CN105753092A - 一种垂钓水体改良的水体澄清剂 - Google Patents
一种垂钓水体改良的水体澄清剂 Download PDFInfo
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Abstract
本发明公开了一种垂钓水体改良的水体澄清剂，由下列重量份的原料制成：菜籽饼粉1516、鲜橘皮1011、木质素磺酸钙46、酒石酸粉末2.22.5、白磷45、凹凸棒粉34、甘蔗渣2325、葵花盘6265、四氧化三铁粉末1.61.9、0.1mol/L草酸亚铁溶液2832、醋酸溶液适量、水适量；本发明的水体澄清剂通过有机质的加入作为养分使水中的植物生长迅速，提高了水中的溶氧量，还有利于小昆虫类动物生长，大大增加了鱼类的食物来源，配合澄清剂的毒害物质吸附作用，有利于鱼类的生长繁殖，进而将水体优化为优质的垂钓水域。
Description
技术领域
本发明涉及水体改良技术领域，尤其涉及一种垂钓水体改良的水体澄清剂。
背景技术
随着人们生活质量的提高，日常生活中使用到大量的化学化工物品，而其产生的大量废弃物则排入到水体中，与此同时，池塘、水库、湖泊等养殖水体中，因饵料、渔药的大量投入和鱼类排泄物的积累，都导致了水体污染、水质浑浊、观赏度下降。因其产生的污染物远大于水体的自身净化能力，部分污染物逐渐沉积在底泥表层，形成厌氧层，而厌氧层的长期存在，一方面导致水体底泥产生出硫化氢等有毒有害物质，另一方面也会为病原菌的繁殖生长提供有利条件，最终影响到水生动植物的健康。
而现有的水质澄清剂虽然能一时的改善水质，但容易出现反复。具体地如申请号为201010615788.9的中国专利公开了一种水质净化剂，其组分为：电气石5-20重量份、蒙脱石20-60重量份、沸石100-500重量份、糖蜜5-30重量份、磷酸盐0.5-5重量份、色氨酸0.1-1重量份、微生物制剂10-50重量份。其中含有大量的无机矿物质粉末，这些无机矿物质粉末在水体中很难被分解和吸收，多次施用后会在池塘底泥中积累，从而可能产生二次污染。
热解炭由于发达的内部孔隙结构和较大的比表面积，对水中有机污染、重金属、悬浮污染物等具有很强的吸附净化能力，而铁是微生物体内多种酶的组分，是微生物氧化还原反应电子传递体系中一种必不可少的电子载体，使用有机铁填充，能显著提高水体中化学耗氧量、总氮及总磷等的去除效果，强化水处理的效果，因此将有机铁和热解炭结合，在水体改良澄清方面具有广阔的应用前景。
发明内容
本发明目的就是为了弥补已有技术的缺陷，提供一种垂钓水体改良的水体澄清剂。
本发明是通过以下技术方案实现的：
一种垂钓水体改良的水体澄清剂，由下列重量份的原料制成：菜籽饼粉15-16、鲜橘皮10-11、木质素磺酸钙4-6、酒石酸粉末2.2-2.5、白磷4-5、凹凸棒粉3-4、甘蔗渣23-25、葵花盘62-65、四氧化三铁粉末1.6-1.9、0.1mol/L草酸亚铁溶液28-32、醋酸溶液适量、水适量。
所述的垂钓水体改良的水体澄清剂制备方法的具体步骤如下：
（1）将葵花盘置于高温炉中，在420-450℃下密闭加热40-60分钟，取出后将其置于体积分数为2.5-3.0%的醋酸溶液中，完全浸没后保持20-24小时以进行充分的酸氧化，之后用水洗涤至中性，50-55℃下烘干，再将其加入到0.1mol/L的草酸亚铁溶液中，再加入木质素磺酸钙，加热至40-45℃，不断搅拌下反应100-120分钟，之后用水洗涤至中性，在70-80℃下烘干，得有机铁改性炭粉备用；
（2）将菜籽饼粉、鲜橘皮、甘蔗渣混合，同时加热白磷，将混合料用磷烟熏烤10-15分钟后投入发酵池中，补充水分至发酵堆最大含水量的60-65%，发酵3-4周后取发酵物料压榨过滤得酵渣和发酵液备用；
（3）将步骤1所得改性炭粉加入到步骤2所得发酵液中，再加入酒石酸粉末和四氧化三铁粉末，调节PH至5.5-6.0，在530-550W功率下超声混合60-65分钟，过滤后用水冲洗至中性、烘干得磁化改性粉末备用；
（4）将步骤3所得粉末置于125-140W高压汞灯下辐照15-20分钟，再与步骤2所得发酵渣、凹凸棒粉以及其他剩余物料混合造粒，即得本发明水体澄清剂。
本发明的优点是：
