CN107019868A - A kind of fire-fighting fire extinguishing material and its production technology - Google Patents

A kind of fire-fighting fire extinguishing material and its production technology Download PDF

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Publication number
CN107019868A
CN107019868A CN201710467111.7A CN201710467111A CN107019868A CN 107019868 A CN107019868 A CN 107019868A CN 201710467111 A CN201710467111 A CN 201710467111A CN 107019868 A CN107019868 A CN 107019868A
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parts
fire
fire extinguishing
retardant expanded
expanded dose
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CN201710467111.7A
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Chinese (zh)
Inventor
王飞
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Hefei Bo Tai Tai Electronic Technology Co Ltd
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Hefei Bo Tai Tai Electronic Technology Co Ltd
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Priority to CN201710467111.7A priority Critical patent/CN107019868A/en
Publication of CN107019868A publication Critical patent/CN107019868A/en
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    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D1/00Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
    • A62D1/0071Foams

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Business, Economics & Management (AREA)
  • Emergency Management (AREA)
  • Fire-Extinguishing Compositions (AREA)

Abstract

The invention discloses a kind of fire-fighting fire extinguishing material and its production technology, the fire extinguishing material includes the raw material of following parts by weight:Compound flame-retardant expanded dose 60~80 parts, 30~50 parts of deionized water;Compound flame-retardant expanded dose includes the raw material of following parts by weight:Compound 20~50 parts of flame-retardant expanded dose of paste, 5~20 parts of epoxy resin, 6~18 parts of Firebrake ZB, 20~40 parts of deionized water;Compound flame-retardant expanded dose of paste includes the raw material of following parts by weight:10~20 parts of diatomite, 3~10 parts of aluminium hydroxide, 1~5 part of calcium chloride, 2~6 parts of antimony oxide, 1~3 part of antifreeze, 5~12 parts of thickener, 10~25 parts of deionized water.Each composition environmental protection of fire extinguishing material of the present invention is nuisanceless, and fire-fighting efficiency is high, can quickly reduce the temperature in fire area and effectively eliminate poisonous dense smoke, simple production process is controllable, is adapted to large-scale production.

