CN105542562A - Water-based ink as all-natural renewable resource and preparation method of water-based ink - Google Patents
Water-based ink as all-natural renewable resource and preparation method of water-based ink Download PDFInfo
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- CN105542562A CN105542562A CN201610141124.0A CN201610141124A CN105542562A CN 105542562 A CN105542562 A CN 105542562A CN 201610141124 A CN201610141124 A CN 201610141124A CN 105542562 A CN105542562 A CN 105542562A
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- water
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- based ink
- renewable resource
- natural renewable
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/26—Emulsion polymerisation with the aid of emulsifying agents anionic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/30—Emulsion polymerisation with the aid of emulsifying agents non-ionic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/52—Amides or imides
- C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
- C08F220/56—Acrylamide; Methacrylamide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F289/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds not provided for in groups C08F251/00 - C08F287/00
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
Abstract
The invention belongs to the field of preparation of water-based ink, and particularly relates to water-based ink as an all-natural renewable resource and a preparation method of the water-based ink. The water-based ink comprises raw materials in percentage by weight as follows: 18% of a viscous liquid secreted by pine trees, 4% of active monomers, 7% of polar monomers, 60% of pure water, 0.2% of a nonionic surfactant, 0.2% of an anionic surfactant, 0.6% of an initiator, 3% of plant cellulose and 7% of an organic pigment. The viscous liquid secreted by the pine trees is subjected to graft polymerization modification, a hydrophilic group is introduced to a macromolecule chain, and the ink with stable performance can be prepared. A product does not contain an organic solvent, VOC (volatile organic compounds), 24 kinds of aromatic amine, formaldehyde and heavy metal elements, is free of organic solvent residues on a printed matter, is non-toxic, odorless, non-flammable and non-combustible, and is ecological, environment-friendly, energy-saving, low-carbon, healthy and safe.
Description
Technical field
The invention belongs to the preparation field of water color ink, be specifically related to a kind of pure natural renewable resource water color ink and preparation method thereof.
Background technology
Along with the fast development of Printing Industry, demand and the Status of development of printing-ink grow with each passing day.Conventional printing inks is produced and is relied on the energy on a large amount of earth, and the synthesis of oil system is as ink main body film forming component, and using petroleum by-products organic solvent as thinner, volatility is fast, and smell is comparatively large, belongs to inflammable explosive article, causes severe contamination.Such as in printing process, during ink volatile dry, these organic solvents discharge VOC volatile matter, produce the smell of strong property, form the Greenhouse effect even more serious than carbonic acid gas, and under the irradiation of sunlight, oxide compound and optical smoke can be formed, major polluting atmosphere environment, affects the healthy of people and environmental quality.And when workshop VOC gathers certain concentration in atmosphere, the electrostatic running into naked light or machine run produces, and will blast and fire etc., serious threat lives and properties.Printing-ink every annual consumption in the whole world has reached 3,000,000 tons according to statistics, the global organic solvent volatile matter VOC discharge amount of pollution that ink causes has reached hundreds of thousands of ton, the annual printing-ink consumption of China has reached 300,000 tons, account for 1/10th of the whole world, being the maximum big country of world's printing-ink consumption, is again the country that ink causes pollution the most serious.
Along with the anxiety of oil, petroleum in short supply, resource-constrained, regeneration is unlimited, environmental pollution, and potential safety hazard etc. destroy the attention that the eubiosis causes the whole society, for developing printing-ink frontier provides safeguard, one is the research and development of plant renewable resources, and two is use water to replace organic solvent, opens up a brand-new ecological path.
Water color ink forms through abrasive machining primarily of water soluble resin, pigment dyestuff, solvent and related auxiliaries.Water color ink is specially adapted to the strict Packaging Printing Product of the health conditions requirings such as cigarette, wine, food, beverage, medicine, toy for children.
Summary of the invention
The object of the invention is to for the deficiencies in the prior art, a kind of pure natural renewable resource water color ink and preparation method thereof is provided.The present invention adopts the secretory substance of natural tree to be main raw material, and resource can regeneration, has ecological, environmental protective, energy-saving low-carbon, healthy and safe advantage.
