CN105523860A - Porous bentonite particle adsorptive microbial fertilizer and preparation method thereof - Google Patents
Porous bentonite particle adsorptive microbial fertilizer and preparation method thereof Download PDFInfo
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- CN105523860A CN105523860A CN201610097846.0A CN201610097846A CN105523860A CN 105523860 A CN105523860 A CN 105523860A CN 201610097846 A CN201610097846 A CN 201610097846A CN 105523860 A CN105523860 A CN 105523860A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D3/00—Calcareous fertilisers
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- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
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Abstract
The invention discloses a porous bentonite particle adsorptive microbial fertilizer and a preparation method thereof. The porous bentonite particle adsorptive microbial fertilizer is prepared from sodium bentonite, carbon powder, starch, epoxy resin, cement, land plaster, sodium alginate, bagasse powder, brown sugar, bran powder, rice washing water, chitosan hydrochloride, yeast powder, rhizobia inoculants, azotobacteria inoculants, lactobacillus powder, streptomyces albulus inoculants and appropriate amount of water. By an adsorption function of porous bentonite, adsorption of microbial agents can be completed, and survival time of the microbial agents in soil can be greatly prolonged. Microorganisms exposed in the nature are susceptible to severe environments, denaturation, death and activity are affected, and acting effects and duration of microbial fertilizers are seriously affected. By an outer high-sugar-content organic matter coating, microbial metabolism is promoted.
Description
Technical field
The invention belongs to the Technology field of fertilizer, be specifically related to a kind of porous bentonite clay particle absorption microbial fertilizer and preparation method thereof.
Background technology
Wilkinite take montmorillonite as the clay mineral of main component.Montmorillonite has the structure of simple Oblique Crystal, a kind of moisture dioctahedron or trioctahedral layer aluminosilicate mineral, two-layer silicon-oxy tetrahedron is had in the outside of single cell, therebetween one deck hydrogen-oxygen aluminium is octahedra, and in tetrahedron and octahedron, the silicon ion of high price and aluminum ion can by its cation replacements at a low price, make montmorillonite structure cell electronegative, become a large negative ion, thus make it have the ability of Liquidity limit, but to Anion-adsorption less effective.
Flaky graphite has good conductivity, but its laminate structure makes it to be not suitable for separately in conductive resin, usually used in combination with carbon black.Spherical carbon black particle is filled between the graphite of stratiform, applies certain pressure to graphite linings, can better contact.The great advantage of graphite conductive adhesive is that Performance comparision is stablized, and have certain acid and alkali-resistance ability, cheap, relative density is little, and dispersing property is good, but resistivity is higher, generally can only be used for middle resistance slurry.
Summary of the invention
In order to better play the absorption property of modified alta-mud in fertilizer, the present invention utilizes inorganic pore-forming material to manufacture countless interconnective microporous pipeline in spray profit soil, and thus have stronger adsorption effect, concrete grammar is as follows:
A kind of porous bentonite clay particle absorption microbial fertilizer, it is characterized in that, be made up of the raw material of following weight part: sodium bentonite 15 ~ 20, carbon dust 5 ~ 7, starch 1 ~ 2, epoxy resin 0.4 ~ 0.8, cement 1 ~ 1.5, terra alba 0.2 ~ 0.5, sodium alginate 5 ~ 8, bagasse powder 20 ~ 30, brown sugar 15 ~ 20, bran powder 30 ~ 45, washing water of rice 15 ~ 20, chitosan hydrochloride 2 ~ 4, yeast powder 1 ~ 2, Rhizobium Inoculant 0.5 ~ 1.0, vinelandii microbial inoculum 2 ~ 3, lactobacillus powder 0.5 ~ 0.8, streptomyces albus microbial inoculum 0.05 ~ 0.10 and appropriate water.
A preparation method for porous bentonite clay particle absorption microbial fertilizer, it is characterized in that, the useful viable count concentration of described Rhizobium Inoculant is 30 ~ 5,000,000,000/g.
A preparation method for porous bentonite clay particle absorption microbial fertilizer, it is characterized in that, the useful viable count concentration of described streptomyces albus microbial inoculum is 10 ~ 2,000,000,000/g.
A preparation method for porous bentonite clay particle absorption microbial fertilizer, it is characterized in that, the useful viable count concentration of described vinelandii microbial inoculum is 60 ~ 8,000,000,000/g.
