CN106752856A - One kind solidification fire prevention plating coating and preparation method thereof - Google Patents
One kind solidification fire prevention plating coating and preparation method thereof Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/206—Applications use in electrical or conductive gadgets use in coating or encapsulating of electronic parts
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The present invention discloses a kind of solidification fire prevention plating coating, the material matched by following parts by weight is made, including 14 28 parts of urethane acrylate, 7 15 parts of ethoxyquin trimethylolpropane trimethacrylate, 18 12 parts of hydroxy-cyclohexyl benzyl ketone, 12 24 parts of epoxy resin, 9 15 parts of amino resins, 6 10 parts of butyl acrylate, 48 parts of hydroxyethyl methacrylate, 26 parts of methacrylic acid, 13 parts of wetting dispersing agent, 13 parts of defoamer, 13 parts of styrene, 24 parts of alcohol ether cosolvent, 13 parts of initiator, 36 parts of 35 parts of deionized water and azodiisobutyronitrile；Solidification fire prevention plating coating has the advantages that rate of drying is fast, viscosity is big and fire line is good.
Description
Technical field
Present invention relates particularly to one kind solidification fire prevention plating coating and preparation method thereof.
Background technology
With increasing substantially for people's economic life level, automobile usage amount increases with surprising rapidity, therewith
The automobile lamp reflector market demand is also increasing.The BMC that automobile lamp reflector is used, without plating
Its rough surface, in order to be able to make up to good sky light effect, need to make its surface light in its electroplating surface metal aluminium lamination
Sliding, therefore plating piece surface can have height metal gloss and mirror effect.Because BMC is being shaped to car light reflection
After cover, article surface is coarse, and contains volatile impurity, if Direct Electroplating, plate surface brightness can be made low, electrodeposited coating meeting
Because the volatilization of volatile impurity influences electroplating quality, and BMC surface polarity is relatively low, and electrodeposited coating attachment is poor.Cause
This, in order to obtain the mirror effect and car light quality of ideal car light reflection, greatly improves plated film brightness, it is necessary to car
The lampshade base material of lamp carries out primary coat PROCESS FOR TREATMENT.
Additionally, the vacuum metallizing coating that domestic car light reflector plated film industry is applied at present, relies primarily on import, product
It is expensive, and solvent is that benzene class etc. has more highly toxic solvent, long-term use has grievous injury to human body.Imported product
Occupation rate of market is higher at home for middle japanese product, and performance is fine, but price, and with benzene class as solvent, to environment and people
Body harm is big.The current country there is no the coating matched for car light reflector plated film requirement, although existing a small amount of product can be used
In car light reflector plated film, but it is also solvent based coating, and heat resistance is relatively low, and film easily occurs during car light long-term use
Hair is color, harden, the phenomenon such as tacky, it is impossible to meet long-term use requirement.Dissected by the molecular structure to Japanese imported product, hair
Now it is the resin with polybutadiene as main chain, and this resin makes it have excellent resistance to height due to its special molecular structure
Warm nature energy, while glass transition temperature is low, can obtain the coating of high solids content.
The content of the invention
The technical problem to be solved in the present invention be to provide it is a kind of can rate of drying is fast, viscosity it is big and fire line is good consolidates
Chemoprevention fire plating coating.
To solve the above problems, the present invention is adopted the following technical scheme that：
One kind solidification fire prevention plating coating, the material matched by following parts by weight is made, including urethane acrylate 14-28
Part, 7-15 parts of ethoxyquin trimethylolpropane trimethacrylate, 1- hydroxy-cyciohexyls -8-12 parts of benzyl ketone, epoxy resin
12-24 parts, amino resins 9-15 parts, butyl acrylate 6-10 parts, hydroxyethyl methacrylate 4-8 parts, methacrylic acid 2-6
Part, wetting dispersing agent 1-3 parts, defoamer 1-3 parts, styrene 1-3 parts, 2-4 parts of alcohol ether cosolvent, initiator 1-3 parts, deionization
Water 3-5 parts and azodiisobutyronitrile 3-6 parts.
Further, the solidification fire prevention plating coating is made up of the material that following parts by weight are matched, including polyurethane
28 parts of acrylate, 7 parts of ethoxyquin trimethylolpropane trimethacrylate, 1- hydroxy-cyciohexyls -8 parts of benzyl ketone, asphalt mixtures modified by epoxy resin
12 parts of fat, 9 parts of amino resins, 6 parts of butyl acrylate, 4 parts of hydroxyethyl methacrylate, 2 parts of methacrylic acid, wetting dispersing agent
3 parts of 1 part, 1 part of defoamer, 1 part of styrene, 2 parts of alcohol ether cosolvent, 1 part of initiator, 3 parts of deionized water and azodiisobutyronitrile.
