CN108193502A - A kind of formaldehydeless ironing and anti-crease finishing technique of real silk fabric - Google Patents

A kind of formaldehydeless ironing and anti-crease finishing technique of real silk fabric Download PDF

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Publication number
CN108193502A
CN108193502A CN201711418671.XA CN201711418671A CN108193502A CN 108193502 A CN108193502 A CN 108193502A CN 201711418671 A CN201711418671 A CN 201711418671A CN 108193502 A CN108193502 A CN 108193502A
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ironing
silk fabric
real silk
crease
formaldehydeless
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CN108193502B (en
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杨坡
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Shanghai Fluorine Chemical Products Ltd By Share Ltd
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Shanghai Fluorine Chemical Products Ltd By Share Ltd
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/207Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/647Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing polyether sequences
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/10Animal fibres
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/20Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Treatment Of Fiber Materials (AREA)

Abstract

The invention discloses a kind of formaldehydeless ironing and anti-crease finishing techniques of real silk fabric, include the following steps:Real silk fabric is subjected to shrunk finish, then make polyurethane organosilicon ironing and anti-crease dressing liquid evenly into real silk fabric by padding process, moisture removal is gone by baking operation, the real silk fabric after drying obtains the real silk fabric of formaldehydeless ironing and anti-crease by high temperature baking.The formaldehydeless ironing and anti-crease finishing technique of real silk fabric of the present invention not only realizes the noniron finish of real silk fabric, but also can also assign the good resilience of real silk fabric, washability and plentiful feel;Simultaneously because polyurethane organosilicon ironing and anti-crease dressing liquid is free of formaldehyde, the safety of real silk fabric after arranging is ensure that from source.