Description

A kind of fire-fighting fire extinguishing material and its production technology
Technical field
The present invention relates to fire-fighting quipment field, and in particular to a kind of fire-fighting fire extinguishing material and its production technology.
Background technology
At present, the main results of frothy gel extinguishing chemical are the oxygen-containing solid fuels for having developed a kind of synthesis. The colloidal sol shape powder of high degree of dispersion is produced after the ignited burning of the material, is evenly distributed in space, is reached and rapidly and efficiently suppress Fire is purposeful.The fire-fighting technique occurs in that many problems related as caused by thermal response, example in actual promotion and application Such as, flame outer spray during burning, produces secondary initiation fire hazard;The existing face temperature of equipment is too high, output toxic gas;In higher temperatures In the case of, particulate floating interval of floating dock is longer.
Because there is the problem of corrosivity is larger, environment is unfriendly, the shelf-life is short in most of gel-likes fire extinguishing material, because This is, it is necessary to research and develop the less fire extinguishing material of a kind of high-efficiency environment friendly, safety and stability, corrosivity, the need for meeting daily fire-fighting emergent.
The content of the invention
, should it is an object of the invention to provide a kind of fire-fighting fire extinguishing material and its production technology for the defect of prior art Each composition environmental protection of material of putting out a fire is nuisanceless, and fire-fighting efficiency is high, can quickly reduce the temperature in fire area and effectively disappear Except poisonous dense smoke, and cost is relatively low, and simple production process is controllable, is adapted to large-scale production.
The present invention solves technical problem and adopted the following technical scheme that:
A kind of fire-fighting fire extinguishing material, includes the raw material of following parts by weight:Compound flame-retardant expanded dose 60~80 parts, deionized water 30 ~50 parts;
Described compound flame-retardant expanded dose includes the raw material of following parts by weight:Compound 20~50 parts of flame-retardant expanded dose of paste, 5~20 parts of epoxy resin, 6~18 parts of Firebrake ZB, 20~40 parts of deionized water;
The compound flame-retardant expanded dose of paste includes the raw material of following parts by weight:10~20 parts of diatomite, aluminium hydroxide 3~ 10 parts, 1~5 part of calcium chloride, 2~6 parts of antimony oxide, 1~3 part of antifreeze, 5~12 parts of thickener, deionized water 10~25 Part.
Preferably, the fire extinguishing material includes the raw material of following parts by weight:Compound flame-retardant expanded dose 68 parts, deionized water 42 parts;
Described compound flame-retardant expanded dose includes the raw material of following parts by weight:Compound 36 parts of flame-retardant expanded dose of paste, epoxy 12 parts of resin, 15 parts of Firebrake ZB, 35 parts of deionized water;
The compound flame-retardant expanded dose of paste includes the raw material of following parts by weight:16 parts of diatomite, 7 parts of aluminium hydroxide, chlorine Change 2 parts of calcium, 3 parts of antimony oxide, 2 parts of antifreeze, 10 parts of thickener, 20 parts of deionized water.
Preferably, the antifreeze is in isopropanol, butyl glycol ether, propandiol butyl ether, 2-Butoxyethyl acetate One or more combinations.
Preferably, the thickener is one or more combinations in modified starch, polyvinyl alcohol, polyacrylamide.
The production technology of above-mentioned fire-fighting fire extinguishing material, comprises the following steps:
(1) preparation of compound flame-retardant expanded dose of paste:Deionized water will be added in diatomite according to parts by weight, stirring 20~ 30 minutes, aluminium hydroxide, calcium chloride, antimony oxide, antifreeze, thickener are added, with 800~1000 rpm/min speed The paste is obtained after stirring;
(2) compound flame-retardant expanded dose of preparation:Compound flame-retardant expanded dose of paste is added to mixer according to parts by weight High speed is stirred, and is added after epoxy resin, Firebrake ZB, is warming up to 40~60 DEG C, after stirring 30~40 minutes, adds deionization Water, stops heating, continues after stirring 1~2 hour;
(3) preparation of fire-fighting fire extinguishing material:Compound flame-retardant expanded dose is added in trough type mixing machine, 1400~1600 Stirred 30~40 minutes under rpm/min high-speed stirred, add after deionized water and continue to stir 1~1.5 hour;It is put into flour mill The fire-fighting fire extinguishing material is made in middle milling, pack.
Preferably, the step(2)Need rotating speed bringing up to 1800~2000 rpm/min after adding water.
Preferably, the step(3)Grain diameter is less than 0.06mm after milling.
Preferably, the shady and cool place of drying is placed in after the fire-fighting fire extinguishing material pack to deposit.
Wherein, diatomite has good caking property, plasticity, thixotropy, fire resistance and stability, can effectively adsorb Toxic and harmful gas and particle in air, environmental protection, beneficial health.
Aluminium hydroxide, calcium chloride, antimony oxide are all widely used inorganic fire-retarded additives, and smoke compared with It is few, do not produce toxic gas.
Firebrake ZB is a kind of non-halogen flame retardant of environment-friendly type, with nontoxic, low aqueous solubility, high thermal stability, granularity it is small, Proportion is small, good dispersion the features such as, be widely used in the fields such as plastics, rubber, coating.
Compared with prior art, the present invention has following beneficial effect:
