CN105641850A - Fire extinguishing agent - Google Patents
Fire extinguishing agent Download PDFInfo
- Publication number
- CN105641850A CN105641850A CN201610232634.9A CN201610232634A CN105641850A CN 105641850 A CN105641850 A CN 105641850A CN 201610232634 A CN201610232634 A CN 201610232634A CN 105641850 A CN105641850 A CN 105641850A
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- CN
- China
- Prior art keywords
- carbonate
- nitrate
- bicarbonate
- extinguishing chemical
- ammonium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/06—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires containing gas-producing, chemically-reactive components
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/0028—Liquid extinguishing substances
- A62D1/0035—Aqueous solutions
- A62D1/0042—"Wet" water, i.e. containing surfactant
Abstract
The invention discloses a fire extinguishing agent which consists of the following components in percentage by weight: 5-40% of at least three kinds of salt containing carbonate, bicarbonate, ammonium, nitrate or nitrite, 5-20% of phosphate, 3-15% of active agent and the balance of water. In the invention, with the components such as at least three or more kinds of salt containing carbonate, bicarbonate, ammonium, nitrate or nitrite, polyphosphate and active agent, when the fire extinguishing agent is applied to a fire scene, some components react at low temperature to absorb heat and generate inert gases and realize the functions of cooling and isolating oxygen; along with the heat absorption of the fire extinguishing agent, the components needing relatively high temperature start reaction to further absorb heat and generate inert gases and realize a continuous fire extinguishment effect of the fire extinguishing agent; and meanwhile, through the components such as phosphate and active agent, an effect of covering the burning materials and retarding flame is realized.
Description
Technical field
The invention belongs to technical field of fire control, particularly relate to a kind of content extinguishing chemical for fire extinguisher.
Background technology
Extinguishing chemical mainly includes three classes, respectively powder extinguishing agent, carbon dioxide extinguishing agent and fire foam, and wherein carbon dioxide extinguishing agent is because preparation cost is high, but traceless feature after fire extinguishing, it is mainly used in the fire of the valuables such as electric, instrument; Fire foam is mainly used in putting out a fire to save life and property and is unsuitable for the fire such as the oil product put out a fire with water, and powder extinguishing agent is applicable to some small-sized fire. But the composition of these three extinguishing chemical is substantially single, such as powder extinguishing agent is to be covered on comburant by non-combustible matter to make flame suffocate; Carbon dioxide extinguishing agent is to carry out the mode of starvation by carbon dioxide to reach the purpose of fire extinguishing, and same fire foam is also by starvation and covers the foam not fired in combustible substance and realize fire extinguishing.
But when fire formula is bigger, the temperature in the scene of a fire quickly raises so that some incombustible also are able to burning at a certain temperature, so, the fire-fighting efficiency of single extinguishing chemical is relatively low, it is necessary to substantial amounts of extinguishing chemical could be put out a fire, and to fire fighter, the transport of extinguishing chemical is brought bigger burden.
Being found by scientific research, effectively reduce the temperature in the scene of a fire, the efficiency improving extinguishing chemical is improved a lot, therefore, the fire extinguishing of science should include reducing the temperature in the scene of a fire, starvation and cutting off comburant to realize quick extinguishing.
Reduce fire scene temperature, by studying, by extinguishing chemical in fire extinguishing procedure, it it is the effective way reducing fire scene temperature by the endothermic reaction, therefore, exploitation reaction equation extinguishing chemical, in the scene of a fire, the endothermic reaction is there is by extinguishing chemical, release noble gas and generation non-combustible matter are covered in combustible substance simultaneously, it it is the research direction of existing extinguishing chemical, technology is now also had to propose this type of extinguishing chemical, such as CN201310302230.9, what claim is a kind of throwing type fire annihilator and preparation method thereof, extinguishing chemical in this technical scheme is to pass through fluorine surfactant, potassium carbonate, ammonium sulfate, carbamide, APP, anion surfactant, sodium lauryl sulphate and water composition, this technical scheme is to be dissolved in above-mentioned each composition in the water of uniform temperature preparing extinguishing chemical, the advantage of this extinguishing chemical is to pass through potassium carbonate, ammonium sulfate, carbamide, APP, anion surfactant, sodium lauryl sulphate is when running into flame, decompose such as nitrogen, ammonia and carbon dioxide etc. go out noble gas, realize starvation, and said components can absorb substantial amounts of heat when decomposing, effectively reduce the temperature of flame, and generate non-combustible matter and surfactant and sodium lauryl sulphate generation foam, the surface being covered in combustible substance realizes fire-retardant.
