CN109777634A - A kind of chance Water blown capsule and preparation method thereof - Google Patents
A kind of chance Water blown capsule and preparation method thereof Download PDFInfo
- Publication number
- CN109777634A CN109777634A CN201910073744.9A CN201910073744A CN109777634A CN 109777634 A CN109777634 A CN 109777634A CN 201910073744 A CN201910073744 A CN 201910073744A CN 109777634 A CN109777634 A CN 109777634A
- Authority
- CN
- China
- Prior art keywords
- capsule
- soluble polymer
- water
- parts
- water soluble
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses a kind of chance Water blown capsules and preparation method thereof, including water soluble polymer film, surfactant and constitutive material, surfactant and constitutive material is distributed in the inside of water soluble polymer film, constitutive material includes carbonate, solid acid, essence microcapsule and lauryl sodium sulfate, wherein the mass fraction of each constitutive material is as follows: 15-60 parts of carbonate, 30-75 parts of solid acid, 2-10 parts of lauryl sodium sulfate, 0.1-1 parts of essence microcapsule.The present invention is wrapped up the foamed material for meeting water reaction using water soluble polymer capsule, and only one gram or so of weight, bubble is stablized lasting, with cleaning, fire extinguishing obstructs smell function, help stable bubble, detergency is improved, carbon dioxide keeps stablizing in surface activating solution, plays isolation smell, the effect of air-isolation, it can be used as household cleaning, isolation smell is used, it can also be used to put out water surface kindling.
Description
Technical field
The present invention relates to a kind of chance Water blown capsule, in particular to a kind of chance Water blown microencapsulation and preparation method thereof.
Background technique
So-called foaming agent is exactly the substance for making object substance pore-forming, it can be divided into chemical foaming agent and physical blowing agent and table
Face activating agent three categories.Chemical foaming agent is that those heated decomposition [U1] can release the gases such as carbon dioxide and nitrogen, and
The compound of pore is formed in polymer composition；Physical blowing agent is exactly that foam pore is physics shape by a certain substance
The variation of state is formed by the expansion of compressed gas, the volatilization of liquid or the dissolution of solid；Foaming agent all has higher
Surface-active, the surface tension of liquid can be effectively reduced, and arrange in liquid film surface electric double layer and surround air, form gas
Bubble, then foam is formed by single isolated bubbles.
Be prepared as large-scale or medium size installations, the mostly fire-fighting fire extinguishing of foaming agent are used, and are divided into inflatable and reaction equation；Small-sized foaming
Mostly inflatable needs canister to pack, most of weight kilogram or more, and heavier-weight is inconvenient to use.
Summary of the invention
Invention is designed to provide a kind of chances Water blown capsule and preparation method thereof, and capsule shape reaction equation foaming agent weighs
It only one gram or so, meets water and forms stable foam, can be used as household cleaning, isolation smell is used, it can also be used to water surface kindling is put out,
To solve the problems mentioned in the above background technology.
To achieve the above object, the invention provides the following technical scheme: a kind of chance Water blown capsule, including water-soluble high score
Surfactant and constitutive material is distributed in sub- film, surfactant and constitutive material, the inside of water soluble polymer film, composition
Raw material includes carbonate, solid acid, essence microcapsule and lauryl sodium sulfate, wherein the mass fraction of each constitutive material is such as
Under: 15-60 parts of carbonate, 30-75 parts of solid acid, 2-10 parts of lauryl sodium sulfate, 0.1-1 parts of essence microcapsule.
Further, carbonate is sodium carbonate, sodium bicarbonate, one of potassium carbonate.
Further, solid acid is one of citric acid, oxalic acid, sulfamic acid.
Further, lauryl sodium sulfate choice of powder shape product.
Further, essence microcapsule selects food grade powder shape product, is lemon flavor essence microcapsule.
Further, the capsule wall of water soluble polymer film is room temperature water solubility plasticization high molecular material, is oligomerization
Spend one of polyvinyl alcohol, [U2] film, sodium carboxymethylcellulose film.
The present invention provides another technical solution: a kind of preparation method for meeting Water blown capsule includes the following steps:
Step 1: capsule shells are made using die casting molding in water soluble polymer film；
Step 2: weighing to be mixed after each component by mass fraction and stir evenly；
Step 3: the mixture of step 2 is fitted into the capsule shells of step 1.