Description

A kind of formaldehydeless ironing and anti-crease finishing technique of real silk fabric
Technical field
The present invention relates to special textile finishing technique field, specifically, it is formaldehydeless non-ironing to be related to a kind of real silk fabric Anti-crease finishing technique.
Background technology
The wash and wear finisher of natural fabric still being most widely used with N- methylol amide resinoids so far, wherein Most representative is 2D resins, but its there are release formaldehyde, finish fabric strength decline, feel is poor the shortcomings of.To meet Ultra-low formaldehyde wash and wear finisher is developed in environmental requirement, improves safety to a certain extent, but fabric feeling and strength Decline is not improved, does not also solve the problems, such as Form aldehyde release fundamentally.In recent years, start to research and develop both at home and abroad formaldehydeless non-ironing whole Agent is managed, but industrial applications are less, finishing technique is complicated, and there are higher price, non-ironing effect not as good as the shortcomings of 2D resins.Very Silk fabrics easy yellowing when high temperature bakes, the non-ironing finishing technique of real silk fabric and cotton, fiber crops finishing technique difference, roasting Drying temperature cannot be too high, so many need hot crosslinked wash and wear finisher that cannot apply.Therefore, silk printing and dyeing enterprise is always In the wash and wear finisher for finding environmental protection, crosslinked at low temperature.
Invention content
The purpose of the present invention is to provide a kind of formaldehydeless ironing and anti-crease finishing technique of real silk fabric, which not only realizes The noniron finish of real silk fabric, and the good resilience of real silk fabric, washability and plentiful feel can also be assigned;While by In polyurethane-organosilicon ironing and anti-crease dressing liquid without formaldehyde, the safety of real silk fabric after arranging is ensure that from source.
To achieve these goals, the technical solution adopted by the present invention is as follows:
The present invention provides a kind of formaldehydeless ironing and anti-crease finishing techniques of real silk fabric, include the following steps:
Real silk fabric is subjected to shrunk finish, then makes polyurethane-organosilicon ironing and anti-crease dressing liquid by padding process Evenly into real silk fabric, moisture removal is gone by baking operation, the real silk fabric after drying is obtained by high temperature baking Obtain the real silk fabric of formaldehydeless ironing and anti-crease.
The pre- washing shrinkage of the shrunk finish be 1-5%, preferably 3%.
The polyurethane-organosilicon ironing and anti-crease dressing liquid is made of the component of following mass percentage:
Preferably, the polyurethane-organosilicon ironing and anti-crease dressing liquid is made of the component of following mass percentage:
Preferably, the polyurethane-organosilicon ironing and anti-crease dressing liquid is made of the component of following mass percentage:
Preferably, the polyurethane-organosilicon ironing and anti-crease dressing liquid is made of the component of following mass percentage:
The process of padding is rolled for two leachings two, and pick-up is 50%~100%, preferably 70%.
The baking operation is dried for open width, and drying temperature is 80 DEG C~100 DEG C, preferably 80 DEG C.
The baking temperature of the high temperature baking is 120 DEG C~160 DEG C, preferably 140 DEG C;Bake the time for 45s~ 2min, preferably 1min.
Due to the adoption of the above technical scheme, the present invention has the following advantages and beneficial effect:
The formaldehydeless ironing and anti-crease finishing technique of real silk fabric of the present invention, since polyurethane-organosilicon ironing and anti-crease arranges Liquid energy crosslinked at low temperature ensure that the complete crosslinking of low temperature;Polyurethane-organosilicon ironing and anti-crease dressing liquid is environmentally protective, technique letter It is single reliable, meet dye-works's energy-saving and emission-reduction requirement.
The formaldehydeless ironing and anti-crease finishing technique of real silk fabric of the present invention not only realizes the noniron finish of real silk fabric, but also The good resilience of real silk fabric, washability and plentiful feel can also be assigned;Simultaneously because polyurethane-organosilicon ironing and anti-crease Dressing liquid is free of formaldehyde, and the safety of real silk fabric after arranging is ensure that from source.
Specific embodiment
In order to illustrate more clearly of the present invention, with reference to preferred embodiment, the present invention is described further.Ability Field technique personnel should be appreciated that following specifically described content is illustrative and be not restrictive, this should not be limited with this The protection domain of invention.
Real silk fabric used in the embodiment of the present invention is purchased from all things profit silk digit printing Co., Ltd, and the trade mark is 11209 electricity Power is spun.
Thermal-reactive polyurethane finishing agent used in the embodiment of the present invention is purchased from Shanghai Fu Ju chemical products limited company, Product grade is 6722.
Nonionic polyoxyalkylene modified organic silicon finishing agent used in the embodiment of the present invention has purchased from the poly- chemical products share of Shanghai fluorine Limit company, product grade SS6170.
Nano-polyurethane finishing agent used in the embodiment of the present invention receives chemistry purchased from opening up, and product grade is Nano PU.
Embodiment 1
A kind of formaldehydeless ironing and anti-crease finishing technique of real silk fabric, includes the following steps:
1) 11209 habotai of real silk fabric is placed on preshrinking machine and carries out shrunk finish, the pre- washing shrinkage of shrunk finish is 3%.
2) polyurethane-organosilicon ironing and anti-crease dressing liquid is made of the component of following mass percent:
The configuration of polyurethane-organosilicon ironing and anti-crease dressing liquid:Above-mentioned several reagents are uniformly mixed by the proportioning and are obtained Obtain the polyurethane-organosilicon ironing and anti-crease dressing liquid.
3) real silk fabric makes polyurethane-organosilicon ironing and anti-crease dressing liquid evenly into real silk fabric by padding process It is interior, it pads process and is rolled for two leachings two, pick-up 70%;
4) real silk fabric after arranging removes remaining moisture on real silk fabric by baking operation;Baking operation is open width Drying, drying temperature are 80 DEG C;
5) real silk fabric after drying obtains the real silk fabric of formaldehydeless ironing and anti-crease, high temperature roasting by high temperature baking The baking temperature for drying process is 140 DEG C, bakes the time as 1min.
Embodiment 2
A kind of formaldehydeless ironing and anti-crease finishing technique of real silk fabric, includes the following steps:
1) 11209 habotai of real silk fabric is placed on preshrinking machine and carries out shrunk finish, the pre- washing shrinkage of shrunk finish is 3%.
