CN105645402B - 一种三维石墨烯宏观体及其制备方法 - Google Patents
一种三维石墨烯宏观体及其制备方法 Download PDFInfo
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- CN105645402B CN105645402B CN201610172262.5A CN201610172262A CN105645402B CN 105645402 B CN105645402 B CN 105645402B CN 201610172262 A CN201610172262 A CN 201610172262A CN 105645402 B CN105645402 B CN 105645402B
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- 238000006243 chemical reaction Methods 0.000 claims abstract description 42
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- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 30
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- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 34
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 26
- 229910002804 graphite Inorganic materials 0.000 claims description 20
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- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 12
- HVBSAKJJOYLTQU-UHFFFAOYSA-N 4-aminobenzenesulfonic acid Chemical compound NC1=CC=C(S(O)(=O)=O)C=C1 HVBSAKJJOYLTQU-UHFFFAOYSA-N 0.000 claims description 9
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 claims description 9
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- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 claims description 8
- 229910052760 oxygen Inorganic materials 0.000 claims description 7
- 239000001301 oxygen Substances 0.000 claims description 7
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 6
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- 150000001336 alkenes Chemical class 0.000 claims description 5
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 4
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- 239000008103 glucose Substances 0.000 claims description 4
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- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 3
- 239000011668 ascorbic acid Substances 0.000 claims description 3
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- 229960005070 ascorbic acid Drugs 0.000 claims description 3
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- 235000010413 sodium alginate Nutrition 0.000 claims description 3
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- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 239000008367 deionised water Substances 0.000 description 6
- 229910021641 deionized water Inorganic materials 0.000 description 6
- 241000446313 Lamella Species 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- 239000005864 Sulphur Substances 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 239000003153 chemical reaction reagent Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- -1 sulfonic acid graphite Alkene Chemical class 0.000 description 4
- 239000003643 water by type Substances 0.000 description 4
- 238000005229 chemical vapour deposition Methods 0.000 description 3
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- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 229910001626 barium chloride Inorganic materials 0.000 description 2
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- 239000011229 interlayer Substances 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 239000012286 potassium permanganate Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000013049 sediment Substances 0.000 description 2
- 238000001338 self-assembly Methods 0.000 description 2
- 239000012279 sodium borohydride Substances 0.000 description 2
- 229910000033 sodium borohydride Inorganic materials 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Inorganic materials [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 230000010148 water-pollination Effects 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 229910002567 K2S2O8 Inorganic materials 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
