CN105802680B - A kind of environmental protection fuel oil compound emulsifying agent - Google Patents

A kind of environmental protection fuel oil compound emulsifying agent Download PDF

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Publication number
CN105802680B
CN105802680B CN201610170707.6A CN201610170707A CN105802680B CN 105802680 B CN105802680 B CN 105802680B CN 201610170707 A CN201610170707 A CN 201610170707A CN 105802680 B CN105802680 B CN 105802680B
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China
Prior art keywords
parts
emulsifying agent
basic components
oil
compound emulsifying
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Expired - Fee Related
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CN201610170707.6A
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Chinese (zh)
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CN105802680A (en
Inventor
骆佳豪
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Yao Yongliang
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Wenzhou Polar Electronics Technology Co Ltd
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Priority to CN201810205040.8A priority Critical patent/CN108179039A/en
Priority to CN201810204568.3A priority patent/CN108329959A/en
Priority to CN201810204567.9A priority patent/CN108395918A/en
Priority to CN201610170707.6A priority patent/CN105802680B/en
Priority to CN201810205046.5A priority patent/CN108219875A/en
Publication of CN105802680A publication Critical patent/CN105802680A/en
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Publication of CN105802680B publication Critical patent/CN105802680B/en
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
    • C10L2230/22—Function and purpose of a components of a fuel or the composition as a whole for improving fuel economy or fuel efficiency
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2250/00—Structural features of fuel components or fuel compositions, either in solid, liquid or gaseous state
    • C10L2250/08—Emulsion details

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  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
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Abstract

The present invention discloses a kind of environmental protection fuel oil compound emulsifying agent, including the mass ratio of basic components and modified component of being used for as 46：1, wherein, wherein basic components include 40 60 parts of acrylic monomers, 2 10 parts of perfluorooctane sulfonate, 24 parts of butyl benzyl phthalate, 0.5 2 parts of nonylphenol polyoxyethylene ether, 6 10 parts of methyl benzotriazazole；Modified component includes 6 10 parts of sulfomethylated humic acid sodium, 10 20 parts of sorbester p17,10 30 parts of cobalt naphthenate, 5 10 parts of triisopropanolamine, 18 25 parts of phthalic anhydride, 10 15 parts of glyceryl oleate, 48 parts of octadecanoid acid.The compound emulsifying agent of this technology production can be used for oil products system, be widely used, and make simply, cost is relatively low, and stability is good.