Further, the solidification fire prevention plating coating is made up of the material that following parts by weight are matched, including polyurethane
14 parts of acrylate, 15 parts of ethoxyquin trimethylolpropane trimethacrylate, 1- hydroxy-cyciohexyls -12 parts of benzyl ketone, epoxy
24 parts of resin, 15 parts of amino resins, 10 parts of butyl acrylate, 8 parts of hydroxyethyl methacrylate, 6 parts of methacrylic acid, wetting point
3 parts of powder, 3 parts of defoamer, 3 parts of styrene, 4 parts of alcohol ether cosolvent, 3 parts of initiator, 5 parts of deionized water and azodiisobutyronitrile
6 parts.
Further, the solidification fire prevention plating coating is made up of the material that following parts by weight are matched, including polyurethane
21 parts of acrylate, 11 parts of ethoxyquin trimethylolpropane trimethacrylate, 1- hydroxy-cyciohexyls -10 parts of benzyl ketone, epoxy
18 parts of resin, 12 parts of amino resins, 8 parts of butyl acrylate, 6 parts of hydroxyethyl methacrylate, 4 parts of methacrylic acid, wetting point
2 parts of powder, 2 parts of defoamer, 2 parts of styrene, 3 parts of alcohol ether cosolvent, 2 parts of initiator, 4 parts of deionized water and azodiisobutyronitrile
5 parts.
The invention solves the problems that another technical problem be provide it is a kind of solidify fire prevention plating coating preparation method, including with
Lower step：
1) extracting epoxy resin 12-24 parts and amino resins 9-15 parts is put into smelting furnace, and it is melted by high-temperature heating, and glue is obtained
Liquid, it is standby；
2）By step 1）Obtained glue and water in proportion 1:2 addition mixing, make glue thinning, standby；
3）Take urethane acrylate 14-28 parts, 7-15 parts of ethoxyquin trimethylolpropane trimethacrylate, 1- hydroxy-cyclohexans
Base -8-12 parts of benzyl ketone and butyl acrylate 6-10 part are poured into container, and are warming up to 100 degrees Celsius, and being incubated reacts it
It is 30 minutes, standby；
4）Treat step 3）Obtained material reaction is finished, 4-8 parts and methacrylic acid 2-6 parts of addition hydroxyethyl methacrylate,
It is slowly stirred uniformly by mixer, then heats to 160 degrees Celsius, stands reaction 2 hours, it is standby；
5）By step 4）Obtained material is added to step 2）In the glue for diluting, and at the uniform velocity stirred by mixer so that
Dilution glue is well mixed with material, standby；
6）By step 5）The material being mixed to get is warming up to 95 degrees Celsius again, and adds wetting dispersing agent 1-3 parts, defoamer 1-
3 parts, styrene 1-3 parts, 2-4 parts, initiator 1-3 parts and deionized water 3-5 parts of alcohol ether cosolvent so that above-mentioned material and step
5）Material be well mixed, and insulation reaction 40 minutes is standby；
7）By step 6）The material obtained after reaction is placed in the place placement of without sunlight irradiation, stands cooling, standby；
8）Take azodiisobutyronitrile 3-6 parts and be added to step 7）In the material obtained after cooling.Coating is obtained final product after stirring, so
The place preservation for drying ventilation is placed in afterwards, you can.
The beneficial effects of the invention are as follows：Based on resin material, with urethane acrylate etc. as auxiliary material, to disappear
The materials such as infusion are auxiliary agent so that expect there is good heat-resistant stability, improve plated film brightness, and being applied on LED can
Rapid curing, and obtain more good reflecting effect.
Specific embodiment
Embodiment 1：
One kind solidification fire prevention plating coating, the material matched by following parts by weight is made, including 28 parts of urethane acrylate,
7 parts of ethoxyquin trimethylolpropane trimethacrylate, 1- hydroxy-cyciohexyls -8 parts of benzyl ketone, 12 parts of epoxy resin, amino tree
9 parts of fat, 6 parts of butyl acrylate, 4 parts of hydroxyethyl methacrylate, 2 parts of methacrylic acid, 1 part of wetting dispersing agent, defoamer 1
Part, 1 part of styrene, 2 parts of alcohol ether cosolvent, 1 part of initiator, 3 parts of deionized water and 3 parts of azodiisobutyronitrile.
