13187752 2013-10-08
EP13187752.4 2013-10-08
PCT/EP2014/071293 WO2015052110A1 (en) 2013-10-08 2014-10-06 Preparation of siloxane-containing block copolycarbonates by means of reactive extrusion

Publications (2)

Publication Number Publication Date
CN105829396A CN105829396A (zh) 2016-08-03
CN105829396B true CN105829396B (zh) 2019-12-20

Family

ID=49303875

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201480055080.9A Active CN105829396B (zh) 2013-10-08 2014-10-06 通过反应性挤出的方式制备含硅氧烷的嵌段共聚碳酸酯

Country Status (7)

Country Link
US (1) US9828462B2 (enExample)
EP (1) EP3055341B1 (enExample)
JP (1) JP6675978B2 (enExample)
KR (1) KR102277384B1 (enExample)
CN (1) CN105829396B (enExample)
ES (1) ES2751459T3 (enExample)
WO (1) WO2015052110A1 (enExample)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6621739B2 (ja) * 2013-10-08 2019-12-18 コベストロ、ドイチュラント、アクチエンゲゼルシャフトCovestro Deutschland Ag 弱酸の塩を用いてポリシロキサン−ポリカーボネートブロック共縮合物を調製する方法
US10287402B2 (en) 2016-04-29 2019-05-14 Exxonmobil Chemical Patents Inc. Polycarbonate-polyolefin block copolymers and methods of making them
CN109196054B (zh) 2016-06-03 2021-08-10 科思创德国股份有限公司 包含特定的共聚碳酸酯作为基质材料的多层复合材料
CN109863203B (zh) 2016-08-24 2022-03-15 科思创德国股份有限公司 包含滑石的聚碳酸酯组合物
KR102454155B1 (ko) * 2016-12-19 2022-10-14 코베스트로 도이칠란트 아게 상용화제를 사용한 실록산-함유 블록 코폴리카르보네이트의 제조
JP6895778B2 (ja) * 2017-03-17 2021-06-30 帝人株式会社 ポリカーボネート樹脂組成物およびそれからなる成形品
EP3502306B1 (de) 2017-12-19 2022-03-02 Covestro Deutschland AG Mehrschichtkörper, umfassend eine substratschicht enthaltend polycarbonat, talk und wachs
WO2020065536A1 (en) 2018-09-24 2020-04-02 Sabic Global Technologies B.V. Flame-retardant polycarbonate resin compositions
ES2933516T3 (es) * 2019-04-02 2023-02-09 Covestro Deutschland Ag Co-policarbonatos en bloque que contienen siloxano con un tamaño de dominio pequeño
CN114746474B (zh) 2019-12-06 2024-11-22 出光兴产株式会社 聚碳酸酯-聚有机硅氧烷共聚物和包含该共聚物的树脂组合物
JP7732899B2 (ja) 2019-12-06 2025-09-02 出光興産株式会社 ポリカーボネート-ポリオルガノシロキサン共重合体及び該共重合体を含む樹脂組成物
JP7659503B2 (ja) 2019-12-06 2025-04-09 出光興産株式会社 ポリカーボネート-ポリオルガノシロキサン共重合体及び該共重合体を含む樹脂組成物
EP3957674A1 (en) 2020-08-20 2022-02-23 Idemitsu Kosan Co.,Ltd. Polycarbonate-polyorganosiloxane copolymer, method for producing the same, and resin composition comprising the copolymer
EP3957672A1 (en) 2020-08-20 2022-02-23 Idemitsu Kosan Co.,Ltd. Polycarbonate-polyorganosiloxane copolymer, method for producing the same, and resin composition comprising the copolymer
EP3957673A1 (en) 2020-08-20 2022-02-23 Idemitsu Kosan Co.,Ltd. Polycarbonate-polyorganosiloxane copolymer, method for producing the same, and resin composition comprising the copolymer
CN116390968A (zh) * 2020-09-23 2023-07-04 三菱瓦斯化学株式会社 热塑性树脂、组合物、成型体、光学透镜和热塑性树脂的制造方法
US20240239962A1 (en) 2021-06-09 2024-07-18 Idemitsu Kosan Co.,Ltd. Polycarbonate resin composition and molded article
WO2022260075A1 (ja) 2021-06-09 2022-12-15 出光興産株式会社 ポリカーボネート系樹脂組成物及び成形体
DE112022002967T5 (de) 2021-06-09 2024-03-21 Idemitsu Kosan Co., Ltd. Polycarbonat-harzzusammensetzung und formkörper
KR20240018482A (ko) 2021-06-09 2024-02-13 이데미쓰 고산 가부시키가이샤 폴리카보네이트계 수지 조성물 및 성형체
CN117440989A (zh) 2021-06-09 2024-01-23 出光兴产株式会社 聚碳酸酯系树脂组合物和成形体
JPWO2022260078A1 (enExample) 2021-06-09 2022-12-15
DE112022002984T5 (de) 2021-06-09 2024-03-21 Idemitsu Kosan Co.,Ltd. Polycarbonatharz-Zusammensetzung und Formkörper
JP7824114B2 (ja) * 2022-03-18 2026-03-04 帝人株式会社 成形品
EP4606841A1 (de) 2024-02-22 2025-08-27 Covestro Deutschland AG Blockcopolymer und verfahren zu dessen herstellung unter verwendung eines speziellen katalysators