A preparation method for porous bentonite clay particle absorption microbial fertilizer, is characterized in that, comprise following step:
(1) mixed by the water of epoxy resin with 4 ~ 5 times of its weight parts, be stirred to and dissolve completely after being heated to 70 ~ 80 DEG C, in the starch being then poured into mixing and carbon dust, stirring and evenly mixing becomes viscosity homogenate;
(2) sodium bentonite is removed sand, then the viscosity homogenate described in (1) is added, cement and terra alba, be stirred to become uniform slurry while add waterside, then being placed on voltage is in the energising field of 300 ~ 350V, slowly stirs 10 ~ 15min and makes carbon dust linear array, dries, then calcine the solid block that 30 ~ 40min becomes porous under being put in the hot conditions of 500 ~ 550 DEG C, crushing and screening is crossed 20 ~ 30 mesh sieves and is obtained granule;
(3) mixed yeast powder, Rhizobium Inoculant and other following remaining component do not related to, add the warm water of 30 ~ 35 DEG C of 40 ~ 50 times of its total weight parts, then stirs 20 ~ 25min and fully dissolve and melt;
(4) granule described in (2) is added in (3) gained solution, Ultrasonic Cleaners is put in unification, power 500 ~ 550W, effect 15 ~ 20min makes to be full of solution in micropore, do not make particle water content 20 ~ 25% higher than the hot blast of 80 DEG C by gas blower drum, again put in solution, secondary action is adsorbed, and obtains adsorption particle agent after completing;
(5) mixing sodium alginate, bagasse powder, brown sugar, bran powder, washing water of rice and chitosan hydrochloride, add the water of 1.5 ~ 2 times of its total weight parts, stir into thick paste, then add (4) described residue lysate and adsorption particle agent, by spray granulating post-drying.
Wilkinite prepares the method for sorbent material substantially: select the high-quality sodium bentonite of nonmetalliferous ore to be raw material, the inflammable micro mist carbon dust of 4g200 order and 2g starch is mixed at the 100g wilkinite of drying after removing sand, add appropriate water again to stir evenly and be squeezed into the particle that diameter is 3mm, dry, high temperature sintering again, because losing of crystal water generates CO with inflammable micropowder combustion
2releasing, define a large amount of micropores.
Final purpose of the present invention is the mineral element in order to sorption chemical element, too tiny by the micropore stayed after carbon dust high-temp combustion, the inorganic elements of fertilizer first must be dissolved, penetrate into again in tiny hole and go, but there is Railway Project here: 1, the surface tension of water is very large, to penetrate in trickle hole very slowly and comparatively difficulty; 2, the inorganic chemistry element after dissolving is through dilution, even if permeate completely, also very little above amount; 3, the micropore manufacture be made up of carbon dust particulate be micropore, be present in wilkinite inside, the micropore of therefore burned rear formation belongs to air-tight state, cannot reserve, let alone absorption.
Several measure of the present invention just in time overcomes the above problems, first carry out processing modified to carbon dust, we are using stronger for a kind of viscosity and the epoxy resin with conductivity joins in carbon dust after binding agent is diluted, stirred postadhesion is on carbon dust surface, become a kind of carbon dust particulate of sticky particle, then carbon dust is added in spray profit soil, freely be energized under the electric field action of conduction, carbon dust freely connects in conduction situation, form toner chain, and the effect of epoxy resin is just to make chain there is for some time, and (epoxy resin becomes modern technique already as the binding agent of electroconductibility, successful), then according to step, high temperature sintering, such formation micro-tube, instead of micropore, ul-trasonic irradiation is carried out when then putting into the chemical element of dissolving, the surface tension of greatly less water, finally dry, carry out second adsorption simultaneously, chemicals quality residual like this will improve greatly, in order to improve the water absorbing properties of spray profit soil particle and rapid functions/drying, a certain amount of cement of special interpolation, add strong absorptive and maintain the certain stability of spray profit soil particle.
Beneficial effect of the present invention: utilize the adsorption after the wilkinite pore-creating of porous, complete the absorption to microbiobacterial agent, greatly can extend the survival time of microbiobacterial agent in soil, be exposed to the microorganism of occurring in nature, be easy to the impact being subject to severe environment, sex change, dead, activity is affected, greatly affect action effect and the time length of microbial fertilizer, what periphery was wrapped up is the organic matter that one deck sugar degree is very high, microbial metabolism can be provided to utilize, better protection microorganism, microorganism can be closed with the root knot of plant and be formed root nodule, the multiple actions such as decomposition of becoming thoroughly decomposed of catalysis organic matter.
Embodiment
Embodiment 1:
A kind of porous bentonite clay particle absorption microbial fertilizer, it is characterized in that, be made up of the raw material of following weight part (Kg): sodium bentonite 16, carbon dust 6, starch 1, epoxy resin 0.5, cement 1.2, terra alba 0.4, sodium alginate 7, bagasse powder 25, brown sugar 18, bran powder 36, washing water of rice 17, chitosan hydrochloride 3, yeast powder 1, Rhizobium Inoculant 0.7, vinelandii microbial inoculum 2, lactobacillus powder 0.6, streptomyces albus microbial inoculum 0.06 and appropriate water.
