CN105714550B - 一种高效环保棉织物用精炼剂及其制备方法 - Google Patents

一种高效环保棉织物用精炼剂及其制备方法 Download PDF

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CN105714550B
CN105714550B CN201610108980.6A CN201610108980A CN105714550B CN 105714550 B CN105714550 B CN 105714550B CN 201610108980 A CN201610108980 A CN 201610108980A CN 105714550 B CN105714550 B CN 105714550B
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周继东
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DONGGUAN DASEN WEAVING MATERIAL Co.,Ltd.
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Abstract

本发明公开了一种高效环保棉织物用精炼剂，以重量份计，包括以下组分：纳米茶皂素10‑20份，烷基糖苷5‑8份，氯化钙6‑10份，壳聚糖3‑7份，纤维素酶8‑15份，果胶酶6‑12份，松香4‑8份，紫苏4‑7份，柠檬酸钠2‑6份，氨水1‑3份，硅藻土1.5‑3份，乳化剂2‑5份，失水山梨醇聚氧乙烯醚单月桂酸酯3.5‑6份，分散剂1‑3份，消泡剂1.5‑2份，去离子水20‑30份。本发明还公开了该高效环保棉织物用精炼剂的制备方法。该精炼剂渗透性好，乳化力强，去污力高，耐高温、耐酸碱，生物降解性好，处理后的织物强力不下降，手感柔软舒适。且制备条件温和生产成本低。

