CN105484027A - Novel formaldehyde-free crease-resist finishing agent and finishing process thereof - Google Patents
Novel formaldehyde-free crease-resist finishing agent and finishing process thereof Download PDFInfo
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- CN105484027A CN105484027A CN201610013205.2A CN201610013205A CN105484027A CN 105484027 A CN105484027 A CN 105484027A CN 201610013205 A CN201610013205 A CN 201610013205A CN 105484027 A CN105484027 A CN 105484027A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/41—Amides derived from unsaturated carboxylic acids, e.g. acrylamide
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
- D06M13/03—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons with unsaturated hydrocarbons, e.g. alkenes, or alkynes
- D06M13/07—Aromatic hydrocarbons
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/192—Polycarboxylic acids; Anhydrides, halides or salts thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
- D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
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- Textile Engineering (AREA)
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- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a novel formaldehyde-free crease-resist finishing agent. The novel formaldehyde-free crease-resist finishing agent is prepared from acryloyl succinic acid monomers, iso-octyl acrylate, styrene, methyl methacrylate, high-density polyethylene wax emulsion, dimethyl silicone oil, a non-phosphorus catalyst, N-beta-aminoethyl-gamma-aminopropyl methyl dimethoxy silane, etherified dihydroxyl ethylene urea, chitosan, polyethylene glycol and itaconic acid. The invention provides a formaldehyde-free phosphorus-free crease-resist finishing agent for a cotton fabric and a finishing method of the finishing agent. The problems that a traditional unsaturated carboxylic acid finishing agent is prone to yellowing, low in power, poor in polymerization effect and the like are solved, damage of phosphorus-containing wastewater to the environment can further be reduced, environment protection and industrial production are facilitated, and after crease-resist and durable pressing finishing is conducted, a treated fabric has good crease resistance, shape memorizing property and washing fastness.
Description
Technical field
The present invention relates to a kind of textile finshing agent, specifically, the present invention relates to a kind of formaldehyde-free crease-proofing finishing agent and finishing technique thereof.
Background technology
COTTON FABRIC has many excellent wearability, as having softness, comfortable, and ventilative, good hygroscopicity, the advantages such as fabulous wearability and low price make it enjoy people to favor.But COTTON FABRIC in dress and washing process easily wrinkling, flat appearance can not be kept, need often to press, therefore bring inconvenience to the life of people.For overcoming cotton clothes ridging defect in wearing process, need to carry out anti-crease finishing to COTTON FABRIC.
Many crease-resistant, the wrinkle resistant class finishing agent great majority of formaldehyde, particularly fabric containing very high concentration of the fabric finishing agent of existing textile industry are the textile auxiliary of main component based on formaldehyde.Along with perfect to textile formaldehyde limit standard of various countries, low formaldehyde and formaldehydeless finishing agent and method for sorting are the focuses of textiles anti-crease finishing research always.The main method of current control burst size of methanal is by N-methylol amide class finishing agent etherificate or modification, and another kind of method uses polybasic carboxylic acid and cellulose generation esterification exactly.In addition some changes be there has also been to the appraisal procedure of noniron finish fabric, no longer only focus on the elastic recovery angle of dry state, and the flat deflection of cloth cover after being washed is as the leading indicator of assessment, namely more focuses on hygrometric state wrinkle resistance and the washability of fabric.With the multi-carboxylic acid that BTCA and citric acid etc. are representative, and long-chain polycarboxylic acid system is the crease-shedding finishing agent of the most potential replacement N-methylol amide compounds.This type of finishing agent containing formaldehyde, can not reach good durable press grade.But also there is certain shortcoming in polybasic carboxylic acid finishing agent, as high in catalyst price, easy contaminated environment, fabric yellowing, fabric strength damage is serious, some SULPHUR DYES and reactive dyeing look also can be caused to become, carboxyl residual on the fabric after arrangement simultaneously, the upper dyestuff of anionic dye is reduced, and the fastness to wet rubbing of cationic dyeing difference etc.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of formaldehyde-free crease-proofing finishing agent and method for sorting thereof, a kind of formaldehydeless and without phosphorus cotton fabric crease-shedding finishing agent and method for sorting thereof are provided, solve the problems such as traditional unsaturated carboxylic acid finishing agent fabric yellowing, brute force is low, polymerization effect is not good, but also the harm of phosphorus-containing wastewater to environment can be reduced, be conducive to environmental protection and suitability for industrialized production, through wrinkle resistant and durable press finish, the fabric after process has good wrinkle resistance, formative memory and washing resistance.