(1) each composition environmental protection of fire-fighting fire extinguishing material of the invention is nuisanceless, and fire-fighting efficiency is high, can quickly reduce ignition zone Temperature in domain simultaneously effectively eliminates poisonous dense smoke, and cost is relatively low, and simple production process is controllable, is adapted to large-scale production.
(2) fire-fighting fire extinguishing material of the invention, is prepared from, compound resistance by compound flame-retardant expanded dose and deionized water Combustion foaming agent contains heat-resisting, fire-retardant, stable compound flame-retardant expanded dose of paste, epoxy resin, Firebrake ZB, compound resistance Fire foaming agent paste by plastic, fire resisting diatomite and a variety of inorganic combustion inhibitor aluminium hydroxides, calcium chloride, antimony oxide, Firebrake ZB is prepared from.
(3) fire-fighting fire extinguishing material of the invention does not produce carburization zone and flue gas, safety and environmental protection, energy during fire extinguishing The stability of gel foam is enough kept, fire-fighting efficiency is high, moreover it is possible to purify air, reduces pollution.After testing its hydroscopicity≤ 0.25%, mobility≤5.6s, electrical insulating property >=9.7kv, A classes of going out fire efficiency≤28g/m3, B classes of going out fire efficiency≤28g/m3, go out C classes fire efficiency≤28g/m3, D classes of going out fire efficiency≤28g/m3
Embodiment
With reference to specific embodiment, the present invention is expanded on further.These embodiments be merely to illustrate the present invention and without In limitation the scope of the present invention.
Embodiment 1
A kind of fire-fighting fire extinguishing material, includes the raw material of following parts by weight:Compound flame-retardant expanded dose 68 parts, 42 parts of deionized water; Compound flame-retardant expanded dose includes the raw material of following parts by weight:Compound 36 parts of flame-retardant expanded dose of paste, 12 parts of epoxy resin, 15 parts of Firebrake ZB, 35 parts of deionized water;Compound flame-retardant expanded dose of paste includes the raw material of following parts by weight:Diatomite 16 Part, 7 parts of aluminium hydroxide, 2 parts of calcium chloride, 3 parts of antimony oxide, 2 parts of antifreeze butyl glycol ether, thickener polyvinyl alcohol 10 Part, 20 parts of deionized water.
The production technology of above-mentioned fire-fighting fire extinguishing material, comprises the following steps:
(1) preparation of compound flame-retardant expanded dose of paste:Deionized water will be added in diatomite according to parts by weight, 25 points are stirred Clock, adds aluminium hydroxide, calcium chloride, antimony oxide, antifreeze, thickener, after being stirred with 800 rpm/min speed Obtain the paste.
(2) compound flame-retardant expanded dose of preparation:Compound flame-retardant expanded dose of paste is added to according to parts by weight and stirred The stirring of machine high speed is mixed, is added after epoxy resin, Firebrake ZB, 50 DEG C are warming up to, after stirring 36 minutes, deionized water is added, stops Only heat, rotating speed, which brings up to 1800 rpm/min, to be continued after stirring 2 hours.
(3) preparation of fire-fighting fire extinguishing material:Compound flame-retardant expanded dose is added in trough type mixing machine, 1600 Stirred 30 minutes under rpm/min high-speed stirred, add after deionized water and continue to stir 1.5 hours;It is put into flour mill and is milled, Grain diameter is less than 0.06mm after milling, and the fire-fighting fire extinguishing material is made in pack, is placed in the shady and cool place of drying and deposits.
The fire-fighting fire extinguishing material hydroscopicity 0.19% after testing, mobility 4.8s, electrical insulating property 10.6kv, A classes of going out fire efficiency ≤ 28g/m3, B classes of going out fire efficiency≤28g/m3, C classes of going out fire efficiency≤28g/m3, D classes of going out fire efficiency≤28g/m3
Embodiment 2
A kind of fire-fighting fire extinguishing material, includes the raw material of following parts by weight:Compound flame-retardant expanded dose 72 parts, 47 parts of deionized water; Compound flame-retardant expanded dose includes the raw material of following parts by weight:Compound 45 parts of flame-retardant expanded dose of paste, 6 parts of epoxy resin, 10 parts of Firebrake ZB, 30 parts of deionized water;Compound flame-retardant expanded dose of paste includes the raw material of following parts by weight:Diatomite 15 Part, 7 parts of aluminium hydroxide, 2 parts of calcium chloride, 3 parts of antimony oxide, 1 part of antifreeze 2-Butoxyethyl acetate, thickener polypropylene 8 parts of acid amides, 16 parts of deionized water.
The production technology of above-mentioned fire-fighting fire extinguishing material, comprises the following steps:
(1) preparation of compound flame-retardant expanded dose of paste:Deionized water will be added in diatomite according to parts by weight, 30 points are stirred Clock, is added aluminium hydroxide, calcium chloride, antimony oxide, antifreeze, thickener, is stirred with 1000 rpm/min speed Obtain the paste afterwards.
(2) compound flame-retardant expanded dose of preparation:Compound flame-retardant expanded dose of paste is added to according to parts by weight and stirred The stirring of machine high speed is mixed, is added after epoxy resin, Firebrake ZB, 60 DEG C are warming up to, after stirring 30 minutes, deionized water is added, stops Only heat, rotating speed, which brings up to 2000 rpm/min, to be continued after stirring 1 hour.
(3) preparation of fire-fighting fire extinguishing material:Compound flame-retardant expanded dose is added in trough type mixing machine, 1600 Stirred 40 minutes under rpm/min high-speed stirred, add after deionized water and continue to stir 1.5 hours;It is put into flour mill and is milled, Grain diameter is less than 0.06mm after milling, and the fire-fighting fire extinguishing material is made in pack, is placed in the shady and cool place of drying and deposits.
