CN105295633A - Aqueous flat lacquer and preparation method - Google Patents
Aqueous flat lacquer and preparation method Download PDFInfo
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- CN105295633A CN105295633A CN201510893528.0A CN201510893528A CN105295633A CN 105295633 A CN105295633 A CN 105295633A CN 201510893528 A CN201510893528 A CN 201510893528A CN 105295633 A CN105295633 A CN 105295633A
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- water
- dumb light
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- light paint
- ether
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- 238000002360 preparation method Methods 0.000 title claims description 9
- 239000004922 lacquer Substances 0.000 title abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 33
- 239000000839 emulsion Substances 0.000 claims abstract description 23
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 14
- 239000003002 pH adjusting agent Substances 0.000 claims abstract description 11
- -1 fluorine modified acrylate Chemical class 0.000 claims abstract description 9
- 238000002156 mixing Methods 0.000 claims abstract description 6
- 229920001909 styrene-acrylic polymer Polymers 0.000 claims abstract description 4
- 239000003973 paint Substances 0.000 claims description 47
- 239000002002 slurry Substances 0.000 claims description 14
- 239000002253 acid Substances 0.000 claims description 13
- 150000002148 esters Chemical class 0.000 claims description 13
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 11
- 239000006185 dispersion Substances 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 239000003999 initiator Substances 0.000 claims description 9
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical group [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- 238000010792 warming Methods 0.000 claims description 6
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 5
- 239000013543 active substance Substances 0.000 claims description 5
- 239000013530 defoamer Substances 0.000 claims description 5
- 230000008719 thickening Effects 0.000 claims description 5
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 4
- 238000004581 coalescence Methods 0.000 claims description 4
- QTKPMCIBUROOGY-UHFFFAOYSA-N 2,2,2-trifluoroethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(F)(F)F QTKPMCIBUROOGY-UHFFFAOYSA-N 0.000 claims description 3
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 claims description 3
- 239000004342 Benzoyl peroxide Substances 0.000 claims description 3
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 3
- 229920002907 Guar gum Polymers 0.000 claims description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical group OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 3
- 238000013019 agitation Methods 0.000 claims description 3
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 3
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 3
- 150000007942 carboxylates Chemical class 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 claims description 3
- 239000000665 guar gum Substances 0.000 claims description 3
- 229960002154 guar gum Drugs 0.000 claims description 3
- 235000010417 guar gum Nutrition 0.000 claims description 3
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims description 3
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 239000000376 reactant Substances 0.000 claims description 3
- 230000035484 reaction time Effects 0.000 claims description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 3
- 229960004418 trolamine Drugs 0.000 claims description 3
- IDQBJILTOGBZCR-UHFFFAOYSA-N 1-butoxypropan-1-ol Chemical compound CCCCOC(O)CC IDQBJILTOGBZCR-UHFFFAOYSA-N 0.000 claims description 2
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 claims description 2
- CUDYYMUUJHLCGZ-UHFFFAOYSA-N 2-(2-methoxypropoxy)propan-1-ol Chemical compound COC(C)COC(C)CO CUDYYMUUJHLCGZ-UHFFFAOYSA-N 0.000 claims description 2
- RNFAKTRFMQEEQE-UHFFFAOYSA-N Tripropylene glycol butyl ether Chemical compound CCCCOC(CC)OC(C)COC(O)CC RNFAKTRFMQEEQE-UHFFFAOYSA-N 0.000 claims description 2
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 claims description 2
- 229940075557 diethylene glycol monoethyl ether Drugs 0.000 claims description 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 2
- 238000000576 coating method Methods 0.000 abstract description 14
- 239000011248 coating agent Substances 0.000 abstract description 10
- 239000000654 additive Substances 0.000 abstract description 8
- 238000001035 drying Methods 0.000 abstract description 7
- 230000000996 additive effect Effects 0.000 abstract description 5
- 229910052731 fluorine Inorganic materials 0.000 abstract description 5
- 239000002994 raw material Substances 0.000 abstract description 4
- 239000011737 fluorine Substances 0.000 abstract description 3
- 239000002904 solvent Substances 0.000 abstract description 3
- 238000003860 storage Methods 0.000 abstract description 3
