CN105619970A - Fold-resistant hard environment-friendly composite material - Google Patents

Fold-resistant hard environment-friendly composite material Download PDF

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Publication number
CN105619970A
CN105619970A CN201510991241.1A CN201510991241A CN105619970A CN 105619970 A CN105619970 A CN 105619970A CN 201510991241 A CN201510991241 A CN 201510991241A CN 105619970 A CN105619970 A CN 105619970A
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China
Prior art keywords
parts
prepared
drying
hard environment
base fabric
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CN201510991241.1A
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Chinese (zh)
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CN105619970B (en
Inventor
李宏杰
张仁彪
陈利松
张中良
杨阳
张婷
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Zhejiang mingshida Co., Ltd
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ZHEJIANG MSD NEW MATERIAL CO Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/028Net structure, e.g. spaced apart filaments bonded at the crossing points
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/12Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/36Layered products comprising a layer of synthetic resin comprising polyesters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/24All layers being polymeric
    • B32B2250/244All polymers belonging to those covered by group B32B27/36
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/40Symmetrical or sandwich layers, e.g. ABA, ABCBA, ABCCBA
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/10Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0276Polyester fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/536Hardness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/546Flexural strength; Flexion stiffness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2309/00Parameters for the laminating or treatment process; Apparatus details
    • B32B2309/02Temperature
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2309/00Parameters for the laminating or treatment process; Apparatus details
    • B32B2309/12Pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2433/00Closed loop articles
    • B32B2433/02Conveyor belts

Landscapes

  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention relates to a fold-resistant hard environment-friendly composite material. The composite material sequentially comprises a bottom membrane, a base cloth and a surface membrane from bottom to top; the bottom membrane is prepared from, by weight, 100 parts of polyethylene glycol terephthalate and 3-8 parts of a coloring material; the surface membrane is prepared from, by weight, 100 parts of polyethylene glycol terephthalate and 3-8 parts of a coloring material; a polyester fiber gridding cloth with the specification of 800-1200 D*800-1200 D is adopted as the base cloth. The fold-resistant hard environment-friendly composite material overcomes the defect that a hard PET material generates the layer stripping phenomenon due to the fact that folding is too much and has the advantages of being good in flatness, stiff, capable of resisting folding, excellent in stripping and the like; the fold-resistant hard environment-friendly composite material can be prepared into a high-strength industrial conveyor belt after being bonded with non-slip rubber, the bearing capacity is high, and the service life is long.