Further, step 1 can also first be made the re-compacted molding of film and capsule shells are made.
Compared with prior art, the present invention is wrapped up the foamed material for meeting water reaction using water soluble polymer capsule, weight
Only one gram or so, when meeting water, capsule dissolves, and the inside substance meets water reaction and generates bubble, and bubble is stablized persistently, has cleaning, go out
Fire obstructs smell function.Capsule shell ingredient is water solubility, can form the polymer substance of micella after dissolution in water, help
Stablize bubble, improves detergency.Capsule 's content is carbonate, acidic materials, surfactant, and carbonate is anti-with acidic materials
Carbon dioxide should be generated, carbon dioxide keeps stablizing in surface activating solution, plays the role of isolation smell, air-isolation can
As household cleaning, completely cut off smell and be used, it can also be used to put out water surface kindling.
Detailed description of the invention
Fig. 1 is capsule structural schematic diagram of the invention.
In figure: 1, water soluble polymer film；2, surfactant；3, carbonate；4, solid acid；5, essence microcapsule.
Specific embodiment
Below in conjunction with the embodiment of the present invention and attached drawing, technical solution of the present invention is clearly and completely described.It is aobvious
So, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on the reality in the present invention
Example is applied, every other embodiment obtained by those of ordinary skill in the art without making creative efforts all belongs to
In the scope of protection of the invention.
Referring to Fig. 1, a kind of chance Water blown capsule, including water soluble polymer film 1, surfactant 2 and constitutive material,
The inside of water soluble polymer film 1 is distributed with surfactant 2 and constitutive material, constitutive material include carbonate 3, solid acid 4,
Essence microcapsule 5 and lauryl sodium sulfate, wherein the mass fraction of each constitutive material is as follows: 15-60 parts of carbonate, solid acid
30-75 parts, 2-10 parts of lauryl sodium sulfate, 0.1-1 parts of essence microcapsule, foaming agent are carbonate and acidic materials, can be produced
Raw carbon dioxide, foaming agent contain surfactant, can stablize the carbon dioxide of generation, form stable foam, surface-active
Lauryl sodium sulfate is selected in agent, and good water solubility, blistering foam stabilizing ability is strong, and selecting to generate simultaneously in generation carbon dioxide has table
The acidic materials of face active ingredient, help cleaning and stable foam.
Foaming agent contain essence microcapsule, help keep it is with fresh air, essence microcapsule is solia particle, can be uniformly dispersed in
In solid mixture, influence of the liquid to system is avoided.
Due to having used acidic materials excessive, facilitate lavatory and other alkaline spots between sanitation and hygiene.
Water soluble polymer film 1 protects foam, and forms some strength, rises and stablizes CO2Effect.
Substance in constitutive material plays synergistic effect, plays protection mutually, cleans, the effect of stable foam.
Solid acid is citric acid, oxalic acid, and the water soluble acids such as sulfamic acid have used oxalic acid, citric acid, and sulfamic acid is
Infusion and ceramic cleaners, cleaning do not damage ceramic surface simultaneously.
A kind of preparation method for meeting Water blown capsule, includes the following steps:
Step 1: capsule shells are made using die casting molding in water soluble polymer film 1, it can soluble in water, the water of capsule shell
Soluble macromolecular can form micella, foam stabilizing and dirt separation be helped, convenient for cleaning；
Step 2: weighing to be mixed after each component by mass fraction and stir evenly；
Step 3: the mixture of step 2 is fitted into the capsule shells of step 1, capsule can be made into common nested one, or
The complex capsule of individual cells is closed, foaming agent meets water reaction, generates carbon dioxide, and foaming agent is protected by capsule, avoided contact with
Moisture content in air and fail.
Embodiment 1
Sodium carbonate 100g, citric acid 230g, lauryl sodium sulfate 10g, lemon flavor essence microcapsule are weighed by mass fraction
1g。
A kind of preparation method for meeting Water blown capsule, includes the following steps:
Step 1: 00#PVA capsule shells are made using die casting molding in water soluble polymer film 1；
Step 2: weighing to be mixed after each component by mass fraction and stir evenly；
Step 3: the mixture of step 2 being fitted into the 00#PVA capsule shells loaded on step 1, the foaming agent foam amount is big and steeps
Foam is stablized.