But the extinguishing chemical of this technical scheme still has following weak point, first weak point is to need hot water in preparing, and in the process of breaking out of fire, the source of hot water can be affected, and then has influence on the efficiency of extinguishing chemical; Second weak point is, in this extinguishing chemical, the decomposition temperature of each composition is higher, and only when fire formula is bigger, the efficiency of extinguishing chemical just can embody, and when fire formula from the beginning of time, the effect of extinguishing chemical is not high.
Summary of the invention
It is an object of the invention to provide a kind of extinguishing chemical, use, with what solve the extinguishing chemical of prior art, the problem that the reaction condition needing bigger fiery formula and extinguishing chemical is higher.
The present invention is achieved by the following technical solutions:
A kind of extinguishing chemical, its composition is by weight percentage, and at least three kinds of salt containing carbonate, bicarbonate radical, ammonium root, nitrate anion or nitrite anions is 5%-40%, phosphate be 5%-20%, activating agent is 3-15%, and surplus is water.
Further, the described salt containing carbonate is one or more the combination in ammonium carbonate, lithium carbonate, sodium carbonate, potassium carbonate, calcium carbonate, magnesium carbonate, brium carbonate, ferric carbonate, manganese carbonate and aluminium carbonate;
The salt of described bicarbonate radical is one or more the combination in ammonium hydrogen carbonate, lithium bicarbonate, sodium bicarbonate, potassium bicarbonate, calcium bicarbonate, magnesium bicarbonate, barium bicarbonate, bicarbonate ferrum, bicarbonate manganese and bicarbonate aluminum;
Described ammonium root is one or more combinations in carbamide, ammonium acetate, ammonium halide, ammonium sulfate or ammonium nitrate;
Described nitrate anion salt is one or more combinations in lithium nitrate, sodium nitrate, potassium nitrate, calcium nitrate, magnesium nitrate, barium nitrate, ferric nitrate, manganese nitrate or aluminum nitrate;
Described nitrite anions salt is one or more combinations in lithium nitrite, sodium nitrite, potassium nitrite, calcium nitrite, magnesium nitrite, barium nitrite, nitrous acid ferrum, nitrous acid manganese or nitrous acid aluminum.
Further, described phosphate is one or more combinations in APP, polyphosphate sodium or PA 800K.
Further, described activating agent is not fluorine-containing activating agent.
Described not fluorine-containing activating agent is one or more combinations in glycine betaine, OP-10, sodium lauryl sulphate, lauryl sulphate acid potassium, dodecyl sodium sulfate or potassium dodecanesulfonate.
Further, the preservative of 0.1-1.0% is also included; Described preservative is ozone.
Further, the antifreezing agent of 10-50% is also included.
Described antifreezing agent be methanol, ethanol, isopropanol, ethylene glycol, propylene glycol, diethylene glycol, butyl glycol ether, propandiol butyl ether, 2-Butoxyethyl acetate, dichloromethane, 1, one or more combinations in 1-dichloroethanes, 1,2-dichloroethanes, dimethyl sulfoxide, Methanamide, calcium chloride, sodium acetate, magnesium chloride.
Further, the wetting agent of 0.1-2% is also included.
Described wetting agent is one or more combinations in epoxy resin latex, starch, paraffin, hydrogenated vegetable oil or polyether polyol.
The invention has the beneficial effects as follows:
The application by least three or more containing carbonate, bicarbonate radical, ammonium root, the salt of nitrate anion or nitrite anions, and Quadrafos, the compositions such as activating agent, when extinguishing chemical is devoted to the scene of a fire, namely part composition realizes reaction at low temperatures, absorb heat and produce noble gas, reach the effect of cooling and starvation, heat absorption along with extinguishing chemical, the composition needing higher temperature starts reaction, continue absorb heat and produce noble gas, extinguishing chemical is made to reach the effect continuing to put out a fire, simultaneously, formed by phosphate and activating agent etc., play covering combustible substance and play fire-retardant effect.
