CN105514491A - 一种全固态无机固体锂离子电解质的制备 - Google Patents
一种全固态无机固体锂离子电解质的制备 Download PDFInfo
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- CN105514491A CN105514491A CN201511001843.4A CN201511001843A CN105514491A CN 105514491 A CN105514491 A CN 105514491A CN 201511001843 A CN201511001843 A CN 201511001843A CN 105514491 A CN105514491 A CN 105514491A
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- 229910001416 lithium ion Inorganic materials 0.000 title claims abstract description 51
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 title claims abstract description 48
- 239000003792 electrolyte Substances 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- 229910003480 inorganic solid Inorganic materials 0.000 title abstract 3
- 239000007787 solid Substances 0.000 claims abstract description 51
- 238000005245 sintering Methods 0.000 claims abstract description 34
- 239000000843 powder Substances 0.000 claims abstract description 30
- 239000000203 mixture Substances 0.000 claims abstract description 22
- 229910012305 LiPON Inorganic materials 0.000 claims abstract description 20
- 239000007784 solid electrolyte Substances 0.000 claims abstract description 18
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims abstract description 9
- 239000004810 polytetrafluoroethylene Substances 0.000 claims abstract description 9
- 238000004544 sputter deposition Methods 0.000 claims abstract description 7
- -1 polytetrafluoroethylene Polymers 0.000 claims abstract description 5
- 238000002156 mixing Methods 0.000 claims abstract description 3
- 239000000463 material Substances 0.000 claims description 27
- 238000000034 method Methods 0.000 claims description 16
- 239000012299 nitrogen atmosphere Substances 0.000 claims description 15
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 14
- 229910020346 SiS 2 Inorganic materials 0.000 claims description 10
- 229910052757 nitrogen Inorganic materials 0.000 claims description 7
- 238000000627 alternating current impedance spectroscopy Methods 0.000 claims description 6
- 239000010416 ion conductor Substances 0.000 abstract description 13
- 230000008901 benefit Effects 0.000 abstract description 8
- 239000002033 PVDF binder Substances 0.000 abstract description 4
- 229920002981 polyvinylidene fluoride Polymers 0.000 abstract description 4
- 229910001216 Li2S Inorganic materials 0.000 abstract description 2
- 229910020343 SiS2 Inorganic materials 0.000 abstract description 2
- 239000000758 substrate Substances 0.000 abstract 2
- 238000003825 pressing Methods 0.000 abstract 1
- 230000014759 maintenance of location Effects 0.000 description 7
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 6
- 239000010410 layer Substances 0.000 description 6
- 239000000075 oxide glass Substances 0.000 description 6
- 239000005387 chalcogenide glass Substances 0.000 description 5
- 239000013078 crystal Substances 0.000 description 4
- 229910052744 lithium Inorganic materials 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 239000005864 Sulphur Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 238000012916 structural analysis Methods 0.000 description 2
- 229910004600 P2S5 Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
- H01M10/0562—Solid materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0068—Solid electrolytes inorganic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- Secondary Cells (AREA)
- Conductive Materials (AREA)
Abstract
Description
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201511001843.4A CN105514491B (zh) | 2015-12-29 | 2015-12-29 | 一种全固态无机固体锂离子电解质的制备 |
Applications Claiming Priority (1)
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CN201511001843.4A CN105514491B (zh) | 2015-12-29 | 2015-12-29 | 一种全固态无机固体锂离子电解质的制备 |
Publications (2)
Publication Number | Publication Date |
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CN105514491A true CN105514491A (zh) | 2016-04-20 |
CN105514491B CN105514491B (zh) | 2018-06-26 |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105826601A (zh) * | 2016-05-06 | 2016-08-03 | 上海交通大学 | Li4SiO4-Li3PO4-LiBO2固溶体陶瓷锂离子导体 |
