JP2013075129A - Manufacturing method of fire extinguishing agent - Google Patents

Manufacturing method of fire extinguishing agent Download PDF

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JP2013075129A
JP2013075129A JP2011228334A JP2011228334A JP2013075129A JP 2013075129 A JP2013075129 A JP 2013075129A JP 2011228334 A JP2011228334 A JP 2011228334A JP 2011228334 A JP2011228334 A JP 2011228334A JP 2013075129 A JP2013075129 A JP 2013075129A
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fire
fire extinguishing
extinguishing agent
dissolving
fire extinguisher
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JP2011228334A
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Japanese (ja)
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Shigeaki Hatakeyama
繁明 畠山
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Abstract

PROBLEM TO BE SOLVED: To solve the problem that it is often the case that a general person, who is not sufficiently trained, cannot use a fire extinguisher, though it is manufactured and sold for the purpose of initial fire extinguishment, while diversification of a fire is advanced in recent years and a performance of a fire extinguishing agent has to be improved.SOLUTION: The fire extinguishing agent with improved fire extinguishing range and fire extinguishing capability is manufactured. Also, the fire extinguishing agent is applied to a conventional fire extinguisher, an aerosol fire extinguishing implement and a fire extinguishing implement, for which a container of a resin or the like to be broken by an impact is filled with the fire extinguishing agent and which is thrown into the origin of fire and broken to extinguish the fire, and is used in multiple items.

Description

本発明は消火剤の製造方法に関する。The present invention relates to a method for producing a fire extinguishing agent.

消火剤成分は、さまざまな組成物により構成されている。
例えば、特開2001−37901号では、尿素、塩化ナトリウム、無水炭酸ソーダ、硫酸アンモニウムなどが開示されている。
The fire extinguisher component is composed of various compositions.
For example, JP-A-2001-37901 discloses urea, sodium chloride, anhydrous sodium carbonate, ammonium sulfate, and the like.

しかし、その製造方法は、各社がノウハウとして公開されていない。
本発明は、消火剤の製造方法について開示することにした。
However, the manufacturing method is not disclosed as know-how by each company.
The present invention has disclosed a method for producing a fire extinguishing agent.

特開2001−37901号JP 2001-37901 A

近年、火災の多様化が進んでいる中で、消火剤の性能も上げなくてはならないが、初期消火を目的として製造・販売されているにも関わらず、消火器は訓練を充分に受けていない一般人が使用出来ない場合が多い。In recent years, with the diversification of fires, the performance of fire extinguishing agents must be improved, but fire extinguishers are well trained despite being manufactured and sold for the purpose of initial fire fighting. There are many cases that no ordinary person can use.

本発明は、消火剤の消火性能を上げることにより、例えば衝撃で簡単に割れる容器に600ml程度の消火剤を充填して、火災時に火元に投げて容器を破壊して消火剤を散布させるという、訓練を必要としない消火用具に使用出来るので、より早く初期消火を完結出来る。
この場合の対象火災はA火災(紙・木等)とB火災(石油類火災)である為、従来の投てき型消火用具のようにA火災のみ消火できる物よりも、応用範囲が広くなるので、より完璧な初期消火を完了することができる。
According to the present invention, by increasing the extinguishing performance of the extinguishing agent, for example, about 600 ml of extinguishing agent is filled in a container that can be easily broken by an impact, and the fire extinguishing agent is sprayed by throwing it to the fire source in the event of a fire. Because it can be used for fire extinguishing equipment that does not require training, the initial fire fighting can be completed more quickly.
Since the target fires in this case are A fires (paper, wood, etc.) and B fires (petroleum fires), the scope of application is wider than those that can extinguish only A fires like conventional throwing fire extinguishing tools. Can complete a more perfect initial fire fighting.

この場合、重量も700gから800gと比較的に軽量なので遠投が出来て、火元から安全な距離を取ることが可能である。In this case, since the weight is comparatively light from 700 g to 800 g, it is possible to carry out long throwing and take a safe distance from the fire source.

