CN105622057B - A kind of ceramic wafer and Recipe for being used to splice profile picture - Google Patents

A kind of ceramic wafer and Recipe for being used to splice profile picture Download PDF

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Publication number
CN105622057B
CN105622057B CN201610132364.4A CN201610132364A CN105622057B CN 105622057 B CN105622057 B CN 105622057B CN 201610132364 A CN201610132364 A CN 201610132364A CN 105622057 B CN105622057 B CN 105622057B
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layer
glaze paint
formula
green
glaze
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CN105622057A (en
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程石明
任富国
李利方
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MANLEY (CHINA) Co Ltd
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MANLEY (CHINA) Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/1305Organic additives
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/131Inorganic additives
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/89Coating or impregnation for obtaining at least two superposed coatings having different compositions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • C04B2235/3463Alumino-silicates other than clay, e.g. mullite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • C04B2235/3463Alumino-silicates other than clay, e.g. mullite
    • C04B2235/3472Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • C04B2235/3463Alumino-silicates other than clay, e.g. mullite
    • C04B2235/3481Alkaline earth metal alumino-silicates other than clay, e.g. cordierite, beryl, micas such as margarite, plagioclase feldspars such as anorthite, zeolites such as chabazite

Abstract

A kind of ceramic wafer and Recipe for being used to splice profile picture, the ceramic wafer of splicing profile picture is made up of green body layer and glazed layer, green body layer is divided into front and bonding plane, front is plane and bonding plane is reeded male and fomale(M&F), the specification of green body layer includes 800mm × 800mm and two kinds of 600mm × 600mm, thickness is 10mm, glazed layer is divided into glaze paint bottom, color layer and glaze paint surface layer, glaze paint bottom uniform fold is in the front of green body layer, color layer is covered in above glaze paint bottom, glaze paint surface layer is covered in above color layer, the thickness of glazed layer is at least 0.3 mm;Formula includes base substrate layer formula, glaze paint bottom formula and glaze paint surface layer formula, and the dry-pressing formed pressure in technological process is 280MPa, and drying temperature is 120 DEG C~312 DEG C, arid cycle is 39min, firing temperature is upper 1194 DEG C of temperature, lower 1191 DEG C of temperature, firing period 48.2min.

