CN105767002B - Aluminum phosphate expelling mouse agent packaging structure and administration device convenient for Slag recovering - Google Patents
Aluminum phosphate expelling mouse agent packaging structure and administration device convenient for Slag recovering Download PDFInfo
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- CN105767002B CN105767002B CN201610315565.8A CN201610315565A CN105767002B CN 105767002 B CN105767002 B CN 105767002B CN 201610315565 A CN201610315565 A CN 201610315565A CN 105767002 B CN105767002 B CN 105767002B
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/26—Phosphorus; Compounds thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
- A01M29/00—Scaring or repelling devices, e.g. bird-scaring apparatus
- A01M29/12—Scaring or repelling devices, e.g. bird-scaring apparatus using odoriferous substances, e.g. aromas, pheromones or chemical agents
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/12—Powders or granules
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Zoology (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Toxicology (AREA)
- Plant Pathology (AREA)
- Agronomy & Crop Science (AREA)
- Birds (AREA)
- Insects & Arthropods (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Medicinal Preparation (AREA)
- Catching Or Destruction (AREA)
Abstract
The invention discloses a kind of aluminum phosphate expelling mouse agents, and by weight, total amount is 100 parts, including aluminum phosphate original powder, 56~65 parts；Polyethylene glycol, 5~7 parts；Aminoquinoxaline, 3~4 parts；Magnesium stearate, 5~6 parts；Sodium carboxymethylcellulose, 5~6 parts；Starch, 5~6 parts；Surplus is cyclodextrin.Repellent effect of the present invention is good, highly practical, implementation easy to spread.A kind of administration device convenient for Slag recovering is also disclosed, including：Car body, the car body include a ride, wheel；A connecting seat is connected with by mechanical arm on the ride；A drill bit is vertically equipped on the connecting seat；A hopper is additionally provided on the connecting seat；It further include a feeding machanism；It is additionally provided with Bluetooth base. station on the ride.The device of the invention dispensing is convenient, highly practical convenient for recycling residue.
Description
Technical field
The present invention relates to aluminum phosphate technical field more particularly to a kind of aluminum phosphate expelling mouse agents, are driven for producing the aluminum phosphate
The preparation method and its packaging structure of mouse agent and the administration device convenient for Slag recovering.
Background technology
Aluminum phosphate is fired with red phosphorus and aluminium powder.It is widely used due to insecticide efficiency is high, economy facilitates.As silo
Stifling phosphatization aluminium content is that the specification of 56.0%~58.5%, 3.20g/ pieces is more.Fumigation grain per ton only needs 3~7, often stands
Square rice is only with 1~2.Phosphatization aluminium toxicity is then decomposed rapidly when predominantly meeting water, acid, release absorb quickly, the violent phosphorus of toxicity
Change hydrogen.A kind of pesticide is can be used as with the mixture of aminoquinoxaline, is also used for welding.
In addition, aluminum phosphate can be additionally used in field rat destruction, suffer to prevent mouse, and existing aluminum phosphate rat destruction meter is in release speed
Degree is very fast, and the purpose of long-term sunstroke prevention is not achieved, and, phosphatization aluminium porcelain enamelling is not easy to clear up, and then lead using rear left residue
Remaining more residue in soil is caused, makes to contain more medicament residue in grain, vegetables, melon and fruit, is unfavorable for food security, it should
Problems demand solves.
Invention content
A kind of aluminum phosphate expelling mouse agent is provided it is an object of the invention to overcome the deficiency of the above-mentioned prior art.
To achieve the above object, the present invention provides a kind of aluminum phosphate expelling mouse agent, and by weight, total amount is 100 parts, including：
Aluminum phosphate original powder, 56~65 parts；
Polyethylene glycol, 5~7 parts；
Aminoquinoxaline, 3~4 parts；
Magnesium stearate, 5~6 parts；
Sodium carboxymethylcellulose, 5~6 parts；
Starch, 5~6 parts；
Surplus is cyclodextrin.
