CN105618885B - A method of reinforced phase is formed by regulation and strengthens composite weld structural material - Google Patents

A method of reinforced phase is formed by regulation and strengthens composite weld structural material Download PDF

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Publication number
CN105618885B
CN105618885B CN201610180155.7A CN201610180155A CN105618885B CN 105618885 B CN105618885 B CN 105618885B CN 201610180155 A CN201610180155 A CN 201610180155A CN 105618885 B CN105618885 B CN 105618885B
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Prior art keywords
solder
base material
composite
welded
welding
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CN105618885A (en
Inventor
周小玉
朱琳
王谦
梁悦
张兆芃
万朝辉
周琳
宋丽新
王思佳
郭大伟
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Zhejiang Bangchi Automobile Parts Co., Ltd.
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Zhejiang Bangchi Automobile Parts Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K1/00Soldering, e.g. brazing, or unsoldering
    • B23K1/06Soldering, e.g. brazing, or unsoldering making use of vibrations, e.g. supersonic vibrations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K1/00Soldering, e.g. brazing, or unsoldering
    • B23K1/14Soldering, e.g. brazing, or unsoldering specially adapted for soldering seams
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K1/00Soldering, e.g. brazing, or unsoldering
    • B23K1/20Preliminary treatment of work or areas to be soldered, e.g. in respect of a galvanic coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K2103/00Materials to be soldered, welded or cut
    • B23K2103/18Dissimilar materials

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Pressure Welding/Diffusion-Bonding (AREA)

Abstract

A method of reinforced phase is formed by regulation and strengthens composite weld structural material, steps are as follows: being first respectively washed the surface of base material to be welded, composite material and solder, removes oxide film dissolving, spot and grease, be dried for standby;Then above-mentioned material is assembled according to the structure of " base material/solder/composite material/solder/base material ", it is then placed in ultrasonic wave auxiliary welding device, heating keeps the temperature while applying ultrasonic wave, under the conditions of reaching predetermined temperature, ultrasonic field, it opens pressurizing device to be welded, drops to room temperature to temperature after the completion of welding, close ultrasonication, weldment is taken out, reinforced phase is obtained and strengthens composite weld structural material.The advantages and positive effects of the present invention are: this method, which forms reinforced phase by regulation, strengthens composite weld structural material, it is able to carry out metal, nonmetallic welding, combination interface reaction is controllable, residual thermal stress is smaller, bond strength is higher.

