CN105796375B - Portable clearing article - Google Patents
Portable clearing article Download PDFInfo
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- CN105796375B CN105796375B CN201410853168.7A CN201410853168A CN105796375B CN 105796375 B CN105796375 B CN 105796375B CN 201410853168 A CN201410853168 A CN 201410853168A CN 105796375 B CN105796375 B CN 105796375B
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- sodium
- detergent
- capsule layer
- alginate
- portable clearing
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Abstract
The present invention provides a kind of portable clearing article, with detergent and capsule layer, detergent is placed in capsule layer, detergent includes ionic macromolecule, and it reacts to form capsule layer with film formation reaction agent by ionic macromolecule, it is characterized in that there is the ion with ionic macromolecule opposite charges using film formation reaction agent so that ionic macromolecule is formed with electrostatic attraction chain each other.The portable clearing article of the present invention has the advantages that easy to carry, preparation flow is simple and not will produce waste, and capsule layer has effects that avoid high volatile substance in detergent to scatter and disappear, when capsule layer and water contact, capsule layer can be dissolved in the water immediately, and the detergent being coated in capsule layer is enable effectively to use.
Description
Technical field
The present invention mainly discloses a kind of cleaning supplies, more particularly a kind of to be dissolvable in water the portable Clean- of water
Product.
Background technology
With the changes of the times, consumer stresses micro-volume and easy to carry for personal cleansing product, therefore often
It will appear the phenomenon that being dispensed with bottle, but after causing use to finish, it mostly will not recycling.Cleaning supplies are for example:
Laundry paks, shampoo, bath oil, facial cleanser etc., these most cleaning supplies be all peddled in a manner of canned or is bottled, although
There is small bottled product for the passengers on the market at present, but is handled in waste and environmental pollution using still having after complete discarding
Problem.
Invention content
To solve the above-mentioned problems, the present invention provides a kind of portable clearing article, has detergent and capsule layer, cleaning
Agent is placed in capsule layer, and detergent includes ionic macromolecule, and ionic macromolecule can be cationic high-molecular or the moon
Ionic macromolecule, ionic macromolecule reacted with film formation reaction agent after formed capsule layer, using film formation reaction agent have with from
The ion of subtype macromolecule opposite charges so that ionic macromolecule is formed with electrostatic attraction chain each other.
Wherein, ionic macromolecule is agar glue, sodium alginate, potassium alginate, ammonium alginate, gelatin, Arabic gum, Huang
Alpine yarrow glue, galactan, guar gum, carragheen, pectin, xanthans, glucan, carboxymethyl starch, hydroxypropyl methyl cellulose, hydroxyl
The one of which of ethyl cellulose, sodium carboxymethylcellulose and carbopol.
Wherein, film formation reaction agent is a kind of divalent or trivalent metal ion salts in iron, copper, magnesium, calcium, strontium, zinc and aluminium.
Wherein, detergent includes cationic surfactant, anion surfactant, nonionic surfactant and two
The one of which of property surfactant.
Wherein, cationic surfactant is cetyl trimethylammonium bromide, hexadecyltrimethylammonium chloride, chlorination
Cetyl pyridinium, Benzene Chloride diformazan hydroxyl, benzyl rope chloramines, dioctadecyl dimethyl ammonium chloride and cetyl trimethyl bromination
The one of which of ammonium.
Wherein, anion surfactant is lauryl sodium sulfate, sodium laureth sulfate, lauroyl glutamate
Sodium, sodium cocoyl glutamate, sodium lauroyl sarcosine, laruyl alcohol sodium sarcosinate, sarcosinate, cocoyl ethoxy sulphur
Sour sodium, succinic acid di-isooctyl sodium sulphate, single Tryfac 5573 potassium, laruyl alcohol polytetroxide ethylene ether sodium sulfate, α-alkenyl sulphur
The one of which of sour sodium and N- methyl-N- cocoyl sodium taurocholates.