Technical scheme of the present invention is:
A kind of novel formaldehyde-free crease proofing agent, comprises the component of following weight portion:
Acryloyl butanedioic acid monomer: 10 ~ 25 parts; Isooctyl acrylate monomer: 2 ~ 9 parts;
Styrene: 3 ~ 15 parts; Methyl methacrylate: 7 ~ 15 parts;
High density polyethylene waxes emulsion: 6 ~ 15 parts; Dimethicone: 2 ~ 12 parts;
Phosphate-free catalyst: 0.5 ~ 2.5 part; Etherificate dihydroxy ethylene urea: 8 ~ 25 parts;
N-β-aminoethyl-γ-aminopropyltriethoxy dimethoxysilane: 1 ~ 8 part;
Shitosan: 15 ~ 25 parts; Polyethylene glycol: 3 ~ 16 parts; Itaconic acid: 2 ~ 15 parts.
Preferably, described acryloyl butanedioic acid monomer is acryloyl aspartic acid monomer, acryloyl malic acid monomer, acryloyl tartaric acid monomer.
Preferably, described phosphate-free catalyst is the compound of nitrilotriacetic acid and tetrasodium salt of EDTA.
Preferably, the weight part ratio of described nitrilotriacetic acid and tetrasodium salt of EDTA is 1:1.5 ~ 1:3.
Preferably, the deacylated tRNA degree of described shitosan is 75 ~ 85%.
Preferably, described dimethyl-silicon oil viscosity is 200 ~ 1000cs.
Present invention also offers a kind of formaldehyde-free crease-proofing finishing agent for fabric free formaldehyde DP finish method, it is characterized in that, described employing is rolled and is cured finishing technique and refer to that normal temperature pads, two leachings two are rolled, pick-up 60 ~ 90%, dry 3 ~ 10min for 80 ~ 100 DEG C, 160 ~ 190 DEG C are cured 2 ~ 4min.
Preferably, described fabric is pure cotton fabric or the cotton content blending/MIXED FABRIC at more than 60wt%.
The present invention at least comprises following beneficial effect:
(1) formaldehyde-free crease-proofing finishing agent of the present invention is applicable to the wrinkle resistant and durable press finish of cotton and BLENDED FABRIC thereof, fabric after process has good wrinkle resistance, formative memory and washing resistance, fabric elasticity after process can improve 70% ~ 90%, strength retention 70% ~ 80%, flat deflection more than 3.5 grades; Crease and shrink resistance, outward appearance is well-pressed, and do not need after washing to press, line ball keeps for a long time again; Without free formaldehyde, do not fire not quick-fried, asepsis environment-protecting.
(2) finishing agent environmental protection of the present invention, is beneficial to suitability for industrialized production.
Detailed description of the invention
Describe embodiments of the present invention in detail below with reference to specific embodiment, to the present invention, how application technology means solve technical problem whereby, and the implementation procedure reaching technique effect can fully understand and implement according to this.
If do not specialize, the conventional means that the technological means adopted in embodiment is well known to those skilled in the art, the raw material adopted also be can business obtain.The various process do not described in detail and method are conventional methods as known in the art.
Embodiment 1
Formaldehyde-free crease-proofing finishing agent, comprises the component of following weight portion: acryloyl butanedioic acid monomer 10 parts; Isooctyl acrylate monomer 2 parts; Styrene 3 parts; Methyl methacrylate 7 parts; High density polyethylene waxes emulsion 6 parts; Dimethicone 2 parts; Phosphate-free catalyst (nitrilotriacetic acid and tetrasodium salt of EDTA weight part ratio are 1:1.5) 0.5 part; N-β-aminoethyl-γ-aminopropyltriethoxy dimethoxysilane 1 part; Etherificate dihydroxy ethylene urea 8 parts; Shitosan 15 parts; Polyethylene glycol 3 parts; Itaconic acid 2 parts.
Embodiment 2
Formaldehyde-free crease-proofing finishing agent, comprises the component of following weight portion: acryloyl butanedioic acid monomer 15 parts; Isooctyl acrylate monomer 6 parts; Styrene 10 parts; Methyl methacrylate 10 parts; High density polyethylene waxes emulsion 10 parts; Dimethicone 10 parts; Phosphate-free catalyst (nitrilotriacetic acid and tetrasodium salt of EDTA weight part ratio are 1:1.5) 1.5 parts; N-β-aminoethyl-γ-aminopropyltriethoxy dimethoxysilane 5 parts; Etherificate dihydroxy ethylene urea 15 parts; Shitosan 20 parts; Polyethylene glycol 10 parts; Itaconic acid 7 parts.