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 230000008033 biological extinction Effects 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 239000002562 thickening agent Substances 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 12
- 239000007787 solid Substances 0.000 description 5
- 229910000838 Al alloy Inorganic materials 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 2
- 125000001153 fluoro group Chemical group F* 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- IUHFWCGCSVTMPG-UHFFFAOYSA-N [C].[C] Chemical group [C].[C] IUHFWCGCSVTMPG-UHFFFAOYSA-N 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000007591 painting process Methods 0.000 description 1
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920003009 polyurethane dispersion Polymers 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses aqueous flat lacquer which comprises fluorine modified acrylate emulsion, styrene acrylic emulsion, matting paste, a filming additive, a defoaming agent, a thickening agent, a leveling agent, a pH adjusting agent and solvent water, wherein the matting paste consists of extinction powder, solvent water and other additives; and the aqueous flat lacquer can be prepared by mixing and dispersing the raw materials at a high speed. The surface drying time of the aqueous flat lacquer disclosed by the invention is not more than 30 minutes, the hard drying time is less than 3 hours, the storage stability is good, and the coating adhesion force is good and uniform.
Description
Technical field
The present invention relates to a kind of water-miscible paint, be specifically related to a kind of water-based dumb light paint and preparation method thereof.
Background technology
In recent years, the coating system that water-borne coatings, high solid part coating etc. meet environmental requirement comes into one's own day by day, and development in recent years is rapid, progressively replaces the coating of conventional organic solvents type, with the fastest developing speed especially with water-borne coatings.Water-borne coatings take water as the coating of solvent or dispersion medium, is also called emulsion paint.Because water instead of organic solvent, water-borne coatings does not have the discharge of VOC to prevent fire, improves environment and the condition of coating material production.The resin raw material being usually used in preparing water-miscible paint at present has water alcohol acid, attribute ACRYLIC EMULSION, aqueous polyurethane dispersion and Aqueous acrylic urethane's dispersion.In these raw materials, ACRYLIC EMULSION has quick-drying, fast light, the feature such as have excellent weather resistance, and suitable large-scale promotion uses, but the ACRYLIC EMULSION of one-component exists the shortcomings such as viscosity is high, levelling property is poor, temperature flowing is poor, low temperature brittleness is high.
Light dumb light paint on current water-miscible paint market based on the clear lacquer or white paint obtains the favor of consumers in general.
Summary of the invention
For the deficiencies in the prior art part, the invention provides a kind of preparation method of dumb light paint of water-based, this dumb light paint surface drying time is not more than 30 minutes, and the time of doing solid work is less than 3 hours, and stability in storage is good, and coating adhesion is good, even.
Technical problem to be solved by this invention is achieved by the following technical programs:
Component and the mass percentage of the water-based dumb light paint in the present invention are:
Fluorin modified crylic acid ester emulsion 55-65%
Styrene acrylic emulsion 10-15%
Mute slurry 5-15%
Film coalescence aid 2-6%
Defoamer 0.5-1%
Thickening material 0.8-1.2%
Flow agent 0.5-0.8%
PH adjusting agent 0.8-1%
Water surplus
Wherein the component of mute slurry and mass percentage are:
Flatting silica 35-55%
Dispersion agent 1-3%
Tensio-active agent 2-5%
PH adjusting agent 0.2-0.5%
Propylene glycol 1-2%
Water surplus
Fluorine is the element that in the periodic table of elements, electronegativity is maximum, has the strongest electronegativity and polarizability, and atomic radius is only greater than hydrogen.The C-F key that fluorine atom replaces the H-shaped one-tenth on c h bond is extremely short, and bond energy is up to 460kJ/mol.Full-fluorine group in fluorine-contaninig polyacrylate polymkeric substance is positioned on the side chain of polymkeric substance; in the process of film forming; perfluoroalkyl in fluorinated acrylate polymer can be enriched on the interface of polymkeric substance and air, and stretches in air, forms " shielding protection " to main chain and interior molecules.Further, fluorine atom tightly can encase carbon carbon backbone chain, makes the stable physical property of fluorinated acrylate emulsion.Therefore, polyacrylic ester macromolecular chain is introduced fluorine and not only can retain original good filming, and further enhancing snappiness and the sticking power of paint film.