Wherein, nonionic surfactant is polysorbate, coconut acid diethanolamide and alkyl poly glucoside
One of which.
Wherein, amphoteric surfactant is coconut oil amido propyl dimethyl betaine, dodecanamide propyl dimethyl sweet tea
Dish alkali, dodecyl amine oxide, the one of which of dodecyl imidazole.
Portable clearing article of the present invention has easy to carry, preparation flow simply and not will produce waste
Advantage, and the capsule layer structure of the portable clearing article of the present invention has high volatile substance is avoided in detergent to scatter and disappear, such as
Essence or aqueous vapor are scattered and disappeared, and when capsule layer and water contact, capsule layer can be dissolved in the water immediately, make to be coated in capsule layer
Detergent can be used effectively.
Description of the drawings
1st figure is that the positive and negative charge of the capsule layer structure of portable clearing article of the present invention is in the enlarged drawing of random alignment.
2nd figure is that the positive and negative charge of the capsule layer structure of portable clearing article of the present invention is in regularly arranged enlarged drawing.
【Primary clustering symbol description】
1 portable clearing article
10 detergents
20 capsule layers
30 ionic macromolecules
40 film formation reaction agent
Specific implementation mode
The purposes of the portable clearing article of the present invention and the basic principle used have had for correlative technology field usual
Skill can be appreciated, therefore with following description, no longer make complete description, only in the portable clearing article of the present invention
Each component specific function realization be described in detail.Meanwhile the schema hereinafter to be compareed, expression are taken off with the present invention
The related structure of technical characteristic and function of dew are illustrated, and also need not completely be drawn according to actual size, why not first chats bright.
As shown in FIG. 1, FIG. 1 is disclosed herein portable clearing article capsule layer structure positive and negative charge be in
The enlarged drawing of machine arrangement.The first embodiment of the present invention is to provide a kind of portable clearing article 1 have detergent 10 and glue
Cystoblast 20, cladding detergent 10 will include this is because in the preparation process of portable clearing article 1 in the capsule layer 20
There is the detergent 10 of ionic macromolecule 30 to instill in the container configured with film formation reaction agent 40 and formed.It is emphasized that
Ionic macromolecule 30 in the detergent 10 of the present invention can select cationic high-molecular or anionic macromolecule, form
It is then with the ion with 30 opposite charges of ionic macromolecule in film reaction agent 40.Therefore, when detergent 10 instills film forming instead
It answers in agent 40, can make the ionic reaction shape of the ionic macromolecule 30 and the opposite charges in film formation reaction agent 40 of detergent 10
Plastic cystoblast 20;It will be apparent that the present invention be using film formation reaction agent 40 have with 30 opposite charges of ionic macromolecule from
Son so that ionic macromolecule 30 is formed with electrostatic attraction chain each other.
Then, the present invention further illustrates to form the process of capsule layer, due on capsule layer 20 have multiple positive charges and
Multiple negative electrical charges, and the distribution scenario of positive charge and negative electrical charge influences whether the stability that capsule layer 20 is formed, and it is distributed feelings
The valence mumber that shape depends between positive charge and negative electrical charge is corresponding, such as:On two anionic macromolecular chains in detergent 10
Monovalent anion, can with the bivalent cation in film formation reaction agent 40 formed chain;Three either in detergent 10
Monovalent anion on anionic macromolecular chain can be formed with the Tricationic in film formation reaction agent 40 and be chained.Positive electricity
Lotus and negative electrical charge can be in regularly arranged or random alignment, in the preferred case, as shown in Fig. 2, ion each other
Positive charge on 30 chain of type macromolecule and the negative electrical charge of film formation reaction agent 40 are each other in regularly arranged, not to this present invention
It limits.When capsule layer 20 and water contact, capsule layer 20 is dissolvable in water water so that detergent 10 in capsule layer 20 can be with
It uses, in addition, detergent 10 can be liquid state or gel.