Detailed description of the invention
Describing technical scheme by the following examples in detail, below example is merely illustrative of, and is only capable of for explaining and illustrate technical scheme, and is not to be construed as the restriction to technical solution of the present invention.
The present invention provides a kind of extinguishing chemical, and its composition is by weight percentage, and at least three kinds of salt containing carbonate, bicarbonate radical, ammonium root, nitrate anion or nitrite anions is 5%-40%, phosphate be 5%-20%, activating agent is 3-15%, and surplus is water. In this application, water is pure water.
The described salt containing carbonate is one or more the combination in ammonium carbonate, lithium carbonate, sodium carbonate, potassium carbonate, calcium carbonate, magnesium carbonate, brium carbonate, ferric carbonate, manganese carbonate and aluminium carbonate.
The salt of described bicarbonate radical is one or more the combination in ammonium hydrogen carbonate, lithium bicarbonate, sodium bicarbonate, potassium bicarbonate, calcium bicarbonate, magnesium bicarbonate, barium bicarbonate, bicarbonate ferrum, bicarbonate manganese and bicarbonate aluminum.
Described ammonium root is one or more combinations in carbamide, ammonium acetate, ammonium halide, ammonium sulfate or ammonium nitrate. In this application, ammonium halide refers to the general name of any one or more combinations in ammonium fluoride, ammonium chloride, ammonium bromide or ammonium iodide.
Described nitrate anion salt is one or more combinations in lithium nitrate, sodium nitrate, potassium nitrate, calcium nitrate, magnesium nitrate, barium nitrate, ferric nitrate, manganese nitrate or aluminum nitrate.
Described nitrite anions salt is one or more combinations in lithium nitrite, sodium nitrite, potassium nitrite, calcium nitrite, magnesium nitrite, barium nitrite, nitrous acid ferrum, nitrous acid manganese or nitrous acid aluminum.
Described phosphate is one or more combinations in APP, polyphosphate sodium or PA 800K.
Described activating agent is not fluorine-containing activating agent.
Described not fluorine-containing activating agent is one or more combinations in glycine betaine, OP-10, sodium lauryl sulphate, lauryl sulphate acid potassium, dodecyl sodium sulfate or potassium dodecanesulfonate. In this application, OP-10 is alkylphenol polyoxyethylene.
The extinguishing chemical of the application also includes the preservative of 0.1-1.0%; Described preservative is ozone.
The extinguishing chemical of the application also includes the antifreezing agent of 10-50%.
Described antifreezing agent be methanol, ethanol, isopropanol, ethylene glycol, propylene glycol, diethylene glycol, butyl glycol ether, propandiol butyl ether, 2-Butoxyethyl acetate, dichloromethane, 1, one or more combinations in 1-dichloroethanes, 1,2-dichloroethanes, dimethyl sulfoxide, Methanamide, calcium chloride, sodium acetate, magnesium chloride.
The extinguishing chemical of the application also includes the wetting agent of 0.1-2%.
Described wetting agent is one or more combinations in epoxy resin latex, starch, paraffin, hydrogenated vegetable oil or polyether polyol.
Embodiment 1
A kind of extinguishing chemical, its composition amounts to 5% for ammonium hydrogen carbonate, potassium carbonate and carbamide by weight percentage, and APP is 5%, and glycine betaine is 3%, and surplus is pure water.
Preparation method is, dissolves in the pure water of 87% after ammonium hydrogen carbonate, potassium carbonate, carbamide, APP and glycine betaine being mixed, and prepares extinguishing chemical after stirring and dissolving.
Embodiment 2
A kind of extinguishing chemical, its composition amounts to 5% for ammonium hydrogen carbonate, potassium carbonate and carbamide by weight percentage, and APP is 5%, and glycine betaine is 3%, and ozone is 0.1%, and water-soluble epoxy resin emulsion is 0.1%, and surplus is pure water.