本発明の方法によれば、人畜に影響のない安全な消火剤を提供することが出来る。
また、溶液を85℃から90℃の温度で15分から25分保つ工程により、消火に不要な量の炭酸ガス・アンモニアを排出でき、消火器や樹脂容器に充填した場合に、周囲温度の影響で内圧が上昇して容器を破損するなどの事故を防げて安全である。
この場合、消火に有効な炭酸ガス・アンモニアは残存する
According to the method of the present invention, it is possible to provide a safe fire extinguishing agent that does not affect human livestock.
In addition, the process of maintaining the solution at a temperature of 85 ° C. to 90 ° C. for 15 to 25 minutes can discharge an unnecessary amount of carbon dioxide / ammonia for extinguishing the fire, and when it is filled in a fire extinguisher or a resin container, it is affected by the ambient temperature. It is safe by preventing accidents such as internal pressure rising and damaging the container.
In this case, carbon dioxide and ammonia effective for extinguishing fire remain.

リン酸二アンモニウムと炭酸水素ナトリウムの混合物は、消火の際、火災の熱に反応して炭酸ガスとアンモニアに分解される。炭酸ガスは燃焼物と空気中の酸素が結合するのを阻害し、アンモニアは冷却効果で燃焼物の温度を降下させると共に、アルカリ性の性状を持つので、燃焼物の酸化を中和して消火することが可能となる。
また、塩化ナトリウムは、リン酸二アンモニウムと炭酸水素ナトリウムの反応を促進する触媒作用と、消火剤の凝固点を降下させる作用がある。
尿素は燃焼物表面の表面張力を小さくし、消火剤を浸透させる効果を有する。
硫酸アンモニウムは、木材や紙などの発火点を上昇させる効果を有するので、消火後の再燃焼を防止することが出来る。
The mixture of diammonium phosphate and sodium bicarbonate is decomposed into carbon dioxide and ammonia in response to the heat of the fire during fire extinguishing. Carbon dioxide gas inhibits the combination of combustion products and oxygen in the air, and ammonia lowers the temperature of the combustion products by the cooling effect and has an alkaline property, so it neutralizes the oxidation of the combustion products and extinguishes the fire. It becomes possible.
Sodium chloride has a catalytic action that promotes the reaction between diammonium phosphate and sodium hydrogen carbonate, and an action that lowers the freezing point of the fire extinguishing agent.
Urea has the effect of reducing the surface tension of the combustion product surface and allowing the extinguishing agent to penetrate.
Ammonium sulfate has the effect of increasing the ignition point of wood, paper, etc., and therefore can prevent reburning after extinguishing.

本発明により製造した消火剤600mlを、衝撃で破壊する樹脂容器に充填して、消防法で定められたAの第二模型(別図1)を使用して消火実験を行ったところ、2本で完全に消火出来た。この模型を水バケツで消火する場合は、24Lの水を必要とする。
よって、本発明の消火剤を使用することで、水の約20倍の消火効果を得ることが確認された。
When 600 ml of fire extinguishing agent manufactured according to the present invention was filled in a resin container that was destroyed by impact, a fire extinguishing experiment was conducted using a second model A (as shown in Figure 1) defined by the Fire Service Act. The fire was completely extinguished. When extinguishing this model with a water bucket, 24L of water is required.
Therefore, it was confirmed that the fire extinguishing effect about 20 times as much as that of water was obtained by using the fire extinguisher of the present invention.

本発明により製造した消火剤600mlを、衝撃で破壊する樹脂容器に充填して、消防法で定められたBの第一模型(別図2)を使用したガソリン消火実験を行ったところ、1本で完全に消火できた。When a fire extinguishing agent 600 ml produced according to the present invention was filled in a resin container that was destroyed by impact, a gasoline fire extinguishing experiment was conducted using the first model B (see Figure 2) defined by the Fire Service Act. The fire was completely extinguished.

本発明により製造した消火剤600mlを、衝撃で破壊する樹脂容器に充填した物を40℃の雰囲気中に入れて24時間放置したあとに、−20℃の雰囲気中に24時間放置し、常温の20℃に24時間放置した。
各温度で2時間毎に容器の状態を観察したところ、容器の膨張、消火剤の凍結による割れ、変形等は確認されなかった。
通常、消火用具の使用温度範囲は−20℃から40℃とすることが望ましいので、本発明により製造した消火剤は、この条件を満たしていることが確認出来た。
A product filled with 600 ml of a fire extinguisher prepared in accordance with the present invention was filled in a resin container that was destroyed by impact and left in a 40 ° C. atmosphere for 24 hours, and then left in a −20 ° C. atmosphere for 24 hours. It was left at 20 ° C. for 24 hours.
When the state of the container was observed every 2 hours at each temperature, expansion of the container, cracking due to freezing of the extinguishing agent, deformation, etc. were not confirmed.
Usually, since it is desirable that the operating temperature range of the fire extinguishing tool is −20 ° C. to 40 ° C., it was confirmed that the fire extinguishing agent produced according to the present invention satisfies this condition.

