CN105585927B - A kind of LED solidifications spary coating type vacuum metallizing coating and preparation method thereof - Google Patents
A kind of LED solidifications spary coating type vacuum metallizing coating and preparation method thereof Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/10—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers containing more than one epoxy radical per molecule
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- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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Abstract
The present invention discloses a kind of LED solidifications spary coating type vacuum metallizing coating, the material matched by following parts by weight is made, including 14 28 parts of urethane acrylate, 7 15 parts of ethoxyquin trimethylolpropane trimethacrylate, 18 12 parts of hydroxy-cyclohexyl benzyl ketone, 12 24 parts of epoxy resin, 9 15 parts of amino resins, 6 10 parts of butyl acrylate, 48 parts of hydroxyethyl methacrylate, 26 parts of methacrylic acid, 13 parts of wetting dispersing agent, 13 parts of defoamer, 13 parts of styrene, 24 parts of alcohol ether cosolvent, 13 parts of initiator, 36 parts of 35 parts of deionized water and azodiisobutyronitrile；LED solidification spary coating type vacuum metallizing coatings have the advantages that rate of drying is fast, viscosity big and good weatherability.
Description
Technical field
Present invention relates particularly to a kind of LED solidification spary coating type vacuum metallizing coatings and preparation method thereof.
Background technology
With increasing substantially for people's economic life level, automobile usage amount increases with surprising rapidity, therewith
The automobile lamp reflector market demand is also increasing.BMC used in automobile lamp reflector, without plating
Its rough surface, in order to be able to make up to good sky light effect, need to make its surface light in its electroplating surface metal aluminium lamination
Sliding, therefore plating piece surface can have height metal gloss and mirror effect.Because BMC is being shaped to car light reflection
After cover, article surface is coarse, and contains volatile impurity, if Direct Electroplating, plate surface brightness can be made low, electrodeposited coating meeting
Because the volatilization of volatile impurity influences electroplating quality, and BMC surface polarity is relatively low, and electrodeposited coating attachment is poor.Cause
This, in order to obtain the mirror effect and car light quality of ideal car light reflection, greatly improves plated film brightness, it is necessary to car
The lampshade base material of lamp carries out primary coat PROCESS FOR TREATMENT.
In addition, the vacuum metallizing coating that domestic car light reflector plated film industry is applied at present, relies primarily on import, product
It is expensive, and solvent is that benzene class etc. has more highly toxic solvent, long-term use has grievous injury to human body.Imported product
Occupation rate of market is higher at home for middle japanese product, and performance is fine, but price, and using benzene class as solvent, to environment and people
Body harm is big.The current country there is no the coating matched for car light reflector plated film requirement, although existing a small amount of product can be used
In car light reflector plated film, but it is also solvent based coating, and heat resistance is relatively low, and film easily occurs during car light is used for a long time
Hair is color, harden, the phenomenon such as tacky, it is impossible to meets to be used for a long time and requires.Dissected by the molecular structure to Japanese imported product, hair
Now it is the resin using polybutadiene as main chain, and this resin makes it have excellent resistance to height due to its special molecular structure
Warm nature energy, while glass transition temperature is low, can obtain the coating of high solids content.
The content of the invention
The technical problem to be solved in the present invention is to provide it is a kind of can rate of drying is fast, viscosity it is big and good weatherability
LED solidifies spary coating type vacuum metallizing coating.
To solve the above problems, the present invention is adopted the following technical scheme that：
A kind of LED solidifies spary coating type vacuum metallizing coating, and the material matched by following parts by weight is made, including polyurethane
14-28 parts of acrylate, 7-15 parts of ethoxyquin trimethylolpropane trimethacrylate, 1- hydroxy-cyciohexyls-benzyl ketone 8-12
Part, 12-24 parts of epoxy resin, 9-15 parts of amino resins, 6-10 parts of butyl acrylate, 4-8 parts of hydroxyethyl methacrylate, methyl
2-6 parts of acrylic acid, 1-3 parts of wetting dispersing agent, 1-3 parts of defoamer, 1-3 parts of styrene, 2-4 parts of alcohol ether cosolvent, initiator 1-3
3-6 parts of part, 3-5 parts of deionized water and azodiisobutyronitrile.