通过热解炭作为澄清剂载体，利用有机铁改性以增加产品的表面粗糙度和亲水性，配合超声作用加入四氧化三铁等磁性材料，极大的增强了澄清剂对水体中重金属离子、有机污染物以及悬浮杂物的吸附性，而汞灯的辐照使澄清剂表面氧化并产生极性基团，进一步增强了澄清剂的生物相容性，令本澄清剂能在水体中稳定的、长期的发挥作用，使其具有极强的水体澄清作用，保证水质的清澈。同时本发明的水体澄清剂通过有机质的加入作为养分使水中的植物生长迅速，提高了水中的溶氧量，还有利于小昆虫类动物生长，大大增加了鱼类的食物来源，配合澄清剂的毒害物质吸附作用，有利于鱼类的生长繁殖，进而将水体优化为优质的垂钓水域。
具体实施方式
一种垂钓水体改良的水体澄清剂，由下列重量份（kg）的原料制成：菜籽饼粉15、鲜橘皮10、木质素磺酸钙4、酒石酸粉末2.2、白磷4、凹凸棒粉3、甘蔗渣23、葵花盘62、四氧化三铁粉末1.6、0.1mol/L草酸亚铁溶液28、醋酸溶液适量、水适量。
所述的垂钓水体改良的水体澄清剂制备方法的具体步骤如下：
（1）将葵花盘置于高温炉中，在420℃下密闭加热40分钟，取出后将其置于体积分数为2.5%的醋酸溶液中，完全浸没后保持20小时以进行充分的酸氧化，之后用水洗涤至中性，50℃下烘干，再将其加入到0.1mol/L的草酸亚铁溶液中，再加入木质素磺酸钙，加热至40℃，不断搅拌下反应100分钟，之后用水洗涤至中性，在70℃下烘干，得有机铁改性炭粉备用；
（2）将菜籽饼粉、鲜橘皮、甘蔗渣混合，同时加热白磷，将混合料用磷烟熏烤10分钟后投入发酵池中，补充水分至发酵堆最大含水量的60%，发酵3周后取发酵物料压榨过滤得酵渣和发酵液备用；
（3）将步骤1所得改性炭粉加入到步骤2所得发酵液中，再加入酒石酸粉末和四氧化三铁粉末，调节PH至5.5，在530W功率下超声混合60分钟，过滤后用水冲洗至中性、烘干得磁化改性粉末备用；
（4）将步骤3所得粉末置于125W高压汞灯下辐照15分钟，再与步骤2所得发酵渣、凹凸棒粉以及其他剩余物料混合造粒，即得本发明水体澄清剂。
为了进一步说明本发明的应用价值，发明人选取两块条件相同且两年内未清洁的养殖鱼塘作为供试对象，其中一块使用本发明澄清剂作为实验组，另一块使用市售普通水体改良剂作为对照组，使用2个月后，实验组鱼塘较对照组可见度明显提高，水体中悬浮颗粒减少，6个月后取鱼塘底泥检测，其中有机污染和重金属残留分别较对照组降低了36%和72%，实验组塘中鱼虾活力较高，可见本发明水体澄清剂具有较好的实际使用效果。
Claims (2)
1.一种垂钓水体改良的水体澄清剂，其特征在于，由下列重量份的原料制成：菜籽饼粉15-16、鲜橘皮10-11、木质素磺酸钙4-6、酒石酸粉末2.2-2.5、白磷4-5、凹凸棒粉3-4、甘蔗渣23-25、葵花盘62-65、四氧化三铁粉末1.6-1.9、0.1mol/L草酸亚铁溶液28-32、醋酸溶液适量、水适量。
2. 根据权利要求书1所述的垂钓水体改良的水体澄清剂，其特征在于，制备方法的具体步骤如下：
（1）将葵花盘置于高温炉中，在420-450℃下密闭加热40-60分钟，取出后将其置于体积分数为2.5-3.0%的醋酸溶液中，完全浸没后保持20-24小时以进行充分的酸氧化，之后用水洗涤至中性，50-55℃下烘干，再将其加入到0.1mol/L的草酸亚铁溶液中，再加入木质素磺酸钙，加热至40-45℃，不断搅拌下反应100-120分钟，之后用水洗涤至中性，在70-80℃下烘干，得有机铁改性炭粉备用；
（2）将菜籽饼粉、鲜橘皮、甘蔗渣混合，同时加热白磷，将混合料用磷烟熏烤10-15分钟后投入发酵池中，补充水分至发酵堆最大含水量的60-65%，发酵3-4周后取发酵物料压榨过滤得酵渣和发酵液备用；
（3）将步骤1所得改性炭粉加入到步骤2所得发酵液中，再加入酒石酸粉末和四氧化三铁粉末，调节PH至5.5-6.0，在530-550W功率下超声混合60-65分钟，过滤后用水冲洗至中性、烘干得磁化改性粉末备用；
（4）将步骤3所得粉末置于125-140W高压汞灯下辐照15-20分钟，再与步骤2所得发酵渣、凹凸棒粉以及其他剩余物料混合造粒，即得本发明水体澄清剂。
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