CN105396254A - Fluorine-containing complex function extinguishing material - Google Patents
Fluorine-containing complex function extinguishing material Download PDFInfo
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- CN105396254A CN105396254A CN201510832703.5A CN201510832703A CN105396254A CN 105396254 A CN105396254 A CN 105396254A CN 201510832703 A CN201510832703 A CN 201510832703A CN 105396254 A CN105396254 A CN 105396254A
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Abstract
A fluorine-containing complex function extinguishing material comprises the following components: 75-98% of water, 0.1-10% of a chemical assistant, 0.5-20% of a flame-retardant and fireproof or fire resistant material, 0-2% of a high water absorbent material, 0-8% of a pyrolysis material, 0-6% of soluble salts with the chemical inhibition function and 0-2% of other auxiliary materials; the chemical assistant comprises a perfluorocarbon surfactant and other chemical assistants, and the other chemical assistants account for 0-9.9%. The fluorine-containing complex function extinguishing material has the advantages of absorbing the advantages of a dry powder extinguishing agent, fire-extinguishing foam, a water extinguishing agent, a cement and sand extinguishing material and the like, achieves the functional advantages of the products, and can further improve the effect for covering the B-category fire disaster liquid level thanks to the perfluorocarbon surfactant. As the fluorine-containing complex function extinguishing material contains solid components, is fluid and can be conveyed by a pump body, and in addition, the specific gravity of the fluorine-containing complex function extinguishing material is greater than that of the common fire-extinguishing foam, the safe applying distance of the fluorine-containing complex function extinguishing material is greater than those of the four extinguishing materials.
Description
Technical field
The invention provides a kind of fluorine-containing complex function extinguish material, this material is gathered current dry powder, water system, foam, cement sand extinguish material functionality advantage, produce a kind of extinguish material containing the material such as solid constituent, surfactant, owing to having surfactant and blowing agent, by producing foam regulation and control proportion, by consumption and solid material, the absorbent material consumption control viscosity of water.
Background technology
One, fire extinguishing main method:
1, isolation method: the combustible of the place caught fire or object and surrounding is isolated or removed, and burning will stop because lacking combustible. during practice, as moved near flammable, the inflammable and combustion-supporting article of burning things which may cause a fire disaster; The object caught fire is moved on to safe place; Close the valve of fuel gas, fluid pipeline, reduce and stop combustible entering combustion zone etc.
2, smother play: stop air flow into combustion zone or water down air with incombustible material, comburant is made to can not get enough oxygen and extinguish. when practical application is, as do not burnt with asbestos mat, wet gunnysack, yellow sand, fire extinguisher etc. or difficult to burn material covers on object; Close cabin on fire, the door and window, hole etc. of building and the top cover of equipment container, Combustion Source of suffocating.
3, cooling method. extinguishing chemical is directly injected on comburant; To reduce the temperature of comburant. when the temperature of comburant is reduced to below the burning-point of this thing, burning just stopped. or on the combustible being sprayed onto by extinguishing chemical near burning things which may cause a fire disaster, prevent radiant heat from affecting and on fire.
4, Chemical Inhibition fire fighting method: chemical is sprayed into the chemical reaction that combustion zone makes it to participate in burning, with produced free radical or active group generation Chemical Inhibition and the secondary catalytic action of burning in combustion process, the chain reaction of burning is interrupted and fire extinguishing thus burning is stopped.
What two, powder extinguishing agent fire-fighting principle used is isolation method and Chemical Inhibition fire fighting method.(1) dry powder covers combustible surface, isolates burning things which may cause a fire disaster and combustible; (2) the volatile decomposition thing of the inorganic salts in dry powder, the free radical produced with fuel in combustion process or active group generation Chemical Inhibition and secondary catalytic action, make the chain reaction of burning interrupt and put out a fire; Shortcoming: pollute heavy; Oil can be sunk to and be lowly not suitable for oil fire; Cannot long-distance sand transport.