Description

A kind of environmental protection fuel oil compound emulsifying agent
Technical field
The present invention relates to emulsifying agent, more particularly to a kind of environmental protection fuel oil compound emulsifying agent.
Background technology
The energy is the lifeline of national security, is asked wherein non-renewable petroleum resources are most important the energy safety of supply One of topic.In order to effectively construct energy security, each state all attaches great importance to oil consumption and deposit, and takes various methods actively to grind Study carefully reduction or substitute the consumption of petroleum resources.With the rapid development of social economy, China is using fuel as leading oil demand Always in rapid growth.
But due to the restriction of crude oil in China refining technique level, oil quality need to be improved, therefore directly burning combustion Material oil, inevitably causes combustion reaction incomplete, forms black smoke, coking and carbon deposit, causes fuel and largely waste, at the same time The problem of also bringing environmental pollution.Generally for ensureing that burning is abundant, excess air need to be injected, and the discharge of these excess airs But heat has been taken away, has caused thermal loss.
It will generally burn at present after Emulsification of Fuel Oil to solve the above problems, but also do not there is one kind effectively to make emulsification Fuel oil active combustion afterwards, at the same can also environmental emission reduction emulsifying agent.
The content of the invention
For overcome the deficiencies in the prior art, the present invention provides a kind of environmental protection fuel oil compound emulsifying agent, by basic components It is prepared in organic solvent with modified component；
Wherein basic components include the material of following mass fraction：
About 40-60 parts of acrylate monomer,
2-10 parts of perfluorooctane sulfonate,
2-4 parts of butyl benzyl phthalate,
0.5-2 parts of nonylphenol polyoxyethylene ether,
6-10 parts of methyl benzotriazazole；
Modified component includes the material of following mass fraction：
2-10 parts of sulfomethylated humic acid sodium,
10-20 parts of sorbester p17,
10-30 parts of cobalt naphthenate,
5-10 parts of triisopropanolamine,
18-25 parts of phthalic anhydride,
10-15 parts of glyceryl oleate,
4-8 parts of octadecanoid acid.
Wherein, the acrylate monomer be styrene, methyl methacrylate or the two according to mass ratio be 1：（2- 20）Composition.
Preferably, the mass ratio of compound emulsifying agent of the present invention, basic components and modified component is 4-6：1.Wherein, Basic components include the component of following mass fraction：
40-50 parts of acrylate monomer,
5-10 parts of perfluorooctane sulfonate,
2-3 parts of butyl benzyl phthalate,
0.5-1 parts of nonylphenol polyoxyethylene ether,
6-8 parts of methyl benzotriazazole；
Modified component includes the component of following mass fraction：
3-8 parts of sulfomethylated humic acid sodium,
12-15 parts of sorbester p17,
15-20 parts of cobalt naphthenate,
5-8 parts of triisopropanolamine,
20-25 parts of phthalic anhydride,
12-15 parts of glyceryl oleate,
4-6 parts of octadecanoid acid.
In the present invention, because using acrylate monomer in component basis and perfluorooctane sulfonate polymerization generation fluorine-containing Oligomer so that polymer shows some physico-chemical properties of fluorochemical to a certain extent.Therefore, possessing excellent dredge It is water-based to be also equipped with certain oil repellency at the same time, containing alcohol-oil interface or heavy oil, diesel oil system can be stably emulsified, increases alcohol The intersolubility of class and diesel oil, application system is extensive, and effect stability；Because using the naphthenic compound in modified group agent and conjunction Suitable charge ratio, has the function that catalytic combustion-supporting, so that the emulsifying agent of the present invention is by after heavy oil emulsive, the row of heavy oil combustion Put and greatly reduce, SO2Discharge can reduce more than 90%, methyl benzotriazazole also has and prevents gasoline engine or diesel-engine equipment The effect of corrosion；The emulsifying agents such as modified component octadecanoid acid, phthalic anhydride, make the emulsifying agent of the present invention have very strong emulsifying capacity, For heavy oil in emulsification, the ratio of heavy oil and water can reach 1:1, the heavy oil after emulsification is the molecular structure of water-in-oil type, and emulsifies Rear heavy oil store more than 1 year be not in water-oil separating for a long time, performance is highly stable.
The emulsifying agent of the present invention can be applied not only to emulsification heavy oil, diesel oil emulsification or containing alcohol radical-diesel oil system, also universal Most of fuel oil is applicable in, application is good, and the compound emulsifying agent of formation has stability good, and easily recycling, is recycled The advantages of.
The present invention emulsifying agent effectively heavy oil, diesel oil or fuel oil can be emulsified, make the heavy oil after emulsification, diesel oil or Fuel oil can more effectively burn, can fuel-economizing 35%-45%, reduction SO after heavy oil emulsifier using the present invention2Discharge 90% More than, it is not in water-oil separating to store more than 1 year, and performance is highly stable.The present invention by a part of conventional heavy oils emulsifying agent into Divide and form composite emulsifying system with new type resin emulsifying agent, can emulsify for more oil systems, make for different oil products Dosage is small, and preparation method is simple, and cost is low, recyclable, and the stability of oil emulsion is good, not stratified, is taking into account many body system oil product original While material, it is possible to achieve good emulsifying effectiveness.
Embodiment
The present invention will be further described in detail with reference to the specific embodiments.
Embodiment 1
Environmental protection fuel oil compound emulsifying agent, by basic components and modified component according to mass ratio 4：1 makes in organic solvent Standby to form, wherein basic components include totally 40 parts of styrene and methyl methacrylate, 2 parts of perfluorooctane sulfonate, O-phthalic 2 parts of acid butyl benzyl ester, 0.5 part of nonylphenol polyoxyethylene ether, 6 parts of methyl benzotriazazole；It is rotten that modified component includes sulphur methyl Grow sour 2 parts of sodium, 10 parts of sorbester p17,10 parts of cobalt naphthenate, 5 parts of triisopropanolamine, 18 parts of phthalic anhydride, 10 parts of glyceryl oleate, 18 4 parts of alkanoic acid.
Prepare in accordance with the following methods：A, organic solvent is added in reaction kettle, is warming up to 50-70 DEG C, then by acrylic acid Ester monomer, perfluorooctane sulfonate are uniformly mixed, then are slowly dropped into organic solvent, control feed time, and charging is finished after continuation of insurance Temperature reaction 2-4h, stops reacting and is cooled to room temperature to obtain fluorine-containing oligomer resin solution；B, by polyoxyethylene nonyl phenyl second In alkene ether, butyl benzyl phthalate input fluorine-containing oligomer resin solution, after being sufficiently stirred 1~2h, add Methyl benzotriazazole, stirring, reaction 1h obtain mixed solution；C, by sulfomethylated humic acid sodium, sapn, cobalt naphthenate, three is different Propanolamine is stirred evenly according to proportioning at 40-70 DEG C, then adds phthalic anhydride, glyceryl oleate and octadecanoid acid, continues to stir 1h, Form homogeneous solution；D, the homogeneous solution of step c is added in the mixed solution that step b is obtained, keeps 40 DEG C of reaction 1-3h, As needed, excessive organic solvent is removed, obtains mixed emulsifier.