Preferably, by weight, total amount is 100 parts, including：
Aluminum phosphate original powder, 65 parts；
Polyethylene glycol, 6 parts；
Aminoquinoxaline, 4 parts；
Magnesium stearate, 5 parts；
Sodium carboxymethylcellulose, 5 parts；
Starch, 5 parts；
Cyclodextrin, 10 parts.
In order to prepare above-mentioned aluminum phosphate expelling mouse agent, the present invention also provides a kind of preparation methods, include the following steps：
Step A：By red phosphorus and aluminium powder in molar ratio 1：4 ignition after evenly mixing, reaction generate aluminum phosphate；
Step B：Aluminum phosphate is crushed with pulverizer, becomes aluminum phosphate original powder；
Step C：By weight, 65 parts of aluminum phosphate original powders are added in reactor, polyethylene glycol 6 is added into reactor
Part, 4 parts of aminoquinoxaline stirs 3 minutes, and then, 20 DEG C keep the temperature 15 minutes；
Step D：Inject 5 parts of magnesium stearate, 5 parts of sodium carboxymethylcellulose, 5 parts of starch, 10 parts of cyclodextrin；Stirring 3 minutes；
5 DEG C are cooled in 5 minutes；
Step E：Spherical aluminum phosphate expelling mouse agent particle is made in the obtained products of step D.
The present invention also provides a kind of packaging structures, for being further packed for above-mentioned spheric granules to reach sustained release
Purpose, the packaging structure include：
Pvc pipe is evenly distributed with rat destruction monomer in the pvc pipe；
Each rat destruction monomer includes a spherical aluminum phosphate expelling mouse agent particle, a water absorbing resin particle, one by pure medium-height grass
Medicine ball with mouse driving function, three made of medicine arrange in a triangle；
The spherical shape aluminum phosphate expelling mouse agent particle, has mouse driving function at water absorbing resin particle made of pure Chinese herbal medicine
The outside of medicine ball is extruded at least two layers chance water dissolvable paper；
The outside for meeting water dissolvable paper is equipped with the pressure-resistant ceramic case that through-hole is distributed in surface, leads to described in surface 2/3
Hole is blocked by degradation plastic.
Preferably, through-hole is distributed in the even tube wall of the pvc pipe.
Preferably, the pvc pipe inner surface is equipped with several wedge blocks.
Preferably, the pvc pipe includes end to end several bellows segments and smooth section, the smooth outer surface of smooth section,
It is recognized to personnel easy to operation.
Preferably, the bellows segment and smooth section mutual conduction.
Preferably, the bellows is different with the surface color of smooth tube.
In order to realize a further object of the present invention, the present invention also provides a kind of administration devices convenient for Slag recovering, including：
Car body, the car body include a ride, four wheels below ride；
A connecting seat is connected with by mechanical arm on the ride；
A drill bit is vertically equipped on the connecting seat, to punch soil layer；
It is additionally provided with a hopper on the connecting seat, several bluetooth positioning devices are filled in the hopper；
The hopper is connected by a bellows with the end of drill bit；
Further include a feeding machanism, the feeding machanism includes a motor, and the motor passes through shaft coupling and an idler wheel phase
Even, it is wound with above-mentioned packaging structure on the idler wheel；Wherein, the drill bit is hollow, and the pvc pipe stretches into the drill bit
Portion；
Be additionally provided with Bluetooth base. station on the ride, to the bluetooth positioning device Bluetooth pairing, and measure its position.
Preferably, the hopper is equipped with the capping that can be opened and closed.
Preferably, the outer surface of the pvc pipe is additionally provided with wear-resistant coating.
Preferably, the mechanical arm is rotatablely connected with ride.