What three, fire foam fire-fighting principle used is isolation method and smother play.(1) relative density due to foam is less, may float on the surface of flammable liquid, or sticks to the surface of flammable solid, forms foam blanket, makes comburant surface and air insulated.
(2) froth bed is by combustible all standing, and isolated air, allows burning things which may cause a fire disaster suffocate.Shortcoming: bubble burst speed is fast, not containing solid constituent, anti-burning weak effect; Proportion is too light, is not easy to get to firepower central point.
What four, water-based extinguishing agent fire-fighting principle used is smother play and cooling method.(1) water-based extinguishing agent is made up of water, bleeding agent, fire retardant and other additives, generally with drop or with the liquid extinguisher of the form of drop and foams mix fire extinguishing; Medicament can be formed and expand thin layer moisture film on fuel oil face, makes combustible and air insulated, thus makes burning things which may cause a fire disaster anoxia asphyxia.(2) water-based extinguishing agent is containing a large amount of water, meets high temperature water evaporates and takes away amount of heat from combustion zone, and reduce the concentration of oxygen in the air of combustion zone, so as to realizing fire extinguishing.Shortcoming: not containing solid constituent, anti-burning weak effect; Large containing saliva amount, viscosity is low, and loss speed is fast, is not easy to produce to pile up effect.
What five, cement, sand extinguish material fire-fighting principle used is isolation method and smother play.(1) when running into fire, covered by cement, sand, isolation burning things which may cause a fire disaster, allows unburned material be protected; (2) by cement, sand to the covering of burning things which may cause a fire disaster material, particularly produce pile up time make burning things which may cause a fire disaster anoxia asphyxia.Shortcoming: conveying is inconvenient; Proportion is not suitable for oil fire greatly.
Summary of the invention
The object of the present invention is to provide a kind of based on water, containing water-insoluble composition, have the fluorine-containing complex function extinguish material of powder extinguishing agent, fire foam, water-based extinguishing agent, cement sand extinguish material fire-extinguishing function concurrently concurrently.
Technical scheme of the present invention is: the weight of extinguish material consists of:
(1) water (component A): 75 ~ 98%;
(2) chemical assistant (B component): 0.1 ~ 10%;
(3) fire-retardant, fire prevention or refractory material (component C): 0.5 ~ 20%;
(4) high-absorbent material (component D): 0 ~ 2%;
(5) pyrolytic material (component E) is met: 0 ~ 8%;
(6) there is organoselenocyanate soluble salts (component F): 0 ~ 6%;
(7) other auxiliary materials (component G): 0 ~ 2%;
Described chemical assistant refers to fluorocarbon surfactant, other chemical assistants, and other chemical assistants consist of 0 ~ 9.9%.
Component A water is the function that this body of material material mainly plays cooling, fluid, foaming; Also comprise the effect of adjusting viscosity.
Described fluorocarbon surfactant refers to fluorine carboanion, cation, nonionic, both sexes, special surfactant, specifically: perfluor R group sulfonate, perfluor R group phosphate, perfluor R group sulfanilic acid, perfluor R group sulfonamide, R group perfluor R group sulfonamide, perfluor R group sulfuryl fluoride, perfluoroalkyl compounds, perfluoroalkyl ester type compound, perfluor epoxy alkyl compounds, perfluor epoxy alkyl ester type compound, perfluoroalkyl epoxy alkyl high molecular polymer.
Described in described fluorocarbon surfactant, R group mainly refers to: ethyl, butyl, hexyl, octyl group; Perfluoroalkyl compounds, perfluoroalkyl ester type compound refer to perfluoroalkyl ethanol, perfluoroalkyl acrylate, perfluoralkyl phosphate, perfluoroalkyl betain, perfluoroalkyl Tetrumethylammonium Iodide compound; Perfluor epoxy alkyl compounds, perfluor epoxy alkyl ester type compound, perfluoroalkyl epoxy alkyl high molecular polymer refer to: perfluorinated ethylene oxide, perfluoro propene oxid, perfluorinated ethylene oxide acrylate, perfluorooctyl propylene ethane, perfluorooctyl propylene oxide.
