CN105638655A - Composite type pesticide penetrant and preparing method thereof - Google Patents
Composite type pesticide penetrant and preparing method thereof Download PDFInfo
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- CN105638655A CN105638655A CN201610057006.1A CN201610057006A CN105638655A CN 105638655 A CN105638655 A CN 105638655A CN 201610057006 A CN201610057006 A CN 201610057006A CN 105638655 A CN105638655 A CN 105638655A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to the technical field of pesticide penetrant, in particular to composite type pesticide penetrant. The pesticide penetrant is prepared from, by weight, 2-30 parts of anionic surfactant, 1-20 parts of nonionic surfactant and 50-97 parts of water, and further comprises 0.1-5 parts of corrosion remover. Anionic surfactant is sodium diethylhexyl sulfosuccinate, and nonionic surfactant is fatty alcohol-polyoxyethylene ether. The ratio of fatty alcohol-polyoxyethylene ether to sodium diethylhexyl sulfosuccinate is (1-6): (1-6). Anionic surfactant and nonionic surfactant are mixed according to a scientific ratio. The production cost can be reduced on the premise of improving the pesticide effect, the technology is simple, and production operation is convenient. The pesticide penetrant is thick liquid which is very soluble in water, and has the effects of emulsification, permeation, humidification, adhering and the like.
Description
Technical field
The present invention relates to pesticide penetrating agent technical field, be specifically related to a kind of compound pesticide penetrating agent.
Background technology
Pesticide penetrating agent is a kind of adjuvant in Pesticide use, owing to needing dilution before a lot of Pesticide use, so, it is necessary for adding certain pesticide penetrating agent, plays potentiation. Penetrating agent is most important to the result of use of pesticide, directly affects the prevention effect of pesticide. Through experimental results demonstrate, pesticide penetrating agent develop with proper use of, can significantly improve pesticidal effects, reduce cost.
The material of Pesticide Infiltration is increased at present mainly by common azone and high gold azone in the pesticide penetrating agent course of processing. But these additives is relatively costly, common azone addition is about 2%, and price is 40,000 yuan/ton, and only portioned product is had potentiation; High gold azone price is costly, and water insoluble.
Penetrating agent is generally divided into nonionic and anion two class. Aerosol-OT salt (fast T) belongs to anion surfactant. It has very strong penetration, permeability Quick uniform, and wettability, emulsibility, foaming characteristic are all good, and production cost is low. Fatty alcohol-polyoxyethylene ether (JFC) belongs to nonionic surfactant. Stability is higher, and water solublity is better, electrolyte-resistant, it is easy to biodegradation, and foam is little, has excellent biological degradability and cryogenic property, not by the impact of the water hardness, good with the compatibility of other surfactants, but production cost is higher. JFC can be frozen into solid, the poorly water-soluble of fast T, not easily dilutable at low temperatures. How two kinds of penetrating agent are passed through composite, obtain the better compound pesticide penetrating agent of serviceability, be the hot issue of current industry.
Summary of the invention
Present invention aims to above-mentioned Problems existing and provide a kind of containing compound pesticide penetrating agents cloudy, two kinds of surfactants of nonionic, the advantage of its acquirement be green, environmental protection and economical and practical.
Technical scheme is as follows:
A kind of compound pesticide penetrating agent, it is characterised in that: the material combination parts by weight of described pesticide penetrating agent are: anion surfactant 2-30 part;Nonionic surfactant 1-20 part; 50 parts-97 parts of water.
As preferably, described pesticide penetrating agent also includes the preservative of 0.1-5 part.
As preferably, described anion surfactant is aerosol-OT salt; Described nonionic surfactant is fatty alcohol-polyoxyethylene ether.
As preferably, the proportioning of described fatty alcohol-polyoxyethylene ether and aerosol-OT salt is 1-6:1-6.
As preferably, the proportioning of described aerosol-OT salt and fatty alcohol-polyoxyethylene ether is 1:6 or 1:2 or 1:1 or 2:1 or 6:1.
As preferably, the material combination parts by weight of described pesticide penetrating agent are: aerosol-OT salt 3 parts; Fatty alcohol-polyoxyethylene ether 18 parts; 79 parts of water.
As preferably, the material combination parts by weight of described pesticide penetrating agent are: aerosol-OT salt 7 parts; Fatty alcohol-polyoxyethylene ether 14 parts; 76 parts of water; Preservative 3 parts.