Further, the material that the LED solidifications spary coating type vacuum metallizing coating is matched by following parts by weight is made, and wraps
Include 28 parts of urethane acrylate, 7 parts of ethoxyquin trimethylolpropane trimethacrylate, 1- hydroxy-cyciohexyls-benzyl ketone 8
Part, 12 parts of epoxy resin, 9 parts of amino resins, 6 parts of butyl acrylate, 4 parts of hydroxyethyl methacrylate, 2 parts of methacrylic acid,
1 part of wetting dispersing agent, 1 part of defoamer, 1 part of styrene, 2 parts of alcohol ether cosolvent, 1 part of initiator, 3 parts of deionized water and azo two
3 parts of isobutyronitrile.
Further, the material that the LED solidifications spary coating type vacuum metallizing coating is matched by following parts by weight is made, and wraps
Include 14 parts of urethane acrylate, 15 parts of ethoxyquin trimethylolpropane trimethacrylate, 1- hydroxy-cyciohexyls-benzyl ketone
12 parts, 24 parts of epoxy resin, 15 parts of amino resins, 10 parts of butyl acrylate, 8 parts of hydroxyethyl methacrylate, methacrylic acid 6
Part, 3 parts of wetting dispersing agent, 3 parts of defoamer, 3 parts of styrene, 4 parts of alcohol ether cosolvent, 3 parts of initiator, 5 parts of deionized water and idol
6 parts of nitrogen bis-isobutyronitrile.
Further, the material that the LED solidifications spary coating type vacuum metallizing coating is matched by following parts by weight is made, and wraps
Include 21 parts of urethane acrylate, 11 parts of ethoxyquin trimethylolpropane trimethacrylate, 1- hydroxy-cyciohexyls-benzyl ketone
10 parts, 18 parts of epoxy resin, 12 parts of amino resins, 8 parts of butyl acrylate, 6 parts of hydroxyethyl methacrylate, methacrylic acid 4
Part, 2 parts of wetting dispersing agent, 2 parts of defoamer, 2 parts of styrene, 3 parts of alcohol ether cosolvent, 2 parts of initiator, 4 parts of deionized water and idol
5 parts of nitrogen bis-isobutyronitrile.
The invention solves the problems that another technical problem to provide the preparation side that a kind of LED solidifies spary coating type vacuum metallizing coating
Method, comprises the following steps：
1) extracting epoxy resin 12-24 parts are put into smelting furnace with 9-15 parts of amino resins, and it is melted by high-temperature heating, are made
Glue is obtained, it is standby；
2) by step 1) made from glue and water in proportion 1:2 addition mixing, make glue thinning, standby；
3) take 14-28 parts of urethane acrylate, 7-15 parts of ethoxyquin trimethylolpropane trimethacrylate, 1- hydroxyls-
6-10 part of cyclohexyl -8-12 parts of benzyl ketone and butyl acrylate are poured into container, and are warming up to 100 degrees Celsius, and being incubated makes it
Reaction 30 minutes, it is standby；
4) treat step 3) made from material reaction finish, 4-8 part of hydroxyethyl methacrylate of addition and methacrylic acid 2-6
Part, it is slowly stirred uniformly by mixer, then heats to 160 degrees Celsius, stands reaction 2 hours, it is standby；
5) by step 4) made from material be added to step 2) in the glue that diluted, and at the uniform velocity stirred by mixer,
So that dilution glue is well mixed with material, it is standby；
6) by step 5) material that is mixed to get is warming up to 95 degrees Celsius again, and add 1-3 parts of wetting dispersing agent, froth breaking
3-5 parts of 1-3 parts of agent, 1-3 parts of styrene, 2-4 parts of alcohol ether cosolvent, 1-3 parts of initiator and deionized water so that above-mentioned material with
Step 5) material be well mixed, and insulation reaction 40 minutes is standby；
7) by step 6) obtained material is placed in the place placement of without sunlight irradiation after reaction, stands cooling, standby；
8) 3-6 parts of azodiisobutyronitrile is taken to be added to step 7) after cooling in obtained material.Painting is produced after stirring
Material, is subsequently placed in the place preservation for drying ventilation, you can.