The fire-fighting fire extinguishing material hydroscopicity 0.23% after testing, mobility 5.4s, electrical insulating property 9.9kv, A classes of going out fire efficiency ≤ 28g/m3, B classes of going out fire efficiency≤28g/m3, C classes of going out fire efficiency≤28g/m3, D classes of going out fire efficiency≤28g/m3
Embodiment 3
A kind of fire-fighting fire extinguishing material, includes the raw material of following parts by weight:Compound flame-retardant expanded dose 75 parts, 48 parts of deionized water; Compound flame-retardant expanded dose includes the raw material of following parts by weight:Compound 47 parts of flame-retardant expanded dose of paste, 12 parts of epoxy resin, 15 parts of Firebrake ZB, 35 parts of deionized water;Compound flame-retardant expanded dose of paste includes the raw material of following parts by weight:Diatomite 17 Part, 8 parts of aluminium hydroxide, 2 parts of calcium chloride, 5 parts of antimony oxide, 2 parts of antifreeze isopropanol, 9 parts of thickener modified starch, go from Sub- 25 parts of water.
The production technology of above-mentioned fire-fighting fire extinguishing material, comprises the following steps:
(1) preparation of compound flame-retardant expanded dose of paste:Deionized water will be added in diatomite according to parts by weight, 22 points are stirred Clock, adds aluminium hydroxide, calcium chloride, antimony oxide, antifreeze, thickener, after being stirred with 850rpm/min speed Obtain the paste.
(2) compound flame-retardant expanded dose of preparation:Compound flame-retardant expanded dose of paste is added to according to parts by weight and stirred The stirring of machine high speed is mixed, is added after epoxy resin, Firebrake ZB, 52 DEG C are warming up to, after stirring 37 minutes, deionized water is added, stops Only heat, rotating speed, which brings up to 1850rpm/min, to be continued after stirring 1.4 hours.
(3) preparation of fire-fighting fire extinguishing material:Compound flame-retardant expanded dose is added in trough type mixing machine, in 1450rpm/ Stirred 35 minutes under min high-speed stirred, add after deionized water and continue to stir 1.2 hours;It is put into flour mill and is milled, milling Grain diameter is less than 0.06mm afterwards, and the fire-fighting fire extinguishing material is made in pack, is placed in the shady and cool place of drying and deposits.
The fire-fighting fire extinguishing material hydroscopicity 0.25% after testing, mobility 5.6s, electrical insulating property 9.6kv, A classes of going out fire efficiency ≤ 28g/m3, B classes of going out fire efficiency≤28g/m3, C classes of going out fire efficiency≤28g/m3, D classes of going out fire efficiency≤28g/m3
Embodiment 4
A kind of fire-fighting fire extinguishing material, includes the raw material of following parts by weight:Compound flame-retardant expanded dose 80 parts, 50 parts of deionized water; Compound flame-retardant expanded dose includes the raw material of following parts by weight:Compound 50 parts of flame-retardant expanded dose of paste, 18 parts of epoxy resin, 16 parts of Firebrake ZB, 38 parts of deionized water;Compound flame-retardant expanded dose of paste includes the raw material of following parts by weight:Diatomite 18 Part, 10 parts of aluminium hydroxide, 5 parts of calcium chloride, 5 parts of antimony oxide, 3 parts of antifreeze propandiol butyl ether, thickener polyvinyl alcohol 11 Part, 25 parts of deionized water.
The production technology of above-mentioned fire-fighting fire extinguishing material, comprises the following steps:
(1) preparation of compound flame-retardant expanded dose of paste:Deionized water will be added in diatomite according to parts by weight, 30 points are stirred Clock, is added aluminium hydroxide, calcium chloride, antimony oxide, antifreeze, thickener, is stirred with 1000 rpm/min speed Obtain the paste afterwards.
(2) compound flame-retardant expanded dose of preparation:Compound flame-retardant expanded dose of paste is added to according to parts by weight and stirred The stirring of machine high speed is mixed, is added after epoxy resin, Firebrake ZB, 60 DEG C are warming up to, after stirring 30 minutes, deionized water is added, stops Only heat, rotating speed, which brings up to 1800 rpm/min, to be continued after stirring 2 hours.
(3) preparation of fire-fighting fire extinguishing material:Compound flame-retardant expanded dose is added in trough type mixing machine, 1600 Stirred 30 minutes under rpm/min high-speed stirred, add after deionized water and continue to stir 1 hour;It is put into flour mill and is milled, mill Grain diameter is less than 0.06mm after powder, and the fire-fighting fire extinguishing material is made in pack, is placed in the shady and cool place of drying and deposits.
The fire-fighting fire extinguishing material hydroscopicity 0.22% after testing, mobility 5.2s, electrical insulating property 10.4kv, A classes of going out fire efficiency ≤ 28g/m3, B classes of going out fire efficiency≤28g/m3, C classes of going out fire efficiency≤28g/m3, D classes of going out fire efficiency≤28g/m3
Each composition environmental protection of fire-fighting fire extinguishing material of the present invention is nuisanceless, and fire-fighting efficiency is high, can quickly reduce and catch fire Temperature in region simultaneously effectively eliminates poisonous dense smoke, and cost is relatively low, and simple production process is controllable, is adapted to large-scale production.
The specific embodiment of the present invention is described above.It is to be appreciated that the invention is not limited in above-mentioned Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow Ring the substantive content of the present invention.