The beneficial effects of the invention are as follows：The expelling mouse agent repellent effect of the present invention is good, and rat destruction monomer uses delta structure,
Spherical aluminum phosphate expelling mouse agent particle is main rat destruction power, and a water absorbing resin particle is for attracting steam to enter spherical aluminum phosphate
Inside expelling mouse agent particle, promote its deliquescence；Using the medicine ball with mouse driving function made of pure Chinese herbal medicine, it is further provided
The repellent effect of the present invention.The present invention not only has repellent effect, also has certain anthelminthic effect.When meeting water, meeting water can
Dissolving paper dissolves, and delta structure is exposed.The expelling mouse agent of the present invention especially can be used poly- by using polyethylene glycol
Ethylene glycol 400 makes polyethylene glycol, aluminum phosphate, aminoquinoxaline form highly uniform chromic fibrous solid matter, in addition,
Due to further embedding aluminum phosphate powder wherein using cyclodextrin, slow release effect is further promoted, in addition, carboxymethyl cellulose
Sodium and starch interaction, further promote slow release effect, avoid aluminum phosphate fast decoupled, and then reach preferable rat destruction effect
Fruit.In addition, if pvc pipe is under the larger environment of moisture, water absorbing resin particle can also absorb extra moisture, avoid phosphatization
Aluminium decomposes too fast.Stability of the present invention is good, and reliability is high, easy for operation, highly practical, novel in design, easy to spread.
Description of the drawings
Fig. 1 is the structural schematic diagram of the rat destruction monomer described in one embodiment of the invention；
Fig. 2 is the dimensional structure diagram of the administration device of the present invention convenient for Slag recovering；
Reference numeral：
Spherical aluminum phosphate expelling mouse agent particle 101；Water absorbing resin particle 102；There is mouse driving function made of pure Chinese herbal medicine
Medicine ball 103；Meet water dissolvable paper 12；Pressure-resistant ceramic case 13；Ride 21；Wheel 22；Motor 231；Idler wheel 232；Pvc pipe
2321；Mechanical arm 24；Connecting seat 25；Hopper 26；Capping 261；Bellows 262；Drill bit 27.
The embodiments will be further described with reference to the accompanying drawings for the realization, the function and the advantages of the object of the present invention.
Specific implementation mode
The embodiment of the present invention is described below in detail, the examples of the embodiments are shown in attached drawing 1 and attached drawing 2, wherein
Same or similar label indicates same or similar element or element with the same or similar functions from beginning to end.Lead to below
It crosses the embodiment being described with reference to the drawings to be exemplary, it is intended to for explaining the present invention, and should not be understood as the limit to the present invention
System.
Repellent effect proves：
1, the test drug A of the configuration present invention.According to by weight, total amount is 100 parts, collection aluminum phosphate original powder, 65
Part；Polyethylene glycol, 6 parts；Aminoquinoxaline, 4 parts；Magnesium stearate, 5 parts；Sodium carboxymethylcellulose, 5 parts；Starch, 5 parts；Ring is pasted
Essence, 10 parts.Then according to following steps, medicament is made：Step A：By red phosphorus and aluminium powder in molar ratio 1：4 light a fire after evenly mixing
Burning, reaction generate aluminum phosphate；Step B：Aluminum phosphate is crushed with pulverizer, becomes aluminum phosphate original powder；Step C：By weight,
65 parts of aluminum phosphate original powders are added in reactor, 6 parts of polyethylene glycol is added into reactor, 4 parts of aminoquinoxaline stirs 3 points
Clock, then, 20 DEG C keep the temperature 15 minutes；Step D：Inject 5 parts of magnesium stearate, 5 parts of sodium carboxymethylcellulose, 5 parts of starch, cyclodextrin
10 parts；Stirring 3 minutes；5 DEG C are cooled in 5 minutes；Step E：Tablet is made in the obtained products of step D.
2, configuration experiment control group drug B.According to the Chinese herbal medicine disclosed in the Chinese patent patent No. 2007100493668
Mouse-drivingblocks select the technical solution of claim 2 therein, by weight ratio, total amount is divided into 100 parts, 10 parts of frutus cnidii；China tree
35 parts of skin；30 parts of perilla herb oil；25 parts of camphor；The medical dextrin for accounting for herbal raw material weight 5 to 10%, be made with test drug A etc.
