CN105586166A - 一种耐腐蚀的玻璃清洁剂及其制备方法 - Google Patents

一种耐腐蚀的玻璃清洁剂及其制备方法 Download PDF

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CN105586166A
CN105586166A CN201610124302.9A CN201610124302A CN105586166A CN 105586166 A CN105586166 A CN 105586166A CN 201610124302 A CN201610124302 A CN 201610124302A CN 105586166 A CN105586166 A CN 105586166A
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费金华
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Suzhou Shengpula New Material Technology Co Ltd
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Abstract

本发明公开了一种耐腐蚀的玻璃清洁剂，包括以下重量百分比的原料：表面活性剂10～20％、羟基化合物20～40％、去污增进剂0.5～2％、纳米胶体粒子0.1～0.5％、添加剂0.1～0.5％、其他原料成分0.2～1％及余量的去离子水。本发明提供的玻璃清洗剂清洗效果好，对玻璃制品清洗以后，无任何残物，去污能力可达98％以上；所选原料配方温和，防止清洁剂对玻璃制品的刺激，避免腐蚀现象发生，有效保护清洁的玻璃制品及玻璃制品配件，使用安全可靠。

Description

一种耐腐蚀的玻璃清洁剂及其制备方法
技术领域
本发明涉及玻璃清洗/清洁剂领域，具体涉及一种具有耐腐蚀功能的玻璃清洁剂及其制备方法。
背景技术
玻璃清洁剂为主要适用于有机玻璃、无机玻璃、光学玻璃、树脂玻璃等各种玻璃用品和光学镜片、眼镜镜片、泳镜镜片、摄影器材镜头、高档精密玻璃仪器的高效清洁制剂。
在现实生活中，人们经常使用自来水或洗洁精来代替玻璃清洗剂用于玻璃的清洁，因为人们印象中玻璃为高耐腐蚀性制品，但事实上，当玻璃在大气和弱酸等介质中使用一段时间后，用肉眼即可观察到玻璃表面粗糙、污染和斑点腐蚀等迹象。长期使用自来水或劣质玻璃清洗剂清洗玻璃制品不但清洗效果差，而且可能导致精密玻璃部件腐蚀损坏、与玻璃连接的零配金属部件腐蚀和污损等情况的产生。
发明内容
针对现有技术不足，本发明提供了一种耐腐蚀的玻璃清洁剂及其制备方法，在取得良好清洁效果的同时，有效保护玻璃制品，避免精密玻璃部件腐蚀损坏。
本发明解决上述技术问题采用的技术方案为：一种耐腐蚀的玻璃清洁剂，包括以下重量百分比的原料：
表面活性剂:10～20％
羟基化合物:20～40％
去污增进剂:0.5～2％
纳米胶体粒子:0.1～0.5％
添加剂:0.1～0.5％
其他原料成分:0.2～1％
去离子水:余量；
所述表面活性剂包括非离子表面活性剂及阴离子表面活性剂，其质量比为1～3：1；所述非离子表面活性剂为脂肪醇聚氧乙烯醚、辛基酚聚氧乙烯醚、椰油酸聚氧乙烯醚、壬基酚聚氧乙烯醚中的一种或几种，所述阴离子表面活性剂为脂肪醇聚氧乙烯醚硫酸钠、十二烷基硫酸钠、烷基磺基琥珀酸单酯二钠中的一种或几种；
所述羟基化合物为异丙醇以及甲醇、乙醇、丙醇、苯酚中的一种或几种，所述异丙醇占羟基化合物的质量比为60～85％，所述羰基化合物主要为醇类化合物，可以起到润湿和抗冻的作用，使得清洁剂可在寒冷的冬季起到良好的清洁效果；
所述去污增进剂为三乙醇胺、聚乙烯比咯烷酮中的一种或几种，具有抗污垢再沉淀性能，可以增强净洗能力，防止清洁剂对玻璃制品的刺激，避免腐蚀现象发生；
所述纳米胶体粒子为纳米级硅藻土、白土、滑石粉、膨润土中的一种，纳米级胶体粒子可起到研磨和吸附作用，达到洗净、吸污的目的；
所述添加剂为染料、香料、防腐剂中的一种或几种；
所述其他原料成分为1,12-二组氨酸基十二烷基二胺盐、醋酸、苯并三氮唑、季铵盐中的一种或几种。
进一步地，所述染料为水性食用色素，其占清洁剂原料的重量百分比＜0.05％。
进一步地，所述香料为水溶性香精，其占清洁剂原料的重量百分比＜0.15％。
进一步地，所述防腐剂为泥泊金酯、均三嗪、羟甲基氨基乙酸钠、辛酸甘油酯中的一种或几种，所述防腐剂占清洁剂原料的重量百分比＜0.3％，本发明中优选尼泊金酯为防腐添加剂。
一种耐腐蚀的玻璃清洁剂的制备方法，包括以下步骤：将羰基化合物和去离子水加入至反应釜中，在常温下搅拌2min，然后将所得溶液加热至45℃，再依次加入非离子表面活性剂和阴离子表面活性剂，搅拌均匀后再依次加入其他原料成分、去污增进剂、纳米胶体粒子、添加剂至反应釜中，搅拌20min后，降温、除泡、包装后既得本发明的玻璃清洁剂。
与现有技术相比，本发明具备的有益效果：本发明提供的玻璃清洗剂清洗效果好，很容易除去玻璃上的各种污垢，包括灰尘、各种食用油、虫胶等，对玻璃制品清洗以后，无任何残物，去污能力可达98％以上；所选原料配方温和，防止清洁剂对玻璃制品的刺激，避免腐蚀现象发生，有效保护清洁的玻璃制品及玻璃制品配件，使用安全可靠。
具体实施方式
下面结合具体实施例对本发明做进一步的说明。
下表为本实施例的优选配方：
以上实施例中所述的一种耐腐蚀的玻璃清洁剂的制备方法，包括以下步骤：将羰基化合物和去离子水加入至反应釜中，在常温下搅拌2min，然后将所得溶液加热至45℃，再依次加入非离子表面活性剂和阴离子表面活性剂，搅拌均匀后再依次加入其他原料成分、去污增进剂、纳米胶体粒子、添加剂至反应釜中，搅拌20min后，降温、除泡、包装后既得本发明的玻璃清洁剂。
为了观察本发明产品的效果，对去污力、防腐蚀性能进行实验测试，去污力采用CAS144标准，防腐蚀性能采用GB/T23436-2009标准进行测试，并采用市面上常见的玻璃洗涤剂作为对照例进行等同测试。具体测试结果如下表所示：
*腐蚀性测试结果数据表示的是按照测试标准测试所得到的质量变化数据，单位为mg/cm2。