The beneficial effects of the invention are as follows：Based on resin material, with urethane acrylate etc. for auxiliary material, to disappear
The materials such as infusion are auxiliary agent so that expect there is good heat-resistant stability, improve plated film brightness, being applied on LED can
Rapid curing, and obtain more good reflecting effect.
Embodiment
Embodiment 1：
A kind of LED solidifies spary coating type vacuum metallizing coating, and the material matched by following parts by weight is made, including polyurethane
28 parts of acrylate, 7 parts of ethoxyquin trimethylolpropane trimethacrylate, 1- hydroxy-cyciohexyls -8 parts of benzyl ketone, asphalt mixtures modified by epoxy resin
12 parts of fat, 9 parts of amino resins, 6 parts of butyl acrylate, 4 parts of hydroxyethyl methacrylate, 2 parts of methacrylic acid, wetting dispersing agent
3 parts of 1 part, 1 part of defoamer, 1 part of styrene, 2 parts of alcohol ether cosolvent, 1 part of initiator, 3 parts of deionized water and azodiisobutyronitrile.
A kind of LED solidifies the preparation method of spary coating type vacuum metallizing coating, comprises the following steps:
1) 9 parts of 12 parts of extracting epoxy resin and amino resins are put into smelting furnace, and it is melted by high-temperature heating, and glue is made
Liquid, it is standby；
2) by step 1) made from glue and water in proportion 1:2 addition mixing, make glue thinning, standby；
3) take 28 parts of urethane acrylate, 7 parts of ethoxyquin trimethylolpropane trimethacrylate, 1- hydroxy-cyciohexyls-
6 parts of 8 parts of benzyl ketone and butyl acrylate are poured into container, and are warming up to 100 degrees Celsius, and insulation makes it react 30 minutes, standby
With；
4) treat step 3) made from material reaction finish, 2 parts of 4 parts of hydroxyethyl methacrylate of addition and methacrylic acid,
It is slowly stirred uniformly by mixer, then heats to 160 degrees Celsius, stands reaction 2 hours, it is standby；
5) by step 4) made from material be added to step 2) in the glue that diluted, and at the uniform velocity stirred by mixer,
So that dilution glue is well mixed with material, it is standby；
6) by step 5) material that is mixed to get is warming up to 95 degrees Celsius again, and add 1 part of wetting dispersing agent, defoamer
3 parts of 1 part, 1 part of styrene, 2 parts of alcohol ether cosolvent, 1 part of initiator and deionized water so that above-mentioned material and step 5) material
It is well mixed, and insulation reaction 40 minutes, it is standby；
7) by step 6) obtained material is placed in the place placement of without sunlight irradiation after reaction, stands cooling, standby；
8) 3 parts of azodiisobutyronitrile is taken to be added to step 7) after cooling in obtained material.Coating is produced after stirring,
It is subsequently placed in the place preservation for drying ventilation, you can.
Embodiment 2：
A kind of LED solidifies spary coating type vacuum metallizing coating, and the material matched by following parts by weight is made, including polyurethane
14 parts of acrylate, 15 parts of ethoxyquin trimethylolpropane trimethacrylate, 1- hydroxy-cyciohexyls -12 parts of benzyl ketone, epoxy
24 parts of resin, 15 parts of amino resins, 10 parts of butyl acrylate, 8 parts of hydroxyethyl methacrylate, 6 parts of methacrylic acid, wetting point
3 parts of powder, 3 parts of defoamer, 3 parts of styrene, 4 parts of alcohol ether cosolvent, 3 parts of initiator, 5 parts of deionized water and azodiisobutyronitrile
6 parts.