As preferably, the material combination parts by weight of described pesticide penetrating agent are: aerosol-OT salt 18 parts; Fatty alcohol-polyoxyethylene ether 3 parts; 76 parts of water; Preservative 3 parts.
The preparation method of described compound pesticide penetrating agent is following steps: when temperature 5-25 DEG C, by aerosol-OT salt (fast T), fatty alcohol-polyoxyethylene ether (JFC), water, preservative according to proportioning, it is sequentially added into equipped with in the container of agitator, open agitator to stir 5-10 minute, to being sufficiently mixed uniformly, get product.
This preservative used is the conventional preservatives of this area, is not described at this.
Aerosol-OT salt, molecular formula C20H36O7SNa. Character: faint yellow to viscous brown oily liquid. Molecular weight 444.25. Soluble in water, aqueous solution is creamy white. 1% pH value of water solution is 6.5-7. Weak to strong acid, highly basic, reducing agent, heavy metallic salt. There is significantly high penetration, permeability Quick uniform. Lubricity, emulsibility, foaming characteristic are all good. Purposes: anionic surfactant. It is widely used as emulsifying agent and the detergent of shampoo, cleaning agent and toothpaste etc. There is excellent foaminess, wettability and washing performance. Avirulence is little to skin irritation. Hard water is stablized, the generation of oil-in-water emulsifiers can be promoted.
Fatty alcohol-polyoxyethylene ether (AEO), is also called polyoxyethylene aliphatic alcohol ether. It it is kind with fastest developing speed in nonionic surfactant, that consumption is maximum. According to different requirements, 1-30 can be connected and rubs oxirane, namely can be widely used for emulsifying, moistening, help the aspects such as dye, diffusion, washing. Ehter bond in molecule is not easily destroyed by acid, alkali, so stability is higher, water solublity is better, and electrolyte-resistant, it is easy to biodegradation, foam is little. There are excellent biological degradability and cryogenic property, not by the impact of the water hardness, are more suitable for washing synthetic fibers, namely can be used for powdered formula, be applicable to again liquid detergent formula. Fatty alcohol-polyoxyethylene ether is good with the compatibility of other surfactants. Hard water is insensitive, and cold washing performance is good, but along with the rising of water temperature, its dissolubility can be gradually lowered. In the scope that pH is 3-11, fatty alcohol-polyoxyethylene ether hydrolysis-stable.
The present invention is thick liquid, without precipitation, free from admixture, has slight isooctanol abnormal smells from the patient. Heat stability is qualified, and low-temperature stability is qualified.
The invention has the beneficial effects as follows:
The present invention adopts two kinds of surfactants of anion surfactant and nonionic surfactant to mix by scientific matching.Nonionic surfactant solution adds anion surfactant, mixed micellazation can be formed, nonionic surfactant molecule inserts in micelle, repulsion between original ionic surface active agent ion is made to weaken, add the interaction between two kinds of surfactants, be easily formed micelle, make the critical micelle concentration of mixed solution decline, interfacial tension declines, and surface activity improves. JFC can be frozen into solid, the poorly water-soluble of fast T, not easily dilutable at low temperatures. After proportioning compound of the present invention, penetrating agent water solublity and temperature tolerance significantly improve, and improve the adaptability of penetrating agent. Especially as JFC: when fast T is 1:6, the present invention is more conducive to medicinal liquid and quickly moistens on plant leaf blade surface, adheres, permeates, spreads, and its resultant effect is substantially better than fast T and is used alone. JFC and fast T are carried out the compound proportioning of science by the present invention, and at the premise decline low production cost improving drug effect, and technique is simple, and production operation is convenient. The present invention is easy to become solution in the thick liquid of water, has the effects such as emulsifying, infiltration, moistening, adhesion.
Detailed description of the invention
The present invention is illustrated by specific examples below, but the present invention is limited to absolutely not these examples. The following stated is only the good embodiment of the present invention, is used only for explaining the present invention, therefore can not be interpreted as the restriction to the scope of the claims of the present invention. Therefore, the protection domain of patent of the present invention should be as the criterion with appended claims.