Description

A method of reinforced phase is formed by regulation and strengthens composite weld structural material
Technical field
It is especially a kind of that reinforced phase reinforcing Combined Welding is formed by regulation the present invention relates to material machine-shaping manufacturing field The method of crack structure material.
Background technique
The high-strength, reliable of material welds and connect, and leads in automobile, ship, aerospace, petrochemical industry and daily product etc. Domain has a wide range of applications.However, it is many tired to realize that high-strength, the reliable welding of material exists in cases of engineering Difficulty, such as: it is easy in different-metal material welding connector there are brittle intermetallic layer, residual thermal stress is larger and interface cohesion The problems such as weak, ceramic material welding point are easy to produce in conjunction with the problems such as weak, residual stress is big.These problems seriously affect Material generates high-strength, reliable connection.It, can be certain by improving the thinkings such as technique from the point of view of current present Research both at home and abroad Degree alleviates these problems, it is contemplated that the factors such as joint form, production flexibility, welding cost, in many occasions, these methods are suitable It is somewhat limited with property, effect needs to be further increased.
By taking the welding of different metal materials and connection as an example, different-metal material welding is to make two kinds or two kinds using welding technique The different metal of the above physics, chemistry, mechanical property realizes firm metallurgical bonding on interface and is formed and be reliably connected.Although Each metal still maintains respective primary characteristic, but its performance is more superior than single metal, therefore, dissimilar metal connection combine always by To most attention.
The welding and connection method of dissimilar metal, main includes soldering, fusion welding and Solid-State Welding etc..The basic technology of soldering It is: prepares base material and solder as requested, then use external heat source, by brazing filler metal melts, realizes interface cohesion after solder solidification. This method needs to abolish the oxidation film of master surface using brazing flux or atmosphere.The basic technology of fusion welding is: preparing as requested Then base material and solder use external heat source, base material or base material and packing material are melted, and interface knot is realized after weld seam solidification It closes.The basic technology of Pressure Welding is: preparing base material and solder as requested, then uses external heat source, base material is non-fusible, passes through Applying pressure promotes interface to realize combination.
Main problem present in above-mentioned technique is: in welding process, dissimilar metal is swift in response, acutely, be difficult to avoid that, The weld metal zone brittle intermetallic thing of generation is difficult to the effect of meeting with stresses, and be easy to cause cracking, reduces the mechanical property of welding point. At present reduce dissimilar material intermetallic compound influence thinking be generally adjust welding parameter, optimization technique, reduction heat input, And then the generation of intermetallic compound is reduced, but dissimilar metal is swift in response, and thoroughly avoids more difficult.Dissimilar material dissolves each other Property it is poor, in fusion welding, liquid phase separation, when crystallisation by cooling, causes weld seam composition uneven, is easy to happen cracking;Thermal expansion coefficient is not Together, weld seam is also easy to produce stress, causes welding deformation, leads to crack initiation;Thermal conductivity is different, and crystallization condition deteriorates, and easily causes crystalline substance Grain roughening;Metal material surface secondary oxidation film growth rapidly, can produce be mingled with, crackle, influence interface cohesion;Metal watch before welding Face cleaning technology is cumbersome, can personnel be caused with toxic side effect using brazing flux in welding process, after-welding brazing flux cleaning is difficult, easily to right The generation adverse effect of combination interface.
Summary of the invention
The purpose of the present invention is there are problem, provide a kind of to form reinforced phase by regulation and strengthen composite weld for above-mentioned The method of structural material, this method under the conditions of ultrasonic field, be used in combination by pressurization, heating, welds and connect the formation enhancing of base material weld seam The composite weld structure mutually strengthened, combination interface reaction is controllable, and bond strength is high, and residual thermal stress is small.
Technical solution of the present invention:
A method of reinforced phase is formed by regulation and strengthens composite weld structural material, steps are as follows:
1) by base material surface clean to be welded, oxide film dissolving, spot and grease is removed, is dried for standby;
2) by composite material surface polishing, polishing, cleaning, oxide film dissolving, spot and grease is removed, is dried for standby;
3) by the polishing of solder surface, polishing, cleaning, oxide film dissolving, spot and grease is removed, is dried for standby;
4) by treated base material, solder metal alloy and composite material to be welded, according to " base material/solder/composite wood The structure of material/solder/base material " assembles, and is then placed in ultrasonic wave auxiliary welding device, is heated to 50-2000 DEG C and keeps the temperature 1- 60min, while applying ultrasonic wave 0.1-120s, the vibration frequency of ultrasonic wave is 1 × 104-1×109Hz, ultrasonic power it is defeated Power is 0.01-5kW out, under the conditions of reaching predetermined temperature, ultrasonic field, opens pressurizing device and is welded, tool heads output Amplitude is 0.01-20 μm, operating pressure 0.01-5.0Mpa, drops to room temperature to temperature after the completion of welding, closes ultrasonication, Weldment is taken out, reinforced phase is obtained and strengthens composite weld structural material.