Film formation reaction agent 40 of the present invention can be divalent or polyvalent metal ion salt, As iron, copper, magnesium, calcium, strontium, zinc
And a kind of divalent in aluminium or trivalent metal ion salts.Metal salt includes:Copper-containing compound, such as copper chloride, copper fluoride, sulfuric acid
Copper, copper nitrate, Kocide SD, copper citrate, copper gluconate, aspartic acid copper, cupric glutamate, sodium copper chlorophyllin, chlorophyll
Copper;Zinc compound, such as zinc chloride, zinc fluoride, zinc sulfate, zinc nitrate, zinc hydroxide, zinc citrate, zinc gluconate, asparagus fern
Propylhomoserin zinc, zinc glutamate, trbasic zinc phosphate and zinc lactate;Calcium containing compound, such as calcium chloride, calcium hydroxide, calcium citrate, gluconic acid
Calcium, Pidolidone calcium, calcium carbonate, calcium lactate, calcium pantothenate, calcium dihydric pyrophosphate, calcium propionate, calcium sulfate, tricalcium phosphate, phosphoric acid hydrogen
Calcium, calcium dihydrogen phosphate and calcium disodium chelate;Magnesium-containing compound, such as magnesium chloride, magnesium sulfate, magnesium hydroxide, L- paddy ammonia
Sour magnesium, magnesia and magnesium carbonate;Titanium-containing compound, such as titanium dioxide.
Ionic macromolecule 30 of the present invention is to have multiple ionic groups on macromolecular chain, can be cationic base
Group or anionic group.In addition, ionic macromolecule can also be macromolecule via being formed by cationic height after modification
Molecule or anionic macromolecule have multiple ionic groups on macromolecular chain.Ionic macromolecule be agar glue (Agar),
Sodium alginate (Sodium Alginate), potassium alginate (Potassium Alginate), ammonium alginate (Ammonium
Alginate), gelatin (Gelatin), Arabic gum (Arabic gum), bassora gum (Tragacanth gum), galactan
(Galactan), guar gum (Guar gum), carragheen (Carrageen), pectin (Pectin), xanthans (Xanthan
Gum), glucan (Dextran), carboxymethyl starch (Carboxymethyl starch), hydroxypropyl methyl cellulose
(Hydroxypropyl Methylcellulose, HPMC), hydroxyethyl cellulose (Hydroxyethyl cellulose,
HEC), wherein the one of sodium carboxymethylcellulose (Carboxymethyl cellulose, CMC) and carbopol (Carbopol)
Kind.
Detergent 10 of the present invention include surfactant, surfactant can be cationic surfactant,
The one of which of anion surfactant, nonionic surfactant and amphoteric surfactant.Wherein, anionic surface is lived
Property agent be lauryl sodium sulfate (sodium dodecyl sulfate, SDS), sodium laureth sulfate (sodium lauryl
Ether sulfate, SLES), sodium lauroyl glutamate (Mono sodium Lauryl Glutamate), cocoyl paddy
Propylhomoserin sodium (Sodium N-Cocoyl Glutamate), sodium lauroyl sarcosine (Sodium Lauroyl Sarcosinate),
Laruyl alcohol sodium sarcosinate (Sodium Lauryl Sarcosinate), sarcosinate (Sodium Cocoyl
Sarcosinate), cocoyl isethionate (Sodium Cocoyl Isethionate), succinic acid di-isooctyl sulfuric acid
Sodium (Sodium 2-Ethylhexyl Sulfosuccinate), single Tryfac 5573 potassium (Potassium MonoLauryl
Phosphate), laruyl alcohol polytetroxide ethylene ether sodium sulfate (Sodium Laureth Sulfate), α-sodium olefin sulfonate
(Sodium α-Olefin Sulfonate) and N- methyl-N- cocoyls sodium taurocholates (Sodium Methyl Cocoyl
Taurate one of which);And cationic surfactant is cetyl trimethylammonium bromide (cetyl
Trimethylammonium bromide, CTAB), hexadecyltrimethylammonium chloride (cetyl trimethylammonium
Chloride), cetylpyridinium chloride (Cetylpyridinium chloride, CPC), Benzene Chloride diformazan hydroxylammonium
(Benzalkonium chloride, BAC), benzyl rope chloramines (Benzethonium chloride), double octadecyldimethyls
Ammonium chloride (Dimethyldioctadecylammonium chloride) and cetyl trimethylammonium bromide
The one of which of (Cetrimonium bromide).In addition, nonionic surfactant is polysorbate
(Polysorbate), coconut acid diethanolamide (Cocoamide DEA) and alkyl poly glucoside (Alkyl
Polyglucosides one of which).Zwitterionic surfactant can be coconut oil amido propyl dimethyl betaine
(Cocoamido Propyl Betaine), dodecanamide propyl dimethyl betaine (Lauramidopropyl Betaine),
Dodecyl amine oxide (Lauryl Dimethyl Amine Oxide), dodecyl imidazole (Sodium
Lauroamphoacetate one of which).