Other chemical assistants described are animal protein, vegetable protein, cement blowing agent, lauryl sodium sulfate, di-sec-octyl succinate sodium sulfonate, alkylolamides, sorbitan monostearate, neopelex, sodium metasilicate, sulfosuccinic acid double tridecyl ester sodium, polyoxyethylated alkyl phenol, polyoxyethylene fatty acid fat, Polyoxyethylene fatty acid amides, secondary alkyl sulfonic acid compound derivatives, sulfonated castor oil, sodium sulfate of polyethenoxy ether of fatty alcohol, nekal, NPE, sodium diethylhexyl sulfosuccinate, octyl phenol APEO, calgon, modified sodium lignosulfonate, Sodium Polyacrylate, octyl phosphate, polyether silicone, sulfonation castor-oil plant sodium alkoxide, silicone oil, tween, sapn wherein one or more.Mainly play the effects such as film forming, dissolving, thickening, foaming, dispersing solid.
Described high-absorbent material be in macromolecule polyacrylic acid sodium, high polymer polyacrylamide, carboxymethyl cellulose, sodium carboxymethylcellulose, hydroxyethylcellulose wherein one or more.Main rising keeps material moisture content, regulates the effect of viscosity of material.
Described fire-retardant, fire prevention or refractory material be in Boratex, ammonium polyphosphate, magnesium hydroxide, aluminium hydroxide, magnesia, aluminium oxide, antimony oxide, magnesium silicate, alumina silicate, shepardite, sepiolite, calcium carbonate, magnesium carbonate, basic magnesium carbonate, asbestos, talcum, hydrotalcite, diatomite, attapulgite, bentonite wherein one or more.For one of this extinguish material material of main part, be mainly insoluble solids material, in fire extinguishing procedure, play fire-retardant buffer action.
Described chance pyrolytic material be in urea, melamine wherein one or more.The main high temperature time-division solution that rises absorbs heat, decomposes the effect producing non-flammable compressive gas dilution oxygen concentration.
It is described that to have organoselenocyanate soluble salts be aluminum phosphate, ammonium phosphate, aluminum sulfate, magnesium sulfate, alum, sodium acid carbonate, potash, in magnesium chloride, aluminium chloride, potassium chloride wherein one or more.Effect is equal to powder extinguishing agent and plays organoselenocyanate to burning things which may cause a fire disaster.
Other auxiliary materials described be in white glue with vinyl, polyvinyl alcohol, xanthans, acrylate, antifreeze wherein one or more.Main rising improves material cohesion, improves the effect of material adaptive temperature scope.
Preparation method of the present invention is that above material can stir by different order or mix, and can select assistant ingredients and proportioning in different fire or in fire extinguishing environment; Fluorocarbon surfactant, fluorocarbon surfactant and other both chemical assistants mixtures can add in extinguish material is produced, and add after also can adding before extinguish material uses or be foamed by foaming machine.
Component is A is water, is that this body of material material must add; B component and component C can add separately in contained material wherein one or more; Component D, component E, component F, component G can add separately in contained material wherein one or more, need portion of material also can not add according to assistant ingredients.
In order to improve fire-fighting efficiency, fluorine-containing complex function extinguish material proportion general control is at 0.2 ~ 0.6L/kg.
The present invention, based on water, containing water-insoluble composition, has powder extinguishing agent, fire foam, water-based extinguishing agent, cement sand extinguish material fire-extinguishing function concurrently concurrently; Be applicable to category-A, category-B and part D class fire.Under its normal temperature, state class is similar to water-based extinguishing agent, but because of containing solid constituent and water suction, thickening composition, therefore viscosity is greater than water-based extinguishing agent, sprays coverage effect and pile up effect to be better than water-based extinguishing agent, and anti-burning effect is better than fire foam and water-based extinguishing agent; Because water is body of material, so cooling effect is better than powder extinguishing agent, cement sand extinguish material, this material belongs to fluid, available pump housing conveying, so safe handling distance is greater than above four class extinguish materials.