Claims (8)

1. a kind of fire-fighting fire extinguishing material, it is characterised in that the fire extinguishing material includes the raw material of following parts by weight:It is compound fire-retardant 60~80 parts of foaming agent, 30~50 parts of deionized water;
Described compound flame-retardant expanded dose includes the raw material of following parts by weight:Compound 20~50 parts of flame-retardant expanded dose of paste, 5~20 parts of epoxy resin, 6~18 parts of Firebrake ZB, 20~40 parts of deionized water;
The compound flame-retardant expanded dose of paste includes the raw material of following parts by weight:10~20 parts of diatomite, aluminium hydroxide 3~ 10 parts, 1~5 part of calcium chloride, 2~6 parts of antimony oxide, 1~3 part of antifreeze, 5~12 parts of thickener, deionized water 10~25 Part.
2. fire-fighting fire extinguishing material according to claim 1, it is characterised in that the fire extinguishing material includes following parts by weight Raw material:Compound flame-retardant expanded dose 68 parts, 42 parts of deionized water;
Described compound flame-retardant expanded dose includes the raw material of following parts by weight:Compound 36 parts of flame-retardant expanded dose of paste, epoxy 12 parts of resin, 15 parts of Firebrake ZB, 35 parts of deionized water;
The compound flame-retardant expanded dose of paste includes the raw material of following parts by weight:16 parts of diatomite, 7 parts of aluminium hydroxide, chlorine Change 2 parts of calcium, 3 parts of antimony oxide, 2 parts of antifreeze, 10 parts of thickener, 20 parts of deionized water.
3. fire-fighting fire extinguishing material according to claim 1, it is characterised in that the antifreeze is isopropanol, ethylene glycol fourth One or more combinations in ether, propandiol butyl ether, 2-Butoxyethyl acetate.
4. fire-fighting fire extinguishing material according to claim 1, it is characterised in that the thickener is modified starch, polyethylene One or more combinations in alcohol, polyacrylamide.
5. a kind of production technology of fire-fighting fire extinguishing material according to claim 1-4 any one, it is characterised in that including Following steps:
(1) preparation of compound flame-retardant expanded dose of paste:Deionized water will be added in diatomite according to parts by weight, stirring 20~ 30 minutes, aluminium hydroxide, calcium chloride, antimony oxide, antifreeze, thickener are added, with 800~1000 rpm/min speed The paste is obtained after stirring;
(2) compound flame-retardant expanded dose of preparation:Compound flame-retardant expanded dose of paste is added to mixer according to parts by weight High speed is stirred, and is added after epoxy resin, Firebrake ZB, is warming up to 40~60 DEG C, after stirring 30~40 minutes, adds deionization Water, stops heating, continues after stirring 1~2 hour;
(3) preparation of fire-fighting fire extinguishing material:Compound flame-retardant expanded dose is added in trough type mixing machine, 1400~1600 Stirred 30~40 minutes under rpm/min high-speed stirred, add after deionized water and continue to stir 1~1.5 hour;It is put into flour mill The fire-fighting fire extinguishing material is made in middle milling, pack.
6. the production technology of fire-fighting fire extinguishing material according to claim 5, it is characterised in that the step(2)Add water After need rotating speed bringing up to 1800~2000 rpm/min.
7. the production technology of fire-fighting fire extinguishing material according to claim 5, it is characterised in that the step(3)After milling Grain diameter is less than 0.06mm.
8. the production technology of fire-fighting fire extinguishing material according to claim 5, it is characterised in that the fire-fighting fire extinguishing material dress The shady and cool place of drying is placed in after bag to deposit.
CN201710467111.7A 2017-06-20 2017-06-20 A kind of fire-fighting fire extinguishing material and its production technology Withdrawn CN107019868A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108421195A (en) * 2018-04-24 2018-08-21 厦门泰消防科技开发有限公司 A kind of environment-friendly type water-based extinguishing agent
CN108905039A (en) * 2018-06-22 2018-11-30 厦门泰消防科技开发有限公司 Extinguishing chemical for liquid fire
CN112156414A (en) * 2020-09-29 2021-01-01 赵杰 High-efficiency instant solid extinguishing agent and preparation method thereof
CN112391175A (en) * 2019-08-19 2021-02-23 唐苑雯 Flame retardant capable of being used at low temperature and preparation method thereof
RU2790706C1 (en) * 2022-07-28 2023-02-28 Государственное бюджетное учреждение "Арктический научно-исследовательский центр Республики Саха (Якутия)" Low temperature extinguishing agent