A kind of preparation method for solidifying fire prevention plating coating, comprises the following steps:
1) 9 parts of 12 parts of extracting epoxy resin and amino resins are put into smelting furnace, and it is melted by high-temperature heating, and glue is obtained, standby
With；
2）By step 1）Obtained glue and water in proportion 1:2 addition mixing, make glue thinning, standby；
3）Take 28 parts of urethane acrylate, 7 parts of ethoxyquin trimethylolpropane trimethacrylate, 1- hydroxy-cyciohexyls-benzene first
6 parts of 8 parts of base ketone and butyl acrylate are poured into container, and are warming up to 100 degrees Celsius, and insulation makes its reaction 30 minutes, standby；
4）Treat step 3）Obtained material reaction is finished, and adds 2 parts of 4 parts of hydroxyethyl methacrylate and methacrylic acid, is passed through
Mixer is slowly stirred uniformly, then heats to 160 degrees Celsius, stands reaction 2 hours, standby；
5）By step 4）Obtained material is added to step 2）In the glue for diluting, and at the uniform velocity stirred by mixer so that
Dilution glue is well mixed with material, standby；
6）By step 5）The material being mixed to get is warming up to 95 degrees Celsius again, and add 1 part of wetting dispersing agent, 1 part of defoamer,
3 parts of 1 part of styrene, 2 parts of alcohol ether cosolvent, 1 part of initiator and deionized water so that above-mentioned material and step 5）Material mixing
Uniformly, and insulation reaction 40 minutes, it is standby；
7）By step 6）The material obtained after reaction is placed in the place placement of without sunlight irradiation, stands cooling, standby；
8）Take 3 parts of azodiisobutyronitrile and be added to step 7）In the material obtained after cooling.Coating is obtained final product after stirring, then
It is placed in the place preservation for drying ventilation, you can.
Embodiment 2：
One kind solidification fire prevention plating coating, the material matched by following parts by weight is made, including 14 parts of urethane acrylate,
15 parts of ethoxyquin trimethylolpropane trimethacrylate, 1- hydroxy-cyciohexyls -12 parts of benzyl ketone, 24 parts of epoxy resin, amino
15 parts of resin, 10 parts of butyl acrylate, 8 parts of hydroxyethyl methacrylate, 6 parts of methacrylic acid, 3 parts of wetting dispersing agent, froth breaking
6 parts of 3 parts of agent, 3 parts of styrene, 4 parts of alcohol ether cosolvent, 3 parts of initiator, 5 parts of deionized water and azodiisobutyronitrile.
A kind of preparation method for solidifying fire prevention plating coating, comprises the following steps:
1) 15 parts of 24 parts of extracting epoxy resin and amino resins are put into smelting furnace, and it is melted by high-temperature heating, and glue is obtained, standby
With；
2）By step 1）Obtained glue and water in proportion 1:2 addition mixing, make glue thinning, standby；
3）Take 14 parts of urethane acrylate, 15 parts of ethoxyquin trimethylolpropane trimethacrylate, 1- hydroxy-cyciohexyls-benzene
10 parts of 12 parts of MIBK and butyl acrylate are poured into container, and are warming up to 100 degrees Celsius, and insulation makes its reaction 30 minutes, standby
With；
4）Treat step 3）Obtained material reaction is finished, and adds 6 parts of 8 parts of hydroxyethyl methacrylate and methacrylic acid, is passed through
Mixer is slowly stirred uniformly, then heats to 160 degrees Celsius, stands reaction 2 hours, standby；
5）By step 4）Obtained material is added to step 2）In the glue for diluting, and at the uniform velocity stirred by mixer so that
Dilution glue is well mixed with material, standby；
6）By step 5）The material being mixed to get is warming up to 95 degrees Celsius again, and add 3 parts of wetting dispersing agent, 3 parts of defoamer,
5 parts of 3 parts of styrene, 4 parts of alcohol ether cosolvent, 3 parts of initiator and deionized water so that above-mentioned material and step 5）Material mixing
Uniformly, and insulation reaction 40 minutes, it is standby；
7）By step 6）The material obtained after reaction is placed in the place placement of without sunlight irradiation, stands cooling, standby；
8）Take 6 parts of azodiisobutyronitrile and be added to step 7）In the material obtained after cooling.Coating is obtained final product after stirring, then
It is placed in the place preservation for drying ventilation, you can.
Embodiment 3：
One kind solidification fire prevention plating coating, the material matched by following parts by weight is made, including 21 parts of urethane acrylate,
11 parts of ethoxyquin trimethylolpropane trimethacrylate, 1- hydroxy-cyciohexyls -10 parts of benzyl ketone, 18 parts of epoxy resin, amino
12 parts of resin, 8 parts of butyl acrylate, 6 parts of hydroxyethyl methacrylate, 4 parts of methacrylic acid, 2 parts of wetting dispersing agent, defoamer
5 parts of 2 parts, 2 parts of styrene, 3 parts of alcohol ether cosolvent, 2 parts of initiator, 4 parts of deionized water and azodiisobutyronitrile.