For achieving the above object, the present invention adopts following technical scheme:
A kind of pure natural renewable resource water color ink, raw material forms mark by weight and counts: the thick liquid 18% of pine tree secretion, reactive monomer 4%, polar monomer 7%, pure water 60%, nonionogenic tenside 0.2%, anion surfactant 0.2%, initiator 0.6%, plant cellulose 3%, pigment dyestuff 7%.
Described initiator is ammonium persulphate.
Described polar monomer is methyl methacrylate.
Described reactive monomer is acrylamide.
Prepare a method for pure natural renewable resource water color ink as above, comprise the following steps:
1) preparation of water-dispersible solution: thick liquid, reactive monomer and the polar monomer secreted by pine tree produce chemical affinity under nonionic and anion surfactant effect, are dispersed in pure water, form water-dispersible solution;
2) preparation of stable water soluble polymkeric substance: water-dispersible solution is heated to 93 ~ 97 DEG C, adds initiator, polymerization 4h, obtained stable water soluble polymkeric substance;
3) preparation of ink: by stable water soluble polymkeric substance and pigment dyestuff, plant cellulose mix and blend, evenly pre-dispersed, grinds to form required fineness, obtained ink.
beneficial effect of the present invention is:
1) pure natural renewable resource water color ink of the present invention, can realize high speed multicolor overprint, possess excellent printing adaptability, and superimposed dedifferentiation is bright in colour, and attachment fastness is strong;
2) ink of the present invention, not containing organic solvent, VOC free organic volatile material, and organic solvent-free remains, nonpoisonous and tasteless, without inflammable and explosive, not containing 24 kinds of aromatic amines, formaldehyde and heavy metal elements, there is ecological, environmental protective, energy-saving low-carbon and healthy and safe advantage, various paper product trade mark can be widely used in, packing box, sanitary product, leather, chemical fibre, food, medicine, plastics film flexible packaging printing etc.
Embodiment
The present invention's the following example further illustrates the present invention, but protection scope of the present invention is not limited to the following example.
embodiment 1
A kind of pure natural renewable resource water color ink, raw material forms mark by weight and counts: the thick liquid 18% of pine tree secretion, acrylamide 4%, methyl methacrylate 7%, pure water 60%, alkylphenol polyoxyethylene 0.2%, Sodium dodecylbenzene sulfonate 0.2%, ammonium persulphate 0.6%, plant cellulose 3%, pigment dyestuff 7%.
Prepare a method for pure natural renewable resource water color ink as above, comprise the following steps:
1) preparation of water-dispersible solution: thick liquid, reactive monomer and the polar monomer secreted by pine tree produce chemical affinity under nonionic and anion surfactant effect, are dispersed in pure water, form water-dispersible solution;
2) preparation of stable water soluble polymkeric substance: water-dispersible solution is heated to 93 ~ 97 DEG C, adds initiator, polymerization 4h, obtained stable water soluble polymkeric substance;
3) preparation of ink: by stable water soluble polymkeric substance and pigment dyestuff, plant cellulose mix and blend, evenly pre-dispersed, grinds to form required fineness, obtained ink.
performance test:
1) the key technical indexes:
Viscosity: 450-500 centipoises;
Fineness: 6-8 μm;
Formaldehyde content: 0 ㎎/kg;
Decomposable asymmetric choice net 24 kinds of aromatic amines: 0 ㎎/kg;
Heavy metal element: 0 ㎎/kg.
2) cost keeping:
This product saves 28% than traditional solvent-borne printing-ink price, according to market sale situation, add apparatus for production line and expand the scale of production, a set of apparatus for production line is produced per year: 130 tons, price per ton: 3.5 ten thousand yuan, expection can take in 4,550,000 yuans by enforcement sale, profit per ton 0.31 ten thousand yuan, profit: 40.3 ten thousand yuans.
The foregoing is only preferred embodiment of the present invention, all equalizations done according to the present patent application the scope of the claims change and modify, and all should belong to covering scope of the present invention.