Claims (5)

1.一种耐腐蚀的玻璃清洁剂，其特征在于，包括以下重量百分比的原料：
表面活性剂:10～20％
羟基化合物:20～40％
去污增进剂:0.5～2％
纳米胶体粒子:0.1～0.5％
添加剂:0.1～0.5％
其他原料成分:0.2～1％
去离子水:余量；
所述表面活性剂包括非离子表面活性剂及阴离子表面活性剂，其质量比为1～3：1；所述非离子表面活性剂为脂肪醇聚氧乙烯醚、辛基酚聚氧乙烯醚、椰油酸聚氧乙烯醚、壬基酚聚氧乙烯醚中的一种或几种，所述阴离子表面活性剂为脂肪醇聚氧乙烯醚硫酸钠、十二烷基硫酸钠、烷基磺基琥珀酸单酯二钠中的一种或几种；
所述羟基化合物为异丙醇以及甲醇、乙醇、丙醇、苯酚中的一种或几种，所述异丙醇占羟基化合物的质量比为60～85％；
所述去污增进剂为三乙醇胺、聚乙烯比咯烷酮中的一种或几种；
所述纳米胶体粒子为纳米级硅藻土、白土、滑石粉、膨润土中的一种；
所述添加剂为染料、香料、防腐剂中的一种或几种；
所述其他原料成分为1,12-二组氨酸基十二烷基二胺盐、醋酸、苯并三氮唑、季铵盐中的一种或几种。
2.根据权利要求1所述的一种耐腐蚀的玻璃清洁剂，其特征在于：所述染料为水性食用色素，其占清洁剂原料的重量百分比＜0.05％。
3.根据权利要求1所述的一种耐腐蚀的玻璃清洁剂，其特征在于：所述香料为水溶性香精，其占清洁剂原料的重量百分比＜0.15％。
4.根据权利要求1所述的一种耐腐蚀的玻璃清洁剂，其特征在于：所述防腐剂为泥泊金酯、均三嗪、羟甲基氨基乙酸钠、辛酸甘油酯中的一种或几种，所述防腐剂占清洁剂原料的重量百分比＜0.3％。
5.一种耐腐蚀的玻璃清洁剂的制备方法，其特征在于，包括以下步骤：
将羰基化合物和去离子水加入至反应釜中，在常温下搅拌2min，然后将所得溶液加热至45℃，再依次加入非离子表面活性剂和阴离子表面活性剂，搅拌均匀后再依次加入其他原料成分、去污增进剂、纳米胶体粒子、添加剂至反应釜中，搅拌20min后，降温、除泡、包装后既得本发明的玻璃清洁剂。
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CN106434014A (zh) * 2016-10-11 2017-02-22 安徽卡塔门窗有限公司 一种窗户玻璃的清洁剂及其制备方法
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