2) polyurethane-organosilicon ironing and anti-crease dressing liquid is made of the component of following mass percent:
The configuration of polyurethane-organosilicon ironing and anti-crease dressing liquid:Above-mentioned several reagents are uniformly mixed by the proportioning and are obtained Obtain the polyurethane-organosilicon ironing and anti-crease dressing liquid.
3) real silk fabric makes polyurethane-organosilicon ironing and anti-crease dressing liquid evenly into real silk fabric by padding process It is interior, it pads process and is rolled for two leachings two, pick-up 70%;
4) real silk fabric after arranging removes remaining moisture on real silk fabric by baking operation;Baking operation is open width Drying, drying temperature are 80 DEG C;
5) real silk fabric after drying obtains the real silk fabric of formaldehydeless ironing and anti-crease, high temperature roasting by high temperature baking The baking temperature for drying process is 140 DEG C, bakes the time as 1min.
Embodiment 3
A kind of formaldehydeless ironing and anti-crease finishing technique of real silk fabric, includes the following steps:
1) 11209 habotai of real silk fabric is placed on preshrinking machine and carries out shrunk finish, the pre- washing shrinkage of shrunk finish is 3%.
2) polyurethane-organosilicon ironing and anti-crease dressing liquid is made of the component of following mass percent:
The configuration of polyurethane-organosilicon ironing and anti-crease dressing liquid:Above-mentioned several reagents are uniformly mixed by the proportioning and are obtained Obtain the polyurethane-organosilicon ironing and anti-crease dressing liquid.
3) real silk fabric makes polyurethane-organosilicon ironing and anti-crease dressing liquid evenly into real silk fabric by padding process It is interior, it pads process and is rolled for two leachings two, pick-up 70%;
4) real silk fabric after arranging removes remaining moisture on real silk fabric by baking operation;Baking operation is open width Drying, drying temperature are 80 DEG C;
5) real silk fabric after drying obtains the real silk fabric of formaldehydeless ironing and anti-crease, high temperature roasting by high temperature baking The baking temperature for drying process is 140 DEG C, bakes the time as 1min.
Embodiment 4
A kind of formaldehydeless ironing and anti-crease finishing technique of real silk fabric, includes the following steps:
1) 11209 habotai of real silk fabric is placed on preshrinking machine and carries out shrunk finish, the pre- washing shrinkage of shrunk finish is 5%.
2) polyurethane-organosilicon ironing and anti-crease dressing liquid is made of the component of following mass percent:
The configuration of polyurethane-organosilicon ironing and anti-crease dressing liquid:Above-mentioned several reagents are uniformly mixed by the proportioning and are obtained Obtain the polyurethane-organosilicon ironing and anti-crease dressing liquid.
3) real silk fabric makes polyurethane-organosilicon ironing and anti-crease dressing liquid evenly into real silk fabric by padding process It is interior, it pads process and is rolled for two leachings two, pick-up 80%;
4) real silk fabric after arranging removes remaining moisture on real silk fabric by baking operation;Baking operation is open width Drying, drying temperature are 100 DEG C;
5) real silk fabric after drying obtains the real silk fabric of formaldehydeless ironing and anti-crease, high temperature roasting by high temperature baking The baking temperature for drying process is 160 DEG C, bakes the time as 45s.
Embodiment 5
A kind of formaldehydeless ironing and anti-crease finishing technique of real silk fabric, includes the following steps:
1) 11209 habotai of real silk fabric is placed on preshrinking machine and carries out shrunk finish, the pre- washing shrinkage of shrunk finish is 1.5%.
2) polyurethane-organosilicon ironing and anti-crease dressing liquid is made of the component of following mass percent:
The configuration of polyurethane-organosilicon ironing and anti-crease dressing liquid:Above-mentioned several reagents are uniformly mixed by the proportioning and are obtained Obtain the polyurethane-organosilicon ironing and anti-crease dressing liquid.
3) real silk fabric makes polyurethane-organosilicon ironing and anti-crease dressing liquid evenly into real silk fabric by padding process It is interior, it pads process and is rolled for two leachings two, pick-up 90%;
4) real silk fabric after arranging removes remaining moisture on real silk fabric by baking operation;Baking operation is open width Drying, drying temperature are 80 DEG C;
5) real silk fabric after drying obtains the real silk fabric of formaldehydeless ironing and anti-crease, high temperature roasting by high temperature baking The baking temperature for drying process is 120 DEG C, bakes the time as 2min.
Comparative example 1
Existing ironing and anti-crease finishing technique includes the following steps:
1) ironing and anti-crease dressing liquid is made of the component of following mass percent:
2D resin finishing agents 10%,
Strong protecting agent 3%,
Silicone softening agent agent 3%,
Polyethylene kind softening agent 2%,
Catalyst MgCl22%,
Water surplus.
2) it pads process to roll for two leachings two, pick-up 70%;
3) baking operation is dried for open width, and drying temperature is 80 DEG C;
4) baking temperature of high temperature baking is 140 DEG C, bakes the time as 1min.
Following performance test is carried out to the real silk fabric of the formaldehydeless ironing and anti-crease made by above-described embodiment 1~5:
(1) DP grades (apparent flatness)
According to AATCC 124-2001《The appearance of fabric after multiple family's laundering》It measures.
(2) burst size of methanal
According to GB/T 2912-1998《The measure part 1 of textile formaldehyde:The formaldehyde of free hydrolysis》Test.
The performance test results that the silk of the formaldehydeless ironing and anti-crease of the present invention is knitted are as shown in table 1:
Table 1
As it can be seen from table 1 the formaldehydeless ironing and anti-crease finishing technique of real silk fabric of the present invention not only realizes real silk fabric Noniron finish, and the good resilience of real silk fabric, washability and plentiful feel can also be assigned;Simultaneously because poly- ammonia Ester-organosilicon ironing and anti-crease dressing liquid is free of formaldehyde, and formaldehydeless release ensure that the safety of real silk fabric after arranging from source Property.Since polyurethane-organosilicon ironing and anti-crease arranges liquid energy crosslinked at low temperature, the complete crosslinking of low temperature ensure that;Polyurethane-organic Silicon ironing and anti-crease dressing liquid is environmentally protective, simple and reliable process, meets dye-works's energy-saving and emission-reduction requirement.
Basic principle, main feature and the advantages of the present invention of the present invention has been shown and described above.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this The principle of invention, various changes and improvements may be made to the invention without departing from the spirit and scope of the present invention, these changes Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its Equivalent defines.