Description

A kind of ceramic wafer and Recipe for being used to splice profile picture
Technical field
The present invention relates to a kind of ceramic wafer, more particularly to a kind of ceramic wafer and Recipe for being used to splice profile picture, Belong to technical field of ceramic industry.
Background technology
The ceramic many people of picture have been very familiar with.Traditional ceramic picture is the Ran Houzai by after many ceramic tile splits According to the different color structure of picture in the glaze paint of ceramic tile, drawn a picture using the color glaze of various different colours, paintings are completed Packed up afterwards when the back side of ceramic tile is in numbering, even if the ceramic picture through the latter width split type of high-temperature process is completed.It is also a kind of Ceramic art works are large size ceramic profile picture, and this artistic work has special requirement, exactly ceramic wafer to ceramic wafer Surface can not glossy and color want stable and consistent.
The content of the invention
In order to solve particular/special requirement of the above-mentioned splicing profile picture to ceramic wafer, the present invention provides a kind of for splicing profile The ceramic wafer and Recipe of picture.
The technical solution adopted in the present invention is:A kind of ceramic wafer and Recipe for being used to splice profile picture, splicing The ceramic wafer of profile picture is made up of green body layer and glazed layer, and green body layer is divided into front and bonding plane, and front is bonded for plane Face is reeded male and fomale(M&F), and the specification of green body layer includes 800mm × 800mm and two kinds, thickness 10mm of 600mm × 600mm, Glazed layer is divided into glaze paint bottom, color layer and glaze paint surface layer, and glaze paint bottom uniform fold is in the front of green body layer, color layer covering Above glaze paint bottom, glaze paint surface layer is covered in above color layer, and the thickness of glazed layer is at least 0.3 mm;Formula includes base Body layer formula, glaze paint bottom formula and glaze paint surface layer formula, the dry-pressing formed pressure in technological process are 280MPa, drying temperature For 120 DEG C~312 DEG C, arid cycle 39min, firing temperature is upper 1194 DEG C of temperature, lower 1191 DEG C of temperature, and firing period is 48.2min。
Base substrate layer formula includes Yongan albite 14.4%, big level ground chicken girt 13.8%, Longhai City's feldspar by weight percentage 12.8%, Zhangping land waste 11.3%, Zhangpu dirt 8.88%, Zhangping feldspar in lump 8.3%, great Nan carclazytes 7.89%, Cheng Xi washings 7%, East of a river washing soil 6.0%, diopside 5%, Yichuan black talc 2.5%, bentonite 1%, sodium humate 0.41%, sodium metasilicate 0.41% are recessed Convex rod soil 0.3%, methylcellulose 0.01%.
Glaze paint bottom formula includes quartz 42.2%, Longyan albite 14.14%, planetesimal kaolin by weight percentage 10.7%, zirconium silicate 8.8%, calcite 5.8%, calcined kaolin 5.8%, silicon pyroxene 3.8%, lucky polo soil 3.2%, talcum powder 2.9%, zinc oxide 2.2%, sodium tripolyphosphate 0.4%, methylcellulose 0.06%.
Glaze paint surface layer formula includes silica 31.3%, white frit 20.18%, calcined kaolin 15.5%, dragon by weight percentage Rock albite 13.9%, lucky polo soil 8.6%, burn talcum 8.5%, aluminum oxide 1.5%, sodium tripolyphosphate 0.46%, methylcellulose 0.06%。
The beneficial effects of the invention are as follows:The color effect of high standard can be reached using ink-jet red ink paste used for seals, cover-coat enamel is Sub-shine glaze The special artistic effect of profile picture can be highlighted, glaze paint surface layer is covered on color layer can effectively prevent weathering of color layer etc. Extraneous factor is attacked.
Brief description of the drawings
The present invention is further described below in conjunction with the accompanying drawings:
Fig. 1 is the cross-sectional structure schematic diagram of the present invention.
1, green body layer in figure, 2, glaze paint bottom, 3, color layer, 4, glaze paint surface layer.
Embodiment
In the embodiment in figure 1, a kind of ceramic wafer and Recipe for being used to splice profile picture, splicing profile picture Ceramic wafer is made up of green body layer 1 and glazed layer, and green body layer 1 is divided for front and bonding plane, front be plane and bonding plane be have it is recessed The male and fomale(M&F) of groove, the specification of green body layer 1 include 800mm × 800mm and two kinds, thickness 10mm of 600mm × 600mm, glazed layer It is divided into glaze paint bottom 2, color layer 3 and glaze paint surface layer 4, the uniform fold of glaze paint bottom 2 covers in the front of green body layer 1, color layer 3 Above glaze paint bottom 2, glaze paint surface layer 4 is covered in above color layer 3, and the thickness of glazed layer is at least 0.3 mm;Formula bag Including that green body layer 1 is formulated, glaze paint bottom 2 is formulated and glaze paint surface layer 4 is formulated, the dry-pressing formed pressure in technological process is 280MPa, Drying temperature be 120 DEG C~312 DEG C, arid cycle 39min, firing temperature is upper 1194 DEG C of temperature, lower 1191 DEG C of temperature, burns till week Phase is 48.2min.
The formula of green body layer 1 includes Yongan albite 14.4%, big level ground chicken girt 13.8%, Longhai City's feldspar 12.8%, Zhangping land waste 11.3%, Zhangpu dirt 8.88%, Zhangping feldspar in lump 8.3%, great Nan carclazytes 7.89%, Cheng Xi washings 7%, east of a river washing soil 6.0%, thoroughly Pyroxene 5%, Yichuan black talc 2.5%, bentonite 1%, sodium humate 0.41%, sodium metasilicate 0.41%, attapulgite 0.3%, methyl are fine Dimension element 0.01%.
Glaze paint bottom 2 is formulated includes quartz 42.2%, Longyan albite 14.14%, planetesimal kaolin by weight percentage 10.7%, zirconium silicate 8.8%, calcite 5.8%, calcined kaolin 5.8%, silicon pyroxene 3.8%, lucky polo soil 3.2%, talcum powder 2.9%, zinc oxide 2.2%, sodium tripolyphosphate 0.4%, methylcellulose 0.06%.
Glaze paint surface layer 4 is formulated includes silica 31.3% by weight percentage, white frit 20.18%, calcined kaolin 15.5%, Longyan albite 13.9%, lucky polo soil 8.6%, burn talcum 8.5%, aluminum oxide 1.5%, sodium tripolyphosphate 0.46%, Methyl cellulose Element 0.06%.
Embodiment:It is in proportion that raw material preparation is good first, then add water to put into the mud that ball mill wears into high fineness raw material Starch, being sent into powder drying tower after iron removaling of sieving after mud milled is spray-dried, and dried powder is passed through large-scale Hydraulic press is dry-pressing formed on mould, and the large size ceramic slab body after shaping is sent into drying kiln drying;It is certain dry to reaching The ceramic body of dry degree carries out carrying out the ink-jet red ink paste used for seals of color layer 3 after applying glaze paint bottom 2, then applies glaze paint surface layer 4.Finally will Complete early stage technique splicing profile picture ceramic wafer base substrate feeding roller kiln burning be made including green body layer 1, glaze paint bottom 2, The ceramic wafer of splicing profile picture including color layer 3 and glaze paint surface layer 4, then can be used as finished product after edging sorting packing and enter Storehouse.