Embodiment 2
Environmental protection fuel oil compound emulsifying agent, by basic components and modified component according to mass ratio 5：1 makes in organic solvent Standby to form, wherein basic components include totally 40 parts of styrene and methyl methacrylate, 5 parts of perfluorooctane sulfonate, O-phthalic 2 parts of acid butyl benzyl ester, 0.5 part of nonylphenol polyoxyethylene ether, 6 parts of methyl benzotriazazole；It is rotten that modified component includes sulphur methyl Grow sour 3 parts of sodium, 12 parts of sorbester p17,15 parts of cobalt naphthenate, 5 parts of triisopropanolamine, 20 parts of phthalic anhydride, 12 parts of glyceryl oleate, 18 4 parts of alkanoic acid.
Prepare in accordance with the following methods：A, organic solvent is added in reaction kettle, is warming up to 50-70 DEG C, then by acrylic acid Ester monomer, perfluorooctane sulfonate are uniformly mixed, then are slowly dropped into organic solvent, control feed time, and charging is finished after continuation of insurance Temperature reaction 2-4h, stops reacting and is cooled to room temperature to obtain fluorine-containing oligomer resin solution；B, by polyoxyethylene nonyl phenyl second In alkene ether, butyl benzyl phthalate input fluorine-containing oligomer resin solution, after being sufficiently stirred 1~2h, add Methyl benzotriazazole, stirring, reaction 1h obtain mixed solution；C, by sulfomethylated humic acid sodium, sapn, cobalt naphthenate, three is different Propanolamine is stirred evenly according to proportioning at 40-70 DEG C, then adds phthalic anhydride, glyceryl oleate and octadecanoid acid, continues to stir 1h, Form homogeneous solution；D, the homogeneous solution of step c is added in the mixed solution that step b is obtained, keeps 50 DEG C of reaction 1-3h, As needed, excessive organic solvent is removed, obtains mixed emulsifier.
Embodiment 3
Environmental protection fuel oil compound emulsifying agent, by basic components and modified component according to mass ratio 5：1 makes in organic solvent Standby to form, wherein basic components include totally 50 parts of styrene and methyl methacrylate, 10 parts of perfluorooctane sulfonate, O-phthalic 3 parts of acid butyl benzyl ester, 1 part of nonylphenol polyoxyethylene ether, 8 parts of methyl benzotriazazole；Modified component includes sulphur methyl humic Sour 8 parts of sodium, 15 parts of sorbester p17,20 parts of cobalt naphthenate, 8 parts of triisopropanolamine, 25 parts of phthalic anhydride, 15 parts of glyceryl oleate, octadecane 6 parts of acid.
Prepare in accordance with the following methods：A, organic solvent is added in reaction kettle, is warming up to 50-70 DEG C, then by acrylic acid Ester monomer, perfluorooctane sulfonate are uniformly mixed, then are slowly dropped into organic solvent, control feed time, and charging is finished after continuation of insurance Temperature reaction 2-4h, stops reacting and is cooled to room temperature to obtain fluorine-containing oligomer resin solution；B, by polyoxyethylene nonyl phenyl second In alkene ether, butyl benzyl phthalate input fluorine-containing oligomer resin solution, after being sufficiently stirred 1~2h, add Methyl benzotriazazole, stirring, reaction 1h obtain mixed solution；C, by sulfomethylated humic acid sodium, sapn, cobalt naphthenate, three is different Propanolamine is stirred evenly according to proportioning at 40-70 DEG C, then adds phthalic anhydride, glyceryl oleate and octadecanoid acid, continues to stir 1h, Form homogeneous solution；D, the homogeneous solution of step c is added in the mixed solution that step b is obtained, keeps 60 DEG C of reaction 1-3h, As needed, excessive organic solvent is removed, obtains mixed emulsifier.
Embodiment 4
Environmental protection fuel oil compound emulsifying agent, by basic components and modified component according to mass ratio 6：1 makes in organic solvent Standby to form, wherein basic components include totally 60 parts of styrene and methyl methacrylate, 10 parts of perfluorooctane sulfonate, O-phthalic 4 parts of acid butyl benzyl ester, 2 parts of nonylphenol polyoxyethylene ether, 10 parts of methyl benzotriazazole；Modified component includes sulphur methyl humic Sour 10 parts of sodium, 20 parts of sorbester p17,30 parts of cobalt naphthenate, 10 parts of triisopropanolamine, 25 parts of phthalic anhydride, 15 parts of glyceryl oleate, 18 8 parts of alkanoic acid.
Prepare in accordance with the following methods：A, organic solvent is added in reaction kettle, is warming up to 50-70 DEG C, then by acrylic acid Ester monomer, perfluorooctane sulfonate are uniformly mixed, then are slowly dropped into organic solvent, control feed time, and charging is finished after continuation of insurance Temperature reaction 2-4h, stops reacting and is cooled to room temperature to obtain fluorine-containing oligomer resin solution；B, by polyoxyethylene nonyl phenyl second In alkene ether, butyl benzyl phthalate input fluorine-containing oligomer resin solution, after being sufficiently stirred 1~2h, add Methyl benzotriazazole, stirring, reaction 1h obtain mixed solution；C, by sulfomethylated humic acid sodium, sapn, cobalt naphthenate, three is different Propanolamine is stirred evenly according to proportioning at 40-70 DEG C, then adds phthalic anhydride, glyceryl oleate and octadecanoid acid, continues to stir 1h, Form homogeneous solution；D, the homogeneous solution of step c is added in the mixed solution that step b is obtained, keeps 60 DEG C of reaction 1-3h, As needed, excessive organic solvent is removed, obtains mixed emulsifier.
By oil product：Compound emulsifying agent：Solvent：Graphene or fullerene are according to 100-120：10-20：5-10：0.1-1 weight It than obtaining oil emulsion after mixing, our experiments show that, can stablize after oil emulsion is static not stratified；For heavy oil emulsive, by one Still water-oil separating is occurred without more than year, and sulphur-containing substance discharge can be reduced with fuel-economizing 30%, for diesel oil in alcohol group, due to tool There is part resin effect, diesel oil in alcohol group can dissolve each other very well, less carbon emission, and component basis can be played with component modification Synergistic effect, can substantially reduce the consumption of diesel oil or heavy oil, and can reduce petrochemical industry cost, while be applicable in multiple systems, Pair at the same time the system with diesel oil and/or diesel oil in alcohol group with good emulsifying effectiveness.
Application examples 1
100kg heavy oil is taken, 60 DEG C is heated to and stirs evenly, adds 10 kg emulsifying agents, 5g solvents, 0.1g fullerenes, warp High-speed stirred 5-15min, adds appropriate 60 DEG C of water as needed, stand 24 it is small when after use.
Application examples 2
120kg fuel oil is taken, 60 DEG C is heated to and stirs evenly, adds 10 kg emulsifying agents, 10g solvents, 0.5g fowlers Alkene, through high-speed stirred 5-15min, the water of 70 DEG C of addition, which is mixed evenly, as needed becomes high-efficiency environment friendly oil emulsion, quiet Put 24 it is small when after use.
The above description is merely a specific embodiment, but protection scope of the present invention is not limited thereto, any Those skilled in the art disclosed herein technical scope in, can without the change that creative work is expected or Replace, should be covered by the protection scope of the present invention.Therefore, protection scope of the present invention should be limited with claims Subject to fixed protection domain.