In the present invention, the preparation method of fluorin modified crylic acid ester emulsion is:
Trifluoroethyl methacrylate, vinylformic acid hexafluoro butyl ester, methyl methacrylate, butyl acrylate, ethylene glycol monobutyl ether are placed in reaction vessel mix and blend with mass ratio 1:2.8:1.25:1:5,75-80 DEG C is warming up to after mixing, be that lauryl mercaptan and the benzoyl peroxide of 1:1.5 drops in reaction vessel as initiator using mass ratio, the mass ratio of initiator and total reactant is 1:16-22; The time that initiator drips is 1.5-2 hour, and the reaction times is 3-4 hour, Keep agitation in reaction process, is then warming up to 90 DEG C, is incubated half an hour, namely obtains fluorin modified crylic acid ester emulsion after question response thing naturally cooling.
Mute slurry is make paint film present the component of mat surface in the dumb light paint in the present invention, and matte effect is by adding flatting silica to reach.If flatting silica is added directly in the emulsion of film forming, easily causes mixing uneven, cause the problem such as paint film uneven distribution, coating surface lustre lacking uniformity formed during application.Therefore, in the present invention, flatting silica is placed in aqueous solvent, adds dispersion agent, tensio-active agent, pH adjusting agent and propylene glycol, stir, make mute slurry.
The dispersion agent used is polyoxyethylene carboxylate, and tensio-active agent is HPMC, and pH adjusting agent is sodium carbonate or sodium bicarbonate.The mute slurry made so not only can quick and conveniently feed in raw material accurately when preparing water-based dumb light paint, and by the control of additive by the pH value of mute slurry, adhesive capacity as far as possible and emulsion matrix keep close state, enable the composition of mute slurry and fluorin modified crylic acid ester emulsion and other additives can effective integration, make dumb light paint entirety present steady state.
In the present invention water-based dumb light paint composition in, styrene acrylic emulsion, for promoting the fusion performance of emulsion in dumb light paint, enables other additives effectively mix with emulsion in water.
Use film coalescence aid be ethylene glycol monobutyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, propandiol butyl ether, dipropylene glycol methyl ether, dipropylene, tripropylene glycol butyl ether one or more.The defoamer used is polyoxyethylene nonylphenol ether, and thickening material is guar gum, and flow agent is virgin pp acid esters flow agent, and pH adjusting agent is trolamine.Above-mentioned additive is all the additive in optimum body series dumb light paint, uses other commercially available auxiliary agents, additive is also feasible, just affect to some extent the film-formation result of dumb light paint and the homogeneity of paint film.
A kind of method preparing water-based dumb light paint in the present invention:
Each component is mixed according to mass percent, with the rate of dispersion of 2500-4000r/min by stock dispersion 1.5-2 hour, makes each component disperses even.
Water-based dumb light paint in the present invention is applicable to the surface of wood materials, metallic substance, glass material.
The present invention has following beneficial effect:
1, the water-based dumb light paint in the present invention is short for set time, and surface drying time is not more than 30 minutes, and the time of doing solid work is less than 3 hours.
2, the water-based dumb light paint stability in storage in the present invention is good, and coating adhesion is good, even.
3, the water-based dumb light paint paint film in the present invention is even, and matte effect is good, and colour generation is high-grade.