Detailed description of the invention
embodiment 1
(1) 1000 grams, water
(2) perfluorinated octyl sulfuryl amine: 5 grams;
(3) NPE 15 grams
(4) 100 grams, talcum stone;
(5) 100 grams, diatomite
(6) sodium acid carbonate 3 grams
(7) melamine 15 grams
(8) polyvinyl alcohol 15% solution 100 grams
All pour above material into beater tub and mix 60 minutes, produce wanted fluorine-containing complex function extinguish material.
Pour No. 93 gasoline 3L into the high 250 millimeters of anti-burning tanks of diameter 30 millimeters, after lighting 60 seconds, add fluorine-containing composite fire extinguishing material by 1L per minute, fray-out of flame after 75 seconds.
embodiment 2
(1) 1000 grams, water
(2) perfluorooctyl propylene oxide 2 grams;
(3) sodium sulfate of polyethenoxy ether of fatty alcohol 40 grams
(4) polysorbate60 30 grams;
(5) antimony oxide 10 grams
(6) 70 grams, ammonium phosphate
(7) carboxymethyl cellulose 30 grams
(8) melamine 15 grams
(9) xanthans 5% solution 18 grams
Material (1), (2), (3), (4), (5), (6), (8) mixing, after 30 minutes, are added (7), (9) mix 30 minutes again and obtain extinguish material.
Pour industrial acetone 3L into the high 250 millimeters of anti-burning tanks of diameter 30 millimeters, after lighting 60 seconds, add fluorine-containing complex function extinguish material by 1L per minute, fray-out of flame after 44 seconds.After fire extinguishes, the extinguish material of fluorine-containing complex function swims on acetone liquid level, without obviously sinking to the bottom phenomenon.
embodiment 3
(1) 1000 grams, water
(2) perfluoro butyl sulfanilic acid: 5 grams;
(3) neopelex 10 grams
(4) sepiolite 50 grams;
(5) 50 grams, diatomite
(6) sodium carboxymethylcellulose 3 grams
(7) melamine 15 grams
(8) polyvinyl alcohol 15% solution 10 grams
Material (1), (2), (3), (4), (5), (7) mixing, after 30 minutes, are added (6), (8) mix 10 minutes again and obtain extinguish material.
Pour No. 120 solvent naphtha 3L into the high 250 millimeters of anti-burning tanks of diameter 30 millimeters, after lighting 60 seconds, add fluorine-containing complex function extinguish material by 1L per minute, fray-out of flame after 95 seconds.
embodiment 4
(1) 1000 grams, water
(2) perfluorinated ethylene oxide 2 grams;
(3) sodium diethylhexyl sulfosuccinate 20 grams
(4) animal protein 3 grams;
(5) ultra-fine hydrotalcite 100 grams
(6) 20 grams, potash
(7) 1 gram, macromolecule polyacrylic acid sodium
(8) 15 grams, urea
(9) xanthans 5% solution 18 grams
Material (1), (3), (4), (5), (6), (7), (8), (9) mixing, after 40 minutes, are obtained extinguish material semi-finished product; (2) carried out and water mixed foaming with foaming machine before using, foaming limit, limit is mixed in agitator and obtains extinguish material.
Pour diesel oil 3L into the high 250 millimeters of anti-burning tanks of diameter 30 millimeters, after lighting 60 seconds, add fluorine-containing complex function extinguish material by 1L per minute, fray-out of flame after 45 seconds.
embodiment 5
(1) 300 kilograms, water
(2) 1 kilogram, perfluoro octyl sulfonic acid potassium
(3) di-sec-octyl succinate sodium sulfonate 3 kilograms,
(4) sodium diethylhexyl sulfosuccinate 6 kilograms
(5) attapulgite 20 kilograms
(6) 35 kilograms, asbestos
(7) high polymer polyacrylamide 0.1 kilogram
(8) white glue with vinyl 0.5 kilogram
By material (1), (2), (3), (4), (6), mixing 30 minutes, (5), (7), (8), mix 20 minutes again, sealing preserve, stir with rapid stirring when need use and obtain required extinguish material in 5 minutes.
