CN105506980A - Preparation method and application of textile softening agent - Google Patents
Preparation method and application of textile softening agent Download PDFInfo
- Publication number
- CN105506980A CN105506980A CN201610070581.5A CN201610070581A CN105506980A CN 105506980 A CN105506980 A CN 105506980A CN 201610070581 A CN201610070581 A CN 201610070581A CN 105506980 A CN105506980 A CN 105506980A
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- Prior art keywords
- preparation
- softener
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- textiles
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/395—Isocyanates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention provides a preparation method of a textile softening agent. The preparation method comprises the following steps: increasing the temperature of fatty acid till fatty acid completely melts; pumping amines into the product, introducing nitrogen for protection and increasing the temperature for reaction; cooling the product, adding a quaternary amination agent for quaterisation reaction; adding a gloss enhancer into the product for reaction; adding a brightness regulator into the product for reaction; cooling the prepared product, and discharging. The invention further provides application of a cross-linked resin for textiles, wherein the cross-linked resin comprises the softening agent prepared by adopting any of the preparation methods, and during application, textiles are soaked with the softening agent with the concentration of 7.5% (o.w.f) at normal temperature for 15 min for softening treatment. With the adoption of the softening agent prepared by adopting the preparation method provided by the invention for softening treatment of textiles, not only are the softness, smoothness and the antistatic property of textiles ensured, but also the fabric luster is increased, color distortion is effectively reduced, textiles are made more brightly-colored and less prone to balling-up; besides, the softening agent can also be used cooperatively with cationic and non-ionic surface active agents.
Description
Technical field
The present invention relates to a kind of softener and application thereof, particularly relate to a kind of preparation method and application thereof of using softener of weaving.
Background technology
Along with the raising of people's living standard, clothes are required also from attractive in appearance, generous to soft, comfortable, beautiful, crease-resistant future development.While textile industry brings vigor to market, also bring unprecedented pressure to enterprise, and softener is a large class in textile finishing auxiliary agent, wide in variety, output is large, can meet the soft treatment of people to all kinds of textiles.
Existing softener, while lifting pliability, also can make a big impact to the color of fabric, therefore cannot while ensuring the quality of products, and the function of improving product, to reach the object reduced costs.
Summary of the invention
The object of the invention is to solve technical problem involved in background technology, providing a kind of preparation method and application thereof of using softener of weaving.
The invention provides a kind of weaving by the preparation method of softener, comprise the following steps:
(1) be first that the aliphatic acid of 57%-75% is warming up to 90 DEG C by mass percent, until all meltings;
(2) in product step (1) obtained, suction mass percent is the amine of 10%-15%, rushes nitrogen protection, heats up 160 DEG C-220 DEG C, reaction 1h-3h;
(3) product obtained for step (2) being down to 50 DEG C-120 DEG C, to add mass percent be the quaternary ammonium reaction that the quaternary amine agent of 3% – 7% carries out 1h-2h;
(4) add in product obtained for step (3) the gloss elevator that mass percent is 10%-15%, reaction 30min;
(5) add in product obtained for step (4) the bright conditioning agent that mass percent is 1.5-3%, reaction 30min;
(6) product that step (5) is obtained is cooled to 90 DEG C, discharging.
Preferably, the aliphatic acid in step (1) is stearic acid, palmitic acid, in tallow oil, hydrogenated oil and fat any one.
Preferably, the amine in step (2) is any one in diethanol amine, triethanolamine, octadecylamine, hydroxyethylethylene diamine, diethylenetriamine, triethylene tetramine.
Preferably, quaternary amine agent is in step (3): any one in dimethyl sulfate side's ester, dithyl sulfate, epoxychloropropane.
Preferably, in step (4), gloss elevator is any one in beeswax, paraffin, palm wax, mineral tallow, aliphatic isocyanates.
Preferably, in step (5), bright conditioning agent comprises dispersions of polyurethanes and thickener, and the mass ratio of dispersions of polyurethanes and thickener is 5:1.
Preferably, step (6) is down to 90 DEG C of Cheng Zhu, in blocks or rare to percentage discharging.