Embodiment 2
Sulfamic acid 350g, sodium carbonate 100g, lauryl sodium sulfate 12g, the micro- glue of lemon flavor essence are weighed by mass fraction
Capsule 2g.
A kind of preparation method for meeting Water blown capsule, includes the following steps:
Step 1: 00#PVA capsule shells are made using die casting molding in water soluble polymer film 1；
Step 2: weighing to be mixed after each component by mass fraction and stir evenly；
Step 3: the mixture of step 2 being fitted into the 00#PVA capsule shells loaded on step 1, the foaming agent is to metal deposit dirt
Dirty strong cleaning force.
Embodiment 3
Oxalic acid 100g, sodium carbonate 50g, lauryl sodium sulfate 8g, lemon flavor essence microcapsule 1g are weighed by mass fraction.
A kind of preparation method for meeting Water blown capsule, includes the following steps:
Step 1: 00#PVA capsule shells are made using die casting molding in water soluble polymer film 1；
Step 2: weighing to be mixed after each component by mass fraction and stir evenly；
Step 3: the mixture of step 2 being fitted into the 00#PVA capsule shells loaded on step 1, the foaming agent is to ceramic surface corruption
Corrosion is low, does not damage gloss.
Embodiment 4
Citric acid 120g, sodium bicarbonate 80g, lauryl sodium sulfate 10g, lemon flavor essence microcapsule are weighed by mass fraction
1g。
A kind of preparation method for meeting Water blown capsule, includes the following steps:
Step 1: 00# starch-based glue softgel shell is made using die casting molding in water soluble polymer film 1；
Step 2: weighing to be mixed after each component by mass fraction and stir evenly；
Step 3: the mixture of step 2 is fitted into the 00# starch-based glue softgel shell loaded on step 1, the blowing agent properties are mild,
Without to human body excitor substance.
Embodiment 5
Oxalic acid 100g, potassium carbonate 140g, lauryl sodium sulfate 10g, lemon flavor essence microcapsule 1g are weighed by mass fraction.
A kind of preparation method for meeting Water blown capsule, includes the following steps:
Step 1: 00# sodium carboxymethylcellulose capsule shells are made using die casting molding in water soluble polymer film 1；
Step 2: weighing to be mixed after each component by mass fraction and stir evenly；
Step 3: the mixture of step 2 being fitted into the 00# sodium carboxymethylcellulose capsule shells loaded on step 1, the foaming agent
Strong detergency is insensitive to water quality.
Embodiment 6
Oxalic acid 120g, potassium carbonate 100g, lauryl sodium sulfate 8g, lemon flavor essence microcapsule 2g are weighed by mass fraction.
A kind of preparation method for meeting Water blown capsule, includes the following steps:
Step 1: 00# sodium carboxymethylcellulose capsule shells are made using die casting molding in water soluble polymer film 1；
Step 2: weighing to be mixed after each component by mass fraction and stir evenly；
Step 3: the mixture of step 2 being fitted into the 00# sodium carboxymethylcellulose capsule shells loaded on step 1, the foaming agent
Decontamination is fast.
The chance Water blown capsule of embodiment 1-6 preparation prevents spray of water when can be used for going to the toilet, and obstructs stink, brings pure and fresh
Smell, it is easy to clean, the comfort that goes to the toilet is improved, foam cleaner can be attached to facade, help the cube of cleaning structure complexity,
It can be used in special occasions fireproof fire-extinguishing, if the water surface catches fire, be suitble to clean alkaline spot, it is more portable relative to liquid cleaner
Band can clean metal, and ceramic scale removes surfactant, select food grade materials, can make Portable solid carbonated drink material
Material.