Get above fluorine-containing complex function extinguish material 800L, get one, steel food tray, diameter 2400 millimeters, the degree of depth 200 millimeters of wall thickness 2.5 millimeters, long 1000 millimeters high 1000 millimeters of baffle plates are plugged on side, add 90L fresh water and will try to get to the heart of a matter all standing in food tray, add 144L solvent naphtha (No. 120), after kindling a fire 60 seconds, add fluorine-containing complex function extinguish material by single-screw (single screw) pump and D50 Fire branch and fire hose conveying, after 55 seconds, fire is complete extinguishes.
embodiment 6
(1) 1000 grams, water
(2) perfluoro propene oxid 2 grams;
(3) perfluor base sodium sulfonate 2 grams
(4) the pungent fat of phosphoric acid; 3 grams
(5) 15 grams, calcium carbonate
(6) 10 grams, magnesium carbonate
(7) high polymer polyacrylamide 1 gram
(8) melamine 5 grams
(9) butyl polyacrylate 2 grams
By material (1), (5), (6), (8) mixing after 10 minutes, add (2), (3), (4), (7), (9) mix 30 minutes again and obtain extinguish material.
Pour industrial acetone 3L into the high 250 millimeters of anti-burning tanks of diameter 30 millimeters, after lighting 60 seconds, add fluorine-containing complex function extinguish material by 1L per minute, fray-out of flame after 84 seconds.
embodiment 7
(1) 300 kilograms, water
(2) butyl perfluorobutylsulfonamide 0.5 kilogram
(3) nekal 3 kilograms,
(4) polyoxyethylene fatty acid acid amides 6 kilograms
(5) super fine magnesium hydroxide 20 kilograms
(6) 35 kilograms, diatomite
(7) high polymer polyacrylamide 0.2 kilogram
By material (1), (5), (6), (8) mixing 10 minutes after, add (2), (3), (4), (7), (9) stir 20 minutes,
Produce fluorine-containing complex function extinguish material 800L, get one, steel food tray, diameter 2400 millimeters, the degree of depth 200 millimeters of wall thickness 2.5 millimeters, long 1000 millimeters high 1000 millimeters of baffle plates are plugged on side, add 90L fresh water and will try to get to the heart of a matter all standing in food tray, add 144L solvent naphtha (No. 120), after kindling a fire 60 seconds, add extinguish material by single-screw (single screw) pump and D50 Fire branch and fire hose conveying, after 95 seconds, fire is complete extinguishes.
embodiment 8
(1) 300 kilograms, water
(2) perfluoro capryl Tetrumethylammonium Iodide compound 0.5 kilogram
(3) perfluoro butyl acrylate 3 kilograms,
(4) sepiolite 16 kilograms
(5) ultrafine aluminium hydroxide 2 kilograms
(6) 25 kilograms, diatomite
(7) aluminum phosphate 1.5 kilograms
(8) high polymer polyacrylamide 0.2 kilogram
By material (1), (2), (4), (5), (6), (7), (8) mixing after 10 minutes, add (3) mixing and within 20 minutes, obtain fluorine-containing complex function extinguish material.
Get above fluorine-containing complex function extinguish material 800L, get one, steel food tray, diameter 2400 millimeters, the degree of depth 200 millimeters of wall thickness 2.5 millimeters, long 1000 millimeters high 1000 millimeters of baffle plates are plugged on side, add 90L fresh water and will try to get to the heart of a matter all standing in food tray, add 144L solvent naphtha (No. 120), after kindling a fire 60 seconds, add fluorine-containing complex function extinguish material by single-screw (single screw) pump and D50 Fire branch and fire hose conveying, after 105 seconds, fire is complete extinguishes.
embodiment 9
(1) 300 kilograms, water
(2) perfluorinated ethylene oxide acrylate 3 kilograms
(3) ammonium polyphosphate 1 kilogram,
(4) 15 kilograms, asbestos
(5) 10 kilograms, potassium chloride
(6) antifreeze 1 kilogram
By material (1), (2), (3), (4), (5), mixing 15 minutes after, then add (6) mixing within 5 minutes, obtain fluorine-containing complex function extinguish material.