Description

一种高效环保棉织物用精炼剂及其制备方法
技术领域：
本发明涉及纺织助剂领域，具体的涉及一种高效环保棉织物用精炼剂。
背景技术：
用化学和物理方法去除棉、毛、麻、蚕丝以及合成纤维等各类纺织品上的天然杂质、沾污物以及织造浆料的工艺过程叫精炼。精炼剂是一种对布料进行印染前处理常用的助剂，最初棉纤维中含有果胶质、蜡质、蛋白质以及色素等，对织物的形状及印染工艺产生影响，不利于加工和使用，因此人们往往对果胶质、棉脂、棉蜡等杂质的煮炼、漂白等方式对织物进行前精炼处理。随着各种纺织材料的出现，各种针对其具体功能的前处理剂也不断涌现。为提高效率，提高处理效果，适应现代化的大规模生产，各种专用精炼不断出现。
随着全球低碳经济及环境保护的高度重视，纺织印染企业的传统前处理工艺受到很大的挑战，传统的棉织物前处理工艺包括退浆、煮炼、漂白等多道工序，工艺流程长，能源消耗大、排污较严重，生产效率低、产品质量差等问题。为应对全球绿色壁垒及环保节能的需要，传统的纺织前处理工艺逐步被短流程退煮漂一步法新工艺所替代，因此，开发环保、高效、节能的纺织前处理精炼剂显得十分重要。
中国专利(201110317707.1)公开了一种纳米茶皂素环保高效精炼剂，以重量百分比计，包括：纳米茶皂素7-15％，仲烷基磺酸钠7-12％、C12-14烷基多苷7-12％、异构C13醇聚氧乙烯醚7-12％，羧甲基纤维素1-5％，螯合分散剂HW-5080.1-2％，4A沸石1-6％，碳酸钠3-8％，消泡剂0.1-1％，余量为离子水。该精炼剂可有效解决利用纳米茶皂素制备纺织前处理的精炼问题，用途广，高效、环保、节能，但是其对织物会有一定的损害，处理后的织物手感发硬。
发明内容：
本发明的目的是提供一种高效环保棉织物用精炼剂，其渗透性好，乳化力强，去污力高，耐高温、耐酸碱，生物降解性好，处理后的织物强力不下降，手感柔软舒适。
本发明的另一个目的是提供该高效环保棉织物用精炼剂的制备方法。
为实现上述目的，本发明采用以下技术方案：
一种高效环保棉织物用精炼剂，以重量份计，包括以下组分：
纳米茶皂素10-20份，烷基糖苷5-8份，
氯化钙6-10份，壳聚糖3-7份，
纤维素酶8-15份，果胶酶6-12份，
松香4-8份，紫苏4-7份，
柠檬酸钠2-6份，氨水1-3份，
硅藻土1.5-3份，乳化剂2-5份，
失水山梨醇聚氧乙烯醚单月桂酸酯3.5-6份，
分散剂1-3份，消泡剂1.5-2份，去离子水20-30份。
作为上述技术方案的优选，一种高效环保棉织物用精炼剂，以重量份计，包括以下组分：
纳米茶皂素20份，烷基糖苷8份，
氯化钙10份，壳聚糖6份，
纤维素酶13份，果胶酶10份，
松香6份，紫苏5份，
柠檬酸钠5份，氨水2份，
硅藻土3份，乳化剂5份，
失水山梨醇聚氧乙烯醚单月桂酸酯6份，
分散剂1份，消泡剂1.5份，去离子水30份。
作为上述技术方案的优选，所述硅藻土的粒径大小为30-50nm。
作为上述技术方案的优选，所述乳化剂为芥酸甲酯、油酸二乙醇酰胺、C15-20直链烷基脂肪醇磷酸酯中的一种或多种混合。
作为上述技术方案的优选，所述分散剂为螯合分散剂HW-508、α-烯基磺酸钠中的一种。
一种高效环保棉织物用精炼剂的制备方法，包括以下步骤：
(1)将氯化钙、壳聚糖、纤维素酶、果胶酶和去离子水混合搅拌均匀，得到混合溶液；
(2)将松香、紫苏、失水山梨醇聚氧乙烯醚单月桂酸酯和去离子水混合搅拌均匀，升温至50-60℃，继续加入纳米茶皂素、乳化剂，混合均匀后转移至高压釜中，升温至90-100℃，恒温1-3h，冷却至室温，得到混合乳液；
(3)向步骤(2)得到的混合乳液中加入硅藻土、分散剂和消泡剂，超声1-3h，加入步骤(1)得到的混合溶液、烷基糖苷、柠檬酸钠，搅拌混合均匀，加入氨水调节pH，得到高效环保棉织物用精炼剂。
作为上述技术方案的优选，步骤(3)中所述超声的条件为：超声功率：1000W，超声时间：3h。
本发明具有以下有益效果：
本发明制备的棉织物精炼剂可以有效去除棉织物上的天然杂质、沾污物以及织造浆料，且其具有一定的生物降解性，对环境和人体无害，该精炼剂处理后的织物纤维强力大，柔软性好，耐酸碱性能优异，且其制备方法简单，生产成本低。
具体实施方式：
为了更好的理解本发明，下面通过实施例对本发明进一步说明，实施例只用于解释本发明，不会对本发明构成任何的限定。
实施例1
一种高效环保棉织物用精炼剂，以重量份计，包括以下组分：
纳米茶皂素10份，烷基糖苷5份，
氯化钙6份，壳聚糖3份，
纤维素酶8份，果胶酶6份，
松香4份，紫苏4份，
柠檬酸钠2份，氨水1份，
硅藻土1.5份，乳化剂2份，
失水山梨醇聚氧乙烯醚单月桂酸酯3.5份，
分散剂1份，消泡剂1.5份，去离子水20份。
其制备方法包括以下步骤：
(1)将氯化钙、壳聚糖、纤维素酶、果胶酶和去离子水混合搅拌均匀，得到混合溶液；
(2)将松香、紫苏、失水山梨醇聚氧乙烯醚单月桂酸酯和去离子水混合搅拌均匀，升温至50℃，继续加入纳米茶皂素、乳化剂，混合均匀后转移至高压釜中，升温至90℃，恒温1h，冷却至室温，得到混合乳液；