Embodiment 1:
A kind of compound pesticide penetrating agent, takes the raw material of following quality: aerosol-OT salt 2.9g; Fatty alcohol-polyoxyethylene ether 17.1g; Water 80g. When temperature 20 DEG C, aerosol-OT salt (fast T), fatty alcohol-polyoxyethylene ether (JFC), water are sequentially added into equipped with, in the container of agitator, opening agitator and stir 10 minutes, to being sufficiently mixed uniformly, get product.
Embodiment 2:
A kind of compound pesticide penetrating agent, takes the raw material of following quality: aerosol-OT salt 2.9g; Fatty alcohol-polyoxyethylene ether 17.1g; Water 79.7g; Preservative 0.3g. When temperature 20 DEG C, aerosol-OT salt (fast T), fatty alcohol-polyoxyethylene ether (JFC), water, preservative are sequentially added into equipped with in the container of agitator, open agitator to stir 10 minutes, to being sufficiently mixed uniformly, get product.
Embodiment 3:
A kind of compound pesticide penetrating agent, takes the raw material of following quality: aerosol-OT salt 6.7g; Fatty alcohol-polyoxyethylene ether 13.3g; Water 79.7g; Preservative 0.3g. When temperature 20 DEG C, aerosol-OT salt (fast T), fatty alcohol-polyoxyethylene ether (JFC), water, preservative are sequentially added into equipped with in the container of agitator, open agitator to stir 10 minutes, to being sufficiently mixed uniformly, get product.
Embodiment 4:
A kind of compound pesticide penetrating agent, takes the raw material of following quality: aerosol-OT salt 10g; Fatty alcohol-polyoxyethylene ether 10g; Water 79.7g; Preservative 0.3g. When temperature 20 DEG C, aerosol-OT salt (fast T), fatty alcohol-polyoxyethylene ether (JFC), water, preservative are sequentially added into equipped with in the container of agitator, open agitator to stir 10 minutes, to being sufficiently mixed uniformly, get product.
Embodiment 5:
A kind of compound pesticide penetrating agent, takes the raw material of following quality: aerosol-OT salt 13.3g;Fatty alcohol-polyoxyethylene ether 6.7g; Water 79.7g; Preservative 0.3g. When temperature 20 DEG C, aerosol-OT salt (fast T), fatty alcohol-polyoxyethylene ether (JFC), water, preservative are sequentially added into equipped with in the container of agitator, open agitator to stir 10 minutes, to being sufficiently mixed uniformly, get product.
Embodiment 6:
A kind of compound pesticide penetrating agent, takes the raw material of following quality: aerosol-OT salt 17.1g; Fatty alcohol-polyoxyethylene ether 2.9g; Water 79.7g; Preservative 0.3g. When temperature 20 DEG C, aerosol-OT salt (fast T), fatty alcohol-polyoxyethylene ether (JFC), water, preservative are sequentially added into equipped with in the container of agitator, open agitator to stir 10 minutes, to being sufficiently mixed uniformly, get product.
Experimental analysis:
1. surface tension, penetration measure contrast:
Take the solution of JFC, fast T, embodiment 2 to 6, by JFC, fast T distilled water diluting 1000 times, by the solution dilution 200 times of embodiment 2 to 6, namely often identical containing penetrating agent gross mass in group, by each group of preparation solution numbers 1 to 7, obtain form 1:
Form 1 is the surface tension of each group of preparation, penetration mensuration contrast.
JFC and the osmosis of the pesticide penetrating agent of fast T compound are more than single JFC surfactant as can be seen from the experiment, but less than single fast T surfactant. Wherein, embodiment 6 i.e. JFC: when the proportioning of fast T is 1:6, osmotic effect is closest to the penetration of fast T. The surface tension of embodiment 6 is substantially better than JFC preparation, close to the surface tension of fast T.
2. result of use measures
The present embodiment 6 is prepared product and is added separately in avermectin micro-emulsion to carry out contrast test with fast T by the applicant, and addition is 5%, prepares dosing A and dosing B.
The each composition proportion of dosing A:
Avermectin micro-emulsion accounting 16%; The present embodiment 6 accounting 5%; Water supplies 100%.
The each composition proportion of dosing B:
Avermectin micro-emulsion accounting 16%; Fast T accounting 5%; Water supplies 100%.
The each composition proportion of matched group:
Avermectin micro-emulsion accounting 16%; Water supplies 100%.