Detergent of the present invention can further include additive.Additive can be selected from mould inhibitor, antiseptic, perfume (or spice)
The one of which or two or more combinations of taste agent, thickener, pigment, colorant or dyestuff and pH-value (pH) conditioning agent.It is mould proof
Agent or antiseptic can be selected from amine, alcohols (such as ethyl alcohol), aldehydes, isothiazoline class (such as different thiophenes of 5- chloro-2-methyls -4-
Oxazoline -3- ketone), imidazoles, esters, chlorine-containing compound, peroxide, carboxylic acids, carbanilide class, carbamates
It is (such as the iodo- 2-propynyl esters of butyl carbamic acid -3-), oxide-based, sulfide-based, sulfonamides, quaternary ammonium salt, nitrile, double
Guanidine compound (such as Chlorhexidine), pyridines, phenols, phthalmide and the one of which containing iodine compound.Flavouring agent can
With the various essence and flavoring agents selected from synthesis or natural extraction, such as the one of which of peppermint oil, lemongrass oil and lemon oil.Pigment
Can be selected from water-soluble colorant, organic pigment or inorganic pigment, inorganic pigment be the oxide of metal, sulfide, sulfate and
The one of which salt or carbon black of chromate.Organic pigment is azo pigments, phthalocyanine color, Heterocyclics Pigments, mordant pigment, dye
The one of which of material, fluorescent whitening agent and fluorescent pigment.
The second embodiment of the present invention is to provide the preparation method of portable clearing article, and steps are as follows:Step 100:
First, detergent 10 is prepared, surfactant and water are stirred at room temperature uniformly;Then, step 200 is carried out:It is equal in stirring
Ionic macromolecule 30 is added in even detergent 10, is stirred for later uniformly;Followed by progress step 300:It can be selective
Be added additive in the detergent 10 stirred evenly, and this additive can be selected from mould inhibitor, antiseptic, flavouring agent,
The one of which or two or more combinations of thickener, pigment, colorant or dyestuff and pH adjusting agent;Then, step 400 is carried out:
Film formation reaction agent solution 40 is provided, and film formation reaction agent solution 40 is positioned in container;Then, step 500 is carried out:It will cleaning
Agent 10 instills in the solution of film formation reaction agent 40, until film formation reaction agent 40 and ionic macromolecule 30 are formed by electrostatic attraction
Link, and then the capsule layer of sizing is formed, ball-type or droplet-shaped is presented in capsule at this time, and is surrounded by detergent in capsule layer;It connects again
It, carries out step 600:The capsule layer for being surrounded by detergent is picked up from container, and carries out standing and drying;Finally, it can select
Property damp-proof treatment can be carried out further to the capsule layer after having dried, such as with spray pattern, the anti-of aliphatic acid will contained
Damp spray even spraying is coated on capsule layer surface in capsule layer surface, or using moisture-proof powder so that capsule layer has anti-
The effect of tide.