(3)向步骤(2)得到的混合乳液中加入硅藻土、分散剂和消泡剂，超声1h，加入步骤(1)得到的混合溶液、烷基糖苷、柠檬酸钠，搅拌混合均匀，加入氨水调节pH，得到高效环保棉织物用精炼剂。
实施例2
一种高效环保棉织物用精炼剂，以重量份计，包括以下组分：
纳米茶皂素20份，烷基糖苷8份，
氯化钙10份，壳聚糖7份，
纤维素酶15份，果胶酶12份，
松香8份，紫苏7份，
柠檬酸钠6份，氨水3份，
硅藻土3份，乳化剂5份，
失水山梨醇聚氧乙烯醚单月桂酸酯6份，
分散剂3份，消泡剂2份，去离子水30份。
其制备方法包括以下步骤：
(1)将氯化钙、壳聚糖、纤维素酶、果胶酶和去离子水混合搅拌均匀，得到混合溶液；
(2)将松香、紫苏、失水山梨醇聚氧乙烯醚单月桂酸酯和去离子水混合搅拌均匀，升温至60℃，继续加入纳米茶皂素、乳化剂，混合均匀后转移至高压釜中，升温至100℃，恒温3h，冷却至室温，得到混合乳液；
(3)向步骤(2)得到的混合乳液中加入硅藻土、分散剂和消泡剂，超声3h，加入步骤(1)得到的混合溶液、烷基糖苷、柠檬酸钠，搅拌混合均匀，加入氨水调节pH，得到高效环保棉织物用精炼剂。
实施例3
一种高效环保棉织物用精炼剂，以重量份计，包括以下组分：
纳米茶皂素20份，烷基糖苷8份，
氯化钙10份，壳聚糖6份，
纤维素酶13份，果胶酶10份，
松香6份，紫苏5份，
柠檬酸钠5份，氨水2份，
硅藻土3份，乳化剂5份，
失水山梨醇聚氧乙烯醚单月桂酸酯6份，
分散剂1份，消泡剂1.5份，去离子水30份。
其制备方法包括以下步骤：
(1)将氯化钙、壳聚糖、纤维素酶、果胶酶和去离子水混合搅拌均匀，得到混合溶液；
(2)将松香、紫苏、失水山梨醇聚氧乙烯醚单月桂酸酯和去离子水混合搅拌均匀，升温至55℃，继续加入纳米茶皂素、乳化剂，混合均匀后转移至高压釜中，升温至95℃，恒温1.5h，冷却至室温，得到混合乳液；
(3)向步骤(2)得到的混合乳液中加入硅藻土、分散剂和消泡剂，超声1.5h，加入步骤(1)得到的混合溶液、烷基糖苷、柠檬酸钠，搅拌混合均匀，加入氨水调节pH，得到高效环保棉织物用精炼剂。
实施例4
一种高效环保棉织物用精炼剂，以重量份计，包括以下组分：
纳米茶皂素12份，烷基糖苷6份，
氯化钙7份，壳聚糖4份，
纤维素酶10份，果胶酶8份，
松香5份，紫苏5份，
柠檬酸钠3份，氨水1.5份，
硅藻土2份，乳化剂3份，
失水山梨醇聚氧乙烯醚单月桂酸酯4份，
分散剂1.5份，消泡剂1.6份，去离子水22份。
其制备方法包括以下步骤：
(1)将氯化钙、壳聚糖、纤维素酶、果胶酶和去离子水混合搅拌均匀，得到混合溶液；
(2)将松香、紫苏、失水山梨醇聚氧乙烯醚单月桂酸酯和去离子水混合搅拌均匀，升温至50℃，继续加入纳米茶皂素、乳化剂，混合均匀后转移至高压釜中，升温至90℃，恒温1.8h，冷却至室温，得到混合乳液；
(3)向步骤(2)得到的混合乳液中加入硅藻土、分散剂和消泡剂，超声2h，加入步骤(1)得到的混合溶液、烷基糖苷、柠檬酸钠，搅拌混合均匀，加入氨水调节pH，得到高效环保棉织物用精炼剂。
实施例5
一种高效环保棉织物用精炼剂，以重量份计，包括以下组分：
纳米茶皂素14份，烷基糖苷7份，
氯化钙8份，壳聚糖5份，
纤维素酶12份，果胶酶10份，
松香6份，紫苏6份，
柠檬酸钠4份，氨水2份，
硅藻土2份，乳化剂4份，
失水山梨醇聚氧乙烯醚单月桂酸酯5份，
分散剂2份，消泡剂1.7份，去离子水24份。
其制备方法包括以下步骤：
(1)将氯化钙、壳聚糖、纤维素酶、果胶酶和去离子水混合搅拌均匀，得到混合溶液；
(2)将松香、紫苏、失水山梨醇聚氧乙烯醚单月桂酸酯和去离子水混合搅拌均匀，升温至60℃，继续加入纳米茶皂素、乳化剂，混合均匀后转移至高压釜中，升温至100℃，恒温2h，冷却至室温，得到混合乳液；
(3)向步骤(2)得到的混合乳液中加入硅藻土、分散剂和消泡剂，超声2.5h，加入步骤(1)得到的混合溶液、烷基糖苷、柠檬酸钠，搅拌混合均匀，加入氨水调节pH，得到高效环保棉织物用精炼剂。
实施例6
一种高效环保棉织物用精炼剂，以重量份计，包括以下组分：
纳米茶皂素16份，烷基糖苷7.5份，
氯化钙9份，壳聚糖6份，
纤维素酶13份，果胶酶11份，
松香7份，紫苏6.5份，
柠檬酸钠5份，氨水2.5份，
硅藻土2.5份，乳化剂4.5份，
失水山梨醇聚氧乙烯醚单月桂酸酯5.5份，
分散剂2.5份，消泡剂1.8份，去离子水28份。
其制备方法包括以下步骤：
(1)将氯化钙、壳聚糖、纤维素酶、果胶酶和去离子水混合搅拌均匀，得到混合溶液；
(2)将松香、紫苏、失水山梨醇聚氧乙烯醚单月桂酸酯和去离子水混合搅拌均匀，升温至60℃，继续加入纳米茶皂素、乳化剂，混合均匀后转移至高压釜中，升温至100℃，恒温2.5h，冷却至室温，得到混合乳液；
(3)向步骤(2)得到的混合乳液中加入硅藻土、分散剂和消泡剂，超声2.8h，加入步骤(1)得到的混合溶液、烷基糖苷、柠檬酸钠，搅拌混合均匀，加入氨水调节pH，得到高效环保棉织物用精炼剂。