In conclusion chance Water blown capsule proposed by the present invention and preparation method thereof, it will using water soluble polymer capsule
The foamed material package of water reaction is met, only one gram or so of weight, capsule dissolves when meeting water, and the inside substance meets water reaction and generates gas
Bubble, bubble are stablized persistently, have cleaning, and fire extinguishing obstructs smell function.Capsule shell ingredient is water solubility, can be in water after dissolution
The middle polymer substance for forming micella, helps stable bubble, improves detergency.Capsule 's content is carbonate, acidic materials, table
Face activating agent, carbonate is reacted with acidic materials generates carbon dioxide, and carbon dioxide keeps stablizing in surface activating solution, plays
Smell is isolated, the effect of air-isolation can be used as household cleaning, and isolation smell is used, it can also be used to put out water surface kindling.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Anyone skilled in the art within the technical scope of the present disclosure, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (8)
1. a kind of chance Water blown capsule, which is characterized in that former including water soluble polymer film (1), surfactant (2) and composition
Surfactant (2) and constitutive material is distributed in material, the inside of water soluble polymer film (1), and constitutive material includes carbonate
(3), solid acid (4), essence microcapsule (5) and lauryl sodium sulfate, wherein the mass fraction of each constitutive material is as follows: carbonic acid
15-60 parts of salt, 30-75 parts of solid acid, 2-10 parts of lauryl sodium sulfate, 0.1-1 parts of essence microcapsule.
2. a kind of chance Water blown capsule according to claim 1, which is characterized in that carbonate be sodium carbonate, sodium bicarbonate,
One of potassium carbonate.
3. a kind of chance Water blown capsule according to claim 1, which is characterized in that solid acid is citric acid, oxalic acid, amino
One of sulfonic acid.
4. a kind of chance Water blown capsule according to claim 1, which is characterized in that lauryl sodium sulfate choice of powder shape
Product.
5. a kind of chance Water blown capsule according to claim 1, which is characterized in that essence microcapsule selects food grade powder
Shape product is lemon flavor essence microcapsule.
6. a kind of chance Water blown capsule according to claim 1, which is characterized in that the capsule of water soluble polymer film (1)
Wall is room temperature water solubility plasticization high molecular material, thin for polyvinyl alcohol with low degree of polymerization, [U1] film, sodium carboxymethylcellulose
One of film.
7. a kind of preparation method according to claim 1-6 for meeting Water blown capsule, which is characterized in that including such as
Lower step:
Step 1: capsule shells are made using die casting molding in water soluble polymer film (1)；
Step 2: weighing to be mixed after each component by mass fraction and stir evenly；
Step 3: the mixture of step 2 is fitted into the capsule shells of step 1.
8. a kind of preparation method for meeting Water blown capsule according to claim 7, which is characterized in that step 1 can also first be made
Capsule shells are made at the re-compacted molding of film.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910073744.9A CN109777634A (en) | 2019-01-25 | 2019-01-25 | A kind of chance Water blown capsule and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910073744.9A CN109777634A (en) | 2019-01-25 | 2019-01-25 | A kind of chance Water blown capsule and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109777634A true CN109777634A (en) | 2019-05-21 |
Family
ID=66501297
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910073744.9A Pending CN109777634A (en) | 2019-01-25 | 2019-01-25 | A kind of chance Water blown capsule and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109777634A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2021123511A1 (en) * | 2019-12-18 | 2021-06-24 | Cleaneor | Foaming composition for hiding excrement and avoiding splashes and falling noises |
| CN116159275A (en) * | 2023-04-03 | 2023-05-26 | 武汉中科先进材料科技有限公司 | Carbon dioxide fire extinguishing microcapsule and preparation method thereof |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2313587A1 (en) * | 1999-07-07 | 2001-01-07 | Henkel Kommanditgesellschaft Auf Aktien | Capsule for controlled release of active substances |