Get above fluorine-containing complex function extinguish material 800L, get one, steel food tray, diameter 2400 millimeters, the degree of depth 200 millimeters of wall thickness 2.5 millimeters, long 1000 millimeters high 1000 millimeters of baffle plates are plugged on side, add 90L fresh water and will try to get to the heart of a matter all standing in food tray, add 144L solvent naphtha (No. 120), after kindling a fire 60 seconds, add fluorine-containing complex function extinguish material by single-screw (single screw) pump and D50 Fire branch and fire hose conveying, after 85 seconds, fire is complete extinguishes.
embodiment 10
(1) 300 kilograms, water
(2) full-fluorine octyl sulfuryl fluoride 0.1 kilogram
(3) Polyethylene Octylphenol Ether 8 kilograms,
(4) shepardite 3 kilograms
(5) 25 kilograms, alum
(6) high polymer polyacrylamide 0.5 kilogram
Material (1), (2), (3), (4), (5), (6) are carried out circulation mixing by singe screw jet pump and obtained fluorine-containing complex function extinguish material after 10 minutes.
Get above fluorine-containing complex function extinguish material 800L, get one, steel food tray, diameter 2400 millimeters, the degree of depth 200 millimeters of wall thickness 2.5 millimeters, long 1000 millimeters high 1000 millimeters of baffle plates are plugged on side, add 90L fresh water and will try to get to the heart of a matter all standing in food tray, add 144L solvent naphtha (No. 120), after kindling a fire 60 seconds, add fluorine-containing complex function extinguish material by single-screw (single screw) pump and D50 Fire branch and fire hose conveying, after 125 seconds, fire is complete extinguishes.
embodiment 11
(1) 300 kilograms, water
(2) perfluoro capryl phosphate 5 kilograms
(3) hydrotalcite 40 kilograms
(4) 15 kilograms, aluminium chloride
(5) sodium metasilicate 1 kilogram
First (1), (3), (4), (5) mixing are stirred for 5 minutes, then by foaming machine, (2) are added Water blown, foam and the mixing of materials stirred are obtained fluorine-containing complex function extinguish material.
Get above containing fluorine-containing complex function extinguish material 800L, get one, steel food tray, diameter 2400 millimeters, the degree of depth 200 millimeters of wall thickness 2.5 millimeters, long 1000 millimeters high 1000 millimeters of baffle plates are plugged on side, add 90L fresh water and will try to get to the heart of a matter all standing in food tray, add 144L solvent naphtha (No. 120), after kindling a fire 60 seconds, add fluorine-containing complex function extinguish material by single-screw (single screw) pump and D50 Fire branch and fire hose conveying, after 89 seconds, fire is complete extinguishes.
Claims (10)
1. a fluorine-containing complex function extinguish material, is characterized in that: the weight of extinguish material consists of:
(1) water (component A): 75 ~ 98%;
(2) chemical assistant (B component): 0.1 ~ 10%;
(3) fire-retardant, fire prevention or refractory material (component C): 0.5 ~ 20%;
(4) high-absorbent material (component D): 0 ~ 2%;
(5) pyrolytic material (component E) is met: 0 ~ 8%;
(6) there is organoselenocyanate soluble salts (component F): 0 ~ 6%;
(7) other auxiliary materials (component G): 0 ~ 2%;
Described chemical assistant refers to fluorocarbon surfactant, other chemical assistants, and other chemical assistants consist of 0 ~ 9.9%.