The tablet of weight, identical appearance.
Test drug A, control group drug B are subjected to laboratory test：
The meriones unguiculatus 60 of selection adult healthy is only randomly divided into 2 groups, is respectively placed in the cylinder that volume is 0.017 cubic metre
In shape specimen jar, take glass poison bait basin 2, be contained with 2 test drug A, 2 control group drug B respectively, instill a small amount of water with
It is deliquesced conducive to aluminum phosphate, covers cylinder cap, record the The dead quantity of meriones unguiculatus in cylinder at intervals of two minutes.
Test data is as follows：
| Test drug A | Control group drug B | |
| 0 minute | 0 | 0 |
| 2 minutes | 0 | 3 |
| 4 minutes | 1 | 7 |
| 8 minutes | 3 | 12 |
| 10 minutes | 8 | 17 |
| 12 minutes | 11 | 22 |
| 14 minutes | 12 | 24 |
| 16 minutes | 15 | 29 |
| 18 minutes | 19 | 30 |
T inspections, P=0.039432 are carried out to it<0.05, that is, test group has 95% or more possibility to have with control group
The difference of conspicuousness, the i.e. repellent effect of test drug A are better than control drug.Thus it proves, aluminum phosphate expelling mouse agent of the invention
With preferable effect.
The present invention also provides a kind of packaging structures, for being further packed for above-mentioned spheric granules to reach sustained release
Purpose, the packaging structure include：Pvc pipe 2321 is evenly distributed with rat destruction monomer in the pvc pipe 2321（Such as Fig. 1）；Each institute
It includes a spherical aluminum phosphate expelling mouse agent particle 101, a water absorbing resin particle 102, one made of pure Chinese herbal medicine to state rat destruction monomer
Medicine ball 103 with mouse driving function, three arranges in a triangle；The spherical shape aluminum phosphate expelling mouse agent particle 101, water-absorbing resin
Grain 102, the outside of the medicine ball 103 with mouse driving function made of pure Chinese herbal medicine are extruded at least two layers chance water dissolvable paper
12；The outside for meeting water dissolvable paper 12 is equipped with the pressure-resistant ceramic case 13 that through-hole is distributed in surface, through-hole described in surface 2/3
It is blocked by degradation plastic.
As an embodiment of the present invention, through-hole is distributed in the even tube wall of the pvc pipe 2321.
As another embodiment of the present invention, 2321 inner surface of the pvc pipe is equipped with several wedge blocks.
Specifically, the pvc pipe 2321 includes end to end several bellows segments and smooth section, the outer surface light of smooth section
It is sliding, it is recognized to personnel easy to operation.
More specifically, the bellows segment and smooth section mutual conduction.
For the ease of identification, the bellows 262 is different with the surface color of smooth tube.
Such as Fig. 2, in order to realize a further object of the present invention, the present invention also provides a kind of dispensing dresses convenient for Slag recovering
It sets, including：Car body, the car body include a ride 21, four wheels 22 positioned at 21 lower section of ride；Pass through on the ride 21
Mechanical arm 24 is connected with a connecting seat 25；A drill bit 27 is vertically equipped on the connecting seat 25, to punch soil layer；It is described
It is additionally provided with a hopper 26 on connecting seat 25, several bluetooth positioning devices are filled in the hopper 26；The hopper 26 passes through one
Bellows 262 is connected with the end of drill bit 27；Further include a feeding machanism, the feeding machanism includes a motor 231, the electricity
Machine 231 is connected by shaft coupling with an idler wheel 232, and above-mentioned packaging structure is wound on the idler wheel 232；Wherein, the brill
First 27 is hollow, and the pvc pipe 2321 stretches into inside the drill bit 27；Be additionally provided with Bluetooth base. station on the ride 21, to institute
Bluetooth positioning device Bluetooth pairing is stated, and measures its position.
Specifically, the hopper 26 is equipped with the capping 261 that can be opened and closed.
