CN105731471A - 一种MoSi2-Mo5Si3-SiO2复合材料的制备方法 - Google Patents
一种MoSi2-Mo5Si3-SiO2复合材料的制备方法 Download PDFInfo
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- CN105731471A CN105731471A CN201610059960.4A CN201610059960A CN105731471A CN 105731471 A CN105731471 A CN 105731471A CN 201610059960 A CN201610059960 A CN 201610059960A CN 105731471 A CN105731471 A CN 105731471A
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 59
- 239000002131 composite material Substances 0.000 title claims abstract description 50
- 239000000377 silicon dioxide Substances 0.000 title claims abstract description 47
- 229910052681 coesite Inorganic materials 0.000 title claims abstract description 41
- 229910052906 cristobalite Inorganic materials 0.000 title claims abstract description 41
- 229910052682 stishovite Inorganic materials 0.000 title claims abstract description 41
- 229910052905 tridymite Inorganic materials 0.000 title claims abstract description 41
- 238000002360 preparation method Methods 0.000 title claims abstract description 23
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims abstract description 20
- 238000010438 heat treatment Methods 0.000 claims abstract description 19
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims abstract description 18
- 238000001027 hydrothermal synthesis Methods 0.000 claims abstract description 17
- 238000000034 method Methods 0.000 claims abstract description 17
- 229910052786 argon Inorganic materials 0.000 claims abstract description 9
- 229910016006 MoSi Inorganic materials 0.000 claims description 21
- 239000011259 mixed solution Substances 0.000 claims description 18
- 238000013019 agitation Methods 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 8
- 238000001914 filtration Methods 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 8
- 238000012856 packing Methods 0.000 claims description 8
- 238000001556 precipitation Methods 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 235000012239 silicon dioxide Nutrition 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 229910052721 tungsten Inorganic materials 0.000 claims description 3
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 abstract description 8
- 239000002245 particle Substances 0.000 abstract description 4
- 230000001788 irregular Effects 0.000 abstract description 3
- 230000003647 oxidation Effects 0.000 abstract description 3
- 238000007254 oxidation reaction Methods 0.000 abstract description 3
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 abstract description 2
- 239000008103 glucose Substances 0.000 abstract description 2
- 238000002156 mixing Methods 0.000 abstract description 2
- 238000004220 aggregation Methods 0.000 abstract 1
- 230000002776 aggregation Effects 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 230000001681 protective effect Effects 0.000 abstract 1
- 239000002994 raw material Substances 0.000 abstract 1
- 229910015503 Mo5Si3 Inorganic materials 0.000 description 13
- 239000000463 material Substances 0.000 description 12
- 238000001291 vacuum drying Methods 0.000 description 12
- 229910020968 MoSi2 Inorganic materials 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 10
- 239000000843 powder Substances 0.000 description 6
- 239000002244 precipitate Substances 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 4
- 230000003026 anti-oxygenic effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229910000765 intermetallic Inorganic materials 0.000 description 3
- 229910052750 molybdenum Inorganic materials 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 238000005049 combustion synthesis Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005485 electric heating Methods 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 238000005216 hydrothermal crystallization Methods 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum oxide Inorganic materials [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000009768 microwave sintering Methods 0.000 description 1
- 239000005078 molybdenum compound Substances 0.000 description 1
- GALOTNBSUVEISR-UHFFFAOYSA-N molybdenum;silicon Chemical class [Mo]#[Si] GALOTNBSUVEISR-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/113—Silicon oxides; Hydrates thereof
- C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
- C01B33/18—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/06—Metal silicides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Silicon Compounds (AREA)
Abstract
Description
Claims (7)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201610059960.4A CN105731471B (zh) | 2016-01-28 | 2016-01-28 | 一种MoSi2‑Mo5Si3‑SiO2复合材料的制备方法 |
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CN201610059960.4A CN105731471B (zh) | 2016-01-28 | 2016-01-28 | 一种MoSi2‑Mo5Si3‑SiO2复合材料的制备方法 |
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CN105731471A true CN105731471A (zh) | 2016-07-06 |
CN105731471B CN105731471B (zh) | 2017-12-05 |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105669207A (zh) * | 2016-01-28 | 2016-06-15 | 陕西科技大学 | 一种SiC-Mo4.8Si3C0.6复合材料的制备方法 |
CN108975918A (zh) * | 2018-08-13 | 2018-12-11 | 四川大学 | 一种高韧性高温结构材料MoSi2-Mo5Si3复合陶瓷的制备 |
CN115321541A (zh) * | 2022-07-27 | 2022-11-11 | 南昌航空大学 | 一种MoSi2@Nb核壳结构材料及其制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5472487A (en) * | 1991-01-18 | 1995-12-05 | United Technologies Corporation | Molybdenum disilicide based materials with reduced coefficients of thermal expansion |
JP2002020160A (ja) * | 2000-06-30 | 2002-01-23 | Isuzu Ceramics Res Inst Co Ltd | 耐摩耗性セラミツクス複合材料とその製造方法 |
CN1344810A (zh) * | 2001-09-26 | 2002-04-17 | 北京科技大学 | 一种制备碳化硅颗粒增强二硅化钼基复合材料的原位复合方法 |
-
2016
- 2016-01-28 CN CN201610059960.4A patent/CN105731471B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5472487A (en) * | 1991-01-18 | 1995-12-05 | United Technologies Corporation | Molybdenum disilicide based materials with reduced coefficients of thermal expansion |
JP2002020160A (ja) * | 2000-06-30 | 2002-01-23 | Isuzu Ceramics Res Inst Co Ltd | 耐摩耗性セラミツクス複合材料とその製造方法 |
CN1344810A (zh) * | 2001-09-26 | 2002-04-17 | 北京科技大学 | 一种制备碳化硅颗粒增强二硅化钼基复合材料的原位复合方法 |
Non-Patent Citations (2)
Title |
---|
A. MISRA,ET AL.: "Microstructures and mechanical properties of a Mo3Si-Mo5Si3 composite", 《SCRIPTA MATERIALIA》 * |
王 博,等: "水热温度对SiC–C/C 复合材料表面水热电泳沉积SiCn–MoSi2复合抗氧化涂层的影响", 《硅酸盐学报》 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105669207A (zh) * | 2016-01-28 | 2016-06-15 | 陕西科技大学 | 一种SiC-Mo4.8Si3C0.6复合材料的制备方法 |
CN108975918A (zh) * | 2018-08-13 | 2018-12-11 | 四川大学 | 一种高韧性高温结构材料MoSi2-Mo5Si3复合陶瓷的制备 |
CN115321541A (zh) * | 2022-07-27 | 2022-11-11 | 南昌航空大学 | 一种MoSi2@Nb核壳结构材料及其制备方法 |
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CN105731471B (zh) | 2017-12-05 |
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Effective date of registration: 20240714 Address after: 710300 No. 15, Zhenxing North Road, Fengjing Industrial Park, Fuyi District, Xi'an City, Shaanxi Province Patentee after: Xi'an Gangyou New Materials Technology Co.,Ltd. Country or region after: China Address before: 233400 building 111, No.8, pedestrian street, middle section of Yuwang Road, Huaiyuan County, Bengbu City, Anhui Province Patentee before: Huaiyuan Hanbang Technology Consulting Co.,Ltd. Country or region before: China |