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5334358A (en) * 1990-06-06 1994-08-02 Bayer Aktiengesellschaft Self-cleaning reactor/mixer with large useful volume
US5344908A (en) * 1993-05-04 1994-09-06 General Electric Company Process for the manufacture of polycarbonate-oligomers without solvent
CN1150595A (zh) * 1995-09-20 1997-05-28 通用电气公司 聚碳酸酯-聚硅氧烷嵌段共聚物的制备方法
US6066700A (en) * 1997-03-12 2000-05-23 Bayer Aktiengesellschaft Process for the production of polysiloxane/polycarbonate block co-condensation products
CN102066494A (zh) * 2008-06-20 2011-05-18 沙伯基础创新塑料知识产权有限公司 聚硅氧烷-聚碳酸酯组合物,制造方法,及由其制成的制品
WO2013066002A1 (en) * 2011-10-31 2013-05-10 Samyang Corporation Polysiloxane-polycarbonate copolymer and method of manufacturing the same

Family Cites Families (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3189662A (en) 1961-01-23 1965-06-15 Gen Electric Organopolysiloxane-polycarbonate block copolymers
US3419634A (en) 1966-01-03 1968-12-31 Gen Electric Organopolysiloxane polycarbonate block copolymers
NL152889B (nl) 1967-03-10 1977-04-15 Gen Electric Werkwijze ter bereiding van een lineair polycarbonaatcopolymeer, alsmede orienteerbare textielvezel van dit copolymeer.
DE8233007U1 (de) 1982-11-25 1983-03-24 Röhm GmbH, 6100 Darmstadt Polycarbonat-kunststofftafel
DE3244953C2 (de) 1982-12-04 1984-11-29 Röhm GmbH, 6100 Darmstadt Verfahren zur Herstellung einer Hohlkammerkunststofftafel
DE3334782A1 (de) 1983-04-19 1984-10-25 Bayer Ag, 5090 Leverkusen Verfahren zur herstellung von polydiorganosiloxanen mit hydroxyaryloxy-endgruppen
EP0222599B1 (en) 1985-11-11 1991-04-24 Hitachi, Ltd. Continuous treatment apparatus for viscous material
CH680196A5 (enExample) 1988-02-16 1992-07-15 List Ag
NO170326C (no) 1988-08-12 1992-10-07 Bayer Ag Dihydroksydifenylcykloalkaner
DE3832396A1 (de) 1988-08-12 1990-02-15 Bayer Ag Dihydroxydiphenylcycloalkane, ihre herstellung und ihre verwendung zur herstellung von hochmolekularen polycarbonaten
DE3833953A1 (de) 1988-10-06 1990-04-19 Bayer Ag Mischungen von speziellen, neuen polycarbonaten mit anderen thermoplasten oder mit elastomeren
CA1340125C (en) 1988-10-06 1998-11-10 Dieter Freitag Mixture of special new polycarbonates with other thermoplastics or with elastomers
US5227449A (en) 1990-07-02 1993-07-13 Xerox Corporation Photoconductive imaging members with polycarbonate binders
TW222292B (enExample) 1991-02-21 1994-04-11 Ciba Geigy Ag
DE4118884A1 (de) 1991-06-07 1992-12-10 List Ag Mischkneter
DE4126425A1 (de) 1991-08-09 1993-02-11 Bayer Ag Vollstaendig selbstreinigender reaktor/mischer mit grossem nutzvolumen
US5519106A (en) * 1992-08-26 1996-05-21 Mitsubishi Chemical Corporation Process for the preparation of aromatic polycarbonate resins
DE4326807A1 (de) 1993-08-10 1995-02-16 Bayer Ag Vollständig selbstreinigender Mischer
US5414054A (en) 1994-06-01 1995-05-09 Miles Inc. Copolycarbonate having improved low-temperature impact strength
PT0900782E (pt) 1994-11-10 2002-07-31 Basf Ag Ester do acido 2-cianacrilico
EP0715882B1 (de) 1994-12-05 1998-02-25 Bayer Ag Selbstreinigender Reaktor/Mischer für hochviskoses und feststoffhaltiges Mischgut
EP0715881B1 (de) 1994-12-05 1998-02-25 Bayer Ag Vollständig selbstreinigender Mischer/Reaktor
DE4444868A1 (de) 1994-12-16 1996-06-20 Bayer Ag UV-geschützte, mehrschichtige Polycarbonatplatten
US5504177A (en) 1995-03-02 1996-04-02 General Electric Company Method for preparation of block copolysiloxanecarbonates
DE19539290A1 (de) 1995-10-23 1997-04-24 Bayer Ag Verfahren zur Herstellung von Poly-(diorganosiloxan)-Polycarbonat-Blockcopolymeren
DE19611852A1 (de) 1996-03-26 1997-10-02 Bayer Ag Selbstreinigender Reaktor/Mischer für hochviskose und kohäsive Mischgüter
EP0839623B1 (de) 1996-10-30 2001-01-31 Ciba SC Holding AG Stabilisatorkombination für das Rotomolding-Verfahren
US6258968B1 (en) * 1997-02-20 2001-07-10 Ge Bayer Silicones Gmbh & Co. Kg Method for producing organofunctional siloxanes and use of same
DE19710081A1 (de) 1997-03-12 1998-09-17 Bayer Ag Verfahren zur Herstellung von Polysiloxan-Polysiloxan-Polycarbonat-Blockcokondensaten
US5821321A (en) 1997-09-16 1998-10-13 Bayer Corporation Molding composition having improved impact strength
DE10150900C1 (de) 2001-10-18 2003-04-24 List Ag Mischkneter mit unterschiedlich dicken Tragelementen für Knetbarren
EP1308084A1 (en) 2002-10-02 2003-05-07 Ciba SC Holding AG Synergistic UV absorber combination
DE10311063A1 (de) 2003-03-13 2004-09-23 Basf Ag Verwendung einer Stabilisatormischung in thermoplastischen Formmassen
DE102007011069A1 (de) 2007-03-07 2008-09-11 Bayer Materialscience Ag Polycarbonatzusammensetzung enthaltend UV-Absorber
DE102008019503A1 (de) 2008-04-18 2009-10-22 Bayer Materialscience Ag Polycarbonate mit Umlagerungsstrukturen, cyclischen und linearen Oligomeren sowie verbessertem Fließverhalten