A kind of LED solidifies the preparation method of spary coating type vacuum metallizing coating, comprises the following steps:
1) 15 parts of 24 parts of extracting epoxy resin and amino resins are put into smelting furnace, and it is melted by high-temperature heating, and glue is made
Liquid, it is standby；
2) by step 1) made from glue and water in proportion 1:2 addition mixing, make glue thinning, standby；
3) 14 parts of urethane acrylate, 15 parts of ethoxyquin trimethylolpropane trimethacrylate, 1- hydroxy-cyclohexans are taken
10 parts of base -12 parts of benzyl ketone and butyl acrylate are poured into container, and are warming up to 100 degrees Celsius, and insulation makes its react 30 points
Clock, it is standby；
4) treat step 3) made from material reaction finish, 6 parts of 8 parts of hydroxyethyl methacrylate of addition and methacrylic acid,
It is slowly stirred uniformly by mixer, then heats to 160 degrees Celsius, stands reaction 2 hours, it is standby；
5) by step 4) made from material be added to step 2) in the glue that diluted, and at the uniform velocity stirred by mixer,
So that dilution glue is well mixed with material, it is standby；
6) by step 5) material that is mixed to get is warming up to 95 degrees Celsius again, and add 3 parts of wetting dispersing agent, defoamer
5 parts of 3 parts, 3 parts of styrene, 4 parts of alcohol ether cosolvent, 3 parts of initiator and deionized water so that above-mentioned material and step 5) material
It is well mixed, and insulation reaction 40 minutes, it is standby；
7) by step 6) obtained material is placed in the place placement of without sunlight irradiation after reaction, stands cooling, standby；
8) 6 parts of azodiisobutyronitrile is taken to be added to step 7) after cooling in obtained material.Coating is produced after stirring,
It is subsequently placed in the place preservation for drying ventilation, you can.
Embodiment 3：
A kind of LED solidifies spary coating type vacuum metallizing coating, and the material matched by following parts by weight is made, including polyurethane
21 parts of acrylate, 11 parts of ethoxyquin trimethylolpropane trimethacrylate, 1- hydroxy-cyciohexyls -10 parts of benzyl ketone, epoxy
18 parts of resin, 12 parts of amino resins, 8 parts of butyl acrylate, 6 parts of hydroxyethyl methacrylate, 4 parts of methacrylic acid, wetting point
2 parts of powder, 2 parts of defoamer, 2 parts of styrene, 3 parts of alcohol ether cosolvent, 2 parts of initiator, 4 parts of deionized water and azodiisobutyronitrile
5 parts.
A kind of LED solidifies the preparation method of spary coating type vacuum metallizing coating, comprises the following steps:
1) 12 parts of 18 parts of extracting epoxy resin and amino resins are put into smelting furnace, and it is melted by high-temperature heating, and glue is made
Liquid, it is standby；
2) by step 1) made from glue and water in proportion 1:2 addition mixing, make glue thinning, standby；
3) 21 parts of urethane acrylate, 11 parts of ethoxyquin trimethylolpropane trimethacrylate, 1- hydroxy-cyclohexans are taken
8 parts of base -10 parts of benzyl ketone and butyl acrylate are poured into container, and are warming up to 100 degrees Celsius, and insulation makes its react 30 points
Clock, it is standby；
4) treat step 3) made from material reaction finish, 4 parts of 6 parts of hydroxyethyl methacrylate of addition and methacrylic acid,
It is slowly stirred uniformly by mixer, then heats to 160 degrees Celsius, stands reaction 2 hours, it is standby；
5) by step 4) made from material be added to step 2) in the glue that diluted, and at the uniform velocity stirred by mixer,
So that dilution glue is well mixed with material, it is standby；
6) by step 5) material that is mixed to get is warming up to 95 degrees Celsius again, and add 2 parts of wetting dispersing agent, defoamer
4 parts of 2 parts, 2 parts of styrene, 3 parts of alcohol ether cosolvent, 2 parts of initiator and deionized water so that above-mentioned material and step 5) material
It is well mixed, and insulation reaction 40 minutes, it is standby；
7) by step 6) obtained material is placed in the place placement of without sunlight irradiation after reaction, stands cooling, standby；
8) 5 parts of azodiisobutyronitrile is taken to be added to step 7) after cooling in obtained material.Coating is produced after stirring,
It is subsequently placed in the place preservation for drying ventilation, you can.