Embodiment
Below by embodiment, content of the present invention is conducted further description.
1, the preparation of fluorin modified crylic acid ester emulsion
Trifluoroethyl methacrylate, vinylformic acid hexafluoro butyl ester, methyl methacrylate, butyl acrylate, ethylene glycol monobutyl ether are placed in reaction vessel mix and blend with mass ratio 1:2.8:1.25:1:5,78 DEG C are warming up to after mixing, be that lauryl mercaptan and the benzoyl peroxide of 1:1.5 drops in reaction vessel as initiator using mass ratio, the mass ratio of initiator and total reactant is 1:20; The time that initiator drips is 2 hours, and the reaction times is 4 hours, Keep agitation in reaction process, is then warming up to 90 DEG C, is incubated half an hour, namely obtains required fluorin modified crylic acid ester emulsion after question response thing naturally cooling.
2, the preparation of mute slurry
By mass percentage be the flatting silica of 50%, 2.5% polyoxyethylene carboxylate, 5% HPMC, the sodium carbonate of 0.2%, the propylene glycol of 2% and 40.3% water mixing, namely obtain required mute slurry after stirring.
3, the preparation of water-based dumb light paint
In embodiment the composition of water-based dumb light paint and mass percentage as shown in the table, wherein defoamer is polyoxyethylene nonylphenol ether, and thickening material is guar gum, and flow agent is virgin pp acid esters flow agent, and pH adjusting agent is trolamine.Stir after each several part component is mixed.
Be coated on respectively in wooden test piece, aluminium alloy test piece and glass coupon by dumb light paint in embodiment, aluminium alloy test piece selects 6063.After paint spraying, record the surface drying of dumb light paint and do solid work the time, and carrying out sticking power test test to above-mentioned coating, testing method is carried out according to " GB/T1720-1979 paint film adhesion assay method ", and test result is as follows.
From result, the sticking power in wooden test piece, aluminium alloy test piece, glass coupon of the dumb light paint in the present invention is all very good.
Can be found out by test result, the surface drying time of the dumb light paint in the present invention in wooden test piece, may be relevant with the water-absorbent of wood materials itself than short on other materials.The test piece of doing solid work time then three kinds of materials does not all have large difference.
The good hand touch of dumb light paint in painting process in the embodiment of the present invention, have slight brush mark, fullness ratio is good, and matte effect is good, and paint film appearance noble quality has texture.
Finally it should be noted that, above embodiment is only in order to illustrate the technical scheme of the embodiment of the present invention but not to be limited, although be described in detail the embodiment of the present invention with reference to preferred embodiment, those of ordinary skill in the art is to be understood that and still can modifies to the technical scheme of the embodiment of the present invention or equivalent replacement, and these are revised or be equal to the scope that replacement also can not make amended technical scheme disengaging embodiment of the present invention technical scheme.
Claims (8)
1. a water-based dumb light paint, is characterized in that the component of described water-based dumb light paint and mass percentage are:
Fluorin modified crylic acid ester emulsion 55-65%
Styrene acrylic emulsion 10-15%
Mute slurry 5-15%
Film coalescence aid 2-6%
Defoamer 0.5-1%
Thickening material 0.8-1.2%
Flow agent 0.5-0.8%
PH adjusting agent 0.8-1%
Water surplus
Wherein the component of mute slurry and mass percentage are:
Flatting silica 35-55%
Dispersion agent 1-3%
Tensio-active agent 2-5%
PH adjusting agent 0.2-0.5%
Propylene glycol 1-2%
Water surplus.