Claims (2)

1. a kind of environmental protection fuel oil compound emulsifying agent, it is characterised in that made in organic solvent with modified component by basic components It is standby to form；
Wherein basic components include the material of following mass fraction：
40-60 parts of acrylate monomer,
2-10 parts of perfluorooctane sulfonate,
2-4 parts of butyl benzyl phthalate,
0.5-2 parts of nonylphenol polyoxyethylene ether,
6-10 parts of methyl benzotriazazole；
Modified component includes the material of following mass fraction：
2-10 parts of sulfomethylated humic acid sodium,
10-20 parts of sorbester p17,
10-30 parts of cobalt naphthenate,
5-10 parts of triisopropanolamine,
18-25 parts of phthalic anhydride,
10-15 parts of glyceryl oleate,
4-8 parts of octadecanoid acid.
2. compound emulsifying agent according to claim 1, it is characterised in that the mass ratio of basic components and modified component is 4- 6：1, wherein,
Wherein basic components include the component of following mass fraction：
40-50 parts of acrylate monomer,
5-10 parts of perfluorooctane sulfonate,
2-3 parts of butyl benzyl phthalate,
0.5-1 parts of nonylphenol polyoxyethylene ether,
6-8 parts of methyl benzotriazazole；
Modified component includes the component of following mass fraction：
3-8 parts of sulfomethylated humic acid sodium,
12-15 parts of sorbester p17,
15-20 parts of cobalt naphthenate,
5-8 parts of triisopropanolamine,
20-25 parts of phthalic anhydride,
12-15 parts of glyceryl oleate,
4-6 parts of octadecanoid acid.
CN201610170707.6A 2016-03-24 2016-03-24 A kind of environmental protection fuel oil compound emulsifying agent Expired - Fee Related CN105802680B (en)

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CN1153203A (en) * 1995-12-08 1997-07-02 刘志强 Fuel oil emulsifying agent
CN1958734A (en) * 2005-11-05 2007-05-09 鲁习武 Emulsifier for fuel
CN102226117A (en) * 2011-05-12 2011-10-26 周鼎力 Preparation method of diesel emulsifier and emulsified diesel for vehicles and ships
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