A preparation method for porous bentonite clay particle absorption microbial fertilizer, it is characterized in that, the useful viable count concentration of described Rhizobium Inoculant is 30 ~ 5,000,000,000/g.
A preparation method for porous bentonite clay particle absorption microbial fertilizer, it is characterized in that, the useful viable count concentration of described streptomyces albus microbial inoculum is 10 ~ 2,000,000,000/g.
A preparation method for porous bentonite clay particle absorption microbial fertilizer, it is characterized in that, the useful viable count concentration of described vinelandii microbial inoculum is 60 ~ 8,000,000,000/g.
A preparation method for porous bentonite clay particle absorption microbial fertilizer, is characterized in that, comprise following step:
(1) mixed by the water of epoxy resin with 4 ~ 5 times of its weight parts, be stirred to and dissolve completely after being heated to 70 ~ 80 DEG C, in the starch being then poured into mixing and carbon dust, stirring and evenly mixing becomes viscosity homogenate;
(2) sodium bentonite is removed sand, then the viscosity homogenate described in (1) is added, cement and terra alba, be stirred to become uniform slurry while add waterside, then being placed on voltage is in the energising field of 300 ~ 350V, slowly stirs 10 ~ 15min and makes carbon dust linear array, dries, then calcine the solid block that 30 ~ 40min becomes porous under being put in the hot conditions of 500 ~ 550 DEG C, crushing and screening is crossed 20 ~ 30 mesh sieves and is obtained granule;
(3) mixed yeast powder, Rhizobium Inoculant and other following remaining component do not related to, add the warm water of 30 ~ 35 DEG C of 40 ~ 50 times of its total weight parts, then stirs 20 ~ 25min and fully dissolve and melt;
(4) granule described in (2) is added in (3) gained solution, Ultrasonic Cleaners is put in unification, power 500 ~ 550W, effect 15 ~ 20min makes to be full of solution in micropore, do not make particle water content 20 ~ 25% higher than the hot blast of 80 DEG C by gas blower drum, again put in solution, secondary action is adsorbed, and obtains adsorption particle agent after completing;
(5) mixing sodium alginate, bagasse powder, brown sugar, bran powder, washing water of rice and chitosan hydrochloride, add the water of 1.5 ~ 2 times of its total weight parts, stir into thick paste, then add (4) described residue lysate and adsorption particle agent, by spray granulating post-drying.
Adopt a kind of porous bentonite clay particle absorption microbial fertilizer of the present invention for the planting experiment of tea tree, select 5 mu of tea tree fields as experimental group, fertilizer 80 ~ 120Kg/ mu of the present invention is evenly laid on tea tree field after base manure mixes in the ratio of 1:6 with the subsoil in tea tree field, the implantation methods of 5 mu of tea tree fields of control group thinking routinely, other water and fertilizer management in the future and the prevention and control of plant diseases, pest control are implemented according to the practical situation of its growing way, result shows, experimental group tea tree field is due to beneficial microorganism content, cause decomposition velocity of organic substances fast, reduce the usage quantity of chemical fertilizer, total every mu of saving mineral manure 200 ~ 250Kg nearly, organic content is enriched simultaneously, the tender leaf amount of tealeaves is more, raising can food consumption, heighten Economic development 24.8%.
Claims (5)
1. a porous bentonite clay particle absorption microbial fertilizer, it is characterized in that, be made up of the raw material of following weight part: sodium bentonite 15 ~ 20, carbon dust 5 ~ 7, starch 1 ~ 2, epoxy resin 0.4 ~ 0.8, cement 1 ~ 1.5, terra alba 0.2 ~ 0.5, sodium alginate 5 ~ 8, bagasse powder 20 ~ 30, brown sugar 15 ~ 20, bran powder 30 ~ 45, washing water of rice 15 ~ 20, chitosan hydrochloride 2 ~ 4, yeast powder 1 ~ 2, Rhizobium Inoculant 0.5 ~ 1.0, vinelandii microbial inoculum 2 ~ 3, lactobacillus powder 0.5 ~ 0.8, streptomyces albus microbial inoculum 0.05 ~ 0.10 and appropriate water.
2. a kind of porous bentonite clay particle adsorbs the preparation method of microbial fertilizer according to claim 1, and it is characterized in that, the useful viable count concentration of described Rhizobium Inoculant is 30 ~ 5,000,000,000/g.
3. a kind of porous bentonite clay particle adsorbs the preparation method of microbial fertilizer according to claim 1, and it is characterized in that, the useful viable count concentration of described streptomyces albus microbial inoculum is 10 ~ 2,000,000,000/g.