Experimental example：
The LED solidification spary coating type vacuum metallizing coatings of the present embodiment are tested by the progress with other coating, contrast this hair
Bright situation.
Experimental method：Control group 1 is coating, and control group 2 is special coating, and experimental group is solidified using the LED of the present invention
Spary coating type vacuum metallizing coating, analyzes Heat-resistant stable degree, brightness and the weatherability in three groups, and contrasted.
Three groups of carry out effect comparisons, the results are shown in Table 1.
By Experimental comparison, three groups of situations have notable difference, a kind of LED solidification spary coating type vacuum metallizing coatings of the invention
Compared with control group, heat-resistant stability of the present invention is good, smear after glossy and good weatherability.
The beneficial effects of the invention are as follows：Based on resin material, with urethane acrylate etc. for auxiliary material, to disappear
The materials such as infusion are auxiliary agent so that expect there is good heat-resistant stability, improve plated film brightness, being applied on LED can
Rapid curing, and obtain more good reflecting effect.
The foregoing is only a specific embodiment of the invention, but protection scope of the present invention is not limited thereto, any
The change or replacement expected without creative work, should all cover within the scope of the present invention.
Claims (4)
1. a kind of LED solidifies spary coating type vacuum metallizing coating, it is characterised in that：The material matched by following parts by weight is made,
14-28 parts of urethane acrylate, 7-15 parts of ethoxyquin trimethylolpropane trimethacrylate, 1- hydroxy-cyciohexyls-benzyl
8-12 parts of ketone, 12-24 parts of epoxy resin, 9-15 parts of amino resins, 6-10 parts of butyl acrylate, hydroxyethyl methacrylate 4-8
Part, 2-6 parts of methacrylic acid, 1-3 parts of wetting dispersing agent, 1-3 parts of defoamer, 1-3 parts of styrene, 2-4 parts of alcohol ether cosolvent, draw
3-6 parts of 1-3 parts of agent, 3-5 parts of deionized water and azodiisobutyronitrile are sent out, the initiator is non-1- hydroxy-cyciohexyls-benzyl
A kind of initiator of ketone and azodiisobutyronitrile, LED solidifies the preparation method of spary coating type vacuum metallizing coating, including following
Step:
1) extracting epoxy resin 12-24 parts are put into smelting furnace with 9-15 parts of amino resins, and it is melted by high-temperature heating, and glue is made
Liquid, it is standby；
2) by step 1) made from glue and water in proportion 1:2 addition mixing, make glue thinning, standby；
3) 14-28 parts of urethane acrylate, 7-15 parts of ethoxyquin trimethylolpropane trimethacrylate, 1- hydroxy-cyclohexans are taken
6-10 part of base -8-12 parts of benzyl ketone and butyl acrylate are poured into container, and are warming up to 100 degrees Celsius, and being incubated reacts it
It is 30 minutes, standby；
4) treat step 3) made from material reaction finish, 2-6 parts of 4-8 part of hydroxyethyl methacrylate of addition and methacrylic acid,
It is slowly stirred uniformly by mixer, then heats to 160 degrees Celsius, stands reaction 2 hours, it is standby；
5) by step 4) made from material be added to step 2) in the glue that diluted, and at the uniform velocity stirred by mixer so that
Dilution glue is well mixed with material, standby；
6) by step 5) material that is mixed to get is warming up to 95 degrees Celsius again, and add 1-3 parts of wetting dispersing agent, defoamer 1-
3-5 parts of 3 parts, 1-3 parts of styrene, 2-4 parts of alcohol ether cosolvent, 1-3 parts of initiator and deionized water so that above-mentioned material and step
5) material is well mixed, and insulation reaction 40 minutes, standby；
7) by step 6) obtained material is placed in the place placement of without sunlight irradiation after reaction, stands cooling, standby；
8) 3-6 parts of azodiisobutyronitrile is taken to be added to step 7) after cooling in obtained material, coating is produced after stirring, so
The place preservation for drying ventilation is placed in afterwards, you can.