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103288482A (en) * 2013-06-12 2013-09-11 许庆华 Composite type diatomite flame-retardant foaming agent
CN104056407A (en) * 2014-06-22 2014-09-24 许盛英 Diatomite mesh gel foam mud fire prevention and extinguishing agent
CN105396254A (en) * 2015-11-26 2016-03-16 襄阳市沧海科技有限公司 Fluorine-containing complex function extinguishing material
CN105641850A (en) * 2016-04-14 2016-06-08 郑建军 Fire extinguishing agent

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103288482A (en) * 2013-06-12 2013-09-11 许庆华 Composite type diatomite flame-retardant foaming agent
CN104056407A (en) * 2014-06-22 2014-09-24 许盛英 Diatomite mesh gel foam mud fire prevention and extinguishing agent
CN105396254A (en) * 2015-11-26 2016-03-16 襄阳市沧海科技有限公司 Fluorine-containing complex function extinguishing material
CN105641850A (en) * 2016-04-14 2016-06-08 郑建军 Fire extinguishing agent

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108421195A (en) * 2018-04-24 2018-08-21 厦门泰消防科技开发有限公司 A kind of environment-friendly type water-based extinguishing agent
CN108905039A (en) * 2018-06-22 2018-11-30 厦门泰消防科技开发有限公司 Extinguishing chemical for liquid fire
CN112391175A (en) * 2019-08-19 2021-02-23 唐苑雯 Flame retardant capable of being used at low temperature and preparation method thereof
CN112156414A (en) * 2020-09-29 2021-01-01 赵杰 High-efficiency instant solid extinguishing agent and preparation method thereof
RU2790706C1 (en) * 2022-07-28 2023-02-28 Государственное бюджетное учреждение "Арктический научно-исследовательский центр Республики Саха (Якутия)" Low temperature extinguishing agent

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