Dosing A and dosing B is diluted 1000 times at field spray with matched group, obtains three kinds of dosings result of use to beet armyworm and prepare form 2:
Form 2 is the result of use contrast of each test group.
The pesticide synergistic excellent of pesticide penetrating agent of the present invention as can be seen from the experiment, slightly above the fast T synergistic effect to pesticide, illustrate that the formula of the present embodiment 6 has the effects such as obvious emulsifying, infiltration, moistening, adhesion, its combination property effect slightly above fast T.
Additionally, Multiple Pesticides has also been carried out multiple comparison test with fast T by as above method by the present embodiment 6 by applicant, addition is 5%, dilutes 3000 times, spraying, prepares water-soluble dosage forms nitrate enhancement such as form 3 to parasite killing, sterilize, kill demodicid mite, weeding:
Form 3 is fast T and the embodiment 6 nitrate enhancement to different pesticide.
By contrast experiment it can be seen that the present invention to parasite killing, sterilize, kill demodicid mite, the water-soluble dosage forms of weeding is respectively provided with synergistic effect and its combination property effect slightly above fast T.
Claims (9)
1. a compound pesticide penetrating agent, it is characterised in that: the material combination parts by weight of described pesticide penetrating agent are: anion surfactant 2-30 part; Nonionic surfactant 1-20 part; 50 parts-97 parts of water.
2. the compound pesticide penetrating agent of one according to claim 1, it is characterised in that: described pesticide penetrating agent also includes the preservative of 0.1-5 part.
3. the compound pesticide penetrating agent of one according to claim 1, it is characterised in that: described anion surfactant is aerosol-OT salt; Described nonionic surfactant is fatty alcohol-polyoxyethylene ether.
4. the compound pesticide penetrating agent of one according to claim 3, it is characterised in that: the proportioning of described fatty alcohol-polyoxyethylene ether and aerosol-OT salt is 1-6:1-6.
5. the compound pesticide penetrating agent of one according to claim 4, it is characterised in that: the proportioning of described aerosol-OT salt and fatty alcohol-polyoxyethylene ether is 1:6 or 1:2 or 1:1 or 2:1 or 6:1.
6. the compound pesticide penetrating agent of one according to claim 5, it is characterised in that: the material combination parts by weight of described pesticide penetrating agent are: aerosol-OT salt 3 parts; Fatty alcohol-polyoxyethylene ether 18 parts; 79 parts of water.
7. the compound pesticide penetrating agent of one according to claim 5, it is characterised in that: the material combination parts by weight of described pesticide penetrating agent are: aerosol-OT salt 7 parts; Fatty alcohol-polyoxyethylene ether 14 parts; 76 parts of water; Preservative 3 parts.
8. the compound pesticide penetrating agent of one according to claim 5, it is characterised in that: the material combination parts by weight of described pesticide penetrating agent are: aerosol-OT salt 18 parts; Fatty alcohol-polyoxyethylene ether 3 parts; 76 parts of water; Preservative 3 parts.
9. the preparation method of a kind of compound pesticide penetrating agent according to claim 1-8, it is characterized in that: the preparation method of described compound pesticide penetrating agent is following steps: when temperature 5-25 DEG C, by aerosol-OT salt, fatty alcohol-polyoxyethylene ether, water, preservative according to proportioning, it is sequentially added into equipped with in the container of agitator, open agitator to stir 5-10 minute, to being sufficiently mixed uniformly, get product.