Preparation method is, by the pure water dissolving in 86.8% after ammonium hydrogen carbonate, potassium carbonate, carbamide, APP, glycine betaine, ozone, the mixing of water-soluble epoxy resin emulsion, prepares extinguishing chemical after stirring and dissolving.
Embodiment 3
A kind of extinguishing chemical, its composition amounts to 5% for ammonium hydrogen carbonate, potassium carbonate and carbamide by weight percentage, and APP is 5%, and glycine betaine is 3%, and ethylene glycol is 10%, and ozone is 0.1%, and water-soluble epoxy resin emulsion is 0.1%, and surplus is pure water.
Preparation method is, by the pure water dissolving in 76.8% after ammonium hydrogen carbonate, potassium carbonate, carbamide, APP, glycine betaine, ethylene glycol, ozone, the mixing of water-soluble epoxy resin emulsion, prepares extinguishing chemical after stirring and dissolving.
Embodiment 4
A kind of extinguishing chemical, its composition amounts to 40% for ammonium hydrogen carbonate, sodium nitrate, potassium carbonate and carbamide by weight percentage, and APP is 20%, and glycine betaine is 3%, and surplus is pure water.
Preparation method is, dissolves in the pure water of 37% after ammonium hydrogen carbonate, sodium nitrate, potassium carbonate, carbamide, APP and glycine betaine being mixed, and prepares extinguishing chemical after stirring and dissolving.
Embodiment 5
A kind of extinguishing chemical, its composition amounts to 40% for ammonium hydrogen carbonate, sodium nitrate, potassium carbonate and carbamide by weight percentage, and APP is 20%, and glycine betaine is 3%, and ozone is 1%, surplus is pure water.
Preparation method is, dissolves in the pure water of 36% after ammonium hydrogen carbonate, sodium nitrate, potassium carbonate, carbamide, APP and glycine betaine being mixed, and the ozone adding 1% prepares extinguishing chemical after stirring and dissolving.
Embodiment 6
A kind of extinguishing chemical, its composition amounts to 40% for ammonium hydrogen carbonate, sodium nitrate, potassium carbonate and carbamide by weight percentage, and APP is 20%, and glycine betaine is 3%, and OP-10 is 12%, ozone is 1%, starch is 2%, ethylene glycol is 10%, and surplus is pure water.
Preparation method is, by the pure water dissolving in 12% after ammonium hydrogen carbonate, sodium nitrate, potassium carbonate, carbamide, APP, glycine betaine, OP-10, starch mixing, the ozone adding 1% prepares extinguishing chemical after stirring and dissolving.
Embodiment 7
A kind of extinguishing chemical, its composition amounts to 40% for ammonium sulfate, ammonium carbonate, potassium carbonate and carbamide by weight percentage, and APP is 20%, and glycine betaine is 3%, and OP-10 is 12%, ozone is 1%, starch is 2%, ethylene glycol is 10%, and surplus is pure water.
Preparation method is, by the pure water dissolving in 12% after ammonium sulfate, ammonium carbonate, potassium carbonate, carbamide, APP, glycine betaine, OP-10, starch mixing, the ozone adding 1% prepares extinguishing chemical after stirring and dissolving.
Embodiment 8
A kind of extinguishing chemical, its composition amounts to 40% for ammonium carbonate, ammonium sulfate, potassium carbonate and carbamide by weight percentage, and APP is 20%, and glycine betaine is 3%, and ozone is 1%, surplus is pure water.
Preparation method is, dissolves in the pure water of 36% after ammonium carbonate, ammonium sulfate, potassium carbonate, carbamide, APP and glycine betaine being mixed, and the ozone adding 1% prepares extinguishing chemical after stirring and dissolving.
Embodiment 9
A kind of extinguishing chemical, its composition amounts to 35% for sodium carbonate, ammonium sulfate, potassium bicarbonate and carbamide by weight percentage, and APP is 15%, and OP-10 is 10%, and ozone is 0.5%, ethylene glycol is 12%, starch is 1%, and surplus is pure water.