Claims (10)

1. a kind of formaldehydeless ironing and anti-crease finishing technique of real silk fabric, it is characterised in that:Include the following steps:
Real silk fabric is subjected to shrunk finish, then makes polyurethane-organosilicon ironing and anti-crease dressing liquid uniform by padding process Ground enters in real silk fabric, and moisture removal is removed by baking operation, and the real silk fabric after drying obtains nothing by high temperature baking The real silk fabric of formaldehyde ironing and anti-crease.
2. the formaldehydeless ironing and anti-crease finishing technique of real silk fabric according to claim 1, it is characterised in that:The preshrunk is whole The pre- washing shrinkage of reason is 1-5%.
3. the formaldehydeless ironing and anti-crease finishing technique of real silk fabric according to claim 2, it is characterised in that:The preshrunk is whole The pre- washing shrinkage of reason is 3%.
4. the formaldehydeless ironing and anti-crease finishing technique of real silk fabric according to claim 1, it is characterised in that:The poly- ammonia Ester-organosilicon ironing and anti-crease dressing liquid is made of the component of following mass percentage:
5. the formaldehydeless ironing and anti-crease finishing technique of real silk fabric according to claim 4, it is characterised in that:The poly- ammonia Ester-organosilicon ironing and anti-crease dressing liquid is made of the component of following mass percentage:
6. the formaldehydeless ironing and anti-crease finishing technique of real silk fabric according to claim 4, it is characterised in that:The poly- ammonia Ester-organosilicon ironing and anti-crease dressing liquid is made of the component of following mass percentage:
7. the formaldehydeless ironing and anti-crease finishing technique of real silk fabric according to claim 4, it is characterised in that:The poly- ammonia Ester-organosilicon ironing and anti-crease dressing liquid is made of the component of following mass percentage:
8. the formaldehydeless ironing and anti-crease finishing technique of real silk fabric according to claim 1, it is characterised in that:It is described to pad work Sequence is rolled for two leachings two, and pick-up is 50%~100%.
9. the formaldehydeless ironing and anti-crease finishing technique of real silk fabric according to claim 1, it is characterised in that:The drying work Sequence is dried for open width, and drying temperature is 80 DEG C~100 DEG C.
10. the formaldehydeless ironing and anti-crease finishing technique of real silk fabric according to claim 1, it is characterised in that:The high temperature The baking temperature for baking process is 120 DEG C~160 DEG C, bakes the time as 45s~2min.
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CN111395015A (en) * 2020-04-15 2020-07-10 淄博大染坊丝绸集团有限公司 Dyeing and finishing process of real silk fabric for summer wear
CN112048913A (en) * 2020-09-02 2020-12-08 浙江丝绸科技有限公司 Durable anti-ultraviolet finishing process for light and thin real silk or silk-containing fabric
CN112981964A (en) * 2021-02-27 2021-06-18 杭州锦锋丝绸有限公司 Anti-wrinkle fabric processing technology and anti-wrinkle fabric
CN114351455A (en) * 2021-11-30 2022-04-15 江苏华佳丝绸股份有限公司 Preparation method of anti-wrinkle real silk fabric

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Publication number Priority date Publication date Assignee Title
CN111395015A (en) * 2020-04-15 2020-07-10 淄博大染坊丝绸集团有限公司 Dyeing and finishing process of real silk fabric for summer wear
CN112048913A (en) * 2020-09-02 2020-12-08 浙江丝绸科技有限公司 Durable anti-ultraviolet finishing process for light and thin real silk or silk-containing fabric
CN112048913B (en) * 2020-09-02 2023-02-10 浙江丝绸科技有限公司 Durable uvioresistant finishing process for light and thin real silk or silk-containing fabric
CN112981964A (en) * 2021-02-27 2021-06-18 杭州锦锋丝绸有限公司 Anti-wrinkle fabric processing technology and anti-wrinkle fabric
CN112981964B (en) * 2021-02-27 2022-12-13 杭州三宏家居科技有限公司 Anti-wrinkle fabric processing technology and anti-wrinkle fabric
CN114351455A (en) * 2021-11-30 2022-04-15 江苏华佳丝绸股份有限公司 Preparation method of anti-wrinkle real silk fabric

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Denomination of invention: A Formaldehyde Free, Non ironing, Anti wrinkle Finishing Process for Silk Fabrics

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