Description

Folding hard environment-protective composite
Technical field
The present invention relates to a kind of composite, especially relate to a kind of folding hard environment-protective composite.
Background technology
In the 17th century, the U.S. starts to apply aerial cableway and transmits bulk material; In the middle of the 19th century, the conveyer belt conveyer of various modern structure occurs in succession. 1868, occur in that belt conveyor conveyer in Britain; 1887, occur in that conveying worm in the U.S.; 1905, occur in that steel belt conveyor in Switzerland; 1906, occur in that inertia conveyer in Britain and Germany. Hereafter, conveyer belt conveyer is subject to the impact of machine-building, motor, chemical industry and metallurgical industry technological progress, constantly perfect, the progressively transmission within finishing department, develop between enterprises, enterprise the material handling even between city, become the indispensable ingredient of materials conveying system mechanization and automatization.
PET resin (polyethylene terephthalate) is a kind of high performance engineering plastics, has good weatherability, dimensional stability, wearability. Along with the development of China's plastics industry, food and packing business, it makes consumption and range of application all in extension sharply.
Summary of the invention
For the deficiency overcoming prior art to exist, the invention provides that a kind of flatness is good, folding, environmental protection folding hard environment-protective composite.
A kind of folding hard environment-protective composite, described composite from bottom to top sequentially includes counterdie, base fabric and facial film, described counterdie is prepared by the raw material of following weight parts and is obtained: polyethylene terephthalate 100 parts, 3��8 parts of colorant, and facial film is prepared by the raw material of following weight parts and obtained: polyethylene terephthalate 100 parts, 3��8 parts of colorant; Described base fabric is 800��1200D �� 800��1200D polyester fiber grid cloth.
As preferably, described counterdie is prepared by the raw material of following weight parts and is obtained: polyethylene terephthalate 100 parts, 5 parts of colorant.
As preferably, described facial film is prepared by the raw material of following weight parts and is obtained: polyethylene terephthalate 100 parts, 5 parts of colorant.
As preferably, described base fabric is 1000D �� 1000D polyester fiber grid cloth.
As preferably, described composite is prepared by following step and is obtained: be coated with one layer of slurry on facial film, after heated drying, it is bonded semi-finished product with base fabric, these semi-finished product have the side of reticulate pattern be coated with one layer of slurry post-drying again, counterdie laminating after combined wheels is dried with starching, after last cooled sizing, cutting edge tentering is batched and is obtained.
As preferably, the starching amount on facial film is 15��22g/m2; In heating, drying process, controlling temperature is 70��120 DEG C; When bonding with base fabric, controlling temperature is 120��155 DEG C, and loading pressure is 360��420N, and binding speed is 8��12m/min.
As preferably, semi-finished product have the starching amount in the side of reticulate pattern to be 15��22g/m2; In drying course, controlling temperature is 70��120 DEG C.
As preferably, when combined wheels and the counterdie laminating after starching drying, it is 160��190 DEG C that temperature controls, and laminate pressure is 350��400N, and laminating speed is 6��10m/min. PET material hardness is big, and calendering not easily shapes, out-of-flatness when being heated, and for this at second time compound tense, optimizes the wheel gentleness speed ratio of combined wheels, then coordinates PET glue base fabric to be bonded, has reached very good fastness.
As preferably, during coating slurry, adopting 80 order gluing wheels. Because polyethylene terephthalate (PET) hardness is big, anti-roll difficulty is big, therefore improves laminating apparatus, and 80 order gluing wheels are used in employing instead, make the uniformity of gluing be improved.
As preferably, described composite is prepared by following step and is obtained:
(1) facial film is coated with one layer of slurry, after heated drying, is bonded semi-finished product with base fabric; Wherein, the starching amount on facial film is 18g/m2; In heating, drying process, controlling temperature is 90 DEG C; When bonding with base fabric, controlling temperature is 135 DEG C, and loading pressure is 390N, and binding speed is 10m/min;