The base material to be welded is aluminium, steel, Al2O3Or ceramics.
The composite material is that silicon particle enhances composite material or silicon carbide fibre enhancing composite material.
The solder is Zn-xAl (x=0-50), Sn-xZn (x=0-80), Sn-In, Sn-Bi, Sn-Ag-Cu, Sn-Pb Or BAl88Si (9-10.5) Mg (1-2) (fusing point 591).
The advantages and positive effects of the present invention are:
This method forms reinforced phase by regulation and strengthens composite weld structural material, is able to carry out metal, nonmetallic weldering It connects, combination interface reaction is controllable, residual thermal stress is smaller, bond strength is higher.
Detailed description of the invention
Fig. 1 is the welding schematic diagram using particulate reinforced composite.
Fig. 2 is individual particle enhancing composite weld structure.
Fig. 3 enhances the welding schematic diagram of composite material using two kinds of particles.
Fig. 4 is double particle enhancing composite weld structures.
Fig. 5 is the welding schematic diagram using short fiber reinforced composite.
Fig. 6 is short fiber reinforced composite weld structure.
Fig. 7 is the welding schematic diagram using short fiber reinforced composite and particulate reinforced composite.
Fig. 8 is staple fiber-particle joint enhancing composite weld structure.
Specific embodiment
The technical solution of the present invention is not limited to the following list, further includes between each specific embodiment Combination.
Embodiment 1:
A method of reinforced phase is formed by regulation and strengthens composite weld structural material, steps are as follows:
1) base material aluminium to be welded and steel surface are cleaned, removes oxide film dissolving, spot and grease, is dried for standby;
2) by the polishing of silicon particle enhancing composite material surface, polishing, cleaning, oxide film dissolving, spot and grease is removed, is dried standby With;
3) by the polishing of the surface solder Sn-9Zn, polishing, cleaning, oxide film dissolving, spot and grease is removed, is dried for standby;
4) by treated base material, solder metal alloy and composite material to be welded, according to " aluminium/solder/composite wood The structure of material/solder/steel " assembles, as shown in Figure 1, being then placed in ultrasonic wave auxiliary welding device, being heated to 260 DEG C and protecting Warm 60min, while applying ultrasonic wave, the vibration frequency of ultrasonic wave is 100kHz, amplitude is 20 μm, and ultrasonic treatment time is The output power of 30s, ultrasonic power are 5kW, under the conditions of reaching predetermined temperature, ultrasonic field, open pressurizing device and are welded It connects, it is 10 μm, operating pressure 3.5MPa that tool heads, which export amplitude, drops to room temperature to temperature after the completion of welding, closes ultrasound and makees With taking-up weldment obtains reinforced phase and strengthens composite weld structural material.
It is as shown in Figure 2 that individual particle enhances composite weld structure.
Embodiment 2:
A method of reinforced phase is formed by regulation and strengthens composite weld structural material, step and the basic phase of embodiment 1 Together, the difference is that: used base material be titanium and aluminium oxide ceramics.
Embodiment 3:
A method of reinforced phase is formed by regulation and strengthens composite weld structural material, step and the basic phase of embodiment 1 Together, the difference is that: used solder be tinbase, zinc-base, silver-based, copper-based or acieral solder.
Embodiment 4:
A method of reinforced phase is formed by regulation and strengthens composite weld structural material, step and the basic phase of embodiment 1 Together, the difference is that: supersonic frequency be 2 × 104-1×109Hz, it is 0.01-20 μm that tool heads, which export amplitude, ultrasonic power Output power be 0.01-5kW, operating pressure 0.01-5.0Mpa.
Embodiment 5:
A method of reinforced phase is formed by regulation and strengthens composite weld structural material, step and the basic phase of embodiment 1 Together, the difference is that: operating pressure size be 0.0001-100Mpa.
Embodiment 6:
A method of reinforced phase is formed by regulation and strengthens composite weld structural material, step and the basic phase of embodiment 1 Together, the difference is that: heating temperature be 50-2000 DEG C.
Embodiment 7:
A method of reinforced phase is formed by regulation and strengthens composite weld structural material, step and the basic phase of embodiment 1 Together, the difference is that: welded using silicon particle and silicon carbide two kinds of particles enhancing composite material as middle layer, such as Shown in Fig. 3, double particle enhancing composite weld structures are obtained, as shown in Figure 4.
Embodiment 8:
A method of reinforced phase is formed by regulation and strengthens composite weld structural material, step and the basic phase of embodiment 1 Together, the difference is that: welded using carborundum brief fiber enhancing composite material as middle layer, as shown in figure 5, obtaining Short fiber reinforced composite weld structure, as shown in Figure 6.
Embodiment 9:
A method of reinforced phase is formed by regulation and strengthens composite weld structural material, step and the basic phase of embodiment 1 Together, the difference is that: use carborundum brief fiber enhancing composite material and silicon particle enhancing composite material as middle layer It is welded, as shown in fig. 7, having obtained staple fiber-particle joint enhancing composite weld structure, as shown in Figure 8.