本発明により製造された消火剤は、消火器やエアゾール式消火用具、衝撃で割れる樹脂等の容器に充填して、火元に投げ割り消火する消火用具に使用される。The fire extinguisher produced according to the present invention is used in a fire extinguisher, an aerosol fire extinguishing tool, a fire extinguishing tool that fills a container such as a resin that can be broken by an impact, and throws it to a fire source.

Claims (3)

消火器及び消火用具に入れる消火剤の製造方法であって、50℃から60℃のお湯に塩化ナトリウム15gから25gを入れて溶解する工程と、リン酸二アンモニウムを100gから150g入れて溶解する工程と、炭酸水素ナトリウムを50gから80gを入れて溶解する工程と、混合した薬液を85℃から90℃の温度で20分から30分の間保つ工程と、尿素を50gから70g入れて溶解する工程と、硫酸アンモニウムを90gから110g入れて溶解して、全体量を600mlとする工程を備えることを特徴とする消火剤の製造方法。A method of manufacturing a fire extinguisher to be put into a fire extinguisher and a fire extinguishing tool, a step of dissolving 15 g to 25 g of sodium chloride in hot water of 50 ° C. to 60 ° C., and a step of dissolving 100 g to 150 g of diammonium phosphate A step of dissolving 50 g to 80 g of sodium hydrogen carbonate, a step of maintaining the mixed chemical solution at a temperature of 85 ° C. to 90 ° C. for 20 to 30 minutes, and a step of dissolving 50 g to 70 g of urea. A method for producing a fire extinguishing agent, comprising a step of adding 90 g to 110 g of ammonium sulfate and dissolving the total amount to 600 ml. 更に凝固点降下剤として、エチレングリコール80mlから120mlを入れる工程を備えることを特徴とする請求項1の消火剤の製造方法。The method for producing a fire extinguishing agent according to claim 1, further comprising a step of adding from 80 ml to 120 ml of ethylene glycol as a freezing point depressant. 更に石油類火災に効果を示す水成膜消火剤を20mlから40mlを入れる工程を備える事を特徴とする請求項2の消火剤の製造方法。The method for producing a fire extinguisher according to claim 2, further comprising a step of adding 20 ml to 40 ml of a water film fire extinguisher which is effective for petroleum fires.
JP2011228334A 2011-09-29 2011-09-29 Manufacturing method of fire extinguishing agent Withdrawn JP2013075129A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017094918A1 (en) * 2015-12-05 2017-06-08 準 森田 Method for manufacturing fire extinguishant, and fire extinguishant
GB2561610A (en) * 2017-04-21 2018-10-24 Firescape Global Ltd Fire extinguishing liquid
WO2021117255A1 (en) * 2019-12-10 2021-06-17 株式会社ファイレスキュー Liquid fire-extinguishing agent/fire-proofing agent to be filled into fire-extinguishing tool/fire extinguisher, and method for manfaucturing liquid fire-extinguishing agent/fire-proofing agent
JP2022028493A (en) * 2020-08-03 2022-02-16 株式会社ファイレスキュー Liquid fire-extinguishing agent, method for producing the liquid fire-extinguishing agent, and fire extinguisher filled with the liquid fire-extinguishing agent

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017094918A1 (en) * 2015-12-05 2017-06-08 準 森田 Method for manufacturing fire extinguishant, and fire extinguishant
JPWO2017094918A1 (en) * 2015-12-05 2017-12-07 準 森田 Extinguishing agent manufacturing method and extinguishing agent
GB2561610A (en) * 2017-04-21 2018-10-24 Firescape Global Ltd Fire extinguishing liquid
GB2561610B (en) * 2017-04-21 2022-08-17 Lifesafe Tech Limited Fire extinguishing liquid
WO2021117255A1 (en) * 2019-12-10 2021-06-17 株式会社ファイレスキュー Liquid fire-extinguishing agent/fire-proofing agent to be filled into fire-extinguishing tool/fire extinguisher, and method for manfaucturing liquid fire-extinguishing agent/fire-proofing agent
JP2022028493A (en) * 2020-08-03 2022-02-16 株式会社ファイレスキュー Liquid fire-extinguishing agent, method for producing the liquid fire-extinguishing agent, and fire extinguisher filled with the liquid fire-extinguishing agent

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