(2) these semi-finished product have the side of reticulate pattern be coated with one layer of slurry post-drying again; Wherein, semi-finished product have the starching amount in the side of reticulate pattern to be 18g/m2; In drying course, controlling temperature is 90 DEG C;
(3) the counterdie laminating after combined wheels is dried with starching, after last cooled sizing, cutting edge tentering is batched and is obtained; Wherein, when combined wheels and the counterdie laminating after starching drying, it is 175 DEG C that temperature controls, and laminate pressure is 375N, and laminating speed is 8.5m/min.
Instant invention overcomes hard PET material and too much cause the shortcoming of delamination because of complications, there are flatness complications good, stiffening, resistance to, peel off the advantages such as excellent; After the present invention bonds with anti-slip rubber, it is possible to make the industrial conveyor-line of high intensity, bearing capacity is strong, long perfomance life.
Detailed description of the invention
Below in conjunction with specific embodiment, the invention will be further described, but invention which is intended to be protected is not limited to this.
Embodiment 1
A kind of folding hard environment-protective composite, described composite from bottom to top sequentially includes counterdie, base fabric and facial film, and described counterdie is prepared by the raw material of following weight parts and obtained: polyethylene terephthalate 100 parts, 5 parts of colorant; Described facial film is prepared by the raw material of following weight parts and is obtained: polyethylene terephthalate 100 parts, 5 parts of colorant; Described base fabric is 1000D �� 1000D polyester fiber grid cloth.
Described composite is prepared by following step and is obtained:
(1) facial film is coated with one layer of slurry, after heated drying, is bonded semi-finished product with base fabric; Wherein, the starching amount on facial film is 18g/m2; In heating, drying process, controlling temperature is 90 DEG C; When bonding with base fabric, controlling temperature is 135 DEG C, and loading pressure is 390N, and binding speed is 10m/min;
(2) these semi-finished product have the side of reticulate pattern be coated with one layer of slurry post-drying again; Wherein, semi-finished product have the starching amount in the side of reticulate pattern to be 18g/m2; In drying course, controlling temperature is 90 DEG C;
(3) the counterdie laminating after combined wheels is dried with starching, after last cooled sizing, cutting edge tentering is batched and is obtained; Wherein, when combined wheels and the counterdie laminating after starching drying, it is 175 DEG C that temperature controls, and laminate pressure is 375N, and laminating speed is 8.5m/min. PET material hardness is big, and calendering not easily shapes, out-of-flatness when being heated, and for this at second time compound tense, optimizes the wheel gentleness speed ratio of combined wheels, then coordinates PET glue base fabric to be bonded, has reached very good fastness.
In above-mentioned steps, during coating slurry, adopt 80 order gluing wheels. Because PET hardness is big, anti-roll difficulty is big, therefore improves laminating apparatus, and 80 order gluing wheels are used in employing instead, make the uniformity of gluing be improved. Described slurry is PET glue, is purchased from Dongguan City hundred million Hua glue company limited.
The present invention is good for a kind of flatness of research and development, folding, tasteless hard composite conveyer belt material, and this products innovation adopts PET film to adopt with 1000D �� 1000D polyester fiber grid cloth and is composited. PET material has the advantages such as good, the environmental protection of thermoplasticity, odorless, tasteless after burning, does not produce toxic gas. Product surface without water ripples, without brilliant point, folding white, grease resistance and chemical is strong, toughness and firm property, resistance to impact intensity good (under low temperature, impact strength is also good, higher by about 20% than PVC standard).
Embodiment 2
A kind of folding hard environment-protective composite, described composite from bottom to top sequentially includes counterdie, base fabric and facial film, and described counterdie is prepared by the raw material of following weight parts and obtained: polyethylene terephthalate 100 parts, 3 parts of colorant; Described facial film is prepared by the raw material of following weight parts and is obtained: polyethylene terephthalate 100 parts, 3 parts of colorant; Described base fabric is 800D �� 800D polyester fiber grid cloth.
