CN105562422A - 一种含氟农药废渣稳定化固化方法 - Google Patents
一种含氟农药废渣稳定化固化方法 Download PDFInfo
- Publication number
- CN105562422A CN105562422A CN201610000488.7A CN201610000488A CN105562422A CN 105562422 A CN105562422 A CN 105562422A CN 201610000488 A CN201610000488 A CN 201610000488A CN 105562422 A CN105562422 A CN 105562422A
- Authority
- CN
- China
- Prior art keywords
- fluorine
- waste residue
- containing pesticide
- fluoro
- pesticide waste
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 40
- 239000010914 pesticide waste Substances 0.000 title claims abstract description 30
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 title abstract description 25
- 239000011737 fluorine Substances 0.000 title abstract description 25
- 229910052731 fluorine Inorganic materials 0.000 title abstract description 25
- 230000008023 solidification Effects 0.000 title abstract description 14
- 238000007711 solidification Methods 0.000 title abstract description 14
- 239000002253 acid Substances 0.000 claims abstract description 24
- 239000004568 cement Substances 0.000 claims abstract description 24
- 125000001153 fluoro group Chemical group F* 0.000 claims description 31
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 16
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 14
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 13
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 13
- 239000004571 lime Substances 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 8
- 230000006641 stabilisation Effects 0.000 claims description 8
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 7
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 7
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims description 5
- 230000001105 regulatory effect Effects 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 6
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 abstract description 4
- 235000011116 calcium hydroxide Nutrition 0.000 abstract description 4
- 239000000920 calcium hydroxide Substances 0.000 abstract description 4
- 229910001861 calcium hydroxide Inorganic materials 0.000 abstract description 4
- 239000000203 mixture Substances 0.000 abstract description 2
- 239000002920 hazardous waste Substances 0.000 abstract 2
- 239000002002 slurry Substances 0.000 abstract 2
- 230000009286 beneficial effect Effects 0.000 abstract 1
- 239000002699 waste material Substances 0.000 description 25
- 238000002386 leaching Methods 0.000 description 17
- 230000007613 environmental effect Effects 0.000 description 11
- 239000000575 pesticide Substances 0.000 description 11
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 10
- 239000000243 solution Substances 0.000 description 10
- 238000003756 stirring Methods 0.000 description 7
- 239000003905 agrochemical Substances 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- 239000004411 aluminium Substances 0.000 description 5
- 239000011777 magnesium Substances 0.000 description 5
- 229910052749 magnesium Inorganic materials 0.000 description 5
- 235000019738 Limestone Nutrition 0.000 description 4
- 239000006028 limestone Substances 0.000 description 4
- 238000009423 ventilation Methods 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- 239000003929 acidic solution Substances 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 229910001506 inorganic fluoride Inorganic materials 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- IRPGOXJVTQTAAN-UHFFFAOYSA-N 2,2,3,3,3-pentafluoropropanal Chemical compound FC(F)(F)C(F)(F)C=O IRPGOXJVTQTAAN-UHFFFAOYSA-N 0.000 description 1
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- KLZUFWVZNOTSEM-UHFFFAOYSA-K Aluminum fluoride Inorganic materials F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 description 1
- 235000004237 Crocus Nutrition 0.000 description 1
- 241000596148 Crocus Species 0.000 description 1
- 238000005903 acid hydrolysis reaction Methods 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003818 cinder Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- ORUIBWPALBXDOA-UHFFFAOYSA-L magnesium fluoride Chemical compound [F-].[F-].[Mg+2] ORUIBWPALBXDOA-UHFFFAOYSA-L 0.000 description 1
- 229910001635 magnesium fluoride Inorganic materials 0.000 description 1
- -1 magnesium-aluminum-calcium Chemical compound 0.000 description 1