Claims (1)

1. a kind of ceramic wafer for being used to splice profile picture, it is characterized in that:Splice the ceramic wafer of profile picture by green body layer and glaze Surface layer is formed, and green body layer is divided into front and bonding plane, and front is plane and bonding plane is reeded male and fomale(M&F), the rule of green body layer Lattice include 800mm × 800mm and two kinds of 600mm × 600mm, and thickness 10mm, glazed layer is divided into glaze paint bottom, color layer and glaze Face surface layer, in the front of green body layer, color layer is covered in above glaze paint bottom glaze paint bottom uniform fold, the covering of glaze paint surface layer On color layer, the thickness of glazed layer is at least 0.3 mm;Formula includes base substrate layer formula, glaze paint bottom formula and glaze paint face Layer formula, the dry-pressing formed pressure in technological process are 280MPa, and drying temperature is 120 DEG C~312 DEG C, and arid cycle is 39min, firing temperature are upper 1194 DEG C of temperature, lower 1191 DEG C of temperature, firing period 48.2min;Base substrate layer formula percentage by weight Than including Yongan albite 14.4%, big level ground chicken girt 13.8%, Longhai City's feldspar 12.8%, Zhangping land waste 11.3%, Zhangpu dirt 8.88%, Zhangping feldspar in lump 8.3%, great Nan carclazytes 7.89%, Cheng Xi washings 7%, east of a river washing soil 6.0%, diopside 5%, Yichuan is black Talcum 2.5%, bentonite 1%, sodium humate 0.41%, sodium metasilicate 0.41%, attapulgite 0.3%, methylcellulose 0.01%;Glaze paint Bottom formula includes quartz 42.2%, Longyan albite 14.14%, planetesimal kaolin 10.7%, zirconium silicate by weight percentage 8.8%, calcite 5.8%, calcined kaolin 5.8%, silicon pyroxene 3.8%, lucky polo soil 3.2%, talcum powder 2.9%, zinc oxide 2.2%, sodium tripolyphosphate 0.4%, methylcellulose 0.06%;Glaze paint surface layer formula includes silica 31.3% by weight percentage, in vain Frit 20.18%, calcined kaolin 15.5%, Longyan albite 13.9%, lucky polo soil 8.6%, burn talcum 8.5%, aluminum oxide 1.5%, sodium tripolyphosphate 0.46%, methylcellulose 0.06%.
CN201610132364.4A 2016-03-10 2016-03-10 A kind of ceramic wafer and Recipe for being used to splice profile picture Active CN105622057B (en)

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Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106220134A (en) * 2016-07-14 2016-12-14 万利(中国)有限公司 A kind of abnormity deck plate
CN107555978A (en) * 2017-08-03 2018-01-09 福建省晋江万利瓷业有限公司 The thick ceramic plate and preparation technology of a kind of extrusion forming

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1686953A (en) * 2005-04-07 2005-10-26 淄博德惠来装饰瓷板有限公司 Fiber porcelain plate with vitrification glaze and preparation method in industrial scale
CN2832978Y (en) * 2005-06-09 2006-11-01 蔡元合 Multi-surface-glazing ceramic board
CN102653476A (en) * 2012-04-17 2012-09-05 陈满坚 Three-dimensional hierarchical glazed ceramic brick and method for preparing same
CN104193296A (en) * 2014-09-01 2014-12-10 张可池 Ceramic plate for cooking bench, and preparation and application method thereof

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004299981A (en) * 2003-03-31 2004-10-28 Toto Ltd Method for producing sanitary ware

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1686953A (en) * 2005-04-07 2005-10-26 淄博德惠来装饰瓷板有限公司 Fiber porcelain plate with vitrification glaze and preparation method in industrial scale
CN2832978Y (en) * 2005-06-09 2006-11-01 蔡元合 Multi-surface-glazing ceramic board
CN102653476A (en) * 2012-04-17 2012-09-05 陈满坚 Three-dimensional hierarchical glazed ceramic brick and method for preparing same
CN104193296A (en) * 2014-09-01 2014-12-10 张可池 Ceramic plate for cooking bench, and preparation and application method thereof

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