In order to play wear-resisting effect, avoids tube body from being damaged in traction process and specifically adopt the following technical scheme that：Institute
The outer surface for stating pvc pipe 2321 is additionally provided with wear-resistant coating.
Specifically, the mechanical arm 24 is rotatablely connected with ride 21.
Operation principle：This administration device is used for the expelling mouse agent by the present invention in field rat destruction, and vole etc. is avoided to wreak havoc damage
Farmland, operating personnel push this car body, and operating personnel's manually manipulator robot arm 24 launches one section at doubtful vole hole
Pvc pipe 2321, this section of pvc pipe 2321 is interior to contain an at least rat destruction monomer.Operating personnel are cut with scissors from smooth section.
Apart from dispensing in 15 cm ranges, it is embedded to bluetooth positioning device, and measure whether positioned channel is established.Pass through mechanical arm 24
Dispensing reduces labor intensity, avoids unknown danger.Mechanical arm 24 is driven using hydraulic system or servo motor 231 drives
It is dynamic.At regular intervals, staff's cart body enters the field of dispensing, is guided according to positioning signal, with scoop by pvc pipe
2321 dig out, and then achieve the purpose that convenient for Slag recovering.
In conclusion the expelling mouse agent repellent effect of the present invention is good, rat destruction monomer uses delta structure, spherical aluminum phosphate
Expelling mouse agent particle 101 is main rat destruction power, and a water absorbing resin particle 102 is for attracting steam to enter spherical aluminum phosphate rat destruction
Inside agent particle 101, promote its deliquescence；Using the medicine ball 103 with mouse driving function made of pure Chinese herbal medicine, further carry
For the repellent effect of the present invention.The present invention not only has repellent effect, also has certain anthelminthic effect.When meeting water, water is met
It can dissolve paper 12 to dissolve, delta structure be exposed.The expelling mouse agent of the present invention can especially be adopted by using polyethylene glycol
With polyethylene glycol 400, polyethylene glycol, aluminum phosphate, aminoquinoxaline is made to form highly uniform chromic fibrous solid matter, this
Outside, due to further embedding aluminum phosphate powder wherein using cyclodextrin, slow release effect is further promoted, in addition, carboxymethyl is fine
The plain sodium of dimension and starch interaction, further promote slow release effect, avoid aluminum phosphate fast decoupled, and then reach preferable rat destruction
Effect.In addition, if pvc pipe 2321 is under the larger environment of moisture, water absorbing resin particle 102 can also absorb extra water
Point, avoid aluminum phosphate from decomposing too fast.Stability of the present invention is good, and reliability is high, easy for operation, highly practical, novel in design,
It is easy to spread.
In the description of this specification, reference term " one embodiment ", " some embodiments ", " example ", " specifically show
The description of example " or " some examples " etc. means specific features, structure, material or spy described in conjunction with this embodiment or example
Point is included at least one embodiment or example of the invention.In the present specification, schematic expression of the above terms are not
Centainly refer to identical embodiment or example.Moreover, particular features, structures, materials, or characteristics described can be any
One or more embodiments or example in can be combined in any suitable manner.
Although the embodiments of the present invention has been shown and described above, it is to be understood that above-described embodiment is example
Property, it is not considered as limiting the invention, those skilled in the art are not departing from the principle of the present invention and objective
In the case of can make changes, modifications, alterations, and variations to the above described embodiments within the scope of the invention.