A kind of preparation method for solidifying fire prevention plating coating, comprises the following steps:
1) 12 parts of 18 parts of extracting epoxy resin and amino resins are put into smelting furnace, and it is melted by high-temperature heating, and glue is obtained, standby
With；
2）By step 1）Obtained glue and water in proportion 1:2 addition mixing, make glue thinning, standby；
3）Take 21 parts of urethane acrylate, 11 parts of ethoxyquin trimethylolpropane trimethacrylate, 1- hydroxy-cyciohexyls-benzene
8 parts of 10 parts of MIBK and butyl acrylate are poured into container, and are warming up to 100 degrees Celsius, and insulation makes its reaction 30 minutes, standby
With；
4）Treat step 3）Obtained material reaction is finished, and adds 4 parts of 6 parts of hydroxyethyl methacrylate and methacrylic acid, is passed through
Mixer is slowly stirred uniformly, then heats to 160 degrees Celsius, stands reaction 2 hours, standby；
5）By step 4）Obtained material is added to step 2）In the glue for diluting, and at the uniform velocity stirred by mixer so that
Dilution glue is well mixed with material, standby；
6）By step 5）The material being mixed to get is warming up to 95 degrees Celsius again, and add 2 parts of wetting dispersing agent, 2 parts of defoamer,
4 parts of 2 parts of styrene, 3 parts of alcohol ether cosolvent, 2 parts of initiator and deionized water so that above-mentioned material and step 5）Material mixing
Uniformly, and insulation reaction 40 minutes, it is standby；
7）By step 6）The material obtained after reaction is placed in the place placement of without sunlight irradiation, stands cooling, standby；
8）Take 5 parts of azodiisobutyronitrile and be added to step 7）In the material obtained after cooling.Coating is obtained final product after stirring, then
It is placed in the place preservation for drying ventilation, you can.
Experimental example：
The solidification fire prevention plating coating of the present embodiment is tested by the carrying out with other coating, contrasts situation of the invention.
Experimental technique：Control group 1 is coating, and control group 2 is special coating, and experimental group uses solidification fire prevention of the invention
Plating coating, analyzes Heat-resistant stable degree in three groups, brightness and fire line, and contrasted.
Three groups carry out effect comparing, as a result see the table below：
By Experimental comparison, three groups of situations have a notable difference, a kind of solidification fire prevention plating coating of the invention compared with control group,
Heat-resistant stability of the present invention is good, smear after glossy and fire line it is good.
The beneficial effects of the invention are as follows：Based on resin material, with urethane acrylate etc. as auxiliary material, to disappear
The materials such as infusion are auxiliary agent so that expect there is good heat-resistant stability, improve plated film brightness, and being applied on LED can
Rapid curing, and obtain more good reflecting effect.
The above, specific embodiment only of the invention, but protection scope of the present invention is not limited thereto, and it is any
The change or replacement expected without creative work, should all cover within the scope of the present invention.
Claims (5)
1. coating is plated in a kind of solidification fire prevention, it is characterised in that：The material matched by following parts by weight is made, including polyurethane
Acrylate 14-28 parts, 7-15 parts of ethoxyquin trimethylolpropane trimethacrylate, 1- hydroxy-cyciohexyls-benzyl ketone 8-12
Part, epoxy resin 12-24 parts, amino resins 9-15 parts, butyl acrylate 6-10 parts, hydroxyethyl methacrylate 4-8 parts, methyl
Acrylic acid 2-6 parts, wetting dispersing agent 1-3 parts, defoamer 1-3 parts, styrene 1-3 parts, 2-4 parts of alcohol ether cosolvent, initiator 1-3
Part, deionized water 3-5 parts and azodiisobutyronitrile 3-6 parts.
2. coating is plated in solidification fire prevention as claimed in claim 1, it is characterised in that：The material system matched by following parts by weight
Into, including 28 parts of urethane acrylate, 7 parts of ethoxyquin trimethylolpropane trimethacrylate, 1- hydroxy-cyciohexyls-benzene first
8 parts of base ketone, 12 parts of epoxy resin, 9 parts of amino resins, 6 parts of butyl acrylate, 4 parts of hydroxyethyl methacrylate, methacrylic acid
2 parts, 1 part of wetting dispersing agent, 1 part of defoamer, 1 part of styrene, 2 parts of alcohol ether cosolvent, 1 part of initiator, 3 parts of deionized water and idol
3 parts of nitrogen bis-isobutyronitrile.