Described composite is prepared by following step and is obtained:
(1) facial film is coated with one layer of slurry, after heated drying, is bonded semi-finished product with base fabric; Wherein, the starching amount on facial film is 15g/m2; In heating, drying process, controlling temperature is 70 DEG C; When bonding with base fabric, controlling temperature is 120 DEG C, and loading pressure is 360N, and binding speed is 8m/min;
(2) these semi-finished product have the side of reticulate pattern be coated with one layer of slurry post-drying again; Wherein, semi-finished product have the starching amount in the side of reticulate pattern to be 15g/m2; In drying course, controlling temperature is 70 DEG C;
(3) the counterdie laminating after combined wheels is dried with starching, after last cooled sizing, cutting edge tentering is batched and is obtained; Wherein, when combined wheels and the counterdie laminating after starching drying, it is 160 DEG C that temperature controls, and laminate pressure is 350N, and laminating speed is 6m/min.
In above-mentioned steps, during coating slurry, adopt 80 order gluing wheels. Because PET hardness is big, anti-roll difficulty is big, therefore improves laminating apparatus, and 80 order gluing wheels are used in employing instead, make the uniformity of gluing be improved.
Embodiment 3
A kind of folding hard environment-protective composite, described composite from bottom to top sequentially includes counterdie, base fabric and facial film, and described counterdie is prepared by the raw material of following weight parts and obtained: polyethylene terephthalate 100 parts, 8 parts of colorant; Described facial film is prepared by the raw material of following weight parts and is obtained: polyethylene terephthalate 100 parts, 8 parts of colorant; Described base fabric is 1200D �� 1200D polyester fiber grid cloth.
Described composite is prepared by following step and is obtained:
(1) facial film is coated with one layer of slurry, after heated drying, is bonded semi-finished product with base fabric; Wherein, the starching amount on facial film is 22g/m2; In heating, drying process, controlling temperature is 120 DEG C; When bonding with base fabric, controlling temperature is 155 DEG C, and loading pressure is 420N, and binding speed is 12m/min;
(2) these semi-finished product have the side of reticulate pattern be coated with one layer of slurry post-drying again; Wherein, semi-finished product have the starching amount in the side of reticulate pattern to be 22g/m2; In drying course, controlling temperature is 120 DEG C;
(3) the counterdie laminating after combined wheels is dried with starching, after last cooled sizing, cutting edge tentering is batched and is obtained; Wherein, when combined wheels and the counterdie laminating after starching drying, it is 190 DEG C that temperature controls, and laminate pressure is 400N, and laminating speed is 10m/min.
In above-mentioned steps, during coating slurry, adopt 80 order gluing wheels. Because PET hardness is big, anti-roll difficulty is big, therefore improves laminating apparatus, and 80 order gluing wheels are used in employing instead, make the uniformity of gluing be improved.
The properties of composite embodiment 1��3 prepared compares, although, indices all meets national standard. But, comparatively speaking, the properties of the preparation-obtained composite of embodiment 1 is superior to embodiment 2,3. The present invention is by preferred environmental protection raw material and improvement of production process so that it is possessing good tensile strength, elongation at break, folding quality, indices all meets national standard.
Embodiment 4
When counterdie after combined wheels and starching drying is fitted, different temperatures (160��190 DEG C), laminate pressure (350��400N) and laminating speed (6��10m/min) impact on product mechanical property, other steps are with reference to embodiment 1, found that, under certain laminating speed, along with the rising of temperature, the fracture strength of products obtained therefrom, extension at break take the lead in reducing after rising; Same, at a certain temperature, change laminating speed, along with speed is accelerated, the fracture strength of products obtained therefrom, elongation at break also embody and first raise the rule reduced afterwards; For reaching the mechanical properties such as good fracture strength, elongation at break, its preferably process conditions be: it is 175 DEG C that temperature controls, and laminate pressure is 375N, and laminating speed is 8.5m/min.