2. water-based dumb light paint as claimed in claim 1, it is characterized in that: the preparation method of described fluorin modified crylic acid ester emulsion is: trifluoroethyl methacrylate, vinylformic acid hexafluoro butyl ester, methyl methacrylate, butyl acrylate, ethylene glycol monobutyl ether are placed in reaction vessel mix and blend with mass ratio 1:2.8:1.25:1:5,75-80 DEG C is warming up to after mixing, be that lauryl mercaptan and the benzoyl peroxide of 1:1.5 drops in reaction vessel as initiator using mass ratio, the mass ratio of initiator and total reactant is 1:16-22; The time that initiator drips is 1.5-2 hour, and the reaction times is 3-4 hour, Keep agitation in reaction process, is then warming up to 90 DEG C, is incubated half an hour, namely obtains fluorin modified crylic acid ester emulsion after question response thing naturally cooling.
3. water-based dumb light paint as claimed in claim 1, is characterized in that: described film coalescence aid is one or more in ethylene glycol monobutyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, propandiol butyl ether, dipropylene glycol methyl ether, dipropylene, tripropylene glycol butyl ether.
4. water-based dumb light paint as claimed in claim 1, it is characterized in that: described defoamer is polyoxyethylene nonylphenol ether, thickening material is guar gum, and flow agent is virgin pp acid esters flow agent, and pH adjusting agent is trolamine.
5. water-based dumb light paint as claimed in claim 1, is characterized in that: the dispersion agent in mute slurry is polyoxyethylene carboxylate.
6. water-based dumb light paint as claimed in claim 1, is characterized in that: the tensio-active agent in mute slurry is HPMC.
7. water-based dumb light paint as claimed in claim 1, is characterized in that: the pH adjusting agent in mute slurry is sodium carbonate or sodium bicarbonate.
8. prepare as arbitrary in claim 1-7 as described in the method for water-based dumb light paint, it is characterized in that: each component is mixed according to mass percent, with the rate of dispersion of 2500-4000r/min by stock dispersion 1.5-2 hour.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510893528.0A CN105295633B (en) | 2015-12-07 | 2015-12-07 | A kind of aqueous dumb light paint and preparation method |
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| CN201510893528.0A CN105295633B (en) | 2015-12-07 | 2015-12-07 | A kind of aqueous dumb light paint and preparation method |
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| CN105295633B CN105295633B (en) | 2017-10-20 |
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| CN110280464A (en) * | 2019-07-08 | 2019-09-27 | 东莞市三诚鑫电子科技有限公司 | The mute androgynous spraying process of the light of plastic part |
| CN110527363A (en) * | 2019-08-30 | 2019-12-03 | 四川嘉宝莉涂料有限公司 | A kind of aqueous full dumb light finishing varnish and preparation method thereof that imitative lime stone is specially matched |
| CN112094554A (en) * | 2020-09-22 | 2020-12-18 | 卡秀万辉(无锡)高新材料有限公司 | Water-based bi-component coating, preparation method thereof and application thereof in anode aluminum substrate coating |
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| CN110280464A (en) * | 2019-07-08 | 2019-09-27 | 东莞市三诚鑫电子科技有限公司 | The mute androgynous spraying process of the light of plastic part |
| CN110527363A (en) * | 2019-08-30 | 2019-12-03 | 四川嘉宝莉涂料有限公司 | A kind of aqueous full dumb light finishing varnish and preparation method thereof that imitative lime stone is specially matched |
| CN112094554A (en) * | 2020-09-22 | 2020-12-18 | 卡秀万辉(无锡)高新材料有限公司 | Water-based bi-component coating, preparation method thereof and application thereof in anode aluminum substrate coating |
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| CN105295633B (en) | 2017-10-20 |
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Correction item: Patentee|Address Correct: Foshan Gaoming Fulongsi New Material Technology Co., Ltd.|528518 Mingcheng Park Seventh Road, Gaoming Cangjiang Industrial Park, Foshan City, Guangdong Province False: Foshan Gaoming flons new materials Co. Ltd.|528518 Mingcheng Park Seventh Road, Gaoming Cangjiang Industrial Park, Foshan City, Guangdong Province Number: 42-02 Volume: 33 |
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