3. coating is plated in solidification fire prevention as claimed in claim 2, it is characterised in that：The material system matched by following parts by weight
Into, including 14 parts of urethane acrylate, 15 parts of ethoxyquin trimethylolpropane trimethacrylate, 1- hydroxy-cyciohexyls-benzene first
12 parts of base ketone, 24 parts of epoxy resin, 15 parts of amino resins, 10 parts of butyl acrylate, 8 parts of hydroxyethyl methacrylate, methyl-prop
6 parts of olefin(e) acid, 3 parts of wetting dispersing agent, 3 parts of defoamer, 3 parts of styrene, 4 parts of alcohol ether cosolvent, 3 parts of initiator, 5 parts of deionized water
With 6 parts of azodiisobutyronitrile.
4. coating is plated in solidification fire prevention as claimed in claim 3, it is characterised in that：The material system matched by following parts by weight
Into, including 21 parts of urethane acrylate, 11 parts of ethoxyquin trimethylolpropane trimethacrylate, 1- hydroxy-cyciohexyls-benzene first
10 parts of base ketone, 18 parts of epoxy resin, 12 parts of amino resins, 8 parts of butyl acrylate, 6 parts of hydroxyethyl methacrylate, metering system
Acid 4 parts, 2 parts of wetting dispersing agent, 2 parts of defoamer, 2 parts of styrene, 3 parts of alcohol ether cosolvent, 2 parts of initiator, 4 parts of deionized water and
5 parts of azodiisobutyronitrile.
5. the preparation method of coating is plated in a kind of solidification fire prevention as claimed in claim 1, it is characterised in that：Including following step
Suddenly:
1) extracting epoxy resin 12-24 parts and amino resins 9-15 parts is put into smelting furnace, and it is melted by high-temperature heating, and glue is obtained
Liquid, it is standby；
2）By step 1）Obtained glue and water in proportion 1:2 addition mixing, make glue thinning, standby；
3）Take urethane acrylate 14-28 parts, 7-15 parts of ethoxyquin trimethylolpropane trimethacrylate, 1- hydroxy-cyclohexans
Base -8-12 parts of benzyl ketone and butyl acrylate 6-10 part are poured into container, and are warming up to 100 degrees Celsius, and being incubated reacts it
It is 30 minutes, standby；
4）Treat step 3）Obtained material reaction is finished, 4-8 parts and methacrylic acid 2-6 parts of addition hydroxyethyl methacrylate,
It is slowly stirred uniformly by mixer, then heats to 160 degrees Celsius, stands reaction 2 hours, it is standby；
5）By step 4）Obtained material is added to step 2）In the glue for diluting, and at the uniform velocity stirred by mixer so that
Dilution glue is well mixed with material, standby；
6）By step 5）The material being mixed to get is warming up to 95 degrees Celsius again, and adds wetting dispersing agent 1-3 parts, defoamer 1-
3 parts, styrene 1-3 parts, 2-4 parts, initiator 1-3 parts and deionized water 3-5 parts of alcohol ether cosolvent so that above-mentioned material and step
5）Material be well mixed, and insulation reaction 40 minutes is standby；
7）By step 6）The material obtained after reaction is placed in the place placement of without sunlight irradiation, stands cooling, standby；
8）Take azodiisobutyronitrile 3-6 parts and be added to step 7）In the material obtained after cooling, coating is obtained final product after stirring, so
The place preservation for drying ventilation is placed in afterwards, you can.
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| CN201611059031.XA CN106752856A (en) | 2016-11-28 | 2016-11-28 | One kind solidification fire prevention plating coating and preparation method thereof |
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| CN201611059031.XA CN106752856A (en) | 2016-11-28 | 2016-11-28 | One kind solidification fire prevention plating coating and preparation method thereof |
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| CN105368300A (en) * | 2015-12-10 | 2016-03-02 | 滁州金桥德克新材料有限公司 | High solid content UV vacuum plating coating, and preparation method thereof |
| CN105585927A (en) * | 2016-03-24 | 2016-05-18 | 浙江新迪在龙涂料科技有限公司 | LED curing coating type vacuum plating pigment and preparing method thereof |
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- 2016-11-28 CN CN201611059031.XA patent/CN106752856A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105368300A (en) * | 2015-12-10 | 2016-03-02 | 滁州金桥德克新材料有限公司 | High solid content UV vacuum plating coating, and preparation method thereof |
| CN105585927A (en) * | 2016-03-24 | 2016-05-18 | 浙江新迪在龙涂料科技有限公司 | LED curing coating type vacuum plating pigment and preparing method thereof |
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