Claims (1)

1. a kind of method for strengthening composite weld structural material by regulating and controlling to be formed reinforced phase, it is characterised in that steps are as follows:
1) by base material surface clean to be welded, oxide film dissolving, spot and grease is removed, is dried for standby;
2) by composite material surface polishing, polishing, cleaning, oxide film dissolving, spot and grease is removed, is dried for standby;
3) by the polishing of solder surface, polishing, cleaning, oxide film dissolving, spot and grease is removed, is dried for standby;
4) by treated base material, solder metal alloy and composite material to be welded, according to " base material/solder/composite material/ The structure of solder/base material " assembles, and is then placed in ultrasonic wave auxiliary welding device, is heated to 50-2000 DEG C and keeps the temperature 1- 60min, while applying ultrasonic wave 0.1-120s, the vibration frequency of ultrasonic wave is 1 × 104-1×109Hz, ultrasonic power it is defeated Power is 0.01-5kW out, under the conditions of reaching predetermined temperature, ultrasonic field, opens pressurizing device and is welded, tool heads output Amplitude is 0.01-20 μm, operating pressure 0.01-5.0Mpa, drops to room temperature to temperature after the completion of welding, closes ultrasonication, Weldment is taken out, reinforced phase is obtained and strengthens composite weld structural material;The composite material is that silicon particle enhances composite material or carbon SiClx fibre reinforced composites;The solder is Sn-xZn, Sn-In, Sn-Bi, Sn-Ag-Cu, Sn-Pb or BAl88Si (9- 10.5) Mg (1-2), wherein x=0-80, BAl88Si (9-10.5) Mg (1-2) fusing point are 591 DEG C;
Base material to be welded is respectively titanium and aluminium oxide ceramics.
CN201610180155.7A 2016-03-25 2016-03-25 A method of reinforced phase is formed by regulation and strengthens composite weld structural material Active CN105618885B (en)

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CN106735833A (en) * 2016-12-26 2017-05-31 天津理工大学 Sound based on eutectic reaction causes instant liquid-phase diffusion welding welding method
CN110293304B (en) * 2019-06-04 2021-09-28 南京理工大学 SiCpElectron beam welding method for particle reinforced aluminum-based composite material
CN112895474A (en) * 2019-12-03 2021-06-04 中国商用飞机有限责任公司 Method for connecting fiber reinforced thermoplastic composite material and metal
CN113510327B (en) * 2021-06-23 2022-12-13 上海空间推进研究所 Dissimilar material brazing gap control method and system
CN118023710A (en) * 2024-01-12 2024-05-14 北京科技大学 Steel/aluminum dissimilar metal welding method for reinforcing and toughening steel surface by adding short fibers

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JPH08164477A (en) * 1994-12-14 1996-06-25 Hitachi Kasei Shoji Kk Ultrasonic soldering joining method
JP2003238268A (en) * 2002-02-15 2003-08-27 Hitachi Ltd Method of joining metal and insulator and vacuum shut- off device
CN1792531A (en) * 2005-12-30 2006-06-28 哈尔滨工业大学 Filling composite welding flux vibrating liquid phase welding method for non-continuous strengthening aluminium base composite material
US7806994B2 (en) * 2004-05-04 2010-10-05 S-Bond Technologies, Llc Electronic package formed using low-temperature active solder including indium, bismuth, and/or cadmium
CN102260088A (en) * 2011-06-28 2011-11-30 哈尔滨工业大学 Low-stress low-temperature ceramic brazing method
CN104772542A (en) * 2015-04-14 2015-07-15 西南交通大学 WC particle in-situ reinforced hard alloy and steel ultrasonic soldering method
CN105269105A (en) * 2015-12-03 2016-01-27 天津理工大学 High-silicon aluminum alloy welding method for forming particle-reinforced weld joints through thermo-acoustic coupling

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08164477A (en) * 1994-12-14 1996-06-25 Hitachi Kasei Shoji Kk Ultrasonic soldering joining method
JP2003238268A (en) * 2002-02-15 2003-08-27 Hitachi Ltd Method of joining metal and insulator and vacuum shut- off device
US7806994B2 (en) * 2004-05-04 2010-10-05 S-Bond Technologies, Llc Electronic package formed using low-temperature active solder including indium, bismuth, and/or cadmium
CN1792531A (en) * 2005-12-30 2006-06-28 哈尔滨工业大学 Filling composite welding flux vibrating liquid phase welding method for non-continuous strengthening aluminium base composite material
CN102260088A (en) * 2011-06-28 2011-11-30 哈尔滨工业大学 Low-stress low-temperature ceramic brazing method
CN104772542A (en) * 2015-04-14 2015-07-15 西南交通大学 WC particle in-situ reinforced hard alloy and steel ultrasonic soldering method
CN105269105A (en) * 2015-12-03 2016-01-27 天津理工大学 High-silicon aluminum alloy welding method for forming particle-reinforced weld joints through thermo-acoustic coupling

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