Preferably, the mass ratio of aliphatic acid, amine, quaternary amine agent, bright conditioning agent, gloss elevator is, 73:11:4.5:3:8.5.
Present invention also offers a kind of weaving with the application of crosslinked resin, comprise the softener prepared by upper arbitrary described preparation method, described softener 7.5% (o.w.f) used for textiles is soaked 15min under normal temperature, carries out sofening treatment.
In sum, the present invention has following advantage:
After the softener using preparation method of the present invention to obtain carries out sofening treatment to textiles, while, antistatic property soft, level and smooth at guarantee textiles, also add cloth cover gloss, effectively reduce look to become, make color vivider, simultaneously not easily balling-up, also can with CATION, non-ionic surface active agent with the use of.
Detailed description of the invention
Embodiment one
4088kg stearic acid is heated to 90 DEG C, makes its whole melting, starts stirring, drops into 616kg diethylenetriamine, and nitrogen protection is opened in insulation, is warming up to 200 DEG C, insulation reaction 2h.Be cooled to 60 DEG C and add 252kg dimethyl suflfate insulation reaction 2h.Be warming up to 100 DEG C, add 476kg aliphatic isocyanates, insulation reaction 30min, add 168kg light conditioning agent, insulation reaction 30min, discharging, through mechanical Cheng Zhu, packaging.
Embodiment 2
4088kg hydrogenation tallow oil is heated to 85 DEG C, makes its whole melting, starts stirring, drops into 616kg hydroxyethylethylene diamine, and nitrogen protection is opened in insulation, is warming up to 190 DEG C, insulation reaction 2h.Be cooled to 60 DEG C and add 252kg epoxychloropropane insulation reaction 2h.Be warming up to 100 DEG C, add 476kg palm wax, insulation reaction 30min, add 168kg light conditioning agent, insulation reaction 30min, discharging, through mechanical Cheng Zhu, packaging.
Embodiment 3
4088kg stearic acid is heated to 80 DEG C, makes its whole melting, starts stirring, drops into 616kg triethanolamine, and nitrogen protection is opened in insulation, is warming up to 215 DEG C, insulation reaction 2h.Be cooled to 100 DEG C and add 252kg epoxychloropropane insulation reaction 2h.Add 285.6kg palm wax, 109.4kg aliphatic isocyanates, insulation reaction 30min, add 168kg light conditioning agent, insulation reaction 30min, discharging, through mechanical Cheng Zhu, packaging.
Embodiment 4
4088kg hydrogenation tallow oil is heated to 87 DEG C, makes its whole melting, starts stirring, drops into 616kg diethylenetriamine, and nitrogen protection is opened in insulation, is warming up to 160 DEG C, insulation reaction 2h.Be cooled to 100 DEG C and add 252kg dimethyl suflfate insulation reaction 2h.Add 285.6kg aliphatic isocyanates, 190.4kg beeswax, insulation reaction 30min, add 168kg light conditioning agent, insulation reaction 30min, discharging, through mechanical Cheng Zhu, packaging.
Embodiment 5
4088kg hydrogenation tallow oil is heated to 90 DEG C, makes its whole melting, starts stirring, drops into 369.6kg diethylenetriamine, and nitrogen protection is opened in the insulation of 246.4kg hydroxyethylethylene diamine, is warming up to 220 DEG C, insulation reaction 2h.Be cooled to 60 DEG C and add 252kg dithyl sulfate insulation reaction 2h.Be warming up to 100 DEG C and add 476kg palm wax, insulation reaction 30min, add 168kg light conditioning agent, insulation reaction 30min, discharging, through mechanical Cheng Zhu, packaging.
The softener that application above-described embodiment is obtained, carries out the soft treatment of fabric.Processing procedure is as follows:
The softener 7.5% (o.w.f) prepared by above-described embodiment used for textiles soaks 15min under normal temperature, carries out sofening treatment, picks up subsequently and use tumble drying at 80 DEG C.
