CN105625093A - 耐刮涂层材料 - Google Patents
耐刮涂层材料 Download PDFInfo
- Publication number
- CN105625093A CN105625093A CN201510973218.XA CN201510973218A CN105625093A CN 105625093 A CN105625093 A CN 105625093A CN 201510973218 A CN201510973218 A CN 201510973218A CN 105625093 A CN105625093 A CN 105625093A
- Authority
- CN
- China
- Prior art keywords
- coating material
- scratch resistance
- percent
- scratch
- resistance coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000463 material Substances 0.000 title claims abstract description 33
- 239000006120 scratch resistant coating Substances 0.000 title abstract 5
- 239000011248 coating agent Substances 0.000 claims abstract description 64
- 238000000576 coating method Methods 0.000 claims abstract description 63
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 18
- -1 acrylic polyol Chemical class 0.000 claims abstract description 16
- 239000002245 particle Substances 0.000 claims abstract description 15
- 229920005862 polyol Polymers 0.000 claims abstract description 8
- 229920005989 resin Polymers 0.000 claims abstract description 6
- 239000011347 resin Substances 0.000 claims abstract description 6
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 5
- 238000009826 distribution Methods 0.000 claims abstract description 5
- 238000007561 laser diffraction method Methods 0.000 claims abstract description 5
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 5
- 238000000790 scattering method Methods 0.000 claims abstract description 5
- 230000000694 effects Effects 0.000 claims description 10
- 239000008187 granular material Substances 0.000 claims description 8
- 239000000377 silicon dioxide Substances 0.000 claims description 8
- 150000005846 sugar alcohols Polymers 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 4
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 claims description 3
- 229940049657 cyclomethicone 5 Drugs 0.000 claims description 3
- 238000005286 illumination Methods 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 238000003475 lamination Methods 0.000 abstract 1
- 150000003077 polyols Chemical class 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 21
- 239000010408 film Substances 0.000 description 11
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 7
- 238000002386 leaching Methods 0.000 description 7
- 239000012528 membrane Substances 0.000 description 7
- 229910052710 silicon Inorganic materials 0.000 description 7
- 239000010703 silicon Substances 0.000 description 7
- 238000012360 testing method Methods 0.000 description 6
- 239000000178 monomer Substances 0.000 description 5
- 239000012790 adhesive layer Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000007711 solidification Methods 0.000 description 4
- 230000008023 solidification Effects 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000002390 adhesive tape Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical compound C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 description 2
- 239000011247 coating layer Substances 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 231100000241 scar Toxicity 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000002788 crimping Methods 0.000 description 1
- 230000005686 electrostatic field Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/0427—Coating with only one layer of a composition containing a polymer binder
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/40—Coatings with pigments characterised by the pigments siliceous, e.g. clays
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/042—Coating with two or more layers, where at least one layer of a composition contains a polymer binder
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/001—Release paper
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3203—Polyhydroxy compounds
- C08G18/3206—Polyhydroxy compounds aliphatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4804—Two or more polyethers of different physical or chemical nature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
- C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6674—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/549—Silicon-containing compounds containing silicon in a ring
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D171/00—Coating compositions based on polyethers obtained by reactions forming an ether link in the main chain; Coating compositions based on derivatives of such polymers
- C09D171/02—Polyalkylene oxides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/08—Polyurethanes from polyethers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/20—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for coatings strippable as coherent films, e.g. temporary coatings strippable as coherent films
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/16—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising curable or polymerisable compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/22—Polyalkenes, e.g. polystyrene
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/32—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming a linkage containing silicon in the main chain of the macromolecule
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/46—Non-macromolecular organic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/10—Homopolymers or copolymers of propene
- C08J2323/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2471/00—Characterised by the use of polyethers obtained by reactions forming an ether link in the main chain; Derivatives of such polymers
- C08J2471/02—Polyalkylene oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2475/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2475/04—Polyurethanes
- C08J2475/08—Polyurethanes from polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2475/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2475/04—Polyurethanes
- C08J2475/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dispersion Chemistry (AREA)
- Laminated Bodies (AREA)
- Adhesive Tapes (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
本发明公开一种耐刮涂层材料,所述耐刮涂层材料用于离型纸,所述耐刮涂层材料由下列质量百分含量的组分组成:硅石颗粒5%、平均分子量为500~2000的丙烯酸多元醇30%、平均分子量为200~2500的聚氧化烯系列多元醇的树脂30%、聚乙二醇20%、环甲基硅氧烷5%、1-羟基环己基苯基甲酮-光引发剂184为10%;所述硅石颗粒的粒径为由激光衍射·散射法测定的粒度分布中粒径在0.1~2μm和1.5~5μm的范围内分别具有峰值、且平均粒径为4μm或以下。本发明既解决离型纸的淋膜层与离型剂涂层涂层结合力不高、剥离力不稳定,又提高了膜表面防静电性能。
Description
技术领域
本发明涉及一种离型纸用材料,特别涉及一种耐刮涂层材料。
背景技术
离型纸又称隔离纸、防粘纸,主要用于贴覆在胶带的表面用于保护胶带表面的胶粘剂层。现有的离型纸一般是在离型纸底纸层的表面淋膜一层淋膜层(采用的材料主要有聚乙烯),然后在淋膜层的表面涂布一层离型剂涂层(采用的材料主要为硅油)得到离型纸。但是由于淋膜层平整度高,离型剂涂层与淋膜层之间附着力差,当离型纸与涂覆有高粘度粘合剂的贴膜贴附时,容易导致离型纸上的离型剂涂层被粘附力更大的粘合剂带走,从而在贴膜的局部表面形成难以清理掉的离型剂涂层区域,破坏了贴膜整体的纯净、一致性。而且由于生产过程静电过大,导致离型涂布层局部不平整,不仅影响产品剥离力稳定性,而且容易产生静电火花导致火灾。
发明内容
本发明目的是提供一种耐刮涂层材料,该耐刮涂层材料既解决离型纸的淋膜层与离型剂涂层结合力不高、剥离力不稳定,又提高了膜表面防静电性能,且同时也提高了耐刮性能。
为达到上述目的,本发明采用的技术方案是:一种耐刮涂层材料,所述耐刮涂层材料用于离型纸,所述耐刮涂层材料由下列质量百分含量的组分组成:
硅石颗粒5%,
平均分子量为500~2000的丙烯酸多元醇30%,
平均分子量为200~2500的聚氧化烯系列多元醇的树脂30%,
聚乙二醇20%,
环甲基硅氧烷5%,
1-羟基环己基苯基甲酮-光引发剂18410%;
所述硅石颗粒的粒径为由激光衍射·散射法测定的粒度分布中粒径在0.1~2μm和1.5~5μm的范围内分别具有峰值、且平均粒径为4μm或以下;
所述耐刮涂层材料采用紫外线波段为280nm~350nm,照度为1200mW/cm2,对所述雾面防静电涂层进行照射,使所述组分在1-羟基环己基苯基甲酮-光引发剂184的作用下进行聚合反应得到所述耐刮涂层材料。
上述技术方案中进一步改进的方案如下:
上述方案中,所述紫外线波段为295nm~300nm。
由于上述技术方案运用,本发明与现有技术相比具有下列优点和效果:
1、本发明耐刮涂层材料,其采用20~30%平均分子量为500~2000的丙烯酸多元醇和30~40%平均分子量为200~2500的聚氧化烯系列多元醇的树脂聚合而成的聚氨酯树脂后并与环甲基硅氧烷4~8%混合,平均分子量为500~2000的丙烯酸多元醇和平均分子量为200~2500的聚氧化烯系列多元醇的树脂中的链提高了膜表面防静电性能,且同时也提高了耐刮性能;其多元醇丙烯酸酯单体具有500~2000的平均分子量,如果分子量小于500,膜的耐磨性趋于降低,如果平均分子量超过2000,固化成膜时适用性变差。如果多元醇丙烯酸酯单体特别为乙二醇,考虑到吸水能力,本发明选择平均分子量为200~1000的聚乙二醇,利用了其优越的吸收结合水的能力,进一步提高了防静电效果。由于这种多元醇丙烯酸单体具有特别优越的吸收结合水形式的水的能力,具有防静电效果,多元醇丙烯酸酯单体全部可以使用这种单体。
2、本发明首先对薄膜层的表面涂布雾面防静电涂层,经雾面防静电涂层通过配方和工艺处理后的表面具有若干均匀凹凸结构和防静电效果,然后在此表面涂布硅离型剂涂层涂层,硅离型剂涂层涂层的底面在液态下渗入所述雾面防静电涂层表面的凹缺处,硅离型剂涂层涂层在凝固后通过凹缺处与雾面防静电涂层固定相连,因此,结合力更加牢固、可靠。而且由于防静电处理,可以消除静电对硅油涂布不稳定带来的影响,离型剥离力会很稳定,也避免生产过程静电火花的发生。
3、本发明中采用光引发剂1-羟基环己基苯基甲酮引发,主要是考虑其在波段为320-400nm紫外光照射下,可瞬间固化成膜,可达到深层固化,具有很好的平整性和强度。所述光引发剂为1-羟基环己基苯基甲酮-光引发剂184,是一种高效不黄变的紫外光引发剂,用于引发不饱和预聚体系的UV聚合反应,其质量含量为5~10%。
4、本发明耐刮涂层材料,所述硅石颗粒为粒径为由激光衍射·散射法测定的粒度分布中粒径在0.1~2μm和1.5~5μm的范围内分别具有峰值、且平均粒径为4μm或以下的硅石颗粒,既大大提高了雾面效果,又保证了固化效果。
5、本发明中紫外光的功率采用1200mW/cm2,主要是功率若低于1200mW/cm2,膜不完全固化,耐磨性降低;若功率若高于1200mW/cm2,影响膜平整度,适用性下降。采用紫外线波段为320~400nm,照度为1200mW/cm2,对所述雾面涂层剂进行照射,使所述组分在本发明特定作为光引发剂的1-羟基环己基苯基甲酮的作用下进行聚合反应得到雾面涂层,厚度为4~10μm,具有防静电效果,再在所述雾面涂层的表面涂覆一层离型剂涂层得到雾面离型层。
具体实施方式
下面结合实施例对本发明作进一步描述:
实施例:一种耐刮涂层材料,所述耐刮涂层材料用于离型纸,该耐刮涂层材料位于离型纸的薄膜层和离型纸的硅油层之间,所耐刮涂层材料与硅油层接触的表面具有若干凹凸点,该耐刮涂层材料形成的雾面防静电涂层厚度为0.95~1微米;
所述耐刮涂层材料由下列质量百分含量的组分组成:
硅石颗粒5%,
平均分子量为500~2000的丙烯酸多元醇30%,
平均分子量为200~2500的聚氧化烯系列多元醇的树脂30%,
聚乙二醇20%,
环甲基硅氧烷5%,
1-羟基环己基苯基甲酮-光引发剂18410%;
所述硅石颗粒的粒径为由激光衍射·散射法测定的粒度分布中粒径在0.1~2μm和1.5~5μm的范围内分别具有峰值、且平均粒径为4μm或以下。
离型纸由淋膜层、离型纸原纸、胶粘剂层、薄膜层、雾面防静电涂层和离型剂涂层六层依次层叠构成,所述雾面防静电涂层与离型剂涂层接触的表面的表面粗糙度为2.821μm~3.324μm。测试标准:ISO4287:1998。粗糙度测试仪:北京时代峰科技有限公司生产的TR200手持式粗糙度仪。
雾面防静电涂层为聚酯雾面涂层。首先对离型纸原纸的一面淋膜材质为PE的淋膜层,另一面涂布一层胶粘剂层,再在胶粘剂层上贴合一层薄膜层,然后在薄膜层的表面涂布雾面防静电涂层(材质为聚酯),经处理后表面具有若干均匀凹凸结构,然后在此表面涂布硅离型离型剂涂层,硅离型离型剂涂层的底面在液态下渗入所述雾面防静电涂层表面的凹缺处,硅离型离型剂涂层在凝固后通过凹缺与雾面防静电涂层固定相连,因此,结合力更加牢固、可靠。而且还可以通过调节雾面防静电涂层的雾度(即粗糙度),来自由调整硅离型离型剂涂层与离型纸原纸之间剥离力的大小。
性能指标如表1所示:
表1
(1)、外观评价:通过目视观测对外观、透明度和裂纹的存在进行评价。没有问题的膜被评定为令人满意(O),有问题的膜被评定为不令人满意(X);
(2)、手戳将离型层面手戳10次,无消光为合格,消光为不合格;
(3)、百格测试百格刀测试无脱落为合格产品,脱落为不合格产品;
(4)、剥离电压用滚轮将胶带压接(1公斤来回,速度0.3m/min)于离型膜面,其后,用手快速剥离(10m/min),用静电场测试仪(型号:SIMCOFMX-003)读取胶带粘离型膜面的剥离静电压的最大值,静电压小于0.3KV为合格产品,静电压大于0.3KV为不合格产品;
(5)、表面阻抗值用表面电阻测试仪G面两根平行铜电极置于样品表面任一处,按下黑色A键,等候30秒左右,LED显示测试处电阻,环境温湿度,作记录。显示表面电阻<1.0E+10Ω/sq,(65%RH,23℃)为合格;显示表面电阻>1.0E+10Ω/sq,(65%RH,23℃)不合格。
(6)耐磨性测试在钢丝面(#0000)的500g/cm2的加压下对硬涂层面摩擦30次后,对没有伤痕记作O,对有伤痕记作X。
(7)铅笔硬度测试按照GB/T6739-2006评价硬质涂层薄膜的铅笔硬度。
上述实施例只为说明本发明的技术构思及特点,其目的在于让熟悉此项技术的人士能够了解本发明的内容并据以实施,并不能以此限制本发明的保护范围。凡根据本发明精神实质所作的等效变化或修饰,都应涵盖在本发明的保护范围之内。
Claims (2)
1.一种耐刮涂层材料,所述耐刮涂层材料用于离型纸,其特征在于:所述耐刮涂层材料由下列质量百分含量的组分组成:
硅石颗粒5%,
平均分子量为500~2000的丙烯酸多元醇30%,
平均分子量为200~2500的聚氧化烯系列多元醇的树脂30%,
聚乙二醇20%,
环甲基硅氧烷5%,
1-羟基环己基苯基甲酮-光引发剂18410%;
所述硅石颗粒的粒径为由激光衍射·散射法测定的粒度分布中粒径在0.1~2μm和1.5~5μm的范围内分别具有峰值、且平均粒径为4μm或以下;
所述耐刮涂层材料采用紫外线波段为280nm~350nm,照度为1200mW/cm2,对所述雾面防静电涂层进行照射,使所述组分在1-羟基环己基苯基甲酮-光引发剂184的作用下进行聚合反应得到所述耐刮涂层材料。
2.根据权利要求1所述的耐刮涂层材料,其特征在于:所述紫外线波段为295nm~300nm。
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210556464.1A CN103074819B (zh) | 2012-12-20 | 2012-12-20 | 抗刮伤雾面防静电离型纸 |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201210556464.1A Division CN103074819B (zh) | 2012-12-20 | 2012-12-20 | 抗刮伤雾面防静电离型纸 |
Publications (1)
Publication Number | Publication Date |
---|---|
CN105625093A true CN105625093A (zh) | 2016-06-01 |
Family
ID=48151510
Family Applications (9)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610084834.4A Pending CN105838277A (zh) | 2012-12-20 | 2012-12-20 | 高可靠性胶带用雾面离型材料 |
CN201610084700.2A Pending CN105837844A (zh) | 2012-12-20 | 2012-12-20 | 保护胶带用抗静电离型膜 |
CN201510973218.XA Pending CN105625093A (zh) | 2012-12-20 | 2012-12-20 | 耐刮涂层材料 |
CN201610084402.3A Active CN105839460B (zh) | 2012-12-20 | 2012-12-20 | 胶带用高结合力雾面涂层材料 |
CN201510982658.1A Pending CN105603824A (zh) | 2012-12-20 | 2012-12-20 | 压敏胶带用防静电离型膜 |
CN201510979627.0A Pending CN105567111A (zh) | 2012-12-20 | 2012-12-20 | 高稳定剥离力防粘膜 |
CN201210556464.1A Active CN103074819B (zh) | 2012-12-20 | 2012-12-20 | 抗刮伤雾面防静电离型纸 |
CN201510982397.3A Pending CN105586806A (zh) | 2012-12-20 | 2012-12-20 | 雾面防静电涂层材料 |
CN201610084833.XA Active CN105839461B (zh) | 2012-12-20 | 2012-12-20 | 胶带用雾面防静电涂层 |
Family Applications Before (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610084834.4A Pending CN105838277A (zh) | 2012-12-20 | 2012-12-20 | 高可靠性胶带用雾面离型材料 |
CN201610084700.2A Pending CN105837844A (zh) | 2012-12-20 | 2012-12-20 | 保护胶带用抗静电离型膜 |
Family Applications After (6)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610084402.3A Active CN105839460B (zh) | 2012-12-20 | 2012-12-20 | 胶带用高结合力雾面涂层材料 |
CN201510982658.1A Pending CN105603824A (zh) | 2012-12-20 | 2012-12-20 | 压敏胶带用防静电离型膜 |
CN201510979627.0A Pending CN105567111A (zh) | 2012-12-20 | 2012-12-20 | 高稳定剥离力防粘膜 |
CN201210556464.1A Active CN103074819B (zh) | 2012-12-20 | 2012-12-20 | 抗刮伤雾面防静电离型纸 |
CN201510982397.3A Pending CN105586806A (zh) | 2012-12-20 | 2012-12-20 | 雾面防静电涂层材料 |
CN201610084833.XA Active CN105839461B (zh) | 2012-12-20 | 2012-12-20 | 胶带用雾面防静电涂层 |
Country Status (1)
Country | Link |
---|---|
CN (9) | CN105838277A (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108582909A (zh) * | 2018-05-02 | 2018-09-28 | 安徽九牛塑业科技有限公司 | 一种可以防静电的塑料包装材料及其制备方法 |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104962043A (zh) * | 2015-05-29 | 2015-10-07 | 吉翔宝(太仓)离型材料科技发展有限公司 | 一种pet光扩散离型膜 |
CN104975537A (zh) * | 2015-06-10 | 2015-10-14 | 东莞市尚鑫纸业有限公司 | 一种具有耐磨性能的离型纸 |
CN105002777A (zh) * | 2015-07-16 | 2015-10-28 | 吉翔宝(太仓)离型材料科技发展有限公司 | 一种抗静电抗菌离型纸及其制备方法 |
CN105002776A (zh) * | 2015-07-16 | 2015-10-28 | 吉翔宝(太仓)离型材料科技发展有限公司 | 一种耐高温抗静电离型纸及其制备方法 |
CN105133422B (zh) * | 2015-07-16 | 2017-10-10 | 吉翔宝(太仓)离型材料科技发展有限公司 | 一种抗刮耐高温抗静电离型纸及其制备方法 |
CN107724070A (zh) * | 2017-10-20 | 2018-02-23 | 浙江剑利美针织服饰有限公司 | 一种石墨烯织物及其制备方法 |
CN107828073B (zh) * | 2017-11-09 | 2021-07-06 | 合肥乐凯科技产业有限公司 | 一种离型硬化膜 |
CN110016220A (zh) * | 2019-03-08 | 2019-07-16 | 苏州中特电材有限公司 | 防静电色母 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1121942A (zh) * | 1994-06-13 | 1996-05-08 | 陶氏康宁公司 | 可辐射固化的低聚物基涂料组合物 |
JP2006169440A (ja) * | 2004-12-17 | 2006-06-29 | Central Glass Co Ltd | 防曇性物品及びその製造法、並びに防曇性被膜形成用塗布剤 |
CN101238187A (zh) * | 2005-08-17 | 2008-08-06 | 中央硝子株式会社 | 防雾涂膜和防雾制品 |
US20090017306A1 (en) * | 2007-07-14 | 2009-01-15 | Bayer Materialscience Ag | Hydrophilic hard coat films |
CN102350846A (zh) * | 2011-07-12 | 2012-02-15 | 苏州斯迪克电子胶粘材料有限公司 | 一种新型雾面离型纸的制备方法 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4890770B2 (ja) * | 2005-02-14 | 2012-03-07 | リンテック株式会社 | 防眩性ハードコートフィルムの製造方法 |
JP2008201893A (ja) * | 2007-02-20 | 2008-09-04 | Sakata Corp | 紫外線硬化型オーバープリントニス組成物、光沢印刷物の製造方法及びその方法によって得られる印刷物 |
KR20120072163A (ko) * | 2010-12-23 | 2012-07-03 | 제일모직주식회사 | Oca 필름용 광학 점착제 조성물 |
CN102330383B (zh) * | 2011-07-12 | 2013-10-30 | 苏州斯迪克新材料科技股份有限公司 | 雾面离型纸及其制备方法 |
CN202169742U (zh) * | 2011-07-12 | 2012-03-21 | 苏州斯迪克电子胶粘材料有限公司 | 雾面离型纸 |
CN102786875B (zh) * | 2012-08-27 | 2015-06-24 | 宁波惠之星新材料科技有限公司 | 抗静电硬化薄膜 |
-
2012
- 2012-12-20 CN CN201610084834.4A patent/CN105838277A/zh active Pending
- 2012-12-20 CN CN201610084700.2A patent/CN105837844A/zh active Pending
- 2012-12-20 CN CN201510973218.XA patent/CN105625093A/zh active Pending
- 2012-12-20 CN CN201610084402.3A patent/CN105839460B/zh active Active
- 2012-12-20 CN CN201510982658.1A patent/CN105603824A/zh active Pending
- 2012-12-20 CN CN201510979627.0A patent/CN105567111A/zh active Pending
- 2012-12-20 CN CN201210556464.1A patent/CN103074819B/zh active Active
- 2012-12-20 CN CN201510982397.3A patent/CN105586806A/zh active Pending
- 2012-12-20 CN CN201610084833.XA patent/CN105839461B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1121942A (zh) * | 1994-06-13 | 1996-05-08 | 陶氏康宁公司 | 可辐射固化的低聚物基涂料组合物 |
JP2006169440A (ja) * | 2004-12-17 | 2006-06-29 | Central Glass Co Ltd | 防曇性物品及びその製造法、並びに防曇性被膜形成用塗布剤 |
CN101238187A (zh) * | 2005-08-17 | 2008-08-06 | 中央硝子株式会社 | 防雾涂膜和防雾制品 |
US20090017306A1 (en) * | 2007-07-14 | 2009-01-15 | Bayer Materialscience Ag | Hydrophilic hard coat films |
CN102350846A (zh) * | 2011-07-12 | 2012-02-15 | 苏州斯迪克电子胶粘材料有限公司 | 一种新型雾面离型纸的制备方法 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108582909A (zh) * | 2018-05-02 | 2018-09-28 | 安徽九牛塑业科技有限公司 | 一种可以防静电的塑料包装材料及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN103074819B (zh) | 2016-03-02 |
CN105839460B (zh) | 2019-01-01 |
CN105603824A (zh) | 2016-05-25 |
CN105839461A (zh) | 2016-08-10 |
CN105567111A (zh) | 2016-05-11 |
CN105586806A (zh) | 2016-05-18 |
CN105839461B (zh) | 2019-01-01 |
CN105837844A (zh) | 2016-08-10 |
CN103074819A (zh) | 2013-05-01 |
CN105839460A (zh) | 2016-08-10 |
CN105838277A (zh) | 2016-08-10 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103074819B (zh) | 抗刮伤雾面防静电离型纸 | |
KR101822700B1 (ko) | 점착제 조성물, 이로부터 형성된 점착필름 및 이를 포함하는 디스플레이 부재 | |
CN104969305B (zh) | 透明层叠膜、透明导电性膜和气体阻隔性层叠膜 | |
JP5906774B2 (ja) | 積層体 | |
KR20030025914A (ko) | 대전방지 하드코트용 조성물, 대전방지 하드코트, 그제조방법 및 대전방지 하드코트를 갖는 적층체 필름 | |
CN103061207B (zh) | 新型雾面防静电离型纸的制备方法 | |
CN104769063A (zh) | 透明双面粘合片及使用其的图像显示装置 | |
CN103103875B (zh) | 用于离型膜的雾面防静电剂 | |
JP2014151496A (ja) | 透明積層フィルム及び透明基板 | |
CN103046432B (zh) | 离型材料用雾面离型剂 | |
JP2012086475A (ja) | 薄膜転写材及びその製造方法並びに薄膜付き成形体及びその製造方法 | |
JP2012086477A (ja) | 薄膜転写材及びその製造方法並びに薄膜付き成形体及びその製造方法 | |
CN108149518A (zh) | 高可靠性胶带用雾面离型材料 | |
JP2012139899A (ja) | (メタ)アクリレート系重合性組成物、それを用いた反射防止フィルム積層体及びその製造方法 | |
KR20160112053A (ko) | 평판 디스플레이용 하드코팅 필름 및 그를 이용한 반사방지 필름 | |
CN110387193A (zh) | 一种纳米金属导电膜用光学胶黏剂组合物及其胶膜 | |
JP2012086476A (ja) | 薄膜転写材及びその製造方法並びに薄膜付き成形体及びその製造方法 | |
WO2022137832A1 (ja) | 光学フィルム | |
CN202924087U (zh) | 一种覆合结构的防眩保护膜 | |
JP2014177119A (ja) | ガスバリア性積層フィルム及び透明基板 | |
TW201512335A (zh) | 耐高溫保護膜組成物及其成形方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160601 |
|
RJ01 | Rejection of invention patent application after publication |