Preparation method is, by the pure water dissolving in 26.5% after sodium carbonate, ammonium sulfate, potassium bicarbonate, carbamide, APP, OP-10, ethylene glycol, starch mixing, the ozone adding 0.5% prepares extinguishing chemical after stirring and dissolving.
Embodiment 10
A kind of extinguishing chemical, its composition amounts to 32% for sodium carbonate, ammonium sulfate, potassium bicarbonate and carbamide by weight percentage, and APP is 10%, and OP-10 is 15%, and ozone is 0.5%, ethylene glycol is 10%, starch is 1%, and surplus is pure water.
Preparation method is, by the pure water dissolving in 31.5% after sodium carbonate, ammonium sulfate, potassium bicarbonate, carbamide, APP, OP-10, ethylene glycol, starch mixing, the ozone adding 0.5% prepares extinguishing chemical after stirring and dissolving.
Embodiment 11
A kind of extinguishing chemical, its composition amounts to 20% for potassium carbonate, ammonium hydrogen sulfate, potassium nitrate and carbamide by weight percentage, and APP is 15%, and OP-10 is 10%, and ozone is 0.5%, ethylene glycol is 12%, starch is 1%, and surplus is pure water.
Preparation method is, by the pure water dissolving in 41.5% after potassium carbonate, ammonium hydrogen sulfate, potassium nitrate, carbamide, APP, OP-10, ethylene glycol, starch mixing, the ozone adding 0.5% prepares extinguishing chemical after stirring and dissolving.
Below it is only the limited embodiments to the technical program, and all of embodiment cannot be enumerated.
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, being appreciated that and these embodiments can be carried out multiple change, amendment, replacement and modification without departing from the principles and spirit of the present invention, the scope of the invention and equivalency.
Claims (10)
1. an extinguishing chemical, it is characterised in that: its composition is by weight percentage, and at least three kinds is 3-15% containing carbonate, bicarbonate radical, ammonium root, salt to be 5%-40%, phosphate the be 5%-20% of nitrate anion or nitrite anions, activating agent, and surplus is water.
2. extinguishing chemical according to claim 1, it is characterised in that: the described salt containing carbonate is one or more the combination in ammonium carbonate, lithium carbonate, sodium carbonate, potassium carbonate, calcium carbonate, magnesium carbonate, brium carbonate, ferric carbonate, manganese carbonate and aluminium carbonate;
The salt of described bicarbonate radical is one or more the combination in ammonium hydrogen carbonate, lithium bicarbonate, sodium bicarbonate, potassium bicarbonate, calcium bicarbonate, magnesium bicarbonate, barium bicarbonate, bicarbonate ferrum, bicarbonate manganese and bicarbonate aluminum;
Described ammonium root is one or more combinations in carbamide, ammonium acetate, ammonium halide, ammonium sulfate or ammonium nitrate;
Described nitrate anion salt is one or more combinations in lithium nitrate, sodium nitrate, potassium nitrate, calcium nitrate, magnesium nitrate, barium nitrate, ferric nitrate, manganese nitrate or aluminum nitrate;
Described nitrite anions salt is one or more combinations in lithium nitrite, sodium nitrite, potassium nitrite, calcium nitrite, magnesium nitrite, barium nitrite, nitrous acid ferrum, nitrous acid manganese or nitrous acid aluminum.
3. extinguishing chemical according to claim 1, it is characterised in that: described phosphate is one or more combinations in APP, polyphosphate sodium or PA 800K.
4. extinguishing chemical according to claim 1, it is characterised in that: described activating agent is not fluorine-containing activating agent.
5. extinguishing chemical according to claim 4, it is characterised in that: described not fluorine-containing activating agent is one or more combinations in glycine betaine, OP-10, sodium lauryl sulphate, lauryl sulphate acid potassium, dodecyl sodium sulfate or potassium dodecanesulfonate.
6. extinguishing chemical according to claim 1, it is characterised in that: also include the preservative of 0.1-1.0%;Described preservative is ozone.
7. extinguishing chemical according to claim 1, it is characterised in that: also include the antifreezing agent of 10-50%.