Textiles after above-mentioned process is detected simultaneously, detect data as shown in the table.
| Test index | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 |
| Bath raio | 1：10 | 1：10 | 1：10 | 1：10 | 1：10 |
| Material ratio | 1；5 | 1；5 | 1；5 | 1；5 | 1；5 |
| Pliability | In | Good | Generally | In | In |
| Smoothness | In | Good | In | In | Generally |
| Whiteness | Generally | In | Good | Generally | In |
| Gloss | In | Good | In | In | In |
| Look becomes | In | In | In | In | In |
More than illustrate it is only explanation of the invention, those of ordinary skill in the art's can completely is made to implement this programme, but be not limitation of the present invention, those skilled in the art can make to the present embodiment the amendment not having creative contribution as required after reading this description, and these are all not creative amendments.As long as but be all subject to the protection of Patent Law in right of the present invention.
Claims (9)
1. weave by a preparation method for softener, it is characterized in that, comprise the following steps:
(1) be first that the aliphatic acid of 57%-75% is warming up to 90 DEG C by mass percent, until all meltings;
(2) in product step (1) obtained, suction mass percent is the amine of 10%-15%, rushes nitrogen protection, heats up 160 DEG C-220 DEG C, reaction 1h-3h;
(3) product obtained for step (2) being down to 50 DEG C-120 DEG C, to add mass percent be the quaternary ammonium reaction that the quaternary amine agent of 3% – 7% carries out 1h-2h;
(4) add in product obtained for step (3) the gloss elevator that mass percent is 10%-15%, reaction 30min;
(5) add in product obtained for step (4) the bright conditioning agent that mass percent is 1.5-3%, reaction 30min;
(6) product that step (5) is obtained is cooled to 90 DEG C, discharging.
2. according to claim 1ly a kind ofly to weave by the preparation method of softener, it is characterized in that, the aliphatic acid in step (1) is stearic acid, palmitic acid, in tallow oil, hydrogenated oil and fat any one.
3. a kind of weaving according to claim 1 uses the preparation method of softener, it is characterized in that, the amine in step (2) is any one in diethanol amine, triethanolamine, octadecylamine, hydroxyethylethylene diamine, diethylenetriamine, triethylene tetramine.
4. according to claim 1ly a kind ofly to weave by the preparation method of softener, it is characterized in that, in step (3), quaternary amine agent is: any one in dimethyl sulfate side's ester, dithyl sulfate, epoxychloropropane.
5. a kind of weaving according to claim 1 uses the preparation method of softener, it is characterized in that, in step (4), gloss elevator is any one in beeswax, paraffin, palm wax, mineral tallow, aliphatic isocyanates.
6. a kind of weaving according to claim 1 uses the preparation method of softener, and it is characterized in that, in step (5), bright conditioning agent comprises dispersions of polyurethanes and thickener, and the mass ratio of dispersions of polyurethanes and thickener is 5:1.
7. according to claim 1ly a kind ofly to weave by the preparation method of softener, it is characterized in that, step (6) is down to 90 DEG C of Cheng Zhu, in blocks or rare to percentage discharging.
8. a kind of weaving according to claim 1 uses the preparation method of softener, and it is characterized in that, the mass ratio of aliphatic acid, amine, quaternary amine agent, bright conditioning agent, gloss elevator is, 73:11:4.5:3:8.5.