| CN1543421A (en) * | 2001-08-16 | 2004-11-03 | 沃尼尔・朗伯有限责任公司 | Water soluble packaging |
| CN1586707A (en) * | 2004-07-16 | 2005-03-02 | 东华大学 | Color physically foamed micro capsule and preparing method |
| CN1935972A (en) * | 2006-09-20 | 2007-03-28 | 王涛 | Washing capsule and its preparing method |
| CN102215811A (en) * | 2008-02-08 | 2011-10-12 | 高露洁-棕榄公司 | Effervescent compositions |
| CN102703230A (en) * | 2011-05-25 | 2012-10-03 | 王国松 | Spray-proof, olid-resistant, anti-sticking automatic foaming powder when wets for toilets |
| WO2015054100A2 (en) * | 2013-10-07 | 2015-04-16 | Monosol, Llc | Water-soluble delayed release capsules, related methods, and related articles |
| CN105796375A (en) * | 2014-12-31 | 2016-07-27 | 罗允俊 | Portable cleaning product |
| CN107057861A (en) * | 2017-05-05 | 2017-08-18 | 盛悦恒 | It is a kind of to be used for the cleaning formulation of ceramic glaze and glassware |
-
2019
- 2019-01-25 CN CN201910073744.9A patent/CN109777634A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2313587A1 (en) * | 1999-07-07 | 2001-01-07 | Henkel Kommanditgesellschaft Auf Aktien | Capsule for controlled release of active substances |
| CN1543421A (en) * | 2001-08-16 | 2004-11-03 | 沃尼尔・朗伯有限责任公司 | Water soluble packaging |
| CN1586707A (en) * | 2004-07-16 | 2005-03-02 | 东华大学 | Color physically foamed micro capsule and preparing method |
| CN1935972A (en) * | 2006-09-20 | 2007-03-28 | 王涛 | Washing capsule and its preparing method |
| CN102215811A (en) * | 2008-02-08 | 2011-10-12 | 高露洁-棕榄公司 | Effervescent compositions |
| CN102703230A (en) * | 2011-05-25 | 2012-10-03 | 王国松 | Spray-proof, olid-resistant, anti-sticking automatic foaming powder when wets for toilets |
| WO2015054100A2 (en) * | 2013-10-07 | 2015-04-16 | Monosol, Llc | Water-soluble delayed release capsules, related methods, and related articles |
| CN105796375A (en) * | 2014-12-31 | 2016-07-27 | 罗允俊 | Portable cleaning product |
| CN107057861A (en) * | 2017-05-05 | 2017-08-18 | 盛悦恒 | It is a kind of to be used for the cleaning formulation of ceramic glaze and glassware |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2021123511A1 (en) * | 2019-12-18 | 2021-06-24 | Cleaneor | Foaming composition for hiding excrement and avoiding splashes and falling noises |
| CN116159275A (en) * | 2023-04-03 | 2023-05-26 | 武汉中科先进材料科技有限公司 | Carbon dioxide fire extinguishing microcapsule and preparation method thereof |
| CN116159275B (en) * | 2023-04-03 | 2024-01-30 | 武汉中科先进材料科技有限公司 | Carbon dioxide fire extinguishing microcapsule and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US6121215A (en) | Foaming effervescent bath product | |
| CN109777634A (en) | A kind of chance Water blown capsule and preparation method thereof | |
| ES2901170T3 (en) | Foam-generating composition for protection against fire and/or heat | |
| JP4830856B2 (en) | Powdered soap composition | |
| US7300912B2 (en) | Foaming cleansing preparation and system comprising coated acid and base particles | |
| KR970701038A (en) | CRANULAR PRODUCT OR TABLET CONTAINING AN EFFER VESCENT SYSTEM AND AN ACTIVE PHARMACEUTICAL SUBSTANCE, AS WELL AS A METHOD FOR ITS PREPARATION | |
| US2560097A (en) | Hand cleaning tablet | |
| JP2002535449A5 (en) | ||
| CN108948615A (en) | A kind of nontoxic crystal mud of intelligence development DIY and preparation method thereof | |
| US8206686B2 (en) | Organic acid free effervescent formulation | |
| JP2898375B2 (en) | Composite solid and method for producing the same | |
| JP2002275051A (en) | Solid cosmetic | |
| CN112352857A (en) | Instant tea tablet and preparation method thereof | |
| JPS585695B2 (en) | Manufacturing method of effervescent tablets | |
| JPS5566507A (en) | Preparation of foamed tablet | |
| JPS6019946B2 (en) | foamable molded product | |
| NO312085B1 (en) | Process for the preparation of porous cellulose matrices and tablets, as well as multiple unit preparation and tablet containing the cellulose matrices | |
| JP2823580B2 (en) | Foaming agent and method for producing the same | |
| US2228483A (en) | Process for the preparation of products delivering carbonic acid gas | |
| JPH0374321A (en) | Bathing agent | |
| JPS58140312A (en) | Stable composition for generating gaseous carbon dioxide | |
| JPH0788295B2 (en) | Bath salt bag | |
| KR20220135537A (en) | Tablet cosmetic composition containing self foaming funtion | |
| JPS6117509A (en) | Bath salts with hinoki smell | |
| JP3936716B2 (en) | Solid cosmetics |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190521 |