2. LED as claimed in claim 1 solidifies spary coating type vacuum metallizing coating, it is characterised in that：Matched somebody with somebody by following parts by weight
The material of ratio is made, including 28 parts of urethane acrylate, 7 parts of ethoxyquin trimethylolpropane trimethacrylate, 1- hydroxyls-ring
Hexyl -8 parts of benzyl ketone, 12 parts of epoxy resin, 9 parts of amino resins, 6 parts of butyl acrylate, 4 parts of hydroxyethyl methacrylate,
2 parts of methacrylic acid, 1 part of wetting dispersing agent, 1 part of defoamer, 1 part of styrene, 2 parts of alcohol ether cosolvent, 1 part of initiator, go from
3 parts of 3 parts of sub- water and azodiisobutyronitrile.
3. LED as claimed in claim 1 solidifies spary coating type vacuum metallizing coating, it is characterised in that：Matched somebody with somebody by following parts by weight
The material of ratio is made, including 14 parts of urethane acrylate, 15 parts of ethoxyquin trimethylolpropane trimethacrylate, 1- hydroxyls-
Cyclohexyl -12 parts of benzyl ketone, 24 parts of epoxy resin, 15 parts of amino resins, 10 parts of butyl acrylate, hydroxyethyl methacrylate
8 parts, 6 parts of methacrylic acid, 3 parts of wetting dispersing agent, 3 parts of defoamer, 3 parts of styrene, 4 parts of alcohol ether cosolvent, 3 parts of initiator,
6 parts of 5 parts of deionized water and azodiisobutyronitrile.
4. LED as claimed in claim 1 solidifies spary coating type vacuum metallizing coating, it is characterised in that：Matched somebody with somebody by following parts by weight
The material of ratio is made, including 21 parts of urethane acrylate, 11 parts of ethoxyquin trimethylolpropane trimethacrylate, 1- hydroxyls-
Cyclohexyl -10 parts of benzyl ketone, 18 parts of epoxy resin, 12 parts of amino resins, 8 parts of butyl acrylate, hydroxyethyl methacrylate 6
Part, 4 parts of methacrylic acid, 2 parts of wetting dispersing agent, 2 parts of defoamer, 2 parts of styrene, 3 parts of alcohol ether cosolvent, 2 parts of initiator, go
5 parts of 4 parts of ionized water and azodiisobutyronitrile.
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| CN106752856A (en) * | 2016-11-28 | 2017-05-31 | 江苏东钢新材料有限公司 | One kind solidification fire prevention plating coating and preparation method thereof |
| CN107726252B (en) * | 2017-10-11 | 2020-04-07 | 佛山电器照明股份有限公司 | Pressed glass lamp cup, preparation method thereof and lamp |
| CN113698830B (en) * | 2021-08-20 | 2022-08-09 | 湖南松井新材料股份有限公司 | Coating composition and application thereof |
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| CN101864204B (en) * | 2010-06-09 | 2011-07-06 | 宜兴市宏泰化工有限公司 | Dedicated high-performance primer of ultraviolet-curing vacuum coating for reflector of automobile lamps |
| CN102108252B (en) * | 2011-03-09 | 2013-07-24 | 上虞市佑谦特种材料有限公司 | Waterborne vacuum film-coated finish paint |
| KR20140023717A (en) * | 2012-08-17 | 2014-02-27 | 주식회사 엘지화학 | Photo-curable and thermo-curable resin composition and dry film type solder resist manufactured using the same |
| CN103740223B (en) * | 2014-01-10 | 2016-03-16 | 厦门大学 | A kind of water base property car light reflector plated film coating and preparation method thereof |
| CN105368298B (en) * | 2015-12-10 | 2017-11-07 | 滁州金桥德克新材料有限公司 | A kind of color coating material of UV vacuum coatings seven and preparation method thereof |
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