CN105862012A (zh) * | 2016-05-27 | 2016-08-17 | 上海交通大学 | 一种固态电解质薄膜及其制备方法、离子器件 |
CN110088969A (zh) * | 2016-11-08 | 2019-08-02 | 菲斯科公司 | 包含机械柔性陶瓷电解质的全固态Li离子电池及其制造方法 |
CN110137565A (zh) * | 2019-05-20 | 2019-08-16 | 天目湖先进储能技术研究院有限公司 | 一种硫化物固态电解质的大规模制备方法 |
CN110265723A (zh) * | 2018-03-12 | 2019-09-20 | 深圳先进技术研究院 | 一种全固态电池的制备方法 |
CN111430787A (zh) * | 2020-03-03 | 2020-07-17 | 桂林电子科技大学 | 复合薄膜固体电解质及其制备方法与应用 |
CN112687946A (zh) * | 2020-12-23 | 2021-04-20 | 北京理工大学前沿技术研究院 | 一种真空镀膜技术制备功能无机固态电解质粉末的方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN2427120Y (zh) * | 1999-09-03 | 2001-04-25 | 林志立 | 门上柜 |
US6365300B1 (en) * | 1998-12-03 | 2002-04-02 | Sumitomo Electric Industries, Ltd. | Lithium secondary battery |
CN1925203A (zh) * | 2005-08-31 | 2007-03-07 | 株式会社小原 | 锂离子二次电池和用于其的固体电解质 |
CN102487154A (zh) * | 2010-12-06 | 2012-06-06 | 中国电子科技集团公司第十八研究所 | 一种多层电解质锂空气电池的制备方法 |
US20140120421A1 (en) * | 2011-07-08 | 2014-05-01 | Murata Manufacturing Co., Ltd. | All-solid battery and manufacturing method therefor |
-
2015
- 2015-12-29 CN CN201511001843.4A patent/CN105514491B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6365300B1 (en) * | 1998-12-03 | 2002-04-02 | Sumitomo Electric Industries, Ltd. | Lithium secondary battery |
CN2427120Y (zh) * | 1999-09-03 | 2001-04-25 | 林志立 | 门上柜 |
CN1925203A (zh) * | 2005-08-31 | 2007-03-07 | 株式会社小原 | 锂离子二次电池和用于其的固体电解质 |
CN102487154A (zh) * | 2010-12-06 | 2012-06-06 | 中国电子科技集团公司第十八研究所 | 一种多层电解质锂空气电池的制备方法 |
US20140120421A1 (en) * | 2011-07-08 | 2014-05-01 | Murata Manufacturing Co., Ltd. | All-solid battery and manufacturing method therefor |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105826601A (zh) * | 2016-05-06 | 2016-08-03 | 上海交通大学 | Li4SiO4-Li3PO4-LiBO2固溶体陶瓷锂离子导体 |
CN105826601B (zh) * | 2016-05-06 | 2018-05-01 | 上海交通大学 | Li4SiO4-Li3PO4-LiBO2固溶体陶瓷锂离子导体 |
CN105862012A (zh) * | 2016-05-27 | 2016-08-17 | 上海交通大学 | 一种固态电解质薄膜及其制备方法、离子器件 |
CN110088969A (zh) * | 2016-11-08 | 2019-08-02 | 菲斯科公司 | 包含机械柔性陶瓷电解质的全固态Li离子电池及其制造方法 |
CN110265723A (zh) * | 2018-03-12 | 2019-09-20 | 深圳先进技术研究院 | 一种全固态电池的制备方法 |
CN110265723B (zh) * | 2018-03-12 | 2021-01-15 | 深圳先进技术研究院 | 一种全固态电池的制备方法 |
CN110137565A (zh) * | 2019-05-20 | 2019-08-16 | 天目湖先进储能技术研究院有限公司 | 一种硫化物固态电解质的大规模制备方法 |
CN111430787A (zh) * | 2020-03-03 | 2020-07-17 | 桂林电子科技大学 | 复合薄膜固体电解质及其制备方法与应用 |
CN112687946A (zh) * | 2020-12-23 | 2021-04-20 | 北京理工大学前沿技术研究院 | 一种真空镀膜技术制备功能无机固态电解质粉末的方法 |
CN112687946B (zh) * | 2020-12-23 | 2022-01-07 | 北京理工大学前沿技术研究院 | 一种真空镀膜技术制备功能无机固态电解质粉末的方法 |
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Publication number | Publication date |
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CN105514491B (zh) | 2018-06-26 |
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GR01 | Patent grant | ||
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CP01 | Change in the name or title of a patent holder | ||
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Address after: 313000 No. 1800 Gangnan Road, Huzhou Economic and Technological Development Zone, Huzhou City, Zhejiang Province Patentee after: Huzhou Shanshan New Energy Technology Co.,Ltd. Address before: 313000 No. 1800 Gangnan Road, Huzhou Economic and Technological Development Zone, Huzhou City, Zhejiang Province Patentee before: HUZHOU CHUANGYA POWER BATTERY MATERIALS Co.,Ltd. |
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PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Preparation of an all solid inorganic solid lithium ion electrolyte Effective date of registration: 20210629 Granted publication date: 20180626 Pledgee: South Taihu New Area sub branch of Huzhou Wuxing Rural Commercial Bank Co.,Ltd. Pledgor: Huzhou Shanshan New Energy Technology Co.,Ltd. Registration number: Y2021990000561 |
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PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20231122 Granted publication date: 20180626 Pledgee: South Taihu New Area sub branch of Huzhou Wuxing Rural Commercial Bank Co.,Ltd. Pledgor: Huzhou Shanshan New Energy Technology Co.,Ltd. Registration number: Y2021990000561 |