9. weave with an application for softener, it is characterized in that, comprise the softener prepared by the arbitrary described preparation method of claim 1-7, described softener 7.5% (o.w.f) used for textiles is soaked 15min under normal temperature, carries out sofening treatment.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610070581.5A CN105506980A (en) | 2016-02-01 | 2016-02-01 | Preparation method and application of textile softening agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610070581.5A CN105506980A (en) | 2016-02-01 | 2016-02-01 | Preparation method and application of textile softening agent |
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| Publication Number | Publication Date |
|---|---|
| CN105506980A true CN105506980A (en) | 2016-04-20 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610070581.5A Pending CN105506980A (en) | 2016-02-01 | 2016-02-01 | Preparation method and application of textile softening agent |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106676892A (en) * | 2016-12-30 | 2017-05-17 | 广东德美精细化工股份有限公司 | Preparation method of novel softener highly resistant to phenolic yellowing |
| CN107523997A (en) * | 2017-08-15 | 2017-12-29 | 广东湛丰精细化工有限公司 | The preparation method of environment-friendly type cation fatty acid softening agent |
| CN107675494A (en) * | 2017-09-13 | 2018-02-09 | 江苏新瑞贝科技股份有限公司 | A kind of natural softening agent and preparation method thereof |
| CN107780207A (en) * | 2017-09-13 | 2018-03-09 | 江苏新瑞贝科技股份有限公司 | A kind of fabric softener and preparation method thereof |
| CN108642879A (en) * | 2018-05-10 | 2018-10-12 | 浙江科峰新材料有限公司 | A kind of preparation process of softening agent film |
| CN109322150A (en) * | 2018-08-24 | 2019-02-12 | 宁波润禾高新材料科技股份有限公司 | A kind of low viscosity environment-friendly type sheet softening agent and preparation method thereof |
| CN109403039A (en) * | 2018-10-29 | 2019-03-01 | 东莞宝丽美化工有限公司 | A kind of preparation method of novel consistent lubricant essence |
| CN114086389A (en) * | 2021-12-31 | 2022-02-25 | 中山市天信助剂实业有限公司 | Softening agent soft essence for spinning and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1099824A (en) * | 1993-09-01 | 1995-03-08 | 王玉文 | Textiles softening agent |
| CN102877312A (en) * | 2012-09-05 | 2013-01-16 | 吴江涵辉纺织有限公司 | Fabric softener |
| CN103194893A (en) * | 2013-04-24 | 2013-07-10 | 广州市番禺区协运来化工用品有限公司 | Softener and preparation method thereof |
| CN105155260A (en) * | 2015-10-14 | 2015-12-16 | 吴江市七都镇庙港雅迪针织制衣厂 | Solid softening agent and preparation method thereof |
-
2016
- 2016-02-01 CN CN201610070581.5A patent/CN105506980A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1099824A (en) * | 1993-09-01 | 1995-03-08 | 王玉文 | Textiles softening agent |
| CN102877312A (en) * | 2012-09-05 | 2013-01-16 | 吴江涵辉纺织有限公司 | Fabric softener |
| CN103194893A (en) * | 2013-04-24 | 2013-07-10 | 广州市番禺区协运来化工用品有限公司 | Softener and preparation method thereof |
| CN105155260A (en) * | 2015-10-14 | 2015-12-16 | 吴江市七都镇庙港雅迪针织制衣厂 | Solid softening agent and preparation method thereof |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106676892A (en) * | 2016-12-30 | 2017-05-17 | 广东德美精细化工股份有限公司 | Preparation method of novel softener highly resistant to phenolic yellowing |
| CN107523997A (en) * | 2017-08-15 | 2017-12-29 | 广东湛丰精细化工有限公司 | The preparation method of environment-friendly type cation fatty acid softening agent |
| CN107675494A (en) * | 2017-09-13 | 2018-02-09 | 江苏新瑞贝科技股份有限公司 | A kind of natural softening agent and preparation method thereof |
| CN107780207A (en) * | 2017-09-13 | 2018-03-09 | 江苏新瑞贝科技股份有限公司 | A kind of fabric softener and preparation method thereof |
| CN108642879A (en) * | 2018-05-10 | 2018-10-12 | 浙江科峰新材料有限公司 | A kind of preparation process of softening agent film |
| CN109322150A (en) * | 2018-08-24 | 2019-02-12 | 宁波润禾高新材料科技股份有限公司 | A kind of low viscosity environment-friendly type sheet softening agent and preparation method thereof |
| CN109403039A (en) * | 2018-10-29 | 2019-03-01 | 东莞宝丽美化工有限公司 | A kind of preparation method of novel consistent lubricant essence |
| CN114086389A (en) * | 2021-12-31 | 2022-02-25 | 中山市天信助剂实业有限公司 | Softening agent soft essence for spinning and preparation method thereof |
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Application publication date: 20160420 |