4. a kind of porous bentonite clay particle adsorbs the preparation method of microbial fertilizer according to claim 1, and it is characterized in that, the useful viable count concentration of described vinelandii microbial inoculum is 60 ~ 8,000,000,000/g.
5. a kind of porous bentonite clay particle adsorbs the preparation method of microbial fertilizer according to claim 1, it is characterized in that, comprises following step:
(1) mixed by the water of epoxy resin with 4 ~ 5 times of its weight parts, be stirred to and dissolve completely after being heated to 70 ~ 80 DEG C, in the starch being then poured into mixing and carbon dust, stirring and evenly mixing becomes viscosity homogenate;
(2) sodium bentonite is removed sand, then the viscosity homogenate described in (1) is added, cement and terra alba, be stirred to become uniform slurry while add waterside, then being placed on voltage is in the energising field of 300 ~ 350V, slowly stirs 10 ~ 15min and makes carbon dust linear array, dries, then calcine the solid block that 30 ~ 40min becomes porous under being put in the hot conditions of 500 ~ 550 DEG C, crushing and screening is crossed 20 ~ 30 mesh sieves and is obtained granule;
(3) mixed yeast powder, Rhizobium Inoculant and other following remaining component do not related to, add the warm water of 30 ~ 35 DEG C of 40 ~ 50 times of its total weight parts, then stirs 20 ~ 25min and fully dissolve and melt;
(4) granule described in (2) is added in (3) gained solution, Ultrasonic Cleaners is put in unification, power 500 ~ 550W, effect 15 ~ 20min makes to be full of solution in micropore, do not make particle water content 20 ~ 25% higher than the hot blast of 80 DEG C by gas blower drum, again put in solution, secondary action is adsorbed, and obtains adsorption particle agent after completing;
(5) mixing sodium alginate, bagasse powder, brown sugar, bran powder, washing water of rice and chitosan hydrochloride, add the water of 1.5 ~ 2 times of its total weight parts, stir into thick paste, then add (4) described residue lysate and adsorption particle agent, by spray granulating post-drying.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN106818179A (en) * | 2017-02-09 | 2017-06-13 | 安徽菲扬农业科技有限公司 | A kind of potato planting method |
CN110724534A (en) * | 2019-10-11 | 2020-01-24 | 云南探花农业科技开发有限公司 | Powdery biological soil conditioner |
CN112322302A (en) * | 2020-10-29 | 2021-02-05 | 安徽智晟通讯科技有限公司 | Efficient soil remediation improver and preparation method thereof |
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CN102483970A (en) * | 2009-06-22 | 2012-05-30 | 孔达利恩股份有限公司 | Electrostatic Discharge Device And Method For Manufacturing The Same |
CN102718603A (en) * | 2012-07-11 | 2012-10-10 | 德州市元和农业科技开发有限责任公司 | Compound microbial fertilizer and preparation method thereof |
CN105254419A (en) * | 2015-10-16 | 2016-01-20 | 阜南县阜合种养农民专业合作联合社 | Liquid fermentation type fertilizer for pear trees and preparation method of fertilizer |
CN105272583A (en) * | 2015-10-21 | 2016-01-27 | 滁州市施集茶场 | Organic tea tree fertilizer with high water retention property and preparation method of organic tea tree fertilizer |
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2016
- 2016-02-23 CN CN201610097846.0A patent/CN105523860A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102483970A (en) * | 2009-06-22 | 2012-05-30 | 孔达利恩股份有限公司 | Electrostatic Discharge Device And Method For Manufacturing The Same |
CN102718603A (en) * | 2012-07-11 | 2012-10-10 | 德州市元和农业科技开发有限责任公司 | Compound microbial fertilizer and preparation method thereof |
CN105254419A (en) * | 2015-10-16 | 2016-01-20 | 阜南县阜合种养农民专业合作联合社 | Liquid fermentation type fertilizer for pear trees and preparation method of fertilizer |
CN105272583A (en) * | 2015-10-21 | 2016-01-27 | 滁州市施集茶场 | Organic tea tree fertilizer with high water retention property and preparation method of organic tea tree fertilizer |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106818179A (en) * | 2017-02-09 | 2017-06-13 | 安徽菲扬农业科技有限公司 | A kind of potato planting method |
CN110724534A (en) * | 2019-10-11 | 2020-01-24 | 云南探花农业科技开发有限公司 | Powdery biological soil conditioner |
CN112322302A (en) * | 2020-10-29 | 2021-02-05 | 安徽智晟通讯科技有限公司 | Efficient soil remediation improver and preparation method thereof |
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Application publication date: 20160427 |