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107041366A (en) * | 2016-12-14 | 2017-08-15 | 东至绿洲环保化工有限公司 | A kind of bleeding agent added applied to agricultural chemicals |
| CN110663686A (en) * | 2019-09-30 | 2020-01-10 | 佛山市舒洁环保科技有限公司 | Environment-friendly pesticide emulsifier |
| CN111233551A (en) * | 2020-02-11 | 2020-06-05 | 济南艾高特生物技术有限公司 | Compound for improving utilization rate of pesticide and fertilizer, preparation method and application thereof |
| CN111513063A (en) * | 2020-05-14 | 2020-08-11 | 广东省科学院产业技术育成中心 | Insecticide additive and preparation method and application thereof |
| CN112956477A (en) * | 2021-02-05 | 2021-06-15 | 郑州昌安植物保护有限公司 | Permeation synergist and preparation method and application thereof |
| CN116082198A (en) * | 2023-02-07 | 2023-05-09 | 河北新启元能源技术开发股份有限公司 | Synthesis method of diisooctyl succinate sodium sulfonate |
| CN116462552A (en) * | 2023-04-17 | 2023-07-21 | 漳州环境集团有限公司 | Fertilizer for rejuvenation of green belt trees, preparation method thereof and fertilizer application method |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1672512A (en) * | 2004-03-26 | 2005-09-28 | 青岛科技大学 | Pesticide synergist containing theasaponin |
| CN101253858A (en) * | 2008-03-10 | 2008-09-03 | 淮安市农业科学研究院 | Cynanchum komarovii bactericidal agent miscible oil and microemulsion |
| CN102027900A (en) * | 2009-09-28 | 2011-04-27 | 南京华洲药业有限公司 | Synergist and synergist-containing diquat aqueous solution |
| JP2011219414A (en) * | 2010-04-09 | 2011-11-04 | Technomining Inc | Disinfection antiseptic agent used for disinfection or antisepsis of facility, environment, equipment, apparatus, and tool for producing/processing food/drink |
| CN103814935A (en) * | 2013-12-13 | 2014-05-28 | 广西田园生化股份有限公司 | Ultra-low volume concentrate containing novaluron and nicotine insecticides |
-
2016
- 2016-01-28 CN CN201610057006.1A patent/CN105638655B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1672512A (en) * | 2004-03-26 | 2005-09-28 | 青岛科技大学 | Pesticide synergist containing theasaponin |
| CN101253858A (en) * | 2008-03-10 | 2008-09-03 | 淮安市农业科学研究院 | Cynanchum komarovii bactericidal agent miscible oil and microemulsion |
| CN102027900A (en) * | 2009-09-28 | 2011-04-27 | 南京华洲药业有限公司 | Synergist and synergist-containing diquat aqueous solution |
| JP2011219414A (en) * | 2010-04-09 | 2011-11-04 | Technomining Inc | Disinfection antiseptic agent used for disinfection or antisepsis of facility, environment, equipment, apparatus, and tool for producing/processing food/drink |
| CN103814935A (en) * | 2013-12-13 | 2014-05-28 | 广西田园生化股份有限公司 | Ultra-low volume concentrate containing novaluron and nicotine insecticides |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107041366A (en) * | 2016-12-14 | 2017-08-15 | 东至绿洲环保化工有限公司 | A kind of bleeding agent added applied to agricultural chemicals |
| CN110663686A (en) * | 2019-09-30 | 2020-01-10 | 佛山市舒洁环保科技有限公司 | Environment-friendly pesticide emulsifier |
| WO2021063250A1 (en) * | 2019-09-30 | 2021-04-08 | 佛山市舒洁环保科技有限公司 | Environmentally friendly pesticide emulsifier |
| CN111233551A (en) * | 2020-02-11 | 2020-06-05 | 济南艾高特生物技术有限公司 | Compound for improving utilization rate of pesticide and fertilizer, preparation method and application thereof |
| CN111233551B (en) * | 2020-02-11 | 2022-05-13 | 济南艾高特生物技术有限公司 | Compound for improving utilization rate of pesticide and fertilizer, preparation method and application thereof |
| CN111513063A (en) * | 2020-05-14 | 2020-08-11 | 广东省科学院产业技术育成中心 | Insecticide additive and preparation method and application thereof |
| CN111513063B (en) * | 2020-05-14 | 2020-12-29 | 广东省科学院产业技术育成中心 | Insecticide additive and preparation method and application thereof |
| CN112956477A (en) * | 2021-02-05 | 2021-06-15 | 郑州昌安植物保护有限公司 | Permeation synergist and preparation method and application thereof |
| CN116082198A (en) * | 2023-02-07 | 2023-05-09 | 河北新启元能源技术开发股份有限公司 | Synthesis method of diisooctyl succinate sodium sulfonate |
| CN116082198B (en) * | 2023-02-07 | 2024-04-26 | 河北新启元能源技术开发股份有限公司 | Synthesis method of diisooctyl succinate sodium sulfonate |
| CN116462552A (en) * | 2023-04-17 | 2023-07-21 | 漳州环境集团有限公司 | Fertilizer for rejuvenation of green belt trees, preparation method thereof and fertilizer application method |
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