- 230000002503 metabolic effect Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000002910 solid waste Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
- B09B3/20—Agglomeration, binding or encapsulation of solid waste
Landscapes
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Processing Of Solid Wastes (AREA)
- Treatment Of Sludge (AREA)
Abstract
Description
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610000488.7A CN105562422B (zh) | 2016-01-04 | 2016-01-04 | 一种含氟农药废渣稳定化固化方法 |
Applications Claiming Priority (1)
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---|---|---|---|
CN201610000488.7A CN105562422B (zh) | 2016-01-04 | 2016-01-04 | 一种含氟农药废渣稳定化固化方法 |
Publications (2)
Publication Number | Publication Date |
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CN105562422A true CN105562422A (zh) | 2016-05-11 |
CN105562422B CN105562422B (zh) | 2018-07-06 |
Family
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Family Applications (1)
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CN201610000488.7A Active CN105562422B (zh) | 2016-01-04 | 2016-01-04 | 一种含氟农药废渣稳定化固化方法 |
Country Status (1)
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CN (1) | CN105562422B (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113929413A (zh) * | 2020-07-08 | 2022-01-14 | 宁夏宸宇环保科技有限公司 | 一种含氟危废稳定化固化体及其制备方法 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101428805A (zh) * | 2008-12-03 | 2009-05-13 | 湖北天进工贸有限公司 | 含氟硅渣的利用技术 |
WO2012056826A1 (ja) * | 2010-10-29 | 2012-05-03 | 三菱マテリアル株式会社 | 有害物質含有水の処理方法および処理装置 |
CN103170303A (zh) * | 2013-04-15 | 2013-06-26 | 北京中地泓科环境科技有限公司 | 利用硅酸盐水泥为原料制备除氟剂的方法 |
US20130267754A1 (en) * | 2004-03-16 | 2013-10-10 | Jdc Corporation | Hydrotalcite-like substance, process for producing the same and method of immobilizing hazardous substance |
CN104030332A (zh) * | 2014-06-03 | 2014-09-10 | 同济大学 | 一种从农药工业含氟废渣中回收冰晶石的方法 |
CN105039699A (zh) * | 2015-06-03 | 2015-11-11 | 江西合纵锂业科技有限公司 | 锂云母固氟重构提取碱金属渣处理与资源化利用方法 |
CN105130346A (zh) * | 2015-09-15 | 2015-12-09 | 韩素梅 | 一种含氟固体废渣的安全处置方法 |
-
2016
- 2016-01-04 CN CN201610000488.7A patent/CN105562422B/zh active Active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20130267754A1 (en) * | 2004-03-16 | 2013-10-10 | Jdc Corporation | Hydrotalcite-like substance, process for producing the same and method of immobilizing hazardous substance |
CN101428805A (zh) * | 2008-12-03 | 2009-05-13 | 湖北天进工贸有限公司 | 含氟硅渣的利用技术 |
WO2012056826A1 (ja) * | 2010-10-29 | 2012-05-03 | 三菱マテリアル株式会社 | 有害物質含有水の処理方法および処理装置 |
CN103170303A (zh) * | 2013-04-15 | 2013-06-26 | 北京中地泓科环境科技有限公司 | 利用硅酸盐水泥为原料制备除氟剂的方法 |
CN104030332A (zh) * | 2014-06-03 | 2014-09-10 | 同济大学 | 一种从农药工业含氟废渣中回收冰晶石的方法 |
CN105039699A (zh) * | 2015-06-03 | 2015-11-11 | 江西合纵锂业科技有限公司 | 锂云母固氟重构提取碱金属渣处理与资源化利用方法 |
CN105130346A (zh) * | 2015-09-15 | 2015-12-09 | 韩素梅 | 一种含氟固体废渣的安全处置方法 |
Non-Patent Citations (1)
Title |
---|
揭武等: ""粉煤灰-水泥固化含氟废渣的研究"", 《粉煤灰综合利用》 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113929413A (zh) * | 2020-07-08 | 2022-01-14 | 宁夏宸宇环保科技有限公司 | 一种含氟危废稳定化固化体及其制备方法 |
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CN105562422B (zh) | 2018-07-06 |
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Application publication date: 20160511 Assignee: Yangzhou Jiejia Testing Technology Co.,Ltd. Assignor: YANGZHOU JIEJIA INDUSTRIAL SOLID WASTE DISPOSAL Co.,Ltd. Contract record no.: X2023320000225 Denomination of invention: A Method for Stabilizing and Solidifying Fluorinated Pesticide Residues Granted publication date: 20180706 License type: Common License Record date: 20231107 |
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EC01 | Cancellation of recordation of patent licensing contract |
Assignee: Yangzhou Jiejia Testing Technology Co.,Ltd. Assignor: YANGZHOU JIEJIA INDUSTRIAL SOLID WASTE DISPOSAL Co.,Ltd. Contract record no.: X2023320000225 Date of cancellation: 20240507 |
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EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20160511 Assignee: Yangzhou Jiejia Testing Technology Co.,Ltd. Assignor: YANGZHOU JIEJIA INDUSTRIAL SOLID WASTE DISPOSAL Co.,Ltd. Contract record no.: X2024980006099 Denomination of invention: A method for stabilizing and solidifying fluorinated pesticide residues Granted publication date: 20180706 License type: Common License Record date: 20240523 |