Claims (6)
1. a kind of aluminum phosphate expelling mouse agent packaging structure, for further packing spheric granules, wherein the spheric granules is to adopt
With the product obtained by aluminum phosphate expelling mouse agent preparation process, wherein the preparation process of aluminum phosphate expelling mouse agent is：Step A：By red phosphorus and
Aluminium powder in molar ratio 1：4 ignition after evenly mixing, reaction generate aluminum phosphate；Step B：Aluminum phosphate is crushed with pulverizer,
As aluminum phosphate original powder；Step C：By weight, 65 parts of aluminum phosphate original powders are added in reactor, poly- second is added into reactor
6 parts of glycol, 4 parts of aminoquinoxaline stir 3 minutes, and then, 20 DEG C keep the temperature 15 minutes；Step D：Inject 5 parts of magnesium stearate, carboxylic
5 parts of sodium carboxymethylcellulose pyce, 5 parts of starch, 10 parts of cyclodextrin；Stirring 3 minutes；5 DEG C are cooled in 5 minutes；Step E：Step D is obtained
To product spherical aluminum phosphate expelling mouse agent particle is made；Wherein, the formula of aluminum phosphate expelling mouse agent is：By weight, total amount 100
Part, including：Aluminum phosphate original powder, 65 parts；Polyethylene glycol, 6 parts；Aminoquinoxaline, 4 parts；Magnesium stearate, 5 parts；Carboxymethyl cellulose
Plain sodium, 5 parts；Starch, 5 parts；Cyclodextrin, 10 parts；
It is characterised in that it includes：
Pvc pipe is evenly distributed with rat destruction monomer in the pvc pipe；
Each rat destruction monomer includes a spherical aluminum phosphate expelling mouse agent particle, a water absorbing resin particle, one by pure Chinese herbal medicine system
At the medicine ball with mouse driving function, three arranges in a triangle；
The spherical shape aluminum phosphate expelling mouse agent particle, water absorbing resin particle, the medicine ball with mouse driving function made of pure Chinese herbal medicine
Outside be extruded at least two layers chance water dissolvable paper；
The outside for meeting water dissolvable paper is equipped with surface and is distributed with the pressure-resistant ceramic case of through-hole, through-hole described in surface 2/3 by
Degradation plastic blocks.
2. packaging structure according to claim 1, which is characterized in that through-hole is distributed in the even tube wall of the pvc pipe.
3. a kind of administration device convenient for Slag recovering, which is characterized in that including：
Car body, the car body include a ride, four wheels below ride；
A connecting seat is connected with by mechanical arm on the ride；
A drill bit is vertically equipped on the connecting seat, to punch soil layer；
It is additionally provided with a hopper on the connecting seat, several bluetooth positioning devices are filled in the hopper；
The hopper is connected by a bellows with the end of drill bit；
Further include a feeding machanism, the feeding machanism includes a motor, and the motor is connected by shaft coupling with an idler wheel, institute
It states and is wound with packaging structure as claimed in claim 1 or 2 on idler wheel；Wherein, the drill bit is hollow, and the pvc pipe stretches into institute
State drill bit internal；
Be additionally provided with Bluetooth base. station on the ride, to the bluetooth positioning device Bluetooth pairing, and measure its position.
4. the administration device according to claim 3 convenient for Slag recovering, which is characterized in that the hopper is equipped with and can open
With the capping of closure.
5. the administration device according to claim 3 convenient for Slag recovering, which is characterized in that the outer surface of the pvc pipe
It is additionally provided with wear-resistant coating.
6. the administration device according to claim 3 convenient for Slag recovering, which is characterized in that the mechanical arm and ride
Rotation connection.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610315565.8A CN105767002B (en) | 2016-05-16 | 2016-05-16 | Aluminum phosphate expelling mouse agent packaging structure and administration device convenient for Slag recovering |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610315565.8A CN105767002B (en) | 2016-05-16 | 2016-05-16 | Aluminum phosphate expelling mouse agent packaging structure and administration device convenient for Slag recovering |
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| CN105767002A CN105767002A (en) | 2016-07-20 |
| CN105767002B true CN105767002B (en) | 2018-07-27 |
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| CN109601552B (en) * | 2018-12-14 | 2021-06-15 | 武汉东昌仓贮技术有限公司 | Conveniently-treated aluminum phosphide fumigant and package |
| CN114586763B (en) * | 2022-03-25 | 2023-08-29 | 陕西省动物研究所 | Multifunctional drug administration device for preventing and controlling mouse damage |
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