The present invention in the above-described embodiments, ingredient during forming portable clearing article and proportioning, such as 1 institute of table
Show.Different adding proportions according to table 1 so that the detergent coated in capsule layer can form different kenels, produce
Raw liquid, the one of which kenel of half solid fraction and solid fraction, the ingredient of number 1 to 3 shown in table 1 can be respectively formed liquid, half consolidate
The kenel of shape and solid fraction, wherein half solid fraction is gel state, and amorphous state is presented, and can arbitrarily change shape, and solid fraction is jelly
State is presented fixed form, can not change shape.Herein it is noted that the shape of above-mentioned detergent such as liquid, half solid fraction and solid
Shape is the time for depending on film formation reaction agent such as calcium chloride solution and impregnating, such as soaking time 1 minute is liquid, soaking time is
It is solid fraction that 30 minutes, which are 1 hour for half solid fraction and soaking time,.It to be formed since ionic macromolecule is reacted with film formation reaction agent
Capsule layer there is stable structure, therefore, even if when detergent is liquid, detergent does not have the situation of leakage still.
Table 1
Although the present invention is disclosed above with preferred embodiment above-mentioned, however, it is not to limit the invention, any to be familiar with
The those skilled in the art of technical field, without departing from the spirit and scope of the present invention, when can make some changes and embellishment, therefore
The scope of patent protection of the present invention must regard subject to this specification scope of the appended claims institute defender.
Claims (8)
1. a kind of portable clearing article has detergent and capsule layer, wherein the capsule layer coats the detergent, it is special
Sign is:The detergent includes by agar glue, sodium alginate, potassium alginate, ammonium alginate, gelatin, Arabic gum, yellow alpine yarrow
Glue, galactan, guar gum, carragheen, pectin, xanthans, glucan, carboxymethyl starch, hydroxypropyl methyl cellulose, hydroxyl second
Selected ionic macromolecule in base cellulose, sodium carboxymethylcellulose and carbopol, and by the agar glue, the sea
Mosanom, the potassium alginate, the ammonium alginate, the gelatin, the Arabic gum, the bassora gum, the galactan
Sugared, the described guar gum, the carragheen, the pectin, the xanthans, the glucan, the carboxymethyl starch, the hydroxyl
Selected institute in propyl methocel, the hydroxyethyl cellulose, the sodium carboxymethylcellulose and the carbopol
State ionic macromolecule with by selected in a kind of divalent or trivalent metal ion salts in iron, copper, magnesium, calcium, strontium, zinc and aluminium
Film formation reaction agent reacts to form the capsule layer, the iron, the copper, the magnesium, the calcium, the strontium, the zinc and described
A kind of divalent or trivalent metal ion salts in aluminium have and the agar glue, sodium alginate, the potassium alginate, described
Ammonium alginate, the gelatin, the Arabic gum, the bassora gum, the galactan, the guar gum, the carragheen,
The pectin, the xanthans, the glucan, the carboxymethyl starch, the hydroxypropyl methyl cellulose, the ethoxy
The ion of cellulose, the sodium carboxymethylcellulose and the carbopol opposite charges, when the capsule layer is contacted with water,
The capsule layer is dissolvable in water water.
2. portable clearing article as described in claim 1, which is characterized in that the film formation reaction agent is also comprising chlorination
Calcium.
3. portable clearing article as described in claim 1, which is characterized in that the detergent includes cation surface activating
Agent, anion surfactant, nonionic surfactant and amphoteric surfactant one of which.
4. portable clearing article as claimed in claim 3, which is characterized in that the cationic surfactant is 16
Alkyl trimethyl ammonium bromide, hexadecyltrimethylammonium chloride, cetylpyridinium chloride, Benzene Chloride diformazan hydroxyl, benzyl rope chloramines
And the one of which of dioctadecyl dimethyl ammonium chloride.