8. extinguishing chemical according to claim 7, it is characterized in that: described antifreezing agent be methanol, ethanol, isopropanol, ethylene glycol, propylene glycol, diethylene glycol, butyl glycol ether, propandiol butyl ether, 2-Butoxyethyl acetate, dichloromethane, 1, one or more combinations in 1-dichloroethanes, 1,2-dichloroethanes, dimethyl sulfoxide, Methanamide, calcium chloride, sodium acetate, magnesium chloride.
9. extinguishing chemical according to claim 1, it is characterised in that: also include the wetting agent of 0.1-2%.
10. extinguishing chemical according to claim 9, it is characterised in that: described wetting agent is one or more combinations in epoxy resin latex, starch, paraffin, hydrogenated vegetable oil or polyether polyol.
Priority Applications (1)
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CN201610232634.9A CN105641850A (en) | 2016-04-14 | 2016-04-14 | Fire extinguishing agent |
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CN201610232634.9A CN105641850A (en) | 2016-04-14 | 2016-04-14 | Fire extinguishing agent |
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CN201610232634.9A Pending CN105641850A (en) | 2016-04-14 | 2016-04-14 | Fire extinguishing agent |
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106955450A (en) * | 2017-03-22 | 2017-07-18 | 中国民用航空飞行学院 | A kind of environment-friendly type aqueous film-forming foam extinguishing agent |
CN107019868A (en) * | 2017-06-20 | 2017-08-08 | 合肥博之泰电子科技有限公司 | A kind of fire-fighting fire extinguishing material and its production technology |
CN107029378A (en) * | 2017-06-06 | 2017-08-11 | 沈阳仁辉消防科技有限公司 | A kind of preparation method of instant high-performance solid extinguishing chemical |
CN107029377A (en) * | 2017-06-06 | 2017-08-11 | 沈阳仁辉消防科技有限公司 | One kind concentration high-efficiency fire-extinguishant and preparation method thereof |
CN108570861A (en) * | 2018-06-15 | 2018-09-25 | 浙江圣山科纺有限公司 | The application on cloth outdoors of the special bright aluminum paste of high glaze |
CN110841237A (en) * | 2019-11-19 | 2020-02-28 | 西安科技大学 | Preparation method and application of water mist additive for inerting and inhibiting coal mine fire |
CN114733130A (en) * | 2022-04-02 | 2022-07-12 | 河北工业大学 | Fire extinguishing composition based on potassium bicarbonate dry powder and preparation method thereof |
WO2024062129A1 (en) * | 2022-09-23 | 2024-03-28 | Lifesafe Technologies Limited | Use of a fire extinguishing liquid |
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Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106955450A (en) * | 2017-03-22 | 2017-07-18 | 中国民用航空飞行学院 | A kind of environment-friendly type aqueous film-forming foam extinguishing agent |
CN106955450B (en) * | 2017-03-22 | 2020-05-19 | 中国民用航空飞行学院 | Environment-friendly aqueous film-forming foam extinguishing agent |
CN107029378A (en) * | 2017-06-06 | 2017-08-11 | 沈阳仁辉消防科技有限公司 | A kind of preparation method of instant high-performance solid extinguishing chemical |
CN107029377A (en) * | 2017-06-06 | 2017-08-11 | 沈阳仁辉消防科技有限公司 | One kind concentration high-efficiency fire-extinguishant and preparation method thereof |
CN107019868A (en) * | 2017-06-20 | 2017-08-08 | 合肥博之泰电子科技有限公司 | A kind of fire-fighting fire extinguishing material and its production technology |
CN108570861A (en) * | 2018-06-15 | 2018-09-25 | 浙江圣山科纺有限公司 | The application on cloth outdoors of the special bright aluminum paste of high glaze |
CN110841237A (en) * | 2019-11-19 | 2020-02-28 | 西安科技大学 | Preparation method and application of water mist additive for inerting and inhibiting coal mine fire |
CN114733130A (en) * | 2022-04-02 | 2022-07-12 | 河北工业大学 | Fire extinguishing composition based on potassium bicarbonate dry powder and preparation method thereof |
WO2024062129A1 (en) * | 2022-09-23 | 2024-03-28 | Lifesafe Technologies Limited | Use of a fire extinguishing liquid |
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