Embodiment 3
Formaldehyde-free crease-proofing finishing agent, comprises the component of following weight portion: acryloyl butanedioic acid monomer 25 parts; Isooctyl acrylate monomer 9 parts; Styrene 15 parts; Methyl methacrylate 15 parts; High density polyethylene waxes emulsion 15 parts; Dimethicone 12 parts; Phosphate-free catalyst (nitrilotriacetic acid and tetrasodium salt of EDTA weight part ratio are 1:3) 2.5 parts; N-β-aminoethyl-γ-aminopropyltriethoxy dimethoxysilane 8 parts; Etherificate dihydroxy ethylene urea 25 parts; Shitosan 25 parts; Polyethylene glycol 16 parts; Itaconic acid 15 parts.
Comparative example 1
Formaldehyde-free crease-proofing finishing agent, comprises the component of following weight portion: acryloyl butanedioic acid monomer 8 parts; Isooctyl acrylate monomer 1 part; Styrene 2 parts; Methyl methacrylate 5 parts; High density polyethylene waxes emulsion 5 parts; Dimethicone 1 part; Phosphate-free catalyst (nitrilotriacetic acid and tetrasodium salt of EDTA weight part ratio are 1:1.5) 0.1 part; N-β-aminoethyl-γ-aminopropyltriethoxy dimethoxysilane 0.5 part; Etherificate dihydroxy ethylene urea 7 parts; Shitosan 10 parts; Polyethylene glycol 2 parts; Itaconic acid 1 part.
Comparative example 2
Formaldehyde-free crease-proofing finishing agent, comprises the component of following weight portion: acryloyl butanedioic acid monomer 30 parts; Isooctyl acrylate monomer 10 parts; Styrene 16 parts; Methyl methacrylate 20 parts; High density polyethylene waxes emulsion 21 parts; Dimethicone 15 parts; Phosphate-free catalyst (nitrilotriacetic acid and tetrasodium salt of EDTA weight part ratio are 1:3) 3 parts; N-β-aminoethyl-γ-aminopropyltriethoxy dimethoxysilane 8 parts; Etherificate dihydroxy ethylene urea 30 parts; Shitosan 35 parts; Polyethylene glycol 18 parts; Itaconic acid 20 parts.
Comparative example 3
Formaldehyde-free crease-proofing finishing agent, comprises the component of following weight portion: acryloyl butanedioic acid monomer 10 parts; Isooctyl acrylate monomer 2 parts; Styrene 3 parts; Methyl methacrylate 7 parts; High density polyethylene waxes emulsion 6 parts; Dimethicone 2 parts; Phosphate-free catalyst (nitrilotriacetic acid) 0.5 part; N-β-aminoethyl-γ-aminopropyltriethoxy dimethoxysilane 1 part; Etherificate dihydroxy ethylene urea 8 parts; Shitosan 15 parts; Polyethylene glycol 3 parts; Itaconic acid 2 parts.
Comparative example 4
Formaldehyde-free crease-proofing finishing agent, comprises the component of following weight portion: acryloyl butanedioic acid monomer 10 parts; Isooctyl acrylate monomer 2 parts; Styrene 3 parts; Methyl methacrylate 7 parts; High density polyethylene waxes emulsion 6 parts; Dimethicone 2 parts; Phosphate-free catalyst (tetrasodium salt of EDTA) 0.5 part; N-β-aminoethyl-γ-aminopropyltriethoxy dimethoxysilane 1 part; Etherificate dihydroxy ethylene urea 8 parts; Shitosan 15 parts; Polyethylene glycol 3 parts; Itaconic acid 2 parts.
Housekeeping operation: be immersed in by fabric and arrange in bath 10 minutes, two to roll through two leachings, in 80 DEG C of preliminary dryings 5 minutes, 3 minutes are cured in 150 DEG C, with 60 DEG C of warm water cleanings, 80 DEG C of oven dry, be placed in drier and be cooled to normal temperature, measure according to AATCC66-2003 and arrange front and back COTTON FABRIC creasy recovery angle.Test result is in table 1.
Claims (8)
1. a novel formaldehyde-free crease proofing agent, is characterized in that, comprises the component of following weight portion:
Acryloyl butanedioic acid monomer: 10 ~ 25 parts; Isooctyl acrylate monomer: 2 ~ 9 parts;
Styrene: 3 ~ 15 parts; Methyl methacrylate: 7 ~ 15 parts;
High density polyethylene waxes emulsion: 6 ~ 15 parts; Dimethicone: 2 ~ 12 parts;
Phosphate-free catalyst: 0.5 ~ 2.5 part; Etherificate dihydroxy ethylene urea: 8 ~ 25 parts;
N-β-aminoethyl-γ-aminopropyltriethoxy dimethoxysilane: 1 ~ 8 part;
Shitosan: 15 ~ 25 parts; Polyethylene glycol: 3 ~ 16 parts; Itaconic acid: 2 ~ 15 parts.
2. formaldehyde-free crease-proofing finishing agent as claimed in claim 1, it is characterized in that, described acryloyl butanedioic acid monomer is acryloyl aspartic acid monomer, acryloyl malic acid monomer, acryloyl tartaric acid monomer.
3. formaldehyde-free crease-proofing finishing agent as claimed in claim 1, it is characterized in that, described phosphate-free catalyst is the compound of nitrilotriacetic acid and tetrasodium salt of EDTA.
4. formaldehyde-free crease-proofing finishing agent as claimed in claim 3, it is characterized in that, the weight part ratio of described nitrilotriacetic acid and tetrasodium salt of EDTA is 1:1.5 ~ 1:3.
5. formaldehyde-free crease-proofing finishing agent as claimed in claim 1, it is characterized in that, the deacylated tRNA degree of described shitosan is 75 ~ 85%.
6. formaldehyde-free crease-proofing finishing agent as claimed in claim 1, it is characterized in that, described dimethyl-silicon oil viscosity is 200 ~ 1000cs.
7. a formaldehyde-free crease-proofing finishing agent as claimed in claim 1 is used for fabric free formaldehyde DP finish technique, it is characterized in that, described employing is rolled and is cured finishing technique and refer to that normal temperature pads, two leachings two are rolled, pick-up 60 ~ 90%, dry 3 ~ 10min for 80 ~ 100 DEG C, 160 ~ 190 DEG C are cured 2 ~ 4min.
8. formaldehyde-free crease-proofing finishing agent as claimed in claim 7 is used for fabric free formaldehyde DP finish method, it is characterized in that, described fabric is pure cotton fabric or the cotton content blending/MIXED FABRIC at more than 60wt%.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610013205.2A CN105484027A (en) | 2016-01-08 | 2016-01-08 | Novel formaldehyde-free crease-resist finishing agent and finishing process thereof |
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| CN201610013205.2A CN105484027A (en) | 2016-01-08 | 2016-01-08 | Novel formaldehyde-free crease-resist finishing agent and finishing process thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105734965A (en) * | 2016-05-06 | 2016-07-06 | 盐城工学院 | Anti-crease finishing agent of cotton fabric and preparation method of anti-crease finishing agent as well as finishing process of cotton fabric |
| CN108823961A (en) * | 2018-05-21 | 2018-11-16 | 合肥云都棉花有限公司 | A kind of modified cotton fiber and its non-ironing cloth of preparation |
| CN110359275A (en) * | 2019-08-05 | 2019-10-22 | 安徽恒益纺织科技有限公司 | A kind of anti-crease finishing method of cotton matter product clothes |
| CN111287001A (en) * | 2020-03-10 | 2020-06-16 | 苏州经贸职业技术学院 | Color-fixing crease-resistant finishing agent, preparation method and application thereof |
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| CN105734965A (en) * | 2016-05-06 | 2016-07-06 | 盐城工学院 | Anti-crease finishing agent of cotton fabric and preparation method of anti-crease finishing agent as well as finishing process of cotton fabric |
| CN105734965B (en) * | 2016-05-06 | 2018-03-02 | 盐城工学院 | A kind of crease proofing agent of bafta, its preparation method and finishing technique |
| CN108823961A (en) * | 2018-05-21 | 2018-11-16 | 合肥云都棉花有限公司 | A kind of modified cotton fiber and its non-ironing cloth of preparation |
| CN110359275A (en) * | 2019-08-05 | 2019-10-22 | 安徽恒益纺织科技有限公司 | A kind of anti-crease finishing method of cotton matter product clothes |
| CN110359275B (en) * | 2019-08-05 | 2021-10-22 | 安徽恒益纺织科技有限公司 | Crease-resistant finishing method for all-cotton clothes |
| CN111287001A (en) * | 2020-03-10 | 2020-06-16 | 苏州经贸职业技术学院 | Color-fixing crease-resistant finishing agent, preparation method and application thereof |
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Application publication date: 20160413 |