Claims (10)

1. a folding hard environment-protective composite, it is characterized in that: described composite from bottom to top sequentially includes counterdie, base fabric and facial film, described counterdie is prepared by the raw material of following weight parts and is obtained: polyethylene terephthalate 100 parts, 3��8 parts of colorant, and facial film is prepared by the raw material of following weight parts and obtained: polyethylene terephthalate 100 parts, 3��8 parts of colorant; Described base fabric is 800��1200D �� 800��1200D polyester fiber grid cloth.
2. folding hard environment-protective composite according to claim 1, it is characterised in that: described counterdie is prepared by the raw material of following weight parts and is obtained: polyethylene terephthalate 100 parts, 5 parts of colorant.
3. folding hard environment-protective composite according to claim 1, it is characterised in that: described facial film is prepared by the raw material of following weight parts and is obtained: polyethylene terephthalate 100 parts, 5 parts of colorant.
4. folding hard environment-protective composite according to claim 1, it is characterised in that: described base fabric is 1000D �� 1000D polyester fiber grid cloth.
5. folding hard environment-protective composite according to claim 1, it is characterized in that: described composite is prepared by following step and obtained: facial film is coated with one layer of slurry, after heated drying, it is bonded semi-finished product with base fabric, these semi-finished product have the side of reticulate pattern be coated with one layer of slurry post-drying again, counterdie laminating after combined wheels is dried with starching, after last cooled sizing, cutting edge tentering is batched and is obtained.
6. folding hard environment-protective composite according to claim 5, it is characterised in that: the starching amount on facial film is 15��22g/m2; In heating, drying process, controlling temperature is 70��120 DEG C; When bonding with base fabric, controlling temperature is 120��155 DEG C, and loading pressure is 360��420N, and binding speed is 8��12m/min.
7. folding hard environment-protective composite according to claim 5, it is characterised in that: semi-finished product have the starching amount in the side of reticulate pattern to be 15��22g/m2; In drying course, controlling temperature is 70��120 DEG C.
8. folding hard environment-protective composite according to claim 5, it is characterised in that: when combined wheels and the counterdie laminating after starching drying, it is 160��190 DEG C that temperature controls, and laminate pressure is 350��400N, and laminating speed is 6��10m/min.
9. folding hard environment-protective composite according to claim 5, it is characterised in that: during coating slurry, adopt 80 order gluing wheels.
10. folding hard environment-protective composite according to claim 5, it is characterised in that: described composite is prepared by following step and is obtained:
(1) facial film is coated with one layer of slurry, after heated drying, is bonded semi-finished product with base fabric; Wherein, the starching amount on facial film is 18g/m2; In heating, drying process, controlling temperature is 90 DEG C; When bonding with base fabric, controlling temperature is 135 DEG C, and loading pressure is 390N, and binding speed is 10m/min;
(2) these semi-finished product have the side of reticulate pattern be coated with one layer of slurry post-drying again; Wherein, semi-finished product have the starching amount in the side of reticulate pattern to be 18g/m2; In drying course, controlling temperature is 90 DEG C;
(3) the counterdie laminating after combined wheels is dried with starching, after last cooled sizing, cutting edge tentering is batched and is obtained; Wherein, when combined wheels and the counterdie laminating after starching drying, it is 175 DEG C that temperature controls, and laminate pressure is 375N, and laminating speed is 8.5m/min.
CN201510991241.1A 2015-12-24 2015-12-24 Folding hard environment-protective composite Active CN105619970B (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003520148A (en) * 2000-01-20 2003-07-02 ミツビシ ポリエステル フィルム ジーエムビーエイチ Thermoformable UV resistant co-extruded matte polyester film, its use and method of manufacture
CN101225611A (en) * 2008-01-29 2008-07-23 福建思嘉环保材料科技有限公司 Terylene camouflage waterproof cloth
CN101509203A (en) * 2008-12-30 2009-08-19 福建思嘉环保材料科技有限公司 Production process for high-strength dacron laminated film construction material
CN102848700A (en) * 2012-08-10 2013-01-02 浙江华生经编新材料有限公司 Gluing method of five-layer flexible composite material
CN202913578U (en) * 2012-10-17 2013-05-01 湖北卓宝建筑节能科技有限公司 Novel integrated waterproof thermal insulation board
CN103317802A (en) * 2013-06-22 2013-09-25 福州大学 High-flame-retardancy polyester-fiber-reinforced PVC (polyvinyl chloride) composite material

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003520148A (en) * 2000-01-20 2003-07-02 ミツビシ ポリエステル フィルム ジーエムビーエイチ Thermoformable UV resistant co-extruded matte polyester film, its use and method of manufacture
CN101225611A (en) * 2008-01-29 2008-07-23 福建思嘉环保材料科技有限公司 Terylene camouflage waterproof cloth
CN101509203A (en) * 2008-12-30 2009-08-19 福建思嘉环保材料科技有限公司 Production process for high-strength dacron laminated film construction material
CN102848700A (en) * 2012-08-10 2013-01-02 浙江华生经编新材料有限公司 Gluing method of five-layer flexible composite material
CN202913578U (en) * 2012-10-17 2013-05-01 湖北卓宝建筑节能科技有限公司 Novel integrated waterproof thermal insulation board
CN103317802A (en) * 2013-06-22 2013-09-25 福州大学 High-flame-retardancy polyester-fiber-reinforced PVC (polyvinyl chloride) composite material

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