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- 239000000908 ammonium hydroxide Substances 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
- 229940092714 benzenesulfonic acid Drugs 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
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- 238000004519 manufacturing process Methods 0.000 description 1
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- 238000012986 modification Methods 0.000 description 1
- ZAOCWQZQPKGTRN-UHFFFAOYSA-N nitrous acid;sodium Chemical compound [Na].ON=O ZAOCWQZQPKGTRN-UHFFFAOYSA-N 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical group 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/30—Particle morphology extending in three dimensions
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- Carbon And Carbon Compounds (AREA)
Abstract
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Families Citing this family (3)
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CN107673343A (zh) * | 2016-08-02 | 2018-02-09 | 福建新峰二维材料科技有限公司 | 一种石墨烯纳米材料的制备方法 |
CN106848246A (zh) * | 2017-03-01 | 2017-06-13 | 辽宁大学 | 一种三维结构TiO2/石墨烯气凝胶复合物及其制备方法和应用 |
CN113777195B (zh) * | 2021-09-09 | 2023-10-31 | 公安部物证鉴定中心 | 环境水样中苯丙胺类毒品的分析方法及其专用石墨烯基三维宏观体材料和固相萃取装置 |
Citations (10)
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CN101691204A (zh) * | 2009-08-13 | 2010-04-07 | 苏州纳米技术与纳米仿生研究所 | 生理条件下稳定的纳米氧化石墨烯及其制备方法 |
CN101993056A (zh) * | 2010-12-01 | 2011-03-30 | 天津大学 | 基于石墨烯的多孔宏观体碳材料及其制备方法 |
CN102244250A (zh) * | 2011-06-14 | 2011-11-16 | 清华大学深圳研究生院 | 石墨烯宏观体/氧化锡复合锂离子电池负极材料及其工艺 |
CN102718210A (zh) * | 2012-07-03 | 2012-10-10 | 新疆大学 | 氧化石墨烯三维自组装气凝胶的制备方法及应用 |
CN102721727A (zh) * | 2012-07-05 | 2012-10-10 | 济南大学 | 基于分子印迹的电化学传感器、其制备方法和用途 |
CN102735728A (zh) * | 2012-07-05 | 2012-10-17 | 济南大学 | 一种电化学免疫传感器、其制备方法及其用途 |
CN103538312A (zh) * | 2013-09-10 | 2014-01-29 | 浙江工业大学 | 一种交替层状氧化石墨烯/聚乙烯醇介电材料及其制备方法 |
CN103606662A (zh) * | 2013-11-12 | 2014-02-26 | 上海交通大学 | 三维石墨烯基二氧化锡复合材料的制备方法及其应用 |
CN103626159A (zh) * | 2012-08-24 | 2014-03-12 | 海洋王照明科技股份有限公司 | 一种磺酸化石墨烯材料及其制备方法和温度感应开关 |
CN103682349A (zh) * | 2013-12-20 | 2014-03-26 | 复旦大学 | 一种免添加剂的磺酸化石墨烯/硫电极片及其制备方法和应用 |
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2016
- 2016-03-24 CN CN201610172262.5A patent/CN105645402B/zh active Active
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101691204A (zh) * | 2009-08-13 | 2010-04-07 | 苏州纳米技术与纳米仿生研究所 | 生理条件下稳定的纳米氧化石墨烯及其制备方法 |
CN101993056A (zh) * | 2010-12-01 | 2011-03-30 | 天津大学 | 基于石墨烯的多孔宏观体碳材料及其制备方法 |
CN102244250A (zh) * | 2011-06-14 | 2011-11-16 | 清华大学深圳研究生院 | 石墨烯宏观体/氧化锡复合锂离子电池负极材料及其工艺 |
CN102718210A (zh) * | 2012-07-03 | 2012-10-10 | 新疆大学 | 氧化石墨烯三维自组装气凝胶的制备方法及应用 |
CN102721727A (zh) * | 2012-07-05 | 2012-10-10 | 济南大学 | 基于分子印迹的电化学传感器、其制备方法和用途 |
CN102735728A (zh) * | 2012-07-05 | 2012-10-17 | 济南大学 | 一种电化学免疫传感器、其制备方法及其用途 |
CN103626159A (zh) * | 2012-08-24 | 2014-03-12 | 海洋王照明科技股份有限公司 | 一种磺酸化石墨烯材料及其制备方法和温度感应开关 |
CN103538312A (zh) * | 2013-09-10 | 2014-01-29 | 浙江工业大学 | 一种交替层状氧化石墨烯/聚乙烯醇介电材料及其制备方法 |
CN103606662A (zh) * | 2013-11-12 | 2014-02-26 | 上海交通大学 | 三维石墨烯基二氧化锡复合材料的制备方法及其应用 |
CN103682349A (zh) * | 2013-12-20 | 2014-03-26 | 复旦大学 | 一种免添加剂的磺酸化石墨烯/硫电极片及其制备方法和应用 |
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Effective date of registration: 20240428 Address after: 315201 No. 1818, Zhong Guan Xi Road, Zhuang City Street, Zhenhai District, Ningbo, Zhejiang. Patentee after: NINGBO GRAPHENE INNOVATION CENTER Co.,Ltd. Country or region after: China Address before: 315201 No. 1219 Zhongguan West Road, Zhenhai District, Ningbo City, Zhejiang Province Patentee before: NINGBO INSTITUTE OF MATERIALS TECHNOLOGY & ENGINEERING, CHINESE ACADEMY OF SCIENCES Country or region before: China |