Claims (4)

1.一种高效环保棉织物用精炼剂，其特征在于，以重量份计，包括以下组分：
纳米茶皂素10-20份，烷基糖苷5-8份，
氯化钙6-10份，壳聚糖3-7份，
纤维素酶8-15份，果胶酶6-12份，
松香4-8份，紫苏4-7份，
柠檬酸钠2-6份，氨水1-3份，
硅藻土1.5-3份，乳化剂2-5份，
失水山梨醇聚氧乙烯醚单月桂酸酯3.5-6份，
分散剂1-3份，消泡剂1.5-2份，去离子水20-30份；
其中，所述硅藻土的粒径大小为30-50nm；
所述分散剂为螯合分散剂HW-508、α-烯基磺酸钠中的一种；
其制备方法包括以下步骤：
(1)将氯化钙、壳聚糖、纤维素酶、果胶酶和去离子水混合搅拌均匀，得到混合溶液；
(2)将松香、紫苏、失水山梨醇聚氧乙烯醚单月桂酸酯和去离子水混合搅拌均匀，升温至50-60℃，继续加入纳米茶皂素、乳化剂，混合均匀后转移至高压釜中，升温至90-100℃，恒温1-3h，冷却至室温，得到混合乳液；
(3)向步骤(2)得到的混合乳液中加入硅藻土、分散剂和消泡剂，超声1-3h，加入步骤(1)得到的混合溶液、烷基糖苷、柠檬酸钠，搅拌混合均匀，加入氨水调节pH，得到高效环保棉织物用精炼剂。
2.如权利要求1所述的一种高效环保棉织物用精炼剂，其特征在于，以重量份计，包括以下组分：
纳米茶皂素20份，烷基糖苷8份，
氯化钙10份，壳聚糖6份，
纤维素酶13份，果胶酶10份，
松香6份，紫苏5份，
柠檬酸钠5份，氨水2份，
硅藻土3份，乳化剂5份，
失水山梨醇聚氧乙烯醚单月桂酸酯6份，
分散剂1份，消泡剂1.5份，去离子水30份。
3.如权利要求1所述的一种高效环保棉织物用精炼剂，其特征在于，所述乳化剂为芥酸甲酯、油酸二乙醇酰胺、C15-20直链烷基脂肪醇磷酸酯中的一种或多种混合。
4.如权利要求1所述的一种高效环保棉织物用精炼剂，其特征在于，步骤(3)中所述超声的条件为：超声功率：1000W，超声时间：3h。
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CN103498337A (zh) * 2013-09-17 2014-01-08 安阳博奥生物新合成有限公司 一种环保型精练剂的应用
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CN103498337A (zh) * 2013-09-17 2014-01-08 安阳博奥生物新合成有限公司 一种环保型精练剂的应用
CN104099788A (zh) * 2014-07-04 2014-10-15 无锡市信达染整机械厂 环境友好的棉织物染色工艺
CN104313886A (zh) * 2014-10-20 2015-01-28 苏州富美纺织科技有限公司 织物精练剂

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