5. portable clearing article as claimed in claim 3, which is characterized in that the anion surfactant is 12
Sodium alkyl sulfate, sodium laureth sulfate, sodium lauroyl glutamate, sodium cocoyl glutamate, sodium lauroyl sarcosine, the moon
Cinnamic alcohol sodium sarcosinate, sarcosinate, cocoyl isethionate, succinic acid di-isooctyl sodium sulphate, single lauryl phosphorus
Acid esters potassium, laruyl alcohol polytetroxide ethylene ether sodium sulfate, α-sodium olefin sulfonate and N- methyl-N- cocoyls sodium taurocholate are wherein
It is a kind of.
6. portable clearing article as claimed in claim 3, which is characterized in that the nonionic surfactant is poly- mountain
The one of which of pears alcohol ester, coconut acid diethanolamide and alkyl poly glucoside.
7. portable clearing article as claimed in claim 3, which is characterized in that the amphoteric surfactant is coconut oil
Amido propyl dimethyl betaine, dodecanamide propyl dimethyl betaine, dodecyl amine oxide, dodecyl imidazole its
Middle one kind.
8. portable clearing article as described in claim 1, which is characterized in that the detergent is liquid state or gelatinous
One of which.
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CN201410853168.7A CN105796375B (en) | 2014-12-31 | 2014-12-31 | Portable clearing article |
Applications Claiming Priority (1)
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CN201410853168.7A CN105796375B (en) | 2014-12-31 | 2014-12-31 | Portable clearing article |
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CN105796375A CN105796375A (en) | 2016-07-27 |
CN105796375B true CN105796375B (en) | 2018-07-13 |
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Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN107789235A (en) * | 2016-08-30 | 2018-03-13 | 广州诣可贸易有限公司 | Foam-like hot spring Essence prescription is used in a kind of scalp conditioning |
CN106580729A (en) * | 2016-11-13 | 2017-04-26 | 何志德 | Preparation formula for novel amino acid face cleaning slice and preparation method thereof |
EP3577205A4 (en) * | 2017-02-06 | 2020-10-28 | The Procter and Gamble Company | Laundry detergent sheet with microcapsules |
CN109777634A (en) * | 2019-01-25 | 2019-05-21 | 关汉杰 | A kind of chance Water blown capsule and preparation method thereof |
CN112080353A (en) * | 2020-09-02 | 2020-12-15 | 广东丽臣奥威实业有限公司 | Mild and efficient surfactant composition for cleaning |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1497008A (en) * | 2002-10-10 | 2004-05-19 | 国际香料和香精公司 | Encapsulated aromatic chemical product |
CN101605526A (en) * | 2007-02-13 | 2009-12-16 | 吉万奥丹股份有限公司 | Microcapsule |
CN102256588A (en) * | 2008-12-18 | 2011-11-23 | 弗门尼舍有限公司 | Microcapsules and uses thereof |
CN102858940A (en) * | 2010-04-28 | 2013-01-02 | 宝洁公司 | Delivery particles |
CN103394092A (en) * | 2013-08-11 | 2013-11-20 | 重庆衡生药用胶囊有限责任公司 | Gellan gum and calcium chloride gelled hydroxypropyl methylcellulose enteric-coated hollow capsule |
-
2014
- 2014-12-31 CN CN201410853168.7A patent/CN105796375B/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1497008A (en) * | 2002-10-10 | 2004-05-19 | 国际香料和香精公司 | Encapsulated aromatic chemical product |
CN101605526A (en) * | 2007-02-13 | 2009-12-16 | 吉万奥丹股份有限公司 | Microcapsule |
CN102256588A (en) * | 2008-12-18 | 2011-11-23 | 弗门尼舍有限公司 | Microcapsules and uses thereof |
CN102858940A (en) * | 2010-04-28 | 2013-01-02 | 宝洁公司 | Delivery particles |
CN103394092A (en) * | 2013-08-11 | 2013-11-20 | 重庆衡生药用胶囊有限责任公司 | Gellan gum and calcium chloride gelled hydroxypropyl methylcellulose enteric-coated hollow capsule |
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