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5334358A (en) * 1990-06-06 1994-08-02 Bayer Aktiengesellschaft Self-cleaning reactor/mixer with large useful volume
US5344908A (en) * 1993-05-04 1994-09-06 General Electric Company Process for the manufacture of polycarbonate-oligomers without solvent
CN1150595A (zh) * 1995-09-20 1997-05-28 通用电气公司 聚碳酸酯-聚硅氧烷嵌段共聚物的制备方法
US6066700A (en) * 1997-03-12 2000-05-23 Bayer Aktiengesellschaft Process for the production of polysiloxane/polycarbonate block co-condensation products
CN102066494A (zh) * 2008-06-20 2011-05-18 沙伯基础创新塑料知识产权有限公司 聚硅氧烷-聚碳酸酯组合物,制造方法,及由其制成的制品
WO2013066002A1 (en) * 2011-10-31 2013-05-10 Samyang Corporation Polysiloxane-polycarbonate copolymer and method of manufacturing the same

Also Published As

Publication number Publication date
CN105829396A (zh) 2016-08-03
EP3055341B1 (en) 2019-10-02
JP2016532733A (ja) 2016-10-20
JP6675978B2 (ja) 2020-04-08
US9828462B2 (en) 2017-11-28
US20160244559A1 (en) 2016-08-25
EP3055341A1 (en) 2016-08-17
ES2751459T3 (es) 2020-03-31
KR102277384B1 (ko) 2021-07-14
KR20160067854A (ko) 2016-06-14
WO2015052110A1 (en) 2015-04-16

Similar Documents

Publication Publication Date Title
CN105829396B (zh) 通过反应性挤出的方式制备含硅氧烷的嵌段共聚碳酸酯
CN106414560B (zh) 具有改进的流变性能的聚硅氧烷-聚碳酸酯嵌段共缩合物
CN105612196B (zh) 使用弱酸的盐制备聚硅氧烷-聚碳酸酯嵌段共缩合物的方法
EP3055344B1 (en) Polysiloxane-polycarbonate block cocondensates
EP3055343B1 (en) Process for preparing polysiloxane-polycarbonate block cocondensates

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant