CN105622057A - Ceramic plate for splicing outline drawing and formula process - Google Patents

Ceramic plate for splicing outline drawing and formula process Download PDF

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Publication number
CN105622057A
CN105622057A CN201610132364.4A CN201610132364A CN105622057A CN 105622057 A CN105622057 A CN 105622057A CN 201610132364 A CN201610132364 A CN 201610132364A CN 105622057 A CN105622057 A CN 105622057A
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China
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layer
green body
glaze paint
glaze
ceramic plate
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CN201610132364.4A
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CN105622057B (en
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程石明
任富国
李利方
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MANLEY (CHINA) Co Ltd
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MANLEY (CHINA) Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/1305—Organic additives
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/131—Inorganic additives
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81—Coating or impregnation
    • C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427—Silicates other than clay, e.g. water glass
    • C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427—Silicates other than clay, e.g. water glass
    • C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
    • C04B2235/3472—Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427—Silicates other than clay, e.g. water glass
    • C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
    • C04B2235/3481—Alkaline earth metal alumino-silicates other than clay, e.g. cordierite, beryl, micas such as margarite, plagioclase feldspars such as anorthite, zeolites such as chabazite

Abstract

The invention provides a ceramic plate for splicing an outline drawing and a formula process. The ceramic plate is composed of a green body layer and a glaze layer. The green body layer has a front face and an adhesion face. The front face is a flat face, and the adhesion face is a concave-convex face with grooves. The green body layer has the specifications of 800 mm*800 mm and 600 mm*600 mm and the thickness of 10 mm. The glaze layer is divided into a glaze bottom layer, a color layer and a glaze surface layer, wherein the glaze bottom layer evenly covers the front face of the green body layer, the color layer covers the upper face of the glaze bottom layer, the glaze surface layer covers the upper face of the color layer, and the thickness of the glaze layer is at least 0.3 mm. Formulas comprise a green body layer formula, a glaze bottom layer formula and a glaze surface layer formula. In the technological process, the dry press forming pressure is 280 MPa, the drying temperature is 120-312 DEG C, the drying cycle is 39 minutes, the sintering temperatures include the upper temperature of 1194 DEG C and the lower temperature of 1191 DEG C, and the sintering cycle is 48.2 minutes.

Description

A kind of ceramic plate for splicing profile picture and Recipe
Technical field
The present invention relates to a kind of ceramic plate, in particular to a kind of ceramic plate for splicing profile picture and Recipe, belong to technical field of ceramic industry.
Background technology
The pottery a lot of people of picture is very familiar. Traditional ceramic picture is by after many ceramic tile splits, and then in the glaze paint of ceramic tile different color structure according to picture, the color glaze of various different colours is adopted to draw a picture, paintings are packed up on the numbering limit, limit, the back side of ceramic tile after completing, even if the ceramic picture of a width split type completes after pyroprocessing. Also having a kind of ceramic art works and large size ceramic profile picture, ceramic plate is had special requirement by this kind of artistic work, and stable and consistent glossy and color can not be wanted in the surface being exactly ceramic plate. .
Summary of the invention
In order to solve above-mentioned splicing profile picture to the particular requirement of ceramic plate, the present invention provides a kind of ceramic plate for splicing profile picture and Recipe.
The technical solution adopted in the present invention is: a kind of ceramic plate for splicing profile picture and Recipe, the ceramic plate of splicing profile picture is made up of green body layer and glazed layer, green body layer is divided into front and bonding plane, front is plane and bonding plane is concavo-convex that has groove, the specification of green body layer comprises 800mm �� 800mm and 600mm �� 600mm two kinds, thickness is 10mm, glazed layer is divided into glaze paint bottom, color layer and glaze paint surface layer, glaze paint bottom uniform fold is in the front of green body layer, color layer covers above glaze paint bottom, glaze paint surface layer covers above color layer, the thickness of glazed layer is at least 0.3mm, formula comprises green body layer formula, glaze paint bottom formula and glaze paint surface layer formula, and the dry-pressing formed pressure in technical process is 280MPa, and drying temperature is 120 DEG C��312 DEG C, drying cycle is 39min, firing temperature is upper temperature 1194 DEG C, lower temperature 1191 DEG C, and firing period is 48.2min.
Green body layer formula comprises Yongan albite 14.4% by weight percentage, big level ground chicken girt 13.8%, dragon sea feldspar 12.8%, Zhangping land waste 11.3%, Zhangpu dirt 8.88%, Zhangping feldspar block 8.3%, great Nan carclazyte 7.89%, Cheng Xi washes 7%, east of a river washing soil 6.0%, diopside 5%, Yichuan black talc 2.5%, wilkinite 1%, Sodium salts humic acids 0.41%, water glass 0.41%, attapulgite 0.3%, methylcellulose gum 0.01%.
Glaze paint bottom formula comprises quartzite 42.2% by weight percentage, Longyan albite 14.14%, planetesimal kaolin 10.7%, zirconium silicate 8.8%, calcite 5.8%, calcined kaolin 5.8%, silicon pyroxene 3.8%, lucky polo soil 3.2%, talcum powder 2.9%, zinc oxide 2.2%, tripoly phosphate sodium STPP 0.4%, methylcellulose gum 0.06%.
Glaze paint surface layer formula comprises silica 31.3% by weight percentage, white frit 20.18%, calcined kaolin 15.5%, Longyan albite 13.9%, and lucky polo soil 8.6%, burns talcum 8.5%, aluminum oxide 1.5%, tripoly phosphate sodium STPP 0.46%, methylcellulose gum 0.06%.
The invention has the beneficial effects as follows: adopt ink-jet red ink paste used for seals can reach the color effect of high standard, cover-coat enamel is the special artistic effect that Sub-shine glaze can highlight profile and draws, and covers the extraneous factor such as the weathering invasion and attack that glaze paint surface layer can effectively prevent color layer on color layer.
Accompanying drawing explanation
Below in conjunction with accompanying drawing, the present invention is further described:
Fig. 1 is the cross-sectional structure schematic diagram of the present invention.
In figure 1, green body layer, 2, glaze paint bottom, 3, color layer, 4, glaze paint surface layer.
Embodiment
In the embodiment in figure 1, a kind of ceramic plate for splicing profile picture and Recipe, the ceramic plate of splicing profile picture is made up of green body layer 1 and glazed layer, green body layer 1 is divided into front and bonding plane, front is plane and bonding plane is concavo-convex that has groove, the specification of green body layer 1 comprises 800mm �� 800mm and 600mm �� 600mm two kinds, thickness is 10mm, glazed layer is divided into glaze paint bottom 2, color layer 3 and glaze paint surface layer 4, glaze paint bottom 2 uniform fold is in the front of green body layer 1, color layer 3 covers above glaze paint bottom 2, glaze paint surface layer 4 covers above color layer 3, the thickness of glazed layer is at least 0.3mm, formula comprises that green body layer 1 is filled a prescription, glaze paint bottom 2 is filled a prescription and glaze paint surface layer 4 is filled a prescription, and the dry-pressing formed pressure in technical process is 280MPa, and drying temperature is 120 DEG C��312 DEG C, drying cycle is 39min, firing temperature is upper temperature 1194 DEG C, lower temperature 1191 DEG C, and firing period is 48.2min.
Green body layer 1 formula comprises Yongan albite 14.4%, big level ground chicken girt 13.8%, dragon sea feldspar 12.8%, Zhangping land waste 11.3%, Zhangpu dirt 8.88%, Zhangping feldspar block 8.3%, great Nan carclazyte 7.89%, Cheng Xi washes 7%, east of a river washing soil 6.0%, diopside 5%, Yichuan black talc 2.5%, wilkinite 1%, Sodium salts humic acids 0.41%, water glass 0.41%, attapulgite 0.3%, methylcellulose gum 0.01%.
Glaze paint bottom 2 is filled a prescription and is comprised quartzite 42.2% by weight percentage, Longyan albite 14.14%, planetesimal kaolin 10.7%, zirconium silicate 8.8%, calcite 5.8%, calcined kaolin 5.8%, silicon pyroxene 3.8%, lucky polo soil 3.2%, talcum powder 2.9%, zinc oxide 2.2%, tripoly phosphate sodium STPP 0.4%, methylcellulose gum 0.06%.
Glaze paint surface layer 4 is filled a prescription and is comprised silica 31.3% by weight percentage, white frit 20.18%, calcined kaolin 15.5%, Longyan albite 13.9%, and lucky polo soil 8.6%, burns talcum 8.5%, aluminum oxide 1.5%, tripoly phosphate sodium STPP 0.46%, methylcellulose gum 0.06%.
Embodiment: first in proportion that raw material preparation is good, again raw material is added water and put into the mud that high fineness worn into by ball mill, after deironing of sieving, send into powder drying tower after mud milled carry out spraying dry, by dried powder by large-sized hydraulic press on mould dry-pressing formed, the large size ceramic slab body after shaping is sent into drying kiln and dries; The ceramic body reaching certain degree of drying is applied the laggard row color layer 3 ink-jet red ink paste used for seals of glaze paint bottom 2, then applies glaze paint surface layer 4. Finally the ceramic plate base substrate completing the splicing profile picture of technique in early stage is sent into the ceramic plate that roller kiln burning makes the splicing profile picture comprising green body layer 1, glaze paint bottom 2, color layer 3 and glaze paint surface layer 4, then after edging sorting is packed, namely can be used as finished product warehouse-in.

Claims (4)

1. one kind for splicing ceramic plate and the Recipe of profile picture, it is characterized in that: the ceramic plate of splicing profile picture is made up of green body layer and glazed layer, green body layer is divided into front and bonding plane, front is plane and bonding plane is concavo-convex that has groove, the specification of green body layer comprises 800mm �� 800mm and 600mm �� 600mm two kinds, thickness is 10mm, glazed layer is divided into glaze paint bottom, color layer and glaze paint surface layer, glaze paint bottom uniform fold is in the front of green body layer, color layer covers above glaze paint bottom, glaze paint surface layer covers above color layer, the thickness of glazed layer is at least 0.3mm, formula comprises green body layer formula, glaze paint bottom formula and glaze paint surface layer formula, and the dry-pressing formed pressure in technical process is 280MPa, and drying temperature is 120 DEG C��312 DEG C, drying cycle is 39min, firing temperature is upper temperature 1194 DEG C, lower temperature 1191 DEG C, and firing period is 48.2min.
2. a kind of ceramic plate for splicing profile picture according to claim 1 and Recipe, it is characterized in that: described green body layer formula comprises Yongan albite 14.4% by weight percentage, big level ground chicken girt 13.8%, dragon sea feldspar 12.8%, Zhangping land waste 11.3%, Zhangpu dirt 8.88%, Zhangping feldspar block 8.3%, great Nan carclazyte 7.89%, Cheng Xi washing 7%, east of a river washing soil 6.0%, diopside 5%, Yichuan black talc 2.5%, wilkinite 1%, Sodium salts humic acids 0.41%, water glass 0.41%, attapulgite 0.3%, methylcellulose gum 0.01%.
3. a kind of ceramic plate for splicing profile picture according to claim 1 and Recipe, is characterized in that: described glaze paint bottom formula comprises quartzite 42.2%, Longyan albite 14.14% by weight percentage, planetesimal kaolin 10.7%, zirconium silicate 8.8%, calcite 5.8%, calcined kaolin 5.8%, silicon pyroxene 3.8%, lucky polo soil 3.2%, talcum powder 2.9%, zinc oxide 2.2%, tripoly phosphate sodium STPP 0.4%, methylcellulose gum 0.06%.
4. a kind of ceramic plate for splicing profile picture according to claim 1 and Recipe, it is characterized in that: described glaze paint surface layer formula comprises silica 31.3% by weight percentage, white frit 20.18%, calcined kaolin 15.5%, Longyan albite 13.9%, lucky polo soil 8.6%, burn talcum 8.5%, aluminum oxide 1.5%, tripoly phosphate sodium STPP 0.46%, methylcellulose gum 0.06%.
CN201610132364.4A 2016-03-10 2016-03-10 A kind of ceramic wafer and Recipe for being used to splice profile picture Active CN105622057B (en)

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CN201610132364.4A CN105622057B (en) 2016-03-10 2016-03-10 A kind of ceramic wafer and Recipe for being used to splice profile picture

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106220134A (en) * 2016-07-14 2016-12-14 万利(中国)有限公司 A kind of abnormity deck plate
CN107555978A (en) * 2017-08-03 2018-01-09 福建省晋江万利瓷业有限公司 The thick ceramic plate and preparation technology of a kind of extrusion forming

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004299981A (en) * 2003-03-31 2004-10-28 Toto Ltd Method for producing sanitary ware
CN1686953A (en) * 2005-04-07 2005-10-26 淄博德惠来装饰瓷板有限公司 Fiber porcelain plate with vitrification glaze and preparation method in industrial scale
CN2832978Y (en) * 2005-06-09 2006-11-01 蔡元合 Multi-surface-glazing ceramic board
CN102653476A (en) * 2012-04-17 2012-09-05 陈满坚 Three-dimensional hierarchical glazed ceramic brick and method for preparing same
CN104193296A (en) * 2014-09-01 2014-12-10 张可池 Ceramic plate for cooking bench, and preparation and application method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004299981A (en) * 2003-03-31 2004-10-28 Toto Ltd Method for producing sanitary ware
CN1686953A (en) * 2005-04-07 2005-10-26 淄博德惠来装饰瓷板有限公司 Fiber porcelain plate with vitrification glaze and preparation method in industrial scale
CN2832978Y (en) * 2005-06-09 2006-11-01 蔡元合 Multi-surface-glazing ceramic board
CN102653476A (en) * 2012-04-17 2012-09-05 陈满坚 Three-dimensional hierarchical glazed ceramic brick and method for preparing same
CN104193296A (en) * 2014-09-01 2014-12-10 张可池 Ceramic plate for cooking bench, and preparation and application method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106220134A (en) * 2016-07-14 2016-12-14 万利(中国)有限公司 A kind of abnormity deck plate
CN107555978A (en) * 2017-08-03 2018-01-09 福建省晋江万利瓷业有限公司 The thick ceramic plate and preparation technology of a kind of extrusion forming

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