Claims (5)
1. a pure natural renewable resource water color ink, it is characterized in that: raw material forms mark by weight and counts: the thick liquid 18% of pine tree secretion, reactive monomer 4%, polar monomer 7%, pure water 60%, nonionogenic tenside 0.2%, anion surfactant 0.2%, initiator 0.6%, plant cellulose 3%, pigment dyestuff 7%.
2. pure natural renewable resource water color ink according to claim 1, is characterized in that: described reactive monomer is acrylamide.
3. pure natural renewable resource water color ink according to claim 1, is characterized in that: described polar monomer is methyl methacrylate.
4. pure natural renewable resource water color ink according to claim 1, is characterized in that: described initiator is ammonium persulphate.
5. prepare the method for pure natural renewable resource water color ink as claimed in claim 1 for one kind, it is characterized in that: comprise the following steps: the 1) preparation of water-dispersible solution: thick liquid, reactive monomer and the polar monomer secreted by pine tree produce chemical affinity under nonionic and anion surfactant effect, be dispersed in pure water, form water-dispersible solution;
2) preparation of stable water soluble polymkeric substance: water-dispersible solution is heated to 93 ~ 97 DEG C, adds initiator, polymerization 4h, obtained stable water soluble polymkeric substance;
3) preparation of ink: by stable water soluble polymkeric substance and pigment dyestuff, plant cellulose mix and blend, evenly pre-dispersed, grinds to form required fineness, obtained ink.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610141124.0A CN105542562B (en) | 2016-03-14 | 2016-03-14 | Pure natural regenerated resources water-based ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610141124.0A CN105542562B (en) | 2016-03-14 | 2016-03-14 | Pure natural regenerated resources water-based ink and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105542562A true CN105542562A (en) | 2016-05-04 |
| CN105542562B CN105542562B (en) | 2018-06-19 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610141124.0A Active CN105542562B (en) | 2016-03-14 | 2016-03-14 | Pure natural regenerated resources water-based ink and preparation method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101302373A (en) * | 2008-06-19 | 2008-11-12 | 楼永财 | Water-soluble water-resistant printing ink for plastic woven sack and preparation thereof |
| CN103342784A (en) * | 2013-06-17 | 2013-10-09 | 华南理工大学 | Frankincense-modified acrylate emulsion and its preparation method and use |
| CN104610513A (en) * | 2013-11-02 | 2015-05-13 | 宏峰行化工(深圳)有限公司 | Synthetic method for high-softening point modified rosin resin emulsion |
| CN105001402A (en) * | 2015-08-03 | 2015-10-28 | 山西科诺奥合成材料有限公司 | Preparation method of acrylic modified rosin ester polymer for high-end sheet-fed printing ink |
-
2016
- 2016-03-14 CN CN201610141124.0A patent/CN105542562B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101302373A (en) * | 2008-06-19 | 2008-11-12 | 楼永财 | Water-soluble water-resistant printing ink for plastic woven sack and preparation thereof |
| CN103342784A (en) * | 2013-06-17 | 2013-10-09 | 华南理工大学 | Frankincense-modified acrylate emulsion and its preparation method and use |
| CN104610513A (en) * | 2013-11-02 | 2015-05-13 | 宏峰行化工(深圳)有限公司 | Synthetic method for high-softening point modified rosin resin emulsion |
| CN105001402A (en) * | 2015-08-03 | 2015-10-28 | 山西科诺奥合成材料有限公司 | Preparation method of acrylic modified rosin ester polymer for high-end sheet-fed printing ink |
Non-Patent Citations (1)
| Title |
|---|
| 林明涛等: "松香/丙烯酸系复合高分子乳液的制备与性能研究", 《林产化学与工业》 * |
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| CN105542562B (en) | 2018-06-19 |
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Effective date of registration: 20180524 Address after: 362700 tax revenue building 501, 46 mayor Hui Road, Shishi, Quanzhou, Fujian Applicant after: Zhang Guozhi Address before: 362714 room 407, R & D building, science and technology incubator base, Shishi, Quanzhou, Fujian Applicant before: SHISHI HENGSHENG ENVIRONMENTALLY FRIENDLY INK TECHNOLOGY R & D CENTER |
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