2. fluorine-containing complex function extinguish material according to claim 1, it is characterized in that: described fluorocarbon surfactant refers to fluorine carboanion, cation, nonionic, both sexes, special surfactant, specifically: perfluor R group sulfonate, perfluor R group phosphate, perfluor R group sulfanilic acid, perfluor R group sulfonamide, R group perfluor R group sulfonamide, perfluor R group sulfuryl fluoride, perfluoroalkyl compounds, perfluoroalkyl ester type compound, perfluor epoxy alkyl compounds, perfluor epoxy alkyl ester type compound, perfluoroalkyl epoxy alkyl high molecular polymer.
3. fluorine-containing complex function extinguish material according to claim 1, is characterized in that: described in described fluorocarbon surfactant, R group mainly refers to: ethyl, butyl, hexyl, octyl group; Perfluoroalkyl compounds, perfluoroalkyl ester type compound refer to perfluoroalkyl ethanol, perfluoroalkyl acrylate, perfluoralkyl phosphate, perfluoroalkyl betain, perfluoroalkyl Tetrumethylammonium Iodide compound; Perfluor epoxy alkyl compounds, perfluor epoxy alkyl ester type compound, perfluoroalkyl epoxy alkyl high molecular polymer refer to: perfluorinated ethylene oxide, perfluoro propene oxid, perfluorinated ethylene oxide acrylate, perfluorooctyl propylene ethane, perfluorooctyl propylene oxide.
4. fluorine-containing complex function extinguish material according to claim 1, it is characterized in that: other chemical assistants described are animal protein, vegetable protein, cement blowing agent, lauryl sodium sulfate, di-sec-octyl succinate sodium sulfonate, alkylolamides, sorbitan monostearate, neopelex, sodium metasilicate, sulfosuccinic acid double tridecyl ester sodium, polyoxyethylated alkyl phenol, polyoxyethylene fatty acid fat, Polyoxyethylene fatty acid amides, secondary alkyl sulfonic acid compound derivatives, sulfonated castor oil, sodium sulfate of polyethenoxy ether of fatty alcohol, nekal, NPE, sodium diethylhexyl sulfosuccinate, octyl phenol APEO, calgon, modified sodium lignosulfonate, Sodium Polyacrylate, octyl phosphate, polyether silicone, sulfonation castor-oil plant sodium alkoxide, silicone oil, tween, sapn wherein one or more.
5. fluorine-containing complex function extinguish material according to claim 1, is characterized in that: described high-absorbent material be in macromolecule polyacrylic acid sodium, high polymer polyacrylamide, carboxymethyl cellulose, sodium carboxymethylcellulose, hydroxyethylcellulose wherein one or more.
6. fluorine-containing complex function extinguish material according to claim 1, is characterized in that: described fire-retardant, fire prevention or refractory material be in Boratex, ammonium polyphosphate, magnesium hydroxide, aluminium hydroxide, magnesia, aluminium oxide, antimony oxide, magnesium silicate, alumina silicate, shepardite, sepiolite, calcium carbonate, magnesium carbonate, basic magnesium carbonate, asbestos, talcum, hydrotalcite, diatomite, attapulgite, bentonite wherein one or more.
7. fluorine-containing complex function extinguish material according to claim 1, is characterized in that: described chance pyrolytic material be in urea, melamine wherein one or more.
8. fluorine-containing complex function extinguish material according to claim 1, it is characterized in that: described in have organoselenocyanate soluble salts be aluminum phosphate, ammonium phosphate, aluminum sulfate, magnesium sulfate, alum, sodium acid carbonate, potash, in magnesium chloride, aluminium chloride, potassium chloride wherein one or more.
9. fluorine-containing complex function extinguish material according to claim 1, is characterized in that: other auxiliary materials described be in white glue with vinyl, polyvinyl alcohol, xanthans, acrylate, antifreeze wherein one or more.
10. a preparation method for fluorine-containing complex function extinguish material described in claim 1, is characterized in that: above material can stir by different order or mix, and can select assistant ingredients and proportioning in different fire or in fire extinguishing environment; Fluorocarbon surfactant, fluorocarbon surfactant and other both chemical assistants mixtures can add in extinguish material is produced, and add